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1.发明授权Polyquaternary ammonium compounds, their preparation, their use in the production of paper and paper treatment agents containing them 失效聚季铵化合物，其制备方法，用于生产包含它们的纸张和纸张处理剂
公开(公告)号：US4423194A
公开(公告)日：1983-12-27
申请号：US410744
申请日：1982-08-23
申请人： Wilfried Lobach , Peter Haas , Gunter Kolb , Guter Sackmann , Joachim Probst
发明人： Wilfried Lobach , Peter Haas , Gunter Kolb , Guter Sackmann , Joachim Probst
CPC分类号： C08F8/44
摘要： The present invention relates to new water-soluble polyquaternary compounds which are obtained by imidation of (A) specific alternating copolymers of maleic anhydride and olefines with (B) specific amines and (C) subsequent alkylation of the reaction product AB, the components (A) and (B) having the meaning given in the text of the Application. The invention furthermore relates to a process for the preparation of these water-soluble polyammonium compounds and their use as agents for improving the wet and dry tear strength of paper. The invention also relates to new intermediate products for the preparation of the compounds according to the invention.
摘要翻译： 本发明涉及通过（A）马来酸酐和烯烃与（B）特定胺的特定交替共聚物的酰亚胺化和（C）随后的反应产物AB，组分（A）的烷基化而得到的新的水溶性聚季铵化合物 ）和（B）具有本申请文本中给出的含义。 本发明还涉及一种制备这些水溶性多铵化合物的方法及其用作改善纸的湿和干撕裂强度的试剂。 本发明还涉及用于制备本发明化合物的新的中间产物。
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公开(公告)号：US4348514A
公开(公告)日：1982-09-07
申请号：US156832
申请日：1980-06-05
申请人： Wilfried Lobach , Gunter Kolb , Wolfgang Lehmann , Gunther Cramm , Friedhelm Muller , Janos Muszik
发明人： Wilfried Lobach , Gunter Kolb , Wolfgang Lehmann , Gunther Cramm , Friedhelm Muller , Janos Muszik
CPC分类号： D21H17/56 , C08G73/0206
摘要： Non-crosslinking, water-soluble polyamines which can be obtained by reacting(A) basic polyureas which have been prepared by condensation of ureas with polyamines containing at least three amino groups, of which at least one is a tertiary amino group, or with mixtures of these polyamines with aliphatic, araliphatic, cycloaliphatic or heterocyclic polyamines containing two primary or two secondary amino groups or one primary or one secondary amino group, and optionally with .omega.-aminocarboxylic acids containing at least three carbon atoms, or lactams thereof,(B) polyalkylenepolyamines of the general formula ##STR1## in which R denotes H or CH.sub.3, the indices y are in each case identical or different and denote the number 0 or 1 andx denotes a number from 4 to 2,500,or mixtures of these polyalkylenepolyamines with amines of the same general formula, but in whichx denotes a number from 1 to 3, and(C) compounds which are polyfunctional towards amino groups, are used as agents for increasing the retention of fibres, fillers and pigments, for accelerating the drainage in the production of paper and for working up effluents from paper machines by filtration, sedimentation and flotation.
