公开(公告)号：US4677217A

公开(公告)日：1987-06-30

申请号：US784274

申请日：1985-10-04

申请人： Ludwig Maier ,  Willy Meyer ,  Konrad Oertle ,  Achim Roloff ,  Werner Topfl

发明人： Ludwig Maier ,  Willy Meyer ,  Konrad Oertle ,  Achim Roloff ,  Werner Topfl

IPC分类号： A01N57/16 ,  A01N57/08 ,  A01N57/24 ,  C07D521/00 ,  C07F9/30 ,  C07F9/32 ,  C07F9/38 ,  C07F9/40 ,  C07F9/53 ,  C07F9/6512 ,  C07F9/6521

CPC分类号： C07D521/00 ,  A01N57/08 ,  C07F9/304 ,  C07F9/3229 ,  C07F9/3808 ,  C07F9/3834 ,  C07F9/4006 ,  C07F9/4015 ,  C07F9/4021 ,  C07F9/4056 ,  C07F9/5325 ,  C07F9/65127 ,  C07F9/65217

摘要： Phenylsulfonamides of the formula ##STR1## in which X is a group ##STR2## Y is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, trifluoromethyl, C.sub.2 -C.sub.5 -alkenyl, C.sub.2 -C.sub.5 -alkynyl, nitro, --COOR.sup.6 or --Q--R.sup.6, A is oxygen, sulfur, a direct bond, C.sub.1 -C.sub.5 -alkylene, C.sub.2 -C.sub.5 -alkenylene, C.sub.1 -C.sub.5 -halogenoalkylene or --NR.sup.7 --(CH.sub.2).sub.m --; --CH.sub.2 --NH--(CH.sub.2).sub.m ; --(CH.sub.2).sub.m --NR.sup.7 -- or --O--(CH.sub.2).sub.p --, --S--(CH.sub.2).sub.p --, --(CH.sub.2).sub.p --O-- or --(CH.sub.2).sub.p --S--, n is zero or one, G is oxygen or sulfur, R.sup.4 is C.sub.1 -C.sub.5 -alkoxy, C.sub.1 -C.sub.5 -halogenoalkoxy, C.sub.1 -C.sub.5 -alkylthio, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -halogenoalkyl, phenyl or hydroxyl, R.sup.5 is hydrogen, C.sub.1 -C.sub.5 -alkoxy, C.sub.1 -C.sub.5 -halogenoalkoxy, C.sub.1 -C.sub.5 -alkylthio, C.sub.1 -C.sub. 5 -alkyl or hydroxyl, R.sup.6 is hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -halogenoalkyl or C.sub.2 -C.sub.6 -alkoxyalkyl, Q is oxygen, sulfur, --SO-- or --SO.sub.2 --, R.sup.7 is hydrogen, C.sub.1 -C.sub.5 -alkyl, phenyl, benzyl or phenyl which is substituted by C.sub.1 -C.sub.5 -alkyl, halogen, or nitro, m is a number from zero to three, p is a number from zero to two and r is one or two are useful as intermediates for phosphorous-containing N-phenylsulfonyl-N'-pyrimdinylurea and N-phenylsulfonyl-N'-triazinylurea herbicides.

摘要翻译： 其中X是基团Y的式“IMAGE”的苯磺酰胺是氢，卤素，C 1 -C 5 - 烷基，三氟甲基，C 2 -C 5 - 烯基，C 2 -C 5炔基，硝基，-COOR 6或-Q- R6，A是氧，硫，直接键，C1-C5-亚烷基，C2-C5-亚烯基，C1-C5-卤代亚烷基或-NR7-（CH2）m-; -CH 2 -NH-（CH 2）m; - （CH 2）m -NR 7 - 或-O-（CH 2）p - ， - S-（CH 2）p - ， - （CH 2）p O-或 - （CH 2）p -S-，n为0或1，G为氧 或硫，R4是C1-C5-烷氧基，C1-C5-卤代烷氧基，C1-C5-烷硫基，C1-C5-烷基，C1-C5-卤代烷基，苯基或羟基，R5是氢，C1-C5-烷氧基，C1 -C5-卤代烷氧基，C1-C5-烷硫基，C1-C5-烷基或羟基，R6是氢，C1-C5-烷基，C1-C5-卤代烷基或C2-C6-烷氧基烷基，Q是氧，硫，-SO - 或-SO 2 - ，R 7是氢，C 1 -C 5 - 烷基，苯基，苄基或被C 1 -C 5 - 烷基，卤素或硝基取代的苯基，m是0至3的数，p是 0至2，r是1或2个可用作含磷的N-苯基磺酰基-N'-嘧啶基脲和N-苯基磺酰基-N'-三嗪基脲除草剂的中间体。

