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公开(公告)号:US4307247A
公开(公告)日:1981-12-22
申请号:US184591
申请日:1980-09-05
IPC分类号: C07C69/533 , B01J27/00 , C07B61/00 , C07C51/00 , C07C51/377 , C07C57/03 , C07C57/05 , C07C67/00 , C07C67/317 , C07C69/54
CPC分类号: C07C51/377
摘要: Saturated, lower aliphatic acids and esters are oxydehydrogenated to the corresponding unsaturated acids and esters by use of a catalyst of the empirical formula:Mo.sub.12 P.sub.0.1-3 Bi.sub.0.01-2 M.sub.0.1-3 Cu.sub.0.01-2 V.sub.0.01-3 X.sub.a M'.sub.b O.sub.c (I)whereM is at least one of K, Rb and Cs;X is at least one of Ba, Zn, Ga, Cd, Ti, when a>0;M' is at least one of Ca, Mg, Ta, Zr, Ce, Ni, Co, Cr, Fe and Tl when b>0;a is a number of 0 to about 2;b is a number of 0 to about 2; andc is a number that satisfies the valence requirements of the other elements present.
摘要翻译: 饱和的低级脂族酸和酯通过使用经验式的催化剂氧化脱氢至相应的不饱和酸和酯:Mo12P0.1-3Bi0.01-2M0.1-3Cu0.01-2V0.01-3XaM'bOc( I)其中M是K,Rb和Cs中的至少一个; 当a> 0时,X是Ba,Zn,Ga,Cd,Ti中的至少一种; 当b> 0时,M'为Ca,Mg,Ta,Zr,Ce,Ni,Co,Cr,Fe和Tl中的至少一种; a是0到2的数; b是0到2的数; 并且c是满足存在的其它元素的化合价要求的数。
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公开(公告)号:US4301030A
公开(公告)日:1981-11-17
申请号:US175235
申请日:1980-08-05
IPC分类号: C07C57/055 , B01J23/76 , B01J27/198 , B01J27/199 , C01B25/45 , C07B61/00 , C07C51/00 , C07C51/235 , C07C51/25 , C07C67/00 , B01J27/14
CPC分类号: B01J23/002 , B01J27/199 , C07C51/252 , B01J2523/00
摘要: Compositions of the empirical formula:Mo.sub.12 P.sub.0.1-3 Bi.sub.0.01-2 M.sub.0.1-3 Cu.sub.0.01-2 V.sub.0.01-3 X.sub.a Y.sub.b O.sub.cwhereM is at least one of K, Rb and Cs;X is at least one of Ba, Zn, Ga, Cd and Ti when a>0;Y is at least one of Ca, Mg, Ta, Zr, Ce, Ni, Co, Cr, Fe and Tl when b>0;a is a number of 0 to about 2;b is a number of 0 to about 2; andc is a number that satisfies the valence requirements of the other elements present,are excellent catalysts for the oxidation of methcrolein to methacrylic acid.
摘要翻译: 经验公式的组成:Mo12P0.1-3Bi0.01-2M0.1-3Cu0.01-2V0.01-3XaYbOc其中M是K,Rb和Cs中的至少一个; 当a> 0时,X是Ba,Zn,Ga,Cd和Ti中的至少一种; 当b> 0时,Y是Ca,Mg,Ta,Zr,Ce,Ni,Co,Cr,Fe和Tl中的至少一种; a是0到2的数; b是0到2的数; 和c是满足存在的其它元素的化合价要求的数字,是将甲基丙烯醛氧化成甲基丙烯酸的优异催化剂。
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公开(公告)号:US4977272A
公开(公告)日:1990-12-11
申请号:US372996
申请日:1989-06-29
申请人: Mark C. Cesa , James E. Rinz , Gilles Klopman , Teodora T. Kopp
发明人: Mark C. Cesa , James E. Rinz , Gilles Klopman , Teodora T. Kopp
IPC分类号: C07C275/40 , C07C275/60 , C07C323/44 , C08F116/12 , C08K5/21 , C08L23/06
CPC分类号: C08K5/21 , C07C275/40 , C07C275/60 , C07C323/44 , C08F116/12 , C08L23/06 , C08L75/02
摘要: This invention relates to new compounds of the formula: ##STR1## where each of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 has zero to 10 C atoms, and no acetylenic unsaturation; each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 is independently selected from H and hydrocarbyl; with the proviso that R.sup.6 is C.sub.1 -C.sub.10 hydrocarbyl; each of R.sup.5 and R.sup.7 is independently selected from H, hydrocarbyl and hydrocarbyl substituted with a group selected from:hydrocarbylcarbonylamino, di(hydrocarbylcarbonyl)amino, N-hydrocarbylcarbonyl(N-hydrocarbyl)amino, formylamino, diformylamino, and formyl(N-hydrocarbyl)amino, hydrocarbyloxy, hydrocarbylthio, formyl, formylthio, hydrocarbylcarbonyloxy, hydrocarbylcarbonylthio, hydrocarbyl carboxyl, hydrocarbyl thiocarboxyl, hydrocarbylamino, dihydrocarbylamino, hydrocarbylcarbonyl, 3-indolyl, 3-(1-hydrocarbyl)indolyl, 3-(1-hydrocarbylcarbonyl)indolyl, 3-(1-formyl)indolyl, carbamoyl, hydrocarbylcarbamoyl, dihydrocarbylcarbamoyl, 5-imidazolyl, 5-(3-hydrocarbyl)imidazolyl, 5-(3-hydrocarbylcarbonyl)imidazolyl, and 5-(3-formyl)imidazolyl; and where at least one of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 contains olefinic unsaturation. The invention also relates to addition polymers of such compounds.