摘要翻译： 非交联性水溶性多胺，其可以通过使（A）通过脲与缩醛反应制备的碱性聚脲与至少三个氨基的多胺（其中至少一个是叔氨基）或与混合物 这些多胺与含有两个伯或仲仲氨基或一个伯或仲仲氨基以及任选含有至少三个碳原子的ω-氨基羧酸或其内酰胺的脂族，芳脂族，脂环族或杂环多胺，（B） 通式为“IMAGE”的聚亚烷基多胺，其中R表示H或CH 3，指数y在各自的情况下相同或不同，表示数字0或1，x表示4至2,500的数，或这些聚亚烷基多胺与胺的混合物 具有相同的通式，但其中x表示1至3的数，和（C）对于氨基具有多官能性的化合物，用作增加剂 考虑到纤维，填料和颜料的保留，用于加速纸张生产中的排水和通过过滤，沉淀和浮选处理造纸机的废水。
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3.发明授权Polyamines containing urea groups prepared from lactam or aminocarboxylic acid 失效含有由内酰胺或氨基羧酸制备的尿素基团的多胺
公开(公告)号：US4384110A
公开(公告)日：1983-05-17
申请号：US358406
申请日：1982-03-15
申请人： Wilfried Lobach , Gunter Kolb , Wolfgang Lehmann , Gunther Cramm , Friedhelm Muller , Janos Muszik
发明人： Wilfried Lobach , Gunter Kolb , Wolfgang Lehmann , Gunther Cramm , Friedhelm Muller , Janos Muszik
CPC分类号： D21H17/56 , C08G73/0206
摘要： Non-crosslinking, water-soluble polyamines which can be obtained by reacting(A) basic polyureas which have been prepared by condensation of ureas with polyamines containing at least three amino groups, of which at least one is a tertiary amino group, or with mixtures of these polyamines with aliphatic, araliphatic, cycloaliphatic or heterocyclic polyamines containing two primary or two secondary amino groups or one primary or one secondary amino group, and optionally with .omega.-aminocarboxylic acids containing at least three carbon atoms, or lactams thereof,(B) polyalkylenepolyamines of the general formula ##STR1## in which R denotes H or CH.sub.3,the indices y are in each case identical or different and denote the number 0 or 1 andx denotes a number from 4 to 2,500, or mixtures of these polyalkylenepolyamines with amines of the same general formula, but in whichx denotes a number from 1 to 3, and(C) compounds which are polyfunctional towards amino groups, are used as agents for increasing the retention of fibres, fillers and pigments, for accelerating the drainage in the production of paper and for working up effluents from paper machines by filtration, sedimentation and flotation.
摘要翻译： 非交联性水溶性多胺，其可以通过使（A）通过脲与缩醛反应制备的碱性聚脲与至少三个氨基的多胺（其中至少一个是叔氨基）或与混合物 这些多胺与含有两个伯或仲仲氨基或一个伯或仲仲氨基以及任选含有至少三个碳原子的ω-氨基羧酸或其内酰胺的脂族，芳脂族，脂环族或杂环多胺，（B） 通式为“IMAGE”的聚亚烷基多胺，其中R表示H或CH 3，指数y在各自的情况下相同或不同，表示数字0或1，x表示4至2,500的数，或这些聚亚烷基多胺与胺的混合物 具有相同的通式，但其中x表示1至3的数，和（C）对于氨基具有多官能性的化合物，用作增加剂 考虑到纤维，填料和颜料的保留，用于加速纸张生产中的排水和通过过滤，沉淀和浮选处理造纸机的废水。
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公开(公告)号：US4250299A
公开(公告)日：1981-02-10
申请号：US969822
申请日：1978-12-15
CPC分类号： C08G69/48 , C08G73/0206 , C08G73/028 , D21H17/55
摘要： Water-soluble polyamines which are obtainable by reacting(A) one or more water-soluble or water-dispersible basic polyamides which have been prepared by condensation of aliphatic polyamines containing at least two primary amino groups and at least one secondary or tertiary amino group, or of mixtures of these polyamines and of aliphatic, cycloaliphatic, araliphatic or heterocyclic polyamines containing two primary or two secondary amino groups or one primary and one secondary amino group, with saturated aliphatic dicarboxylic acids containing 4-10 carbon atoms, or with functional derivatives thereof and optionally with .omega.-aminocarboxylic acids containing at least 3 carbon atoms, or lactams thereof,(B) one or more polyalkylenepolyamines of the general formula ##STR1## in which R denotes H or CH.sub.3,y is in each case the same or different and denotes the number 0 or 1 andx denotes a number from 4 to 2,500, or mixtures of these polyalkylenepolyamines with amines of the same general formula, but in whichX denotes a number from 1 to 3, and(C) compounds which are polyfunctional towards amino groups, are suitable as agents for increasing the retention of fibres, fillers and pigments, for accelerating drainage during the production of paper and for working up effluents from paper machines.
