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    Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators
    1.
    发明授权
    Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators 失效
    使用具有长烷基链的2,2,6,6四烷基哌啶-N-氧基作为聚合调节剂

    公开(公告)号：US06569940B1

    公开(公告)日：2003-05-27

    申请号：US09720440

    申请日：2000-12-22

    申请人： Wiebke Wunderlich ,  Margot Clauss ,  Michael Roth ,  Francesco Fuso

    发明人： Wiebke Wunderlich ,  Margot Clauss ,  Michael Roth ,  Francesco Fuso

    IPC分类号： C07D25106

    CPC分类号： C08F2/38 ,  C08F4/00

    摘要： The present invention relates to a polymerizable composition, comprising a) at least one ethylenically unsaturated monomer or oligomer, b) a radical source capable of starting polymerization of the ethylenically unsaturated monomer or oligomer and c) at least one compound of formula (I), wherein n is 1 or 2; R3, R4, R9, R10 are each independently of one another C1-C18alkyl, C2-C18alkenyl or C2-C18alkinyl; or R3 and R4 and/or R9 and R10 form together with the linking carbon atom a C3-C12cycloakyl radical; R5, R6, R7, R8 are each independently of one another hydrogen, C1-C18alkyl, C2-C18alkenyl or C2C18alkinyl; X is —O—, —O—C(O)—, —NR2— or —NR2—C(O)—; R2 is hydrogen, C1-C18alkyl or phenyl; if n is 1, R1 is C8-C36alkyl, C8-C36alkenyl or C8-C36alkinyl; if n is 2, R1 is C10-C36alkylen, C10-C36alkenylen or C10-C36alkinylen. Further objects of the present invention are a process for polymerization and the use of compounds of formula (I) for the polymerization of ethylenically unsaturated monomers.

    摘要翻译： 本发明涉及一种可聚合组合物，其包含a）至少一种烯键式不饱和单体或低聚物，b）能够启动烯属不饱和单体或低聚物聚合的自由基源，和c）至少一种式（I）化合物， 其中n为1或2; R 3，R 4，R 9，R 10各自独立地为C 1 -C 18烷基，C 2 -C 18烯基或C 2 -C 18炔基; 或R 3和R 4和/或R 9和R 10与连接碳原子一起形成C 3 -C 12环烷基; R5，R6，R7，R8各自独立地为氢，C1-C18烷基，C2-C18链烯基或C2C18炔基; X是-O - ， - O-C（O） - ， - NR2-或-NR2-C（O） - ; R2是氢，C1-C18烷基或苯基; 如果n为1，则R1为C8-C36烷基，C8-C36烯基或C8-C36炔基; 如果n为2，则R1为C10-C36亚烷基，C10-C36烯基或C10-C36炔基。 本发明的另外的目的是聚合方法和式（I）化合物用于烯属不饱和单体聚合的方法。

    Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators
    2.
    发明授权
    Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators 失效
    使用具有长烷基链的2,2,6,6四烷基哌啶-N-氧基作为聚合调节剂

    公开(公告)号：US06864313B2

    公开(公告)日：2005-03-08

    申请号：US10354613

    申请日：2003-01-30

    申请人： Wiebke Wunderlich ,  Margot Clauss ,  Michael Roth ,  Francesco Fuso

    发明人： Wiebke Wunderlich ,  Margot Clauss ,  Michael Roth ,  Francesco Fuso

    IPC分类号： C08F2/02 ,  C08F2/14 ,  C08F2/16 ,  C08F2/38 ,  C08F4/00 ,  C07D251/06 ,  C08K5/3492

    CPC分类号： C08F4/00 ,  C08F2/38

    摘要： The present invention relates to a polymerizable composition, comprising a) at least one ethylenically unsaturated monomer or oligomer, b) a radical source capable of starting polymerization of the ethylenically unsaturated monomer or oligomer and c) at least one compound of formula (I) wherein n is 1 or 2 R3, R4, R9, R10 are each independently of one another C1-C18alkyl, C2-C18alkenyl or C2-C18alkinyl; or R3 and R4 and/or R9 and R10 form together with the linking carbon atom a C3-C12cycloalkyl radical; R5, R6, R7, R8 are each independently of one another hydrogen, C1-C18alkyl, C2-C18alkenyl or C2-C18alkinyl; X is —O—, —O—C(O)—, —NR2— or —NR2—C(O)—; R2 is hydrogen, C1-C18alkyl or phenyl; if n is 1, R1 is C8-C38alkyl, C8-C36alkenyl or C8-C36alkinyl if n is 2 R1 is C10-C38alkylen, C10-C36alkenylen or C10-C36alkinylen. Further objects of the present invention are a process for polymerization and the use of compounds of formula I for the polymerization of ethylenically unsaturated monomers.