公开(公告)号：US4952726A

公开(公告)日：1990-08-28

申请号：US440004

申请日：1989-11-21

申请人： Willy Meyer ,  Konrad Oertle

发明人： Willy Meyer ,  Konrad Oertle

IPC分类号： C07D249/16 ,  A01N43/70 ,  A01N47/36 ,  C07C20060101 ,  C07C67/00 ,  C07C301/00 ,  C07C309/86 ,  C07C311/15 ,  C07C311/16 ,  C07C311/17 ,  C07C311/29 ,  C07C311/39 ,  C07C311/53 ,  C07C311/65 ,  C07C325/00 ,  C07C331/16 ,  C07C331/32 ,  C07D239/42 ,  C07D239/46 ,  C07D239/47 ,  C07D239/48 ,  C07D239/52 ,  C07D239/56 ,  C07D239/69 ,  C07D251/16 ,  C07D251/18 ,  C07D251/22 ,  C07D251/46 ,  C07D251/52 ,  C07D521/00

CPC分类号： C07C309/86 ,  A01N47/36 ,  C07C311/65 ,  C07D521/00

摘要： N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the formula I ##STR1## wherein A is 3,3,3-trifluoropropyl or 3,3-difluorobutyl,R.sup.1 is hydrogen, halogen, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfonyl, C.sub.1 -C.sub.4 -alkylsulfonyl, --CO--R.sup.6, --NR.sup.7 R.sup.8, --CO--NR.sup.9 R.sup.10 or --SO.sub.2 --NR.sup.11 R.sup.12,R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkysulfonyl or C.sub.1 -C.sub.4 -alkylsulfonyl,R.sup.3 and R.sup.4 independently of one another are each hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.2 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkylthio, C.sub.2 -C.sub.4 -alkoxyalkyl, C.sub.1 -C.sub.4 -alkoxy or --NR.sup.13 R.sup.13,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,R.sup.6 is C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.2 -C.sub.6 -alkoxyalkoxy, hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -haloalkyl,R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13 independently of one another are each hydrogen or C.sub.1 -C.sub.4 -alkyl,E is nitrogen or the methine bridge, andZ is oxygen or sulfur;and also the salts of these compounds.

摘要翻译： 式I的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲其中A是3,3,3-三氟丙基或3,3-二氟丁基，R 1是氢，卤素，硝基，氰基，C 1 C 1-4烷基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4 - 烷基亚磺酰基，C 1 -C 4烷基磺酰基，-CO-R 6，-NR 7 R 8，-CO-NR 9 R 10或-SO 2 -NR 11 R 12，R 2是氢，卤素，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4烷基亚磺酰基或C 1 -C 4烷基磺酰基，R 3和R 4彼此独立地各自为氢， 卤素，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 2 -C 4卤代烷氧基，C 1 -C 4烷硫基，C 1 -C 4卤代烷硫基，C 2 -C 4烷氧基烷基，C 1 -C 4烷氧基或-NR 12 R 13， ，C 1 -C 4烷基或C 1 -C 4 - 烷氧基，R 6是C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷氧基，C 1 -C 4烷硫基，C 2 -C 6烷氧基烷氧基，氢，C 1 -C 4烷基或C 1 -C 4 卤代烷基，R 7，R 8，R 9，R 10，R 11，R 12和R 13各自独立地为氢或C 1 -C 4烷基，E为氮或次甲基桥，Z为氧或硫; 以及这些化合物的盐。

