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    Process for the preparation of water-dilutable coating binders based on acrylate copolymers, and their use
    3.
    发明授权
    Process for the preparation of water-dilutable coating binders based on acrylate copolymers, and their use 失效
    基于丙烯酸酯共聚物制备水可稀释涂料粘合剂的方法及其用途

    公开(公告)号：US5811484A

    公开(公告)日：1998-09-22

    申请号：US663127

    申请日：1996-06-24

    申请人： Werner Wilfinger ,  Ingo Kriessmann ,  Kurt Gossak

    发明人： Werner Wilfinger ,  Ingo Kriessmann ,  Kurt Gossak

    IPC分类号： C08G81/00 ,  B05D7/26 ,  C08F8/14 ,  C08F8/44 ,  C08G81/02 ,  C09D133/06 ,  C09D133/14 ,  C09D161/20 ,  C08L33/00

    CPC分类号： C08F8/14 ,  C08F8/44 ,  C09D133/06

    摘要： A process is disclosed for preparing water-dilutable, acrylate copolymer-based lacquer binders. A polycarboxylic component is reacted with an epoxide group-containing polyhydroxylic component, and the carboxylic groups are then at least partially neutralized. As epoxide group-containing monomers for the polyhydroxylic components, glycidyl(meth)acrylate and/or glycidylallylether are used in proportions from 0.1 to 3% by weight. Associated with cross-linking components and if required with other lacquer binders, these lacquer binders are suitable for producing water-dilutable baking enamels with a low auxiliary organic solvent content.

    摘要翻译： PCT No.PCT / AT94 / 00203 Sec。 371日期1996年6月24日 102（e）1996年6月24日PCT 1994年12月22日PCT公布。 第WO95 / 17450号公报 日期1995年6月29日公开了一种制备水可稀释丙烯酸酯共聚物基漆粘合剂的方法。 使多元羧酸成分与含环氧基的多羟基成分反应，然后将羧基至少部分中和。 作为多羟基成分的含环氧基的单体，使用0.1〜3重量％的（甲基）丙烯酸缩水甘油酯和/或缩水甘油基醚。 与交联组分相关，如果需要与其它漆粘合剂相关，这些漆粘合剂适用于生产具有低辅助有机溶剂含量的水可稀释烘烤搪瓷。

    Aqueous binders for coatings with improved gloss
    5.
    发明授权
    Aqueous binders for coatings with improved gloss 有权
    用于具有改善光泽度的涂层的水性粘合剂

    公开(公告)号：US08546479B2

    公开(公告)日：2013-10-01

    申请号：US12293091

    申请日：2007-03-04

    申请人： Johann Billiani ,  Karl Rossmann ,  Rami-Raimund Awad ,  Thomas Fraydl ,  Ingo Kriessmann

    发明人： Johann Billiani ,  Karl Rossmann ,  Rami-Raimund Awad ,  Thomas Fraydl ,  Ingo Kriessmann

    IPC分类号： C08G18/67

    CPC分类号： C09D133/066 ,  C08F212/08 ,  C08F220/06 ,  C08F220/18

    摘要： A water-reducible mixture of (meth)acrylic copolymers having a hydroxyl number of from 40 mg/g to 250 mg/g, an acid number of from 15 mg/g to 80 mg/g, a weight average molar mass Mw from 9 kg/mol to 40 kg/mol and a glass transition temperature Tg from −40° C. to 80° C., based on polymerised monomers comprising at least one alkyl ester A of an olefinically un-saturated carboxylic acid having from 1 to 8 carbon atoms in the alkyl group, at least one hydroxy functional alkyl ester B of an olefinically unsaturated carboxylic acid, at least one aliphatic compound C that has both hydroxy and carboxyl functionalities, or which is a lactone or a cyclic lactone, at least one vinyl monomer D which does not comprise a moiety derived from an olefinically unsaturated carboxylic acid, at least one olefinically unsaturated carboxylic acid E, a process for its preparation, and a method of use thereof in the preparation of paints.