摘要翻译： 可通过使（A）一种或多种水溶性或水分散性碱性聚酰胺反应获得的水溶性多胺，其通过含有至少两个伯氨基和至少一个仲或叔氨基的脂族多胺的缩合制备， 或这些多胺和含有两个伯或仲仲氨基或一个伯和一个仲氨基的脂族，脂环族，芳脂族或杂环多胺与含有4-10个碳原子的饱和脂族二羧酸或其官能衍生物的混合物 和任选地含有至少3个碳原子的ω-氨基羧酸或其内酰胺，（B）一种或多种通式为“IMAGE”的聚亚烷基多胺，其中R表示H或CH 3，y各自相同或不同， 表示数字0或1，x表示4至2,500的数字，或这些聚亚烷基多胺与相同通用形式的胺的混合物 但是其中X表示1至3的数字，和（C）对氨基具有多官能性的化合物，可适用于增加纤维，填料和颜料的保留作用，用于在纸张生产过程中加速排水， 用于处理造纸机的污水。
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公开(公告)号：US4250298A
公开(公告)日：1981-02-10
申请号：US969820
申请日：1978-12-15
IPC分类号： C08G69/00 , C08G69/26 , C08G69/36 , C08G69/48 , C08G73/00 , C08G73/02 , D21H17/55 , D21H17/56
CPC分类号： C08G73/0206 , C08G69/48 , D21H17/55
摘要： Water-soluble amines which are not self-crosslinking and are obtainable by reacting(A) one or more water-soluble or water-dispersable amines containing amide groups, prepared by condensation of (a) 1 mol of dicarboxylic acid or functional derivatives thereof, (b) 0 to 30 mols of aminocarboxylic acids containing at least three C atoms, or lactams thereof, and (c) 1.4 to 30 mols of polyalkylenepolyamines of the general formula ##STR1## in which R denotes H or CH.sub.3,y is in each case the same or different and denotes the number 0 or 1 andx denotes a number from 4 to 15,and(B) compounds which are polyfunctional towards amino groups, are suitable as agents for increasing the retention of fibres, fillers and pigments, for accelerating drainage during the production of paper and for working up effluents from paper machines.
摘要翻译： 不是自交联的水溶性胺，可通过使（A）一种或多种含有酰胺基团的水溶性或水分散性胺（a）1mol二羧酸或其官能衍生物 （b）0至30摩尔含有至少3个C原子的氨基羧酸或其内酰胺，和（c）1.4至30摩尔的通式为“IMAGE”的聚亚烷基多胺，其中R表示H或CH3，y分别表示 情况相同或不同，表示数字0或1，x表示4至15的数字，和（B）对氨基具有多官能团的化合物适合作为增加纤维，填料和颜料保留的试剂，用于 在纸张生产过程中加速排水，并从造纸机处理废水。
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公开(公告)号：US4250112A
公开(公告)日：1981-02-10
申请号：US037007
申请日：1979-05-08
CPC分类号： D21H17/54 , C08G73/0206 , Y10S210/928
摘要： Water-soluble polyalkylenepolyamines which are not self-crosslinking and contain quaternary dialkylammonium groups, and which are obtained by reaction of polyalkylenepolyamines of the general formula ##STR1## in which R denotes hydrogen or methyl,y denotes the number 0 or 1 and the y's may be identical or different andx denotes a number from 2 to 15,with bifunctional compounds of the general formula ##STR2## in which z denotes a number from 1 to 6 andR.sub.1 and R.sub.2 denote lower alkyl or lower hydroxyalkyl, are suitable for use as auxiliaries in the manufacture of paper.