公开(公告)号：US4908467A

公开(公告)日：1990-03-13

申请号：US179339

申请日：1988-04-08

申请人： Willy Meyer ,  Konrad Oertle

发明人： Willy Meyer ,  Konrad Oertle

IPC分类号： C07D249/16 ,  A01N43/70 ,  A01N47/36 ,  C07C20060101 ,  C07C67/00 ,  C07C301/00 ,  C07C309/86 ,  C07C311/15 ,  C07C311/16 ,  C07C311/17 ,  C07C311/29 ,  C07C311/39 ,  C07C311/53 ,  C07C311/65 ,  C07C325/00 ,  C07C331/16 ,  C07C331/32 ,  C07D239/42 ,  C07D239/46 ,  C07D239/47 ,  C07D239/48 ,  C07D239/52 ,  C07D239/56 ,  C07D239/69 ,  C07D251/16 ,  C07D251/18 ,  C07D251/22 ,  C07D251/46 ,  C07D251/52 ,  C07D521/00

CPC分类号： C07C309/86 ,  A01N47/36 ,  C07C311/65 ,  C07D521/00

摘要： N-Phenylsulfonyl-B'-pyrimidinyl- and -triazinylureas of the formula I ##STR1## wherein A is 3,3,3-trifluoropropyl or 3,3-difluorobutyl,R.sup.1 is hydrogen, halogen, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, --CO--R.sup.6, --NR.sup.7 R.sup.8, --CO--NR.sup.9 R.sup.10 or --SO.sub.2 --NR.sup.11 R.sup.12,R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl or C.sub.1 -C.sub.4 -alkylsulfonyl,R.sup.3 and R.sup.4 independently of one another are each hydrogen, halogen C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.2 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkylthio, C.sub.2 -C.sub.4 -alkoxyalkyl, C.sub.1 -C.sub.4 -alkoxy or --NR.sup.12 R.sup.13,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,R.sup.6 is C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.2 -C.sub.6 -alkoxyalkoxy, hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -haloalkyl,R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13 independently of one another are each hydrogen or C.sub.1 -C.sub.4 -alkyl,E is nitrogen or the methine bridge, andZ is oxygen or sulfur;and also the salts of these compounds.

摘要翻译： 式I的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲其中A是3,3,3-三氟丙基或3,3-二氟丁基，R 1是氢，卤素，硝基，氰基，C 1 C 1-4烷基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4 - 烷基亚磺酰基，C 1 -C 4烷基磺酰基，-CO-R 6，-NR 7 R 8，-CO-NR 9 R 10或-SO 2 -NR 11 R 12，R 2是氢，卤素，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4烷基亚磺酰基或C 1 -C 4烷基磺酰基，R 3和R 4彼此独立地各自为氢， 卤素，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 2 -C 4卤代烷氧基，C 1 -C 4烷硫基，C 1 -C 4卤代烷硫基，C 2 -C 4烷氧基烷基，C 1 -C 4烷氧基或-NR 12 R 13， ，C 1 -C 4烷基或C 1 -C 4 - 烷氧基，R 6是C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷氧基，C 1 -C 4 - 烷硫基，C 2 -C 6 - 烷氧基烷氧基，氢，C 1 -C 4烷基或C 1 -C 4 卤代烷基，R 7，R 8，R 9，R 10，R 11，R 12和R 13各自独立地为氢或C 1 -C 4烷基，E为氮或次甲基桥，Z为氧或硫; 以及这些化合物的盐。

