Method of removing iron contaminants from liquid streams during the manufacture and/or purification of aromatic acids
    6.
    发明授权
    Method of removing iron contaminants from liquid streams during the manufacture and/or purification of aromatic acids 有权
    在制造和/或纯化芳香酸期间从液体流中除去铁污染物的方法

    公开(公告)号:US07135596B2

    公开(公告)日:2006-11-14

    申请号:US10420092

    申请日:2003-04-22

    IPC分类号: C07C51/255 C07C51/42

    摘要: This invention relates to control or removal of amounts of dissolved iron that may be present in liquid process streams in the manufacture of aromatic acids. The present invention further relates to the control or removal of dissolved iron contaminants present in liquid streams during the manufacture of a crude aromatic acid. The present invention also further relates to the control or removal of dissolved iron contaminants present in liquid streams during the purification of a crude aromatic acid. The present invention also further relates to controlling of decreasing the formation of iron oxides on the surfaces of equipment used during the manufacture of crude aromatic acid and/or purification of crude aromatic acid.

    摘要翻译: 本发明涉及在芳香族酸的制造中可能存在于液体工艺流中的溶解铁的量的控制或去除。 本发明还涉及在制备粗芳香酸期间控制或除去存在于液体流中的溶解的铁污染物。 本发明还涉及在粗芳族酸的纯化期间控制或除去存在于液体流中的溶解的铁污染物。 本发明还涉及减少在制备粗芳香酸期间使用的设备表面上的铁氧化物的形成和/或粗芳香酸的纯化的控制。

    Process for preparing linear monofunctional and telechelic difunctional
polymers and compositions obtained thereby
    7.
    发明授权
    Process for preparing linear monofunctional and telechelic difunctional polymers and compositions obtained thereby 失效
    制备线型单官能和遥爪双官能聚合物的方法及由此得到的组合物

    公开(公告)号:US5512635A

    公开(公告)日:1996-04-30

    申请号:US167668

    申请日:1993-12-15

    摘要: This invention relates to a process for preparation of non-crosslinked linear monofunctional and telechelic difunctional unsaturated polymers wherein the functional groups are reactive terminal groups other than vinyl groups. The average functionality number of the monofunctional unsaturated polymers is at least 0.7, as determined by nuclear magnetic resonance spectroscopy (NMR). The average functionality number of the telechelic difunctional polymers is at least 1.7, as determined by NMR. Monofunctional olefins and difunctional olefins are reacted with cyclic olefins or unsaturated polymers to prepare difunctional polymers. The process is substantially free of side reactions comprising double bond migration and cyclization. The unsaturated functional polymers can be reacted in condensation, addition and transesterification reactions to prepare polyesters, graft copolymers, polyurethanes, polyureas, polyamides, thermoplastic and thermosetting resins, block copolymers, ion exchange resins, adhesives, films, fibers, foams and flocculants.

    摘要翻译: 本发明涉及一种制备非交联线性单官能和遥爪双官能不饱和聚合物的方法,其中官能团是乙烯基以外的反应性末端基团。 通过核磁共振光谱(NMR)测定,单官能不饱和聚合物的平均官能度至少为0.7。 通过NMR确定的遥爪双官能聚合物的平均官能度至少为1.7。 单官能烯烃和双官能烯烃与环烯烃或不饱和聚合物反应以制备双官能聚合物。 该方法基本上不含包含双键迁移和环化的副反应。 不饱和官能聚合物可以在缩合,加成和酯交换反应中进行反应,以制备聚酯,接枝共聚物,聚氨酯,聚脲,聚酰胺,热塑性和热固性树脂,嵌段共聚物,离子交换树脂,粘合剂,薄膜,纤维,泡沫和絮凝剂。

    Ruthenium-containing catalyst composition for olefin metathesis
    8.
    发明授权
    Ruthenium-containing catalyst composition for olefin metathesis 失效
    用于烯烃复分解的含钌催化剂组合物

    公开(公告)号:US6156692A

    公开(公告)日:2000-12-05

    申请号:US842251

    申请日:1997-04-24

    摘要: A ruthenium-containing metathesis catalyst system which contains a ruthenium compound (A), a phosphorus compound (B), and a compound (C) containing a carbon-to-carbon triple bond. The mole ratio of compounds A:B:C is typically in the range of about 1.0:0.01-100:0.01-100. The ruthenium compound (A) is a Ru(II), Ru(III), or Ru(IV) compound containing an anionic ligand (X) and optionally an arene ligand and optionally a phosphorus compound ligand. The phosphorus compound (B) is optional if the ruthenium compound (A) contains a phosphorus-containing ligand. The catalyst system is employed in processes to metathesize olefins, including ring-opening metathesis polymerization of cyclic olefins, metathesis of acyclic olefins, acyclic diene metathesis oligomerization or polymerization, cross-metathesis of cyclic and acyclic olefins, ring-closing metathesis, metathesis depolymerization of unsaturated polymers, and metathesis of functionalized olefins.

    摘要翻译: 含有钌化合物(A),磷化合物(B)和含有碳 - 碳三键的化合物(C)的含钌复分解催化剂体系。 化合物A:B:C的摩尔比通常在约1.0:0.01-100:0.01-100的范围内。 钌化合物(A)是含有阴离子配体(X)的Ru(II),Ru(III)或Ru(IV)化合物以及任选的芳族配体和任选的磷化合物配体。 如果钌化合物(A)含有含磷配体,磷化合物(B)是任选的。 催化剂体系用于将烯烃分离的方法,包括环烯烃的开环易位聚合,无环烯烃的复分解,无环二烯复分解低聚或聚合,环状和非环烯烃的交叉复分解,闭环复分解,复分解解聚 不饱和聚合物和官能化烯烃的复分解。