    摘要翻译： 具有羟值为40mg / g至250mg / g，酸值为15mg / g至80mg / g，重量平均摩尔质量Mw为9的（甲基）丙烯酸共聚物的水可稀释混合物 kg / mol至40kg / mol，玻璃化转变温度Tg为-40℃至80℃，基于包含至少一种具有1至8个的烯属不饱和羧酸的烷基酯A的聚合单体 烷基中的碳原子，烯属不饱和羧酸的至少一种羟基官能的烷基酯B，至少一种具有羟基和羧基官能团的脂肪族化合物C，或者是内酯或环状内酯，至少一种乙烯基 单体D，其不包含衍生自烯属不饱和羧酸的部分，至少一种烯属不饱和羧酸E，其制备方法及其在制备涂料中的用途。

    AQUEOUS BINDERS FOR COATINGS WITH IMPROVED GLOSS
    6.
    发明申请
    AQUEOUS BINDERS FOR COATINGS WITH IMPROVED GLOSS 有权
    具有改进的GLOSS的涂料的水性粘合剂

    公开(公告)号：US20090221741A1

    公开(公告)日：2009-09-03

    申请号：US12293091

    申请日：2007-03-04

    申请人： Johann Billiani ,  Karl Rossmann ,  Rami-Raimund Awad ,  Thomas Fraydl ,  Ingo Kriessmann

    发明人： Johann Billiani ,  Karl Rossmann ,  Rami-Raimund Awad ,  Thomas Fraydl ,  Ingo Kriessmann

    IPC分类号： C09D133/02

    CPC分类号： C09D133/066 ,  C08F212/08 ,  C08F220/06 ,  C08F220/18

    摘要： A water-reducible mixture of (meth)acrylic copolymers having a hydroxyl number of from 40 mg/g to 250 mg/g, an acid number of from 15 mg/g to 80 mg/g, a weight average molar mass Mw from 9 kg/mol to 40 kg/mol and a glass transition temperature Tg from −40° C. to 80° C., based on polymerised monomers comprising at least one alkyl ester A of an olefinically un-saturated carboxylic acid having from 1 to 8 carbon atoms in the alkyl group, at least one hydroxy functional alkyl ester B of an olefinically unsaturated carboxylic acid, at least one aliphatic compound C that has both hydroxy and carboxyl functionalities, or which is a lactone or a cyclic lactone, at least one vinyl monomer D which does not comprise a moiety derived from an olefinically unsaturated carboxylic acid, at least one olefinically unsaturated carboxylic acid E, a process for its preparation, and a method of use thereof in the preparation of paints.

    摘要翻译： 具有羟值为40mg / g至250mg / g，酸值为15mg / g至80mg / g，重量平均摩尔质量Mw为9的（甲基）丙烯酸共聚物的水可稀释混合物 kg / mol至40kg / mol，玻璃化转变温度Tg为-40℃至80℃，基于包含至少一种具有1至8个的烯属不饱和羧酸的烷基酯A的聚合单体 烷基中的碳原子，烯属不饱和羧酸的至少一种羟基官能的烷基酯B，至少一种具有羟基和羧基官能团的脂肪族化合物C，或者是内酯或环状内酯，至少一种乙烯基 单体D，其不包含衍生自烯属不饱和羧酸的部分，至少一种烯属不饱和羧酸E，其制备方法及其在制备涂料中的用途。

    Aqueous self-crosslinking copolymer dispersions, a process for preparing them and their use in binders for coating materials
    7.
    发明授权
    Aqueous self-crosslinking copolymer dispersions, a process for preparing them and their use in binders for coating materials 有权
    水性自交联共聚物分散体，其制备方法及其在涂料粘合剂中的应用

    公开(公告)号：US06515042B2

    公开(公告)日：2003-02-04

    申请号：US09419214

    申请日：1999-10-15

    申请人： Ingo Kriessmann ,  Rami-Raimund Awad ,  Hannelore Gsöll ,  Bernhard Hirschmann ,  Karl Rossmann