公开(公告)号：US4780125A

公开(公告)日：1988-10-25

申请号：US525366

申请日：1983-08-22

申请人： Willy Meyer ,  Dieter Reinehr ,  Konrad Oertle ,  Rolf Schurter

发明人： Willy Meyer ,  Dieter Reinehr ,  Konrad Oertle ,  Rolf Schurter

IPC分类号： B01J31/24 ,  A01N47/36 ,  A01P13/00 ,  C07B61/00 ,  C07C303/22 ,  C07C309/29 ,  C07C309/30 ,  C07C309/44 ,  C07C309/86 ,  C07C309/87 ,  C07C311/15 ,  C07C311/16 ,  C07C311/29 ,  C07C311/53 ,  C07C311/54 ,  C07C311/58 ,  C07C311/65 ,  C07C317/10 ,  C07D239/42 ,  C07D239/46 ,  C07D239/47 ,  C07D239/52 ,  C07D239/69 ,  C07D251/16 ,  C07D251/42 ,  C07D251/46 ,  C07D251/52 ,  C07D521/00 ,  A01N43/66

CPC分类号： C07C311/65 ,  A01N47/36 ,  C07C309/00 ,  C07D239/47 ,  C07D521/00

摘要： The invention relates to N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N-triazinylureas of the general formula ##STR1## wherein R.sub.1 is hydrogen, halogen, nitro, amino, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.4 haloalkyl or a --Q--R.sub.7, --CO--OR.sub.8 or --(CO).sub.n --NR.sub.9 R.sub.10 radical,R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, halogen or alkoxyalkyl containing not more than 4 carbon atoms,R.sub.3 is C.sub.2 -C.sub.10 alkenyl which is substituted by one or more fluorine or bromine atoms or by one or more hydroxyl, cyano, nitro, --(Y).sub.m --CO--(Z).sub.n --R.sub.8, --SO.sub.2 --NR.sub.11 R.sub.12, --S(O).sub.p --C.sub.1 --C.sub.3 haloalkyl or --S(O).sub.n --C.sub.1 -C.sub.3 alkyl groups and which may additionally be substituted by one or more chlorine atoms,R.sub.4 is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkoxy, R.sub.5 is hydrogen, halogen, --NR.sub.13 R.sub.14, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.2 haloalkoxy,R.sub.6 is hydrogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy,X is oxygen or sulfur, andE is nitrogen or the methine group, andR.sub.7 is C.sub.1 -C.sub.4 alkyl which is substituted by halogen or C.sub.1 -C.sub.3 alkoxy or is C.sub.3 -C.sub.5 alkenyl,R.sub.8 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl or C.sub.2 -C.sub.6 alkoxyalkyl,R.sub.9, R.sub.10, R.sub.11, R.sub.12, R.sub.13 and R.sub.14, each independently of the other, are hydrogen or C.sub.1 -C.sub.3 alkyl,Q is oxygen, sulfur, the sulfinyl or sulfonyl bridge,Y is oxygen, sulfur or --NR.sub.16 --, wherein R.sub.16 is hydrogen or C.sub.1 -C.sub.3 alkyl,Z is oxygen, sulfur or --NR.sub.17 --, wherein R.sub.17 is hydrogen or C.sub.1 -C.sub.3 alkyl,m and n are each 0 to 1, andp is 0, 1 or 2, and to the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases.These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.