    摘要翻译： 本发明涉及一种可聚合组合物，其包含a）至少一种烯键式不饱和单体或低聚物，b）能够开始烯键式不饱和单体或低聚物聚合的自由基，和c）至少一种式（I）化合物，其中n为1 或2R3，R4，R9，R10各自独立地为C1-C18烷基，C2-C18链烯基或C2-C18链炔基; 或R 3和R 4和/或R 9和R 10与连接碳原子一起形成C 3 -C 12环烷基; R 5，R 6，R 7，R 8各自独立地为氢，C 1 -C 18烷基，C 2 -C 18烯基或C 2 -C 18炔基; X （O） - ，-NR2-或-NR2-C（O） - ; R2是氢，C1-C18烷基或苯基;如果n是1，则R1是C8-C38烷基，C8-C36烯基或 C8-C36炔基是n为2R1的是C10-C38亚烷基，C10-C36烯基或C10-C36炔基。本发明的另一个目的是一种聚合方法和式Ⅰ化合物用于烯属不饱和单体的聚合。

    Nitroxyl derivatives with glycidyl or alkylcarbonyl groups as initiators for radical polymerization
    3.
    发明授权
    Nitroxyl derivatives with glycidyl or alkylcarbonyl groups as initiators for radical polymerization 失效
    具有缩水甘油基或烷基羰基的硝基衍生物作为自由基聚合的引发剂

    公开(公告)号：US06566468B1

    公开(公告)日：2003-05-20

    申请号：US09623547

    申请日：2000-09-05

    申请人： Francesco Fuso ,  Michael Roth ,  Wiebke Wunderlich

    发明人： Francesco Fuso ,  Michael Roth ,  Wiebke Wunderlich

    IPC分类号： C08F400

    CPC分类号： C08F4/00 ,  C07D211/46 ,  C07D211/74 ,  C07D211/94

    摘要： Glycidyl and alkylcarbonyl functional nitroxide radical polymerization initiator compounds of formula (Ia) or (Ib), where R1, R2 and A are as defined within, R3 is a radical of formula (II)  where X is phenylene, naphthylene or biphenylene, which are unsubstituted or substituted by NO2, halogen, amino, hydroxy, cyano, carboxy, C1-C4alkoxy, C1-C4alkylthio, C1-C4alkylamino or di(C1-C4alkyl)amino; the R12 are independently of each other H or CH3; D is a group  a group C(O)—R13 or a group C(O)—R9—C(O)—R13; R13 is C1-C18alkyl and m is a number from 1 to 4, provide polymeric resin products having low polydispersity, polymerization processes that proceed with good monomer to polymer conversion efficiencies and polymers that contain a glycidyl or alkylcarbonyl group.

    摘要翻译： 式（Ia）或（Ib）的缩水甘油基和烷基羰基官能的氮氧自由基聚合引发剂化合物，其中R 1，R 2和A如R3中所定义，是式（II）的基团，其中X是亚苯基，亚萘基或亚联苯基，其是未取代的 或被NO 2，卤素，氨基，羟基，氰基，羧基，C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4烷基氨基或二（C 1 -C 4烷基）氨基取代; R 12彼此独立地为H或CH 3; D为 C（O）-R13基或C（O）-R9-C（O）-R13基; R13为C1-C18烷基，m为1至4的数，提供具有低多分散性的聚合物树脂产物， 继续进行良好的单体与聚合物的转化效率以及含有缩水甘油基或烷基羰基的聚合物。

    N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators
    4.
    发明授权
    N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators 失效
    N-烷氧基-4,4-二氧基 - 聚烷基 - 哌啶作为自由基聚合引发剂

    公开(公告)号：US07868171B2

    公开(公告)日：2011-01-11

    申请号：US11729484

    申请日：2007-03-29

    申请人： Francesco Fuso ,  Wiebke Wunderlich ,  Andreas Kramer ,  Jochen Fink

    发明人： Francesco Fuso ,  Wiebke Wunderlich ,  Andreas Kramer ,  Jochen Fink

    IPC分类号： C07D401/04 ,  C08K5/35

    CPC分类号： C07D491/10 ,  C08K5/3435

    摘要： The present invention relates to selected glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiator compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers and the use of glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiators for radical polymerization.