    发明人： Ingo Kriessmann ,  Rami-Raimund Awad ,  Hannelore Gsöll ,  Bernhard Hirschmann ,  Karl Rossmann

    IPC分类号： C09D15100

    CPC分类号： C08F265/06 ,  C08F257/02 ,  C09D151/00 ,  Y10S525/902

    摘要： Aqueous self-crosslinking copolymer dispersions ABC obtainable by free-radically initiated copolymerization in the first stage of a monomer mixture A comprising olefinically unsaturated monomers A1 having carbonyl groups, unsaturated carboxylic acids or monoesters of unsaturated dicarboxylic acids A2, monomers A3 selected from vinylaromatic compounds, n-butyl methacrylate and also alkyl esters of unsaturated carboxylic acids or dialkyl esters of unsaturated dicarboxylic acids, esters A4 selected from alkyl esters of unsaturated carboxylic acids of dialkyl esters of unsaturated dicarboxylic acids, and other free-radically polymerizable monomers A5, and subsequent addition of a second monomer mixture B and further polymerization in the second stage, the mixture B comprising olefinically unsaturated monomers B1 corresponding to A1, esters B2 corresponding to A4, and monomers B3 corresponding to A5, and subsequently adding compounds C having hydrazine or hydrazide groups.

    摘要翻译： 在单体混合物A的第一阶段中通过自由基引发共聚获得的水性自交联共聚物分散体ABC包含具有羰基的烯属不饱和单体A1，不饱和羧酸或不饱和二羧酸A2的单酯，选自乙烯基芳族化合物的单体A3， 甲基丙烯酸正丁酯以及不饱和羧酸的烷基酯或不饱和二羧酸的二烷基酯，选自不饱和二羧酸的二烷基酯的不饱和羧酸的烷基酯和其它可自由基聚合的单体A5的酯A4，以及随后的加成 的第二单体混合物B和在第二阶段进一步聚合，混合物B包含对应于A1的烯属不饱和单体B1，对应于A4的酯B2和对应于A5的单体B3，随后加入具有肼或酰肼基团的化合物C.

    Diester of phosphoric acid and monoepoxide reacted with epoxide to form product reacted with monoisocyanate
    9.
    发明授权
    Diester of phosphoric acid and monoepoxide reacted with epoxide to form product reacted with monoisocyanate 失效
    磷酸和单环氧化物的二酯与环氧化物反应形成与单异氰酸酯反应的产物

    公开(公告)号：US4992525A

    公开(公告)日：1991-02-12

    申请号：US187427

    申请日：1988-04-28

    申请人： Ingo Kriessmann ,  Willibald Paar

    发明人： Ingo Kriessmann ,  Willibald Paar

    IPC分类号： C08G59/14 ,  C08G59/30 ,  C08G59/32 ,  C08G59/56 ,  C09D5/44 ,  C09D163/00

    CPC分类号： C08G59/1488 ,  C08G59/14 ,  C08G59/56 ,  C09D5/4434

    摘要： Cationic resins based on epoxy resins which are modified through the introduction of phosphoric acid segments and the process of producing the resins are described. The reaction of the phosphoric acid is carried out in a multiple-step process whereby, in a first step, the diester is formed through reaction of ortho-phosphoric acid with 2 moles of a monoepoxy compound or through reaction of a polyphosphoric acid with n-1 moles of a monoalcohol and subsequent reaction with n+1 moles of a monoepoxy compound. The remaining acid group is reacted with a di- or polyepoxy resin. The products obtained can still contain unreacted epoxy groups. The protonable groups are introduced via the epoxy groups and/or via the hydroxy groups present or set free by opening of the oxirane ring. The binders can be combined with hardening components or may be formulated as self-crosslinking binders. The binders have excellent resistance to corrosion when stoved as electrodeposited coatings.

