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公开(公告)号：US5331101A
公开(公告)日：1994-07-19
申请号：US461600
申请日：1990-01-05
IPC分类号： B01J23/75 , B01J23/76 , B01J23/83 , C07B61/00 , C07C209/16 , C07C209/24 , C07C213/02 , C07C217/08 , C07C209/14
CPC分类号： B01J23/75 , B01J23/83 , C07C209/16 , C07C209/24
摘要： A process for preparing amines or imines which comprises contacting an alcohol, aldehyde, or ketone with an aminating agent in the presence of a catalyst under reaction conditions sufficient to form an amine or imine, wherein the catalyst comprises a homogeneous mixture of (a) 10-90 mole percent cobalt or an insoluble salt thereof, (b) 9-89 mole percent copper or an insoluble salt thereof, and (c) 1-20 mole percent of a metal or insoluble salt of a metal selected from the group consisting of a Lanthanum series metal, thorium, uranium, scandium, titanium, and yttrium is described. A process which employs zirconium as component (c) and which is supported on a carrier material, wherein the carrier material has been neutralized with a base, is also disclosed.
摘要翻译： 一种制备胺或亚胺的方法，其包括在足以形成胺或亚胺的反应条件下，在催化剂存在下使醇，醛或酮与胺化剂接触，其中所述催化剂包含（a）10 -90摩尔％的钴或其不溶性盐，（b）9-89摩尔％的铜或其不溶性盐，和（c）1-20摩尔％的选自以下的金属的金属或不溶性盐： 描述了镧系金属，钍，铀，钪，钛和钇。 还公开了使用锆作为组分（c）并负载在载体材料上的方法，其中载体材料已经用碱中和。
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公开(公告)号：US4668347A
公开(公告)日：1987-05-26
申请号：US804721
申请日：1985-12-05
CPC分类号： C25D11/30 , C25D11/02 , C25D11/026
摘要： Metals and alloys of metals which have the property of electrolytic rectification can be coated with an anticorrosive coating by immersion in a strongly alkaline aqueous bath comprising a water soluble fluoride, a water soluble iron salt, and mixtures thereof by the application of a sufficiently high voltage to obtain spark discharge at the surface to be coated, said potential being applied between the metal or alloy to be coated utilized as an anode and a cathode immersed in the aqueous bath. A durable coating is thereby applied to the surface of said metals or alloys thereof which is resistant to a corrosive salt spray environment.
摘要翻译： 具有电解精馏性质的金属和金属合金可以通过浸渍在包含水溶性氟化物，水溶性铁盐及其混合物的强碱性水浴中的防腐涂层上，通过施加足够高的电压 在待涂覆的表面上获得火花放电，所述电位施加在用作阳极的待涂覆的金属或合金和浸在水浴中的阴极之间。 因此，耐久性涂层施加到耐腐蚀性盐雾环境的金属或其合金的表面上。
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公开(公告)号：USRE31430E
公开(公告)日：1983-10-25
申请号：US238712
申请日：1981-02-26
摘要： Copper, copper oxide, copper-chromium oxide, copper-molybdenum oxide or mixtures thereof have been found to be excellent heterogeneous catalysts for the conversion of nitriles in the presence of water to the corresponding amides. Using one such catalyst in a continuous flow reactor, acrylonitrile was almost 100% converted to acrylamide during more than six weeks of continuous operation.
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4.发明授权Method of producing amines from alcohols, aldehydes, ketones and mixtures thereof 失效从醇，醛，酮及其混合物制备胺的方法
公开(公告)号：US4153581A
公开(公告)日：1979-05-08
申请号：US829758
申请日：1977-09-01
IPC分类号： C07B61/00 , B01J23/00 , B01J23/75 , B01J23/755 , B01J23/80 , B01J37/03 , C07C67/00 , C07C209/00 , C07C209/16 , C07C209/26 , B01J23/40 , B01J23/74
CPC分类号： B01J23/755 , B01J23/75 , B01J23/80 , C07C209/16 , B01J37/03
摘要： A method of producing amines, the method comprising contacting at reactive conditions at least one alcohol, aldehyde or ketone, or a mixture thereof, with an aminating agent in the presence of a catalyst, is improved by employing as the catalyst a composition comprising cobalt, copper and a third component selected from the group consisting of iron, zinc, zirconium and mixtures thereof. For example, polypropylene glycol is quantitatively aminated by contacting it with ammonia at about 175.degree. C. and in the presence of a catalyst comprising (metal basis) 30 mole percent cobalt, 63 mole percent copper and about 7 mole percent iron.
摘要翻译： 一种生产胺的方法，包括在反应条件下使至少一种醇，醛或酮或其混合物与胺化剂在催化剂存在下接触的方法通过使用包含钴， 铜和选自铁，锌，锆及其混合物的第三组分。 例如，聚丙二醇通过在约175℃下和在含有（金属基准）30摩尔％钴，63摩尔％铜和约7摩尔％铁的催化剂存在下与氨进行定量胺化。
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公开(公告)号：US3994973A
公开(公告)日：1976-11-30
申请号：US157647
申请日：1971-06-28
CPC分类号： B01J37/16 , B01J23/24 , B01J23/26 , B01J23/72 , B01J23/85 , B01J23/86 , B01J23/868 , B01J23/885
摘要： Cupreous catalysts containing (a) copper prepared by reducing copper oxide, (b) reduced copper oxide, or (c) copper oxide have been found to be excellent heterogeneous catalysts for the conversion of nitriles in the presence of water to the corresponding amides. High conversions and yields are obtained with little or no deleterious by-products.
