摘要:
The present invention relates to a thermally stable modified selectively hydrogenated alkenyl arene/conjugated diene copolymer wherein a primary or secondary amine functional group is grafted to the block copolymer primarily in the alkenyl arene blocks thereof.
摘要:
The present invention relates to a polymer composition containing a condensation polymer and a thermally stable modified selectively hydrogenated alkenyl arene/conjugated diene copolymer wherein a primary or secondary amine functional group is grafted to the block copolymer primarily in the alkenyl arene blocks thereof.
摘要:
A thermoplastic polymer and an article of manufacture consisting essentially of this polymer are described herein which possess excellent mechanical properties at both room and elevated temperatures. The polymer is obtained by modifying a block copolymer composed of a conjugated diene compound and an alkenyl arene compound. The block copolymer is first selectively hydrogenated and thereafter modified by grafting carboxyl containing functional groups primarily in the alkenyl arene block via metalation. The mechanical properties may be varied and controlled by varying the degree of functionalization (amount of carboxyl groups), and the degree of neutralization of the carboxyl groups from an acid to a metal carboxylate salt.
摘要:
A toughened multiphase thermoplastic composition is provided by incorporating at least one functionalized, selectively hydrogenated alkenyl arene/conjugated diene block copolymer to which has been grafted an effective amount of carboxyl functional groups primarily in the alkenyl arene blocks thereof with a thermoplastic polyester. The carboxyl functional groups may be in the form of carboxylic acids, their salts, their esters, and combinations of two or more of these.
摘要:
The present invention relates to polymer composition containing a thermoplastic polymer containing a primary or secondary amine and a thermally stable modified selectively hydrogenated alkenyl arene/conjugated diene copolymer wherein an amide functional group is grafted to the block copolymer primarily in the alkenyl arene blocks thereof.
摘要:
A thermoplastic polymer which possesses excellent mechanical properties at both room and elevated temperatures is obtained by reacting an acyl sulfate with a block copolymer composed of at least one conjugated diene block and one alkenyl arene block. The block copolymer is first selectively hydrogenated and thereafter modified by grafting sulfonic acid functional groups primarily in the alkenyl arene blocks. The mechanical properties may be varied and controlled by varying the degree of functionalization (amount of sulfonation), and the degree of neutralization of the sulfonic acid groups to metal sulfonate salts.
摘要:
The present invention relates to novel compositions comprising (a) anionic block copolymers having at least two blocks of a mono alkenyl arene and at least one block of a conjugated diene and mono alkenyl arene having a specific arrangement of the monomers in the copolymer block, and (b) tailored softening modifiers have a particular structure that results in a surprising improvement in properties for the composition. Also included are processes for the manufacturing such novel compositions and various end-uses and applications for such compositions.
摘要:
The present invention is a novel block copolymer containing a controlled distribution copolymer block of a conjugated diene and a mono alkenyl arene, where the controlled distribution copolymer block has terminal regions that are rich in conjugated diene units and a center region that is rich in mono alkenyl arene units. Also disclosed is a method for manufacture of the block copolymer.
摘要:
Hydrogenated butadiene polymers having terminal functional groups have minimum viscosity at any molecular weight when the 1,2-addition is between 30% and 70%. Hydrogenated butadiene polymers having about two terminal hydroxyl groups per molecule have surprisingly lower viscosities at 30% to 70% 1,2-addition than similar polymers having either higher or lower amounts of 1,2-addition. The polymers are useful in making coatings, sealants, binders, and block copolymers with polyesters, polyamides, and polycarbonates.
摘要:
The anionic polymerization of unsaturated monomers with functionalized initiators having the structure R.sup.1 R.sup.2 R.sup.3 Si--O--A'--Li is improved by selecting A' from the structures --CH.sub.2 --CH.sub.2 --CH.sub.2 -- (1,3-propyl), --CH.sub.2 --CH(CH.sub.3)--CH.sub.2 -- (2-methyl-1,3-propyl), --CH.sub.2 --C(CH.sub.3).sub.2 --CH.sub.2 --(2,2-dimethyl-1,3-propyl), or --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --(1,8-octyl). This narrow class of polymerization initiators operate at surprisingly higher polymerization temperatures with surprisingly lower amounts of dead initiator than similar initiators wherein A' is --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --(1,4-butyl), --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --(1,5-pentyl), or --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --(1,6-hexyl).