摘要翻译: 本发明涉及下式的新化合物:其中R 1,R 2,R 3,R 4,R 5,R 6和R 7各自具有0至10个C原子,且不具有炔属不饱和度; R1,R2,R3和R4各自独立地选自H和烃基; 条件是R6为C1-C10烃基; R 5和R 7各自独立地选自H,烃基和被选自以下的基团取代的烃基:烃基羰基氨基,二(烃基羰基)氨基,N-烃基羰基(N-烃基)氨基,甲酰氨基,二酰基氨基和甲酰基(N-烃基) 氨基,烃氧基,烃基硫代,甲酰基,甲酰硫基,烃基羰基氧基,烃基羰基硫代,烃基羧基,烃基硫代羧基,烃基氨基,二烃基氨基,烃基羰基,3-吲哚基,3-(1-烃基)吲哚基,3-(1-烃基羰基)吲哚基, (1-甲酰基)吲哚基,氨基甲酰基,烃基氨基甲酰基,二烃基氨基甲酰基,5-咪唑基,5-(3-烃基)咪唑基,5-(3-烃基羰基)咪唑基和5-(3-甲酰基)咪唑基; 并且其中R 1,R 2,R 3,R 4,R 5,R 6和R 7中的至少一个包含烯属不饱和键。 本发明还涉及这些化合物的加成聚合物。
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4.
公开(公告)号:US5854317A
公开(公告)日:1998-12-29
申请号:US769454
申请日:1996-12-18
申请人: James E. Rinz
发明人: James E. Rinz
IPC分类号: C08G85/00 , C08F8/30 , C08G59/40 , C08G59/50 , C08G73/16 , C08L63/10 , C08L79/08 , C08K5/3412 , C08K3/22 , C08L67/06
CPC分类号: C08L79/08 , C08F8/30 , C08G59/4014 , C08G59/5066 , C08G73/16 , C08L63/10
摘要: This invention relates to a process for making a thickened thermoset resin composition, comprising: mixing (A) a carboxylic acid containing thermoset resin composition; and (B) at least one compound represented by the formula ##STR1## wherein in Formula (B-I): R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or methyl; R.sup.5 is hydrogen, a hydrocarbon group or a substituted hydrocarbon group, the substituents on said substituted hydrocarbon group comprising oxygen and/or nitrogen; and n is at least 1.
摘要翻译: 本发明涉及一种制备增稠的热固性树脂组合物的方法,包括:(A)含羧酸的热固性树脂组合物; (B-1)表示的至少一种化合物,其中在式(B-I)中:R 1,R 2,R 3和R 4独立地为氢或甲基; R5是氢,烃基或取代烃基,所述取代烃基上的取代基包括氧和/或氮; 且n至少为1。
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5.
公开(公告)号:US6040391A
公开(公告)日:2000-03-21
申请号:US141931
申请日:1998-08-28
申请人: James E. Rinz
发明人: James E. Rinz
IPC分类号: C08G85/00 , C08F8/30 , C08G59/40 , C08G59/50 , C08G73/16 , C08L63/10 , C08L79/08 , C08C19/22 , C08F8/32 , C08L63/00
CPC分类号: C08L79/08 , C08F8/30 , C08G59/4014 , C08G59/5066 , C08G73/16 , C08L63/10
摘要: This invention relates to a process for making a thickened thermoset resin composition, comprising: mixing(A) a carboxylic acid containing thermoset resin composition; and(B) at least one compound represented by the formula ##STR1## wherein in Formula (B-I): R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or methyl; R.sup.5 is hydrogen, a hydrocarbon group or a substituted hydrocarbon group, the substituents on said substituted hydrocarbon group comprising oxygen and/or nitrogen; and n is at least 1.