摘要翻译： 本发明涉及通式为（I）的N-苯基磺酰基-N'-嘧啶基脲和N-苯基磺酰基-N-三嗪基脲，其中R 1是氢，卤素，硝基，氨基，C 1 -C 5烷基，C 1 -C 4卤代烷基或 -Q-R7，-CO-OR8或 - （CO）n-NR9R10基，R2是氢，C1-C4烷基，C1-C4烷氧基，C1-C4烷硫基，C1-C4卤代烷基，C1-C4卤代烷氧基，卤素或不大于 4个碳原子，R 3是被一个或多个氟或溴原子或一个或多个羟基，氰基，硝基， - （Y）m -CO-（Z）n -R 8，-SO 2 -NR 11 R 12取代的C 2 -C 10链烯基 ，-S（O）p-C 1 -C 3卤代烷基或-S（O）n -C 1 -C 3烷基，并且其可以另外被一个或多个氯原子取代，R 4是C 1 -C 3烷基，C 1 -C 3卤代烷基，C 1 -C 3烷氧基或 C1-C3卤代烷氧基，R5是氢，卤素，-NR13R14，C1-C3烷基，C1-C3卤代烷基，C1-C3烷氧基或C1-C2卤代烷氧基，R6是氢，C1-C3烷基或C1-C3烷氧基，X是氧或硫，E是 氮或次甲基，并且R 7为被所取代的C 1 -C 4烷基 卤素或C 1 -C 3烷氧基或C 3 -C 5链烯基，R 8为C 1 -C 4烷基，C 1 -C 4卤代烷基或C 2 -C 6烷氧基烷基，R 9，R 10，R 11，R 12，R 13和R 14各自独立地为氢或C 1 -C 3烷基， Q是氧，硫，亚磺酰基或磺酰基桥，Y是氧，硫或-NR 16 - ，其中R 16是氢或C 1 -C 3烷基，Z是氧，硫或-NR 17 - ，其中R 17是氢或C 1 -C 3烷基， m和n各自为0至1，p为0,1或2，以及这些化合物与胺，碱金属碱或碱土金属碱的盐。 这些化合物具有良好的芽前和芽后选择性除草和生长调节性质。

公开(公告)号：US4559078A

公开(公告)日：1985-12-17

申请号：US562659

申请日：1983-12-19

申请人： Ludwig Maier ,  Willy Meyer ,  Konrad Oertle ,  Achim Roloff ,  Werner Topfl

发明人： Ludwig Maier ,  Willy Meyer ,  Konrad Oertle ,  Achim Roloff ,  Werner Topfl

IPC分类号： A01N57/16 ,  A01N57/08 ,  A01N57/24 ,  C07D521/00 ,  C07F9/30 ,  C07F9/32 ,  C07F9/38 ,  C07F9/40 ,  C07F9/53 ,  C07F9/6512 ,  C07F9/6521 ,  C07F9/65

CPC分类号： C07D521/00 ,  A01N57/08 ,  C07F9/304 ,  C07F9/3229 ,  C07F9/3808 ,  C07F9/3834 ,  C07F9/4006 ,  C07F9/4015 ,  C07F9/4021 ,  C07F9/4056 ,  C07F9/5325 ,  C07F9/65127 ,  C07F9/65217

摘要： Phosphorus-containing N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N'-triazinylureas of the formula ##STR1## and the salts of these compounds with amines, alkali or alkaline earth metal bases or quaternary ammonium bases have good pre-emergence and post-emergence selective herbicidal and growth-regulating properties.In this formula, X is a group ##STR2## Y is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, trifluoromethyl, C.sub.2 -C.sub.5, alkenyl, C.sub.2 -C.sub.5 -alkynyl, nitro, --COOR.sup.6 or --Q--R.sup.6, Z is nitrogen or the methine group, E is oxygen or sulfur, R.sup.1 is hydrogen or C.sub.1 -C.sub.5 -alkyl and R.sup.2 and R.sup.3 independently of one another are C.sub.1 -C.sub.3 -alkyl, C.sub.1 -C.sub.3 -alkoxy, C.sub.1 -C.sub.3 -halogenoalkyl, C.sub.1 -C.sub.3 -halogenoalkoxy, cyclopropyl, amino, methylamino or dimethylamino, and A is oxygen, sulfur, C.sub.1 -C.sub.5 -alkylene, C.sub.2 -C.sub.5 -alkenylene, C.sub.1 -C.sub.5 -halogenoalkylene or --NR.sup.7 --(CH.sub.2).sub.m --; --CH.sub.2 --NH--(CH.sub.2).sub.m --; --(CH.sub.2).sub.m --NR.sup.7 -- or --O--(CH.sub.2).sub.p --, --S--(CH.sub.2).sub.p --, --(CH.sub.2).sub.p --O-- or --(CH.sub.2).sub.p --S--, n is zero or one, G is oxygen or sulfur, R.sup.4 is C.sub.1 -C.sub.5 -alkoxy, C.sub.1 -C.sub.5 -halogenoalkoxy, C.sub.1 -C.sub.5 -alkylthio, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -halogenoalkyl, phenyl or hydroxyl, R.sup.5 is hydrogen, C.sub.1 -C.sub.5 -alkoxy, C.sub.1 -C.sub.5 -halogenoalkoxy, C.sub.1 -C.sub.5 -alkylthio, C.sub.1 -C.sub.5 -alkyl or hydroxyl, R.sup.6 is C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -halogenoalkyl or C.sub.2 -C.sub.6 -alkoxyalkyl, Q is oxygen, sulfur, --SO-- or --SO.sub.2 --, R.sup.7 is hydrogen, C.sub.1 -C.sub.5 -alkyl, phenyl, benzyl or phenyl which is substituted by C.sub.1 -C.sub.5 -alkyl, halogen or nitro, m is a number from zero to three, p is a number from zero to two and r is one or two.