    摘要翻译： 本发明涉及形成开链或环状缩酮结构的选择的缩水甘油基或羰基官能的N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶化合物，可聚合组合物，其包含a）至少一种烯属不饱和单体和b）缩水甘油基 或羰基官能的N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶氮氧根引发剂化合物。 本发明的另外的方面是用于使烯键式不饱和单体聚合的方法和使用缩水甘油基或羰基官能的N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶氮氧根引发剂进行自由基聚合。

    N-alkoxy-4, 4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
    5.
    发明申请
    N-alkoxy-4, 4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization 失效
    N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶化合物与缩水甘油基或烷基羰基作为受控自由基聚合的官能引发剂

    公开(公告)号：US20070173570A1

    公开(公告)日：2007-07-26

    申请号：US11729484

    申请日：2007-03-29

    申请人： Francesco Fuso ,  Wiebke Wunderlich ,  Andreas Kramer ,  Jochen Fink

    发明人： Francesco Fuso ,  Wiebke Wunderlich ,  Andreas Kramer ,  Jochen Fink

    IPC分类号： C08K5/34 ,  C07D491/10

    CPC分类号： C07D491/10 ,  C08K5/3435

    摘要： The present invention relates to selected glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiator compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers and the use of glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiators for radical polymerization.

    摘要翻译： 本发明涉及形成开链或环状缩酮结构的选择的缩水甘油基或羰基官能的N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶化合物，可聚合组合物，其包含a）至少一种烯属不饱和单体和b）缩水甘油基 或羰基官能的N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶氮氧根引发剂化合物。 本发明的另外的方面是用于使烯键式不饱和单体聚合的方法和使用缩水甘油基或羰基官能的N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶氮氧根引发剂进行自由基聚合。

    Polymer blends with improved impact resistance
    7.
    发明授权
    Polymer blends with improved impact resistance 失效
    具有改善耐冲击性的聚合物共混物

    公开(公告)号：US06765062B2

    公开(公告)日：2004-07-20

    申请号：US10192091

    申请日：2002-07-10

    申请人： Hui Chin ,  James Botkin ,  Francesco Fuso ,  Wiebke Wunderlich

    发明人： Hui Chin ,  James Botkin ,  Francesco Fuso ,  Wiebke Wunderlich

    IPC分类号： C08L2506

    CPC分类号： C08L77/06 ,  C08L67/00 ,  C08L67/02 ,  C08L71/123 ,  C08L77/00 ,  C08L25/00 ,  C08L2666/02 ,  C08L71/00

    摘要： Polymer blends, in particular polyphenylene ether-polyamide blends, are effectively compatibilized by incorporating under blending conditions certain oligomers, cooligomers, polymers and copolymers of narrow molecular weight distribution that are prepared under free radical polymerization conditions with glycidyl-functionalized nitroxyl initiators. The oligomers, cooligomers, polymers and copolymers contain at least one oxyamine group and at least one glycidyl-containing initiator group. The polymer blends have excellent mechanical properties.

    摘要翻译： 聚合物共混物，特别是聚苯醚 - 聚酰胺共混物通过在共混条件下引入在自由基聚合条件下与缩水甘油基官能化的硝酰基引发剂一起制备的某些低分子量，低​​分子量，窄分子量分布的聚合物和共聚物而有效相容。 低聚物，低聚物，聚合物和共聚物含有至少一个羟胺基团和至少一个含缩水甘油基的引发剂基团。 聚合物共混物具有优异的机械性能。

    Method of producing comb or star copolymers using epoxy-functionalized nitroxylethers
    8.
    发明授权
    Method of producing comb or star copolymers using epoxy-functionalized nitroxylethers 失效
    使用环氧官能化硝酰基醚制备梳状或星型共聚物的方法

    公开(公告)号：US07291682B2

    公开(公告)日：2007-11-06

    申请号：US10524926

    申请日：2003-08-26

    申请人： Wiebke Wunderlich-Wippert ,  Rudolf Pfaendner ,  Francesco Fuso ,  Jochen Fink

    发明人： Wiebke Wunderlich-Wippert ,  Rudolf Pfaendner ,  Francesco Fuso ,  Jochen Fink