摘要翻译： 已经发现含有（a）通过还原氧化铜制备的铜，（b）还原氧化铜或（c）氧化铜）的铜催化剂是用于在水存在下将腈转化为相应酰胺的极好的非均相催化剂。 通过很少或没有有害的副产物获得高转化率和产率。
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公开(公告)号：US4772750A
公开(公告)日：1988-09-20
申请号：US914960
申请日：1986-10-03
IPC分类号： B01J23/75 , B01J23/80 , B01J23/86 , B01J23/889 , B01J37/02 , C07C209/16 , C07C85/08 , C07C85/04
CPC分类号： B01J37/023 , B01J23/75 , B01J23/80 , B01J23/868 , B01J23/8896 , C07C209/16
摘要： A method for producing amines, the method comprising contacting at reactive conditions at least one alcohol, aldehyde or ketone, or a mixture thereof, with an aminating agent in the presence of a cobalt/copper catalyst, is improved by employing as the catalyst a composition comprising cobalt and copper, the catalyst being prepared by the molten salt impregnation technique.
摘要翻译： 一种制备胺的方法，包括在反应条件下使钴/铜催化剂存在下与胺化剂至少一种醇，酮或其混合物接触的方法通过使用催化剂作为催化剂， 包括钴和铜，催化剂通过熔融盐浸渍技术制备。
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公开(公告)号：USRE32640E
公开(公告)日：1988-04-12
申请号：US815263
申请日：1985-12-23
IPC分类号： B01J23/26 , B01J23/72 , B01J23/86 , C07C231/06 , C07C233/09
CPC分类号： C07C231/06 , B01J23/26 , B01J23/72 , B01J23/86 , C07C233/09
摘要： Aliphatic nitriles are converted to the corresponding amides by contacting the nitrile in the presence of water with a cupreous catalyst containing copper metal.
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公开(公告)号：USRE31356E
公开(公告)日：1983-08-23
申请号：US238395
申请日：1981-02-26
摘要： .[.Aliphatic nitriles.]. .Iadd.Olefinic nitriles of three to six carbon atoms .Iaddend.are converted to the corresponding amides by contacting the nitrile in the presence of water with a cupreous catalyst containing copper prepared by reducing copper hydroxide or a copper salt.
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9.发明授权Method of producing amines from alcohols, aldehydes, ketones and mixtures thereof 失效从醇，醛，酮及其混合物生产氨基酸的方法
公开(公告)号：US4152353A
公开(公告)日：1979-05-01
申请号：US828464
申请日：1977-08-29
IPC分类号： B01J23/755 , B01J23/80 , B01J37/03 , C07C85/02
CPC分类号： B01J23/80 , B01J23/755 , B01J37/03
摘要： A method of producing amines, the method comprising contacting at reactive conditions at least one alcohol, aldehyde or ketone or a mixture thereof with an aminating agent in the presence of a catalyst, is improved by employing as the catalyst a composition comprising nickel, copper and a third component selected from the group consisting of iron, zinc, zirconium and mixtures thereof. For example, polypropylene glycol is quantitatively aminated by contacting it with ammonia at about 175.degree. C. and in the presence of a catalyst comprising (metal basis) 30 mole percent nickel, 63 mole percent copper and about 7 mole percent iron.
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10.发明授权Imines and secondary amines containing hydrogen bonding moieties in their backbone and polymers made therefrom 失效在其主链中含有氢键部分的亚胺和仲胺和由其制备的聚合物
公开(公告)号：US5109098A
公开(公告)日：1992-04-28
申请号：US497383
申请日：1990-03-21
CPC分类号： C08G18/5072 , C08G18/10 , C08G18/12 , C08G18/503 , C08G18/5036 , C08L63/00
摘要： Imines and secondary amines comprising a backbone portion containing a plurality of polyalkyleneoxy moieties and one or more internal urea, thiourea, biuret, thiobiuret, amide, or thioamide moieties, and a plurality of imino or secondary amino end groups, wherein each imino or secondary amino end group is separated from a urea, thiourea, biuret, dithiobiuret, amide, or thioamide moiety by at least one alkylene, cycloalkylene, aralkylene, arylene, alkyleneoxy, or ppolyalkyleneoxy moiety are disclosed. Prepolymers and polymers prepared from the imines and secondary amines are also disclosed. In addition, the imines and secondary amines of the invention are also useful as epoxy resin curing agents.
摘要翻译： 包含含有多个聚亚烷基氧基部分和一个或多个内部尿素，硫脲，缩二脲，硫代嘌呤，酰胺或硫代酰胺部分的骨架部分和多个亚氨基或仲氨基端基的亚胺和仲胺，其中每个亚氨基或仲氨基 公开了通过至少一个亚烷基，亚环烷基，亚芳基，亚芳基，亚烷基氧基或聚亚烷基氧基部分的尿素，硫脲，缩二脲，二硫代脂肪族，酰胺或硫代酰胺部分。 还公开了由亚胺和仲胺制备的预聚物和聚合物。 此外，本发明的亚胺和仲胺也可用作环氧树脂固化剂。
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