摘要翻译： 具有式“IMAGE”的含磷N-苯基磺酰基-N'-嘧啶基脲和N-苯基磺酰基-N'-三嗪基脲和这些化合物与胺，碱金属或碱土金属碱或季铵碱的盐具有良好的出苗前 和出苗后选择性除草和生长调节性质。 在该式中，X是基团Y是氢，卤素，C 1 -C 5 - 烷基，三氟甲基，C 2 -C 5，烯基，C 2 -C 5炔基，硝基，-COOR 6或-Q-R 6，Z是氮 或次甲基，E是氧或硫，R1是氢或C1-C5-烷基，R2和R3彼此独立地是C1-C3-烷基，C1-C3-烷氧基，C1-C3-卤代烷基，C1-C3 - 卤代烷氧基，环丙基，氨基，甲基氨基或二甲基氨基，A是氧，硫，C1-C5-亚烷基，C2-C5-亚烯基，C1-C5-卤代亚烷基或-NR7-（CH2）m- -CH 2 -NH-（CH 2）m - ; - （CH 2）m -NR 7 - 或-O-（CH 2）p - ， - S-（CH 2）p - ， - （CH 2）p O-或 - （CH 2）p -S-，n为0或1，G为氧 或硫，R4是C1-C5-烷氧基，C1-C5-卤代烷氧基，C1-C5-烷硫基，C1-C5-烷基，C1-C5-卤代烷基，苯基或羟基，R5是氢，C1-C5-烷氧基，C1 -C 5 - 卤代烷氧基，C 1 -C 5 - 烷硫基，C 1 -C 5 - 烷基或羟基，R 6是C 1 -C 5 - 烷基，C 1 -C 5 - 卤代烷基或C 2 -C 6 - 烷氧基烷基，Q是氧，硫，-SO-或 - SO 2 - ，R 7为氢，C 1 -C 5 - 烷基，苯基，苄基或被C 1 -C 5 - 烷基，卤素或硝基取代的苯基，m为0至3的数，p为0至2的数， r是一两个。

公开(公告)号：US5104440A

公开(公告)日：1992-04-14

申请号：US697178

申请日：1991-05-08

申请人： Willy Meyer ,  Dieter Reinehr ,  Konrad Oertle ,  Rolf Schurter

发明人： Willy Meyer ,  Dieter Reinehr ,  Konrad Oertle ,  Rolf Schurter

IPC分类号： B01J31/24 ,  A01N47/36 ,  A01P13/00 ,  C07B61/00 ,  C07C303/22 ,  C07C309/29 ,  C07C309/30 ,  C07C309/44 ,  C07C309/86 ,  C07C309/87 ,  C07C311/15 ,  C07C311/16 ,  C07C311/29 ,  C07C311/53 ,  C07C311/54 ,  C07C311/58 ,  C07C311/65 ,  C07C317/10 ,  C07D239/42 ,  C07D239/46 ,  C07D239/47 ,  C07D239/52 ,  C07D239/69 ,  C07D251/16 ,  C07D251/42 ,  C07D251/46 ,  C07D251/52 ,  C07D521/00

