Electroconductive coatings having excellent coating holdout properties
    3.
    发明授权
    Electroconductive coatings having excellent coating holdout properties 失效
    具有优异涂层保持性能的导电涂层

    公开(公告)号:US4007148A

    公开(公告)日:1977-02-08

    申请号:US534384

    申请日:1974-12-19

    摘要: An electroconductive composition useful for coating raw paper stock is provided by combining (1) an electroconductive resin, e.g., poly(vinyl/benzyl trimethyl ammonium chloride) and (2) a water-swellable, cross-linked polymer, e.g., crosslinked polyacrylamide, in the form of discrete particles having swollen diameters in the range from about 1 to about 100 micrometers. Application of this electroconductive coating composition to paper or to some other nonconductive substrate yields an article having decreased surface electrical resistivity and increased organic solvent resistance or holdout. Solvent resistance and other coating properties are further enhanced by including in the electroconductive composition a water-dispersible, film-forming amide polymer and a low viscosity binder such as a latex of styrene/butadiene copolymer.

    摘要翻译: 通过组合(1)导电树脂,例如聚(乙烯基/苄基三甲基氯化铵)和(2)水溶胀性交联聚合物,例如交联的聚丙烯酰胺,提供用于涂布原纸的导电组合物, 其形式为具有在约1至约100微米范围内的溶胀直径的离散颗粒。 将这种导电涂料组合物应用于纸或某些其它不导电的基材产生具有降低的表面电阻率和增加的有机溶剂阻力或粘附性的制品。 通过在导电组合物中包含水分散性成膜酰胺聚合物和低粘度粘合剂如苯乙烯/丁二烯共聚物的胶乳,进一步提高了耐溶剂性和其它涂层性能。

    Fountain compositions for use in lithographic printing comprising
aqueous solutions of polyacrylamide based polymers and blends of
polyacrylamide and polyacrylic acid with an organic chelating agent
    4.
    发明授权
    Fountain compositions for use in lithographic printing comprising aqueous solutions of polyacrylamide based polymers and blends of polyacrylamide and polyacrylic acid with an organic chelating agent 失效
    用于平版印刷的喷射组合物包括聚丙烯酰胺基聚合物的水溶液和聚丙烯酰胺和聚丙烯酸与有机螯合剂的共混物

    公开(公告)号:US4116896A

    公开(公告)日:1978-09-26

    申请号:US727825

    申请日:1976-09-29

    CPC分类号: B41N3/08

    摘要: Precipitation at relatively high pH levels, e.g. above about 4 or more, in an acidic water/alcohol type fountain composition containing polyvalent metal cations and, as an active polymer component for rendering the non-image areas of a lithographic plate hydrophilic, a polyacrylamide-based polymer having a weight average molecular weight (M.sub.w) of from about 5,000 to about 1,000,000 and having from about 3 to about 70 percent of the carbonyl sites as carboxyl groups, or a blend of polyacrylamide and polyacrylic acid, or the like, is controlled by providing in the fountain composition an effective amount of an organic chelating agent for polyvalent metal cations which is substantially inert with respect to the active polymer component. The suitable chelating agents are further characterized in that at 25.degree. C, each (A) has a 1:1 stability constant with zinc of at least about 10.sup.7.5 ; (B) has a solubility of at least about 0.001 moles per liter in the water/alcohol solvent system over the pH range of from about 3 to about 7; and (C) when in a stable complexed form with polyvalent metal cation(s), has a solubility of at least about 0.001 moles per liter in the water/alcohol solvent system over the pH range of from about 3 to about 7. A preferred chelating agent is the pentasodium salt of diethylenetriaminepentaacetic acid.

    摘要翻译: 在相对较高的pH值下析出,例如 在含有多价金属阳离子的酸性水/醇型润版液组合物中的约4以上,作为使平版印刷版的非图像区亲水性的活性聚合物组分,具有重均分子量的聚丙烯酰胺类聚合物 通过在喷泉组合物中提供有效的(Mw)为约5,000至约1,000,000并且具有约3-约70%的作为羧基的羰基位点或聚丙烯酰胺和聚丙烯酸的共混物等, 相对于活性聚合物组分基本上是惰性的多价金属阳离子的有机螯合剂的量。 合适的螯合剂的特征还在于,在25℃下,每个(A)的锌稳定常数为1:1至少约为107.5; (B)在约3至约7的pH范围内在水/醇溶剂体系中具有至少约0.001摩尔/升的溶解度; 和(C)当以多价金属阳离子稳定复合形式时,在约3至约7的pH范围内,在水/醇溶剂体系中溶解度至少约为0.001摩尔/升。优选的 螯合剂是二亚乙基三胺五乙酸的五钠盐。