Basic chromium aluminum sulfates and their preparation
    1.
    发明授权
    Basic chromium aluminum sulfates and their preparation 失效
    碱性硫酸铝及其制备方法

    公开(公告)号:US4629616A

    公开(公告)日:1986-12-16

    申请号:US589769

    申请日:1984-03-15

    摘要: The invention relates to basic chromium aluminum sulfates which are soluble in cold water and are of the general formulaCr.sub.x Al.sub.2-x (OH).sub.2 y. (SO.sub.4).sub.3-y.n H.sub.2 Owhere x is from 0.1 to 1.9, y is from 0.01 to 2 and n is from 4 to 24, and a process for the preparation thereof. The process comprises reacting chromium (III)--containing waste sulfuric acid having a water content of 20-50% by weight with aluminum oxide and/or aluminum oxide hydroxide and/or aluminum hydroxide at a temperature of 100.degree. to 200.degree. C. The molten product is converted to droplet form and allowed to solidify in free fall.

    摘要翻译: 本发明涉及可溶于冷水并具有通式Cr x Al 2-x(OH)2 y)的碱性铬酸铝硫酸盐。 (SO 4)3-y.nH 2 O,其中x为0.1至1.9,y为0.01至2,n为4至24,以及其制备方法。 该方法包括在100至200℃的温度下将含水量为20-50重量%的含铬(III)的废硫酸与氧化铝和/或氧化铝氢氧化物和/或氢氧化铝反应。 熔融产物转化为液滴形式,并在自由落体下固化。

    Auxiliary, and process, for the soaking of hides
    3.
    发明授权
    Auxiliary, and process, for the soaking of hides 失效
    辅助和加工,用于浸泡皮革

    公开(公告)号:US4322210A

    公开(公告)日:1982-03-30

    申请号:US176684

    申请日:1980-08-08

    IPC分类号: C14C1/04 C14C1/08

    CPC分类号: C14C1/04

    摘要: An auxiliary for the soaking of hides and skins, which consists of a salt of the formula IM.sup.+ [O.sub.3 S--S--R].sup.- Iwhere R is an organic radical of 1 to 8 carbon atoms, which may carry one or more functional groups, and M.sup.+ is one equivalent of a cation, mixtures thereof with other conventional soaking auxiliaries, and processes for their use. Using the novel auxiliary avoids all toxicity hazards and odor nuisance, as well as avoiding oxidation losses, and achieves good loosening of the hair.

    摘要翻译: 用于浸泡皮革和皮革的辅助剂,其由式I M + [O 3 S-SR] -I的盐组成,其中R是可以携带一个或多个官能团的1至8个碳原子的有机基团,以及 M +是一种阳离子,其它常规浸泡助剂的混合物,以及它们的使用方法。 使用新型辅助剂可避免所有毒性危害和气味滋扰,避免氧化损失,达到良好的头发松动。

    Deliming hides
    4.
    发明授权
    Deliming hides 失效
    划定生皮

    公开(公告)号:US4377387A

    公开(公告)日:1983-03-22

    申请号:US348277

    申请日:1982-02-12

    IPC分类号: C14C1/08

    CPC分类号: C14C1/08

    摘要: Conventionally limed hides are delimed for from one to six hours under conventional deliming conditions in respect of liquor length, temperature and pH of the liquor, by a process in which a cyclic carbonate of a polyhydric aliphatic alcohol of 2 to 6 carbon atoms is employed as the active agent.

    摘要翻译: 通常使用2至6个碳原子的多元脂肪醇的环状碳酸酯作为方法,在常规的分离条件下,关于液体的长度,液体的温度和pH值,将常规的褐色皮革分离为1至6小时, 活性剂。

    Preparation of J-acid urea
    6.
    发明授权
    Preparation of J-acid urea 失效
    制备J-酸尿素

    公开(公告)号:US5144064A

    公开(公告)日:1992-09-01

    申请号:US764359

    申请日:1991-09-23

    IPC分类号: C07C303/22 C07C309/51

    CPC分类号: C07C303/22

    摘要: J-Acid urea of the formula ##STR1## is prepared by reacting 7-amino-4-hydroxynaphthalene-2-sulfonic acid (J-acid) with urea at from 100.degree. to 140.degree. C. under a pressure ranging from atmospheric pressure to 10 bar in an inert solvent to a partial extent, precipitating unconverted J-acid in an acidic medium and separating it off, and, if desired, isolating J-acid urea from the resulting neutralized solution by salting out.

    摘要翻译: 通过使7-氨基-4-羟基萘-2-磺酸(J-酸)与尿素在100-140℃下在大气压至大约压力的压力下反应制备式“IMAGE”的γ-酸尿素 10巴在惰性溶剂中的一部分程度,在酸性介质中沉淀未转化的J-酸,并将其分离出来,如果需要,通过盐析从得到的中和溶液中分离出J-酸尿素。

    Preparation of N-hydroxypyrazoles
    7.
    发明授权
    Preparation of N-hydroxypyrazoles 失效
    N-羟基吡唑的制备

    公开(公告)号:US4945167A

    公开(公告)日:1990-07-31

    申请号:US367047

    申请日:1989-06-16

    摘要: N-hydroxypyrazoles of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 may be identical or different and are each hydrogen or halogen, are prepared by a process in which a pyrazole of the general formula II ##STR2## where R.sup.1, R.sup.2 and R.sup.3 have the meanings stated for formula I, is reacted with an aliphatic or aromatic peroxocarboxylic acid, preferably in the presence of from 0 to 15 moles of an alkali metal hydroxide, alkaline earth metal hydroxide, alkali meteal carbonate or alkaline earth metal carbonate in such a way that the reaction temperature is from -5.degree. C. to 60.degree.C.The reaction can be carried out in water as a solvent or in a 2-phase system consisting of water and an inert organic solvent which is poorly miscible with water, in the presence or absence of a suitable phase transfer catalyst. The peroxocarboxylic acid can be prepared in the reaction mixture before the reaction from H.sub.2 O.sub.2 and an acyl halide or a carboxylic anhydride or can be used in the form of an alkali metal salt or alkaline earth metal salt.