摘要翻译: 本发明涉及一种制备增稠的热固性树脂组合物的方法,包括:(A)含羧酸的热固性树脂组合物; 和(B)至少一种由下式表示的化合物其中在式(B-I)中:R 1,R 2,R 3和R 4独立地为氢或甲基; R5是氢,烃基或取代烃基,所述取代烃基上的取代基包括氧和/或氮; 且n至少为1。
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公开(公告)号:US4868061A
公开(公告)日:1989-09-19
申请号:US195934
申请日:1988-05-19
申请人: Mark C. Cesa , James E. Rinz , Teodora T. Kopp
发明人: Mark C. Cesa , James E. Rinz , Teodora T. Kopp
IPC分类号: C07D233/72 , C07D403/04 , C08K5/3445 , C08L23/02
CPC分类号: C07D403/04 , C07D233/72 , C08K5/3445 , C08L23/02 , C08L23/06
摘要: This invention relates to new compounds of the formula: ##STR1## where each of R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 has zero to 10 C atoms, and no acetylenic unsaturation; each of R.sup.1, R.sup.2 and R.sup.3 is independently selected from H and hydrocarbyl; each of R.sup.4 and R.sup.5 is independently selected from H, hydrocarbyl and hydrocarbyl substituted with a group selected from:hydrocarbylcarbonylamino, di(hydrocarbylcarbonyl)amino, N-hydrocarbylcarbonyl(N-hydrocarbyl)amino, formylamino, diformylamino, and formyl(N-hydrocarbyl)amino, hydrocarbyloxy, hydrocarbylthio, formyl, formylthio, hydrocarbylcarbonyloxy, hydrocarbylcarbonylthio, hydrocarbyl carboxyl, hydrocarbyl thiocarboxyl, hydrocarbylamino, dihydrocarbylamino, hydrocarbylcarbonyl, 3-indolyl, 3-(1-hydrocarbyl)indolyl, 3-(1-hydrocarbylcarbonyl)indolyl, 3-(1-formyl)indolyl, carbamoyl, hydrocarbylcarbamoyl, dihydrocarbylcarbamoyl, 5-imidazolyl, 5-(3-hydrocarbyl)imidazolyl, 5-(3-hydrocarbylcarbonyl)imidazolyl, and 5-(3-formyl)imidazolyl,and where at least one of R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 contains olefinic unsaturation. The invention also relates to addition polymers of such compounds.
摘要翻译: 本发明涉及下式的新化合物:其中R 1,R 2,R 3,R 4和R 5各自具有0至10个C原子,且不具有炔属不饱和度; R 1,R 2和R 3各自独立地选自H和烃基; R 4和R 5各自独立地选自H,烃基和烃基,其被选自:烃基羰基氨基,二(烃基羰基)氨基,N-烃基羰基(N-烃基)氨基,甲酰氨基,二酰基氨基和甲酰基(N-烃基) 氨基,烃氧基,烃基硫代,甲酰基,甲酰硫基,烃基羰基氧基,烃基羰基硫代,烃基羧基,烃基硫代羧基,烃基氨基,二烃基氨基,烃基羰基,3-吲哚基,3-(1-烃基)吲哚基,3-(1-烃基羰基)吲哚基, (1-甲酰基)吲哚基,氨基甲酰基,烃基氨基甲酰基,二烃基氨基甲酰基,5-咪唑基,5-(3-烃基)咪唑基,5-(3-烃基羰基)咪唑基和5-(3-甲酰基)咪唑基, R1,R2,R3,R4和R5含有烯属不饱和键。 本发明还涉及这些化合物的加成聚合物。
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公开(公告)号:US4740611A
公开(公告)日:1988-04-26
申请号:US924717
申请日:1986-10-30
申请人: Mark C. Cesa , James E. Rinz , Gilles Klopman , Teodora T. Kopp
发明人: Mark C. Cesa , James E. Rinz , Gilles Klopman , Teodora T. Kopp
IPC分类号: C07C275/40 , C07C127/19
CPC分类号: C07C275/40
摘要: Disclosed are new compounds ##STR1## where each of R and R' have zero to 10 C atoms; R is H or hydrocarbyl; R' is H, hydrocarbyl, or hydrocarbyl substituted with hydrocarbylcarbonylamino, di(hydrocarbylcarbonyl)amino, hydrocarbylcarbonyl(hydrocarbyl)amino, formylamino, diformylamino and formyl(hydrocarbyl)amino, hydrocarbyloxy, hydrocarbylthio, formylthio, hydrocarbylcarbonylthio, hydrocarbyloxycarbonyl, hydrocarbyl carboxyl, hydrocarbylamino, dihydrocarbylamino, formyl, 3-indolyl, 3-(1-hydrocarbyl)indolyl, 3-(1-hydrocarbylcarbonyl)indolyl, 3-(1-formyl)indolyl, carbamoyl, hydrocarbylcarbamoyl, dihydrocarbylcarbamoyl, 5-imidazolyl, 5-(3-hydrocarbyl)imidazolyl, 5-(3-hydrocarbylcarbonyl)imidazolyl, or 5-(3-formyl)imidazolyl, and R" is phenyl or a C.sub.1 to C.sub.6 alkyl group; and methods of making such compounds.