    摘要翻译： 描述了通过引入磷酸链段改性的基于环氧树脂的阳离子树脂和制备树脂的方法。 磷酸的反应是以多步法进行的，其中在第一步中，通过邻磷酸与2摩尔单环氧化合物的反应或通过多磷酸与正磷酸的反应形成二酯， 1摩尔一元醇，随后与n + 1摩尔单环氧化合物反应。 剩余的酸基与二环氧树脂或聚环氧树脂反应。 所得产物仍可含有未反应的环氧基。 可质子化基团通过环氧基和/或经由存在的羟基或通过开环的环氧乙烷环自由引入。 粘合剂可以与硬化组分组合，或者可以配制成自交联粘合剂。 当作为电沉积涂层被烘烤时，粘合剂具有优异的耐腐蚀性。

    Preparation and use of cold-plastic coating compositions based on acrylate resins
    10.
    发明授权
    Preparation and use of cold-plastic coating compositions based on acrylate resins 失效
    基于丙烯酸酯树脂的冷塑料涂料组合物的制备和使用

    公开(公告)号：US06359029B1

    公开(公告)日：2002-03-19

    申请号：US09598600

    申请日：2000-06-21

    申请人： Ingo Kriessmann ,  Gerfried Klintschar ,  Ulrich Epple ,  Adolf Labenbacher

    发明人： Ingo Kriessmann ,  Gerfried Klintschar ,  Ulrich Epple ,  Adolf Labenbacher

    IPC分类号： C08K340

    CPC分类号： C09D5/004 ,  C08F2/44 ,  C09D4/00 ,  C09D4/06 ,  C08F222/1006 ,  C08F265/04

    摘要： Binders for road-marking paints, comprising a (meth)acrylate copolymer A and one or more olefinincally unsaturated monomers B which can be cured by adding free-radical initiators C, wherein the binders have mass fractions of from 20 to 80% of the (meth)acrylate copolymer A and from 80 to 20% of the olefinically unsaturated monomers B, where the (meth)acrylate copolymers A are obtainable by reacting, mass fractions of, from 10 to 50% of compounds A1 selected from the group consisting of from 10 to 50% of compounds A1 selected from the group consisting of monoexpoxides, lactones and lactams having from 4 to 18 carbon atoms, from 1 to 25% of olefinically unsaturated monomers A2 which contain at least one acid group selected from the group consisting of carboxyl groups, sulfonic acid groups and phosphonic acid groups, from 5 to 70% of methacylates A3 of linear, branched or cyclic alchohols having from 1 to 20 carbon atoms, from 2 to 84% of acrylates A4 of linear, branched or cyclic alcohols having from 2 to 20 carbon atoms, and also if desired, up to 70% of other vinyl monomers A5 by free-radical polymerization, where the compounds A1 are first charged and the monomers A2 to A5, and also a free-radical initiator A7, are added.

    摘要翻译： 用于道路标线涂料的粘合剂，包含（甲基）丙烯酸酯共聚物A和一种或多种可通过加入自由基引发剂C固化的烯族不饱和单体B，其中粘合剂的质量分数为（（甲基）丙烯酸酯共聚物A的20〜80％ 甲基）丙烯酸酯共聚物A和80〜20％的烯属不饱和单体B，其中（甲基）丙烯酸酯共聚物A可通过使10-50％的化合物A1的质量分数反应，所述化合物A1选自十 至50％的选自单过氧化物，内酯和具有4至18个碳原子的内酰胺，1至25％的烯属不饱和单体A2的化合物A1，其含有至少一个选自羧基的酸基 ，磺酸基和膦酸基团，5-70％具有1-20个碳原子的直链，支链或环状醇酸酯的甲基丙烯酸酯A3，2-84％直链，支链或环状醇的丙烯酸酯A4 通过自由基聚合，如果需要，可以使用2-20个碳原子，以及如果需要，最多70％的其它乙烯基单体A5，其中首先加入化合物A1，并且单体A2至A5，以及自由基引发剂A7， 被添加。