    摘要翻译: 其中R 1,R 2和R 3可以相同或不同并且各自为氢或卤素的通式I(I)的N-羟基吡唑通过其中通式II的吡唑(IMAGE)( II)其中R 1,R 2和R 3具有式I所述的含义,与脂族或芳族过氧羧酸反应,优选在0至15摩尔碱金属氢氧化物,碱土金属氢氧化物,碱金属碳酸盐 或碱土金属碳酸盐,使得反应温度为-5℃至60℃。该反应可以在作为溶剂的水中或在由水和惰性有机物组成的2相体系中进行 在有或没有合适的相转移催化剂的情况下与水很难混溶的溶剂。 过氧化羧酸可以在与H 2 O 2和酰卤或羧酸酐反应之前在反应混合物中制备,或者可以以碱金属盐或碱土金属盐的形式使用。

    Tetrachloroperylene-3,4,9,10-tetracarboxylic acid diimide pigment and
its use
    8.
    发明授权
    Tetrachloroperylene-3,4,9,10-tetracarboxylic acid diimide pigment and its use 失效
    四氯化苯-3,4,9,10-四羧酸二酰亚胺颜料及其用途

    公开(公告)号:US4846892A

    公开(公告)日:1989-07-11

    申请号:US92600

    申请日:1987-09-03

    CPC分类号: C09B5/62 C09B67/0025

    摘要: A tetrachloroperylene-3,4,9,10-tetracarboxylic acid diimide pigment which contains not less than 85% by weight of the tetrachloro compound of the formula ##STR1## which is present to the extent of not less than 95% by weight in the .beta.-modification and which, in an X-ray spectrum, exhibits 2.sup..crclbar. CuK.sub..alpha. main lines at 9.0.degree., 13.3.degree., 15.0.degree., 16.8.degree., 19.1.degree., 21.5.degree., 24.2.degree., 25.4.degree., 26.5.degree., 27.0.degree. and 27.5.degree..In finishes, the pigment gives very brilliant colorations which are very highly lightfast and fast to weathering and which, upon weathering, neither bleach nor darken up.

    摘要翻译: 含有不少于85重量%的式“IMAGE”的四氯化合物的四氯化亚丙基-3,4,9,10-四羧酸二酰亚胺颜料,其量为不少于95重量% 在9.0°,13.3°,15.0°,16.8°,19.1°,21.5°,24.2度,25.4度,26.5度,X射线谱中显示2( - )CuKα主线, 27.0°和27.5°。 在表面处理中,颜料产生非常明亮的着色,其具有非常高的耐光性和耐候性,并且在风化时,既不漂白也不变暗。

    Bisazo compounds containing anthranilic acid and thiazole moieties
    9.
    发明授权
    Bisazo compounds containing anthranilic acid and thiazole moieties 失效
    含有邻氨基苯甲酸和噻唑部分的双偶氮化合物

    公开(公告)号:US4694075A

    公开(公告)日:1987-09-15

    申请号:US820018

    申请日:1986-01-21

    CPC分类号: C09B44/02

    摘要: The compounds of the formula ##STR1## where Y is hydrogen, chlorine, bromine or nitro, Z is hydrogen, chlorine, bromine, a sulfonic ester group or unsubstituted or substituted sulfamyl, X is --O-- or ##STR2## R is alkylene which may or may not be interrupted by oxygen or ##STR3## m is 0 or 1, p is 1 or 2, R.sup.1 and R.sup.2 independently of one another are each hydrogen, unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aralkyl, or aryl, or R.sup.1 and R.sup.2 together with the nitrogen form a heterocyclic structure, R.sup.3 is hydrogen or unsubstituted or substituted alkyl, R.sup.6 and R.sup.7 independently of one another are each hydrogen, unsubstituted or substituted alkyl, alkoxy or acylamino, K is a radical of a coupling component, A.crclbar. is an anion, R.sup.4 is unsubtituted or substituted alkyl and R.sup.5 is hydrogen or C.sub.1 -C.sub.4 -alkyl, and the radical ##STR4## may furthermore be an unsubstituted or substituted piperazine radical, are useful for dyeing acid-modified fibers, leather and in particular paper.

    摘要翻译: 其中Y是氢,氯,溴或硝基,Z是氢,氯,溴,磺酸酯基或未取代或取代的亚磺酰基的式“IMAGE”的化合物,X是-O-或R是 氧可以或不会被氧中断,或者m为0或1,p为1或2,R 1和R 2彼此独立地为氢,未取代或取代的烷基,烯基,环烷基,芳烷基或芳基,或 R 1和R 2与氮一起形成杂环结构,R 3为氢或未取代或取代的烷基,R 6和R 7彼此独立地为氢,未取代或取代的烷基,烷氧基或酰氨基,K为偶联组分的基团, A( - )是阴离子,R4是未取代的或取代的烷基,R5是氢或C1-C4-烷基,基团还可以是未取代或取代的哌嗪基,可用于染色酸改性纤维, 皮革,特别是纸张。