摘要翻译: 公开了新化合物“IMAGE”,其中R和R'各自具有0-10个C原子; R是H或烃基; (烃基)氨基,烃基羰基(烃基)氨基,甲酰氨基,二酰基氨基和甲酰基(烃基)氨基,烃氧基,烃基硫代,甲酰硫基,烃基羰基硫基,烃氧基羰基,烃基羧基,烃基氨基, 3-(1-烃基)吲哚基,3-(1-烃基羰基)吲哚基,3-(1-甲酰基)吲哚基,氨基甲酰基,烃基氨基甲酰基,二烃基氨基甲酰基,5-咪唑基,5-(3- 烃基)咪唑基,5-(3-烃基羰基)咪唑基或5-(3-甲酰基)咪唑基,R“为苯基或C1至C6烷基; 以及制备这些化合物的方法。
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公开(公告)号:US4705864A
公开(公告)日:1987-11-10
申请号:US928770
申请日:1986-11-10
申请人: Mark C. Cesa , James E. Rinz , Teodora T. Kopp
发明人: Mark C. Cesa , James E. Rinz , Teodora T. Kopp
IPC分类号: C07D233/76 , C07D403/04 , C07D233/78
CPC分类号: C07D403/04 , C07D233/76
摘要: A compound of the formula ##STR1## useful as an ultraviolet light absorber where each of R and R' has zero to 10 C atoms and no ethylenic or acetylenic unsaturation; R is H or hydrocarbyl; R' is H, hydrocarbyl, or hydrocarbyl substituted with hydrocarbylcarbonylamino, dithydrocarbylcarbonyl)amino, hydrocarbylcarbonyl(hydrocarbyl)amino, formylamino, diformylamino and formyl(hydrocarbyl)amino, hydrocarbyloxy, hydrocarbylthio, formylthio, hydrocarbylcarbonylthio, hydrocarbyloxycarbonyl, hydrocarbyl carboxyl, hydrocarbylamino, dihydrocarbylamino, formyl, 3-indolyl, 3-(1-hydrocarbyl)indolyl, 3-(1-hydrocarbylcarbonyl)indolyl, 3-(1-formyl)indolyl, carbamoyl, hydrocarbylcarbamoyl, dihydrocarbylcarbamoyl, 5-imidazolyl, 5-(3-hydrocarbyl)imidazolyl, 5-(3-hydrocarbylcarbonyl)imidazolyl, or 5-(3-formyl)imidazolyl.
摘要翻译: 用作紫外光吸收剂的式“IMAGE”的化合物,其中R和R'各自具有0-10个碳原子,没有烯属或炔属不饱和键; R是H或烃基; (烃基)氨基,甲酰氨基,二酰基氨基和甲酰基(烃基)氨基,烃氧基,烃基硫代,甲酰硫基,烃基羰基硫基,烃氧基羰基,烃基羧基,烃基氨基,二烃基氨基, 3-(1-烃基)吲哚基,3-(1-烃基羰基)吲哚基,3-(1-甲酰基)吲哚基,氨基甲酰基,烃基氨基甲酰基,二烃基氨基甲酰基,5-咪唑基,5-(3-烃基) 咪唑基,5-(3-烃基羰基)咪唑基或5-(3-甲酰基)咪唑基。
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