摘要翻译： 不是自交联并含有季二烷基铵基团的水溶性聚亚烷基多胺，其通过通式（IMAGE）的聚亚烷基多胺反应得到，其中R表示氢或甲基，y表示数字0或1，y可以 相同或不同，x表示2至15的数，具有通式“IMAGE”的双官能化合物，其中z表示1至6的数，R1和R2表示低级烷基或低级羟烷基，适用于 助剂在纸的制造。
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7.发明授权Aqueous reaction of polyamine with alkylene dihalide in presence of emulsifier 失效乳化剂存在下多胺与亚烷基二卤化物的水反应
公开(公告)号：US4254255A
公开(公告)日：1981-03-03
申请号：US4803
申请日：1979-01-19
IPC分类号： B01D21/01 , B01D37/02 , C08G69/00 , C08G73/00 , C08G73/02 , D21F1/82 , D21H17/54 , D21H17/56 , C08G69/48
CPC分类号： D21H17/54 , C08G73/0206 , C08G73/028
摘要： Water-soluble condensation products which are not self-crosslinking and are prepared from polyacidic amines and compounds which are polyfunctional towards amino groups, in an aqueous medium at temperatures from 0.degree. to 120.degree. C. and pH values above 6 in the presence of emulsifiers are used in the production of paper.
摘要翻译： 在水性介质中，在0〜120℃的温度下，在乳化剂存在下，pH值大于6时，不自交联并由多胺和多氨基官能化合物制得的水溶性缩合产物 用于生产纸张。
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公开(公告)号：US4319019A
公开(公告)日：1982-03-09
申请号：US167879
申请日：1980-07-14
CPC分类号： C08G69/48 , C08G73/0206 , C08G73/028 , D21H17/55
摘要： Water-soluble polyamines which are obtainable by reacting(A) one or more water-soluble or water-dispersible basic polyamides which have been prepared by condensation of aliphatic polyamines containing at least two primary amino groups and at least one secondary or tertiary amino group, or of mixtures of these polyamines and of aliphatic, cycloaliphatic, araliphatic or heterocyclic polyamines containing two primary or two secondary amino groups or one primary and one secondary amino group, with saturated aliphatic dicarboxylic acids containing 4-10 carbon atoms, or with functional derivatives thereof and optionally with .omega.-aminocarboxylic acids containing at least 3 carbon atoms, or lactams thereof,(B) one or more polyalkylenepolyamines of the general formula ##STR1## in which R denotes H or CH.sub.3,y is in each case the same or different and denotes the number 0 or 1 andx denotes a number from 4 to 2,500, or mixtures of these polyalkylenepolyamines with amines of the same general formula, but in whichX denotes a number from 1 to 3, and(C) compounds which are polyfunctional towards amino groups, are suitable as agents for increasing the retention of fibres, fillers and pigments, for accelerating drainage during the production of paper and for working up effluents from paper machines.
摘要翻译： 可通过使（A）一种或多种水溶性或水分散性碱性聚酰胺反应获得的水溶性多胺，其通过含有至少两个伯氨基和至少一个仲或叔氨基的脂族多胺的缩合制备， 或这些多胺和含有两个伯或仲仲氨基或一个伯和一个仲氨基的脂族，脂环族，芳脂族或杂环多胺与含有4-10个碳原子的饱和脂族二羧酸或其官能衍生物的混合物 和任选地含有至少3个碳原子的ω-氨基羧酸或其内酰胺，（B）一种或多种通式为“IMAGE”的聚亚烷基多胺，其中R表示H或CH 3，y各自相同或不同， 表示数字0或1，x表示4至2,500的数字，或这些聚亚烷基多胺与相同通用形式的胺的混合物 但是其中X表示1至3的数字，和（C）对氨基具有多官能性的化合物，可适用于增加纤维，填料和颜料的保留作用，用于在纸张生产过程中加速排水， 用于处理造纸机的污水。
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