    IPC分类号： C08F283/06 ,  C08G65/22

    CPC分类号： C08G65/22 ,  C08F283/06 ,  C08F293/005 ,  C08F2438/02 ,  C08L71/02 ,  C08L2205/05 ,  C08L2666/04

    摘要： The present invention provides a method of forming comb or star copolymers. The comb or star copolymers are useful in surface modification of thermoplastic materials or as surfactants. The method is aimed at attaching a polymeric side chain differing in polarity and chemical structure from the backbone and forming a comb or star copolymer structure. In particular the process comprises polymerizing in a first step a polymer backbone from epoxy and nitroxylether group containing monomers and in a second step polymerizing under controlled radical conditions a comb or star structure onto this backbone. The epoxy group containing monomers are for example of the formula (II)

    摘要翻译： 本发明提供了形成梳状或星型共聚物的方法。 梳状或星形共聚物可用于热塑性材料或表面活性剂的表面改性。 该方法旨在将不同极性和化学结构的聚合物侧链与骨架连接并形成梳状或星型共聚物结构。 特别地，该方法包括在第一步骤中聚合来自环氧基和含硝酰基醚基团的单体的聚合物主链，并且在第二步中在受控自由基条件下将梳状或星形结构聚合到该主链上。 含环氧基的单体例如为式（II）

    N-alkoxy-4,4-dioxy-polyalkyl-piperidines as radical polymerization inhibitors
    9.
    发明授权
    N-alkoxy-4,4-dioxy-polyalkyl-piperidines as radical polymerization inhibitors 失效
    N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶作为自由基聚合抑制剂

    公开(公告)号：US07235663B2

    公开(公告)日：2007-06-26

    申请号：US10450227

    申请日：2001-11-12

    申请人： Francesco Fuso ,  Wiebke Wunderlich ,  Andreas Kramer ,  Jochen Fink

    发明人： Francesco Fuso ,  Wiebke Wunderlich ,  Andreas Kramer ,  Jochen Fink

    IPC分类号： C07D319/10 ,  C07D323/04 ,  C08F4/00 ,  C08F2/16 ,  C08K5/3492

    CPC分类号： C07D405/12 ,  C07D211/94 ,  C07D491/10 ,  C08F4/00

    摘要： The present invention relates to selected glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiator compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers and the use of glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiators for radical polymerization.

    摘要翻译： 本发明涉及形成开链或环状缩酮结构的选择的缩水甘油基或羰基官能的N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶化合物，可聚合组合物，其包含a）至少一种烯属不饱和单体和b）缩水甘油基 或羰基官能的N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶氮氧根引发剂化合物。 本发明的另外的方面是用于使烯键式不饱和单体聚合的方法和使用缩水甘油基或羰基官能的N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶氮氧根引发剂进行自由基聚合。

    Polymer blends with improved impact resistance
    10.
    发明授权
    Polymer blends with improved impact resistance 失效
    具有改善耐冲击性的聚合物共混物

    公开(公告)号：US06444754B1

    公开(公告)日：2002-09-03

    申请号：US09634441

    申请日：2000-08-08

    申请人： Hui Chin ,  James Botkin ,  Francesco Fuso ,  Wiebke Wunderlich

    发明人： Hui Chin ,  James Botkin ,  Francesco Fuso ,  Wiebke Wunderlich

    IPC分类号： C08L7112

    CPC分类号： C08L77/06 ,  C08L67/00 ,  C08L67/02 ,  C08L71/123 ,  C08L77/00 ,  C08L25/00 ,  C08L2666/02 ,  C08L71/00

    摘要： Polymer blends, in particular polyphenylene ether-polyamide blends, are effectively compatibilized by incorporating under blending conditions certain oligomers, cooligomers, polymers and copolymers of narrow molecular weight distribution that are prepared under free radical polymerization conditions with glycidyl-functionalized nitroxyl initiators. The oligomers, cooligomers, polymers and copolymers contain at least one oxyamine group and at least one glycidyl-containing initiator group. The polymer blends have excellent mechanical properties.

    摘要翻译： 聚合物共混物，特别是聚苯醚 - 聚酰胺共混物通过在共混条件下引入在自由基聚合条件下与缩水甘油基官能化的硝酰基引发剂一起制备的某些低分子量，低​​分子量，窄分子量分布的聚合物和共聚物而有效相容。 低聚物，低聚物，聚合物和共聚物含有至少一个羟胺基团和至少一个含缩水甘油基的引发剂基团。 聚合物共混物具有优异的机械性能。