CPC分类号： C07C311/65 ,  A01N47/36 ,  C07C309/00 ,  C07D239/47 ,  C07D521/00

摘要： The invention relates to N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N-triazinylures of the general formula ##STR1## wherein R.sub.1 is hydrogen, halogen, nitro, amino, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.4 haloalkyl or a --Q--R.sub.7, --CO--OR.sub.8 or --(CO).sub.n --NR.sub.9 R.sub.10 radical,R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, halogen or alkoxyalkyl containing not more than 4 carbon atoms,R.sub.3 is C.sub.2 -C.sub.10 alkenyl which is substituted by one or more fluorine or bromine atoms or by one or more hydroxyl, cyano, nitro, --(Y).sub.m --CO--(Z).sub.n --R.sub.8, --SO.sub.2 --NR.sub.11 R.sub.12, --S(O).sub.P --C.sub.1 -C.sub.3 haloalkyl or --S(O).sub.n --C.sub.1 -C.sub.3 alkyl groups and which may additionally be substituted by one or more chlorine atoms,R.sub.4 is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkoxy,R.sub.5 is hydrogen, halogen, --NR.sub.13 R.sub.14, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.2 haloalkoxy,R.sub.6 is hydrogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy,X is oxygen or sulfur, andE is nitrogen or the methine group, and R.sub.7 is C.sub.1 -C.sub.4 alkyl which is substituted by halogen or C.sub.1 -C.sub.3 alkoxy or is C.sub.3 -C.sub.5 alkenyl,R.sub.8 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl or C.sub.2 -C.sub.6 alkoxyalkyl, R.sub.9, R.sub.10, R.sub.11, R.sub.12, R.sub.13 and R.sub.14, each independently of the other, are hydrogen or C.sub.1 -C.sub.3 alkyl,Q is oxygen, sulfur, the sulfinyl or sulfonyl bridge,Y is oxygen, sulfur or --NR.sub.16 --, wherein R.sub.16 is hydrogen or C.sub.1 -C.sub.3 alkyl,Z is oxygen, sulfur or --NR.sub.17 --, wherein R.sub.17 is hydrogen or C.sub.1 -C.sub.3 alkyl, m and n are each 0 or 1, andp is 0, 1 or 2, and to the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases.These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.

公开(公告)号：US5041603A

公开(公告)日：1991-08-20

申请号：US464578

申请日：1990-01-12

申请人： Willy Meyer ,  Dieter Reinehr ,  Konrad Oertle ,  Rolf Schurter

发明人： Willy Meyer ,  Dieter Reinehr ,  Konrad Oertle ,  Rolf Schurter

IPC分类号： B01J31/24 ,  A01N47/36 ,  A01P13/00 ,  C07B61/00 ,  C07C303/22 ,  C07C309/29 ,  C07C309/30 ,  C07C309/44 ,  C07C309/86 ,  C07C309/87 ,  C07C311/15 ,  C07C311/16 ,  C07C311/29 ,  C07C311/53 ,  C07C311/54 ,  C07C311/58 ,  C07C311/65 ,  C07C317/10 ,  C07D239/42 ,  C07D239/46 ,  C07D239/47 ,  C07D239/52 ,  C07D239/69 ,  C07D251/16 ,  C07D251/42 ,  C07D251/46 ,  C07D251/52 ,  C07D521/00

CPC分类号： C07C311/65 ,  A01N47/36 ,  C07C309/00 ,  C07D239/47 ,  C07D521/00

摘要： The invention relates to N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N-triazinylureas of the general formula ##STR1## wherein R.sub.1 is hydrogen, halogen, nitro, amino, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.4 haloalkyl or a --Q--R.sub.7, --CO--OR.sub.8 or --(CO).sub.n --NR.sub.9 R.sub.10 radical,R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, halogen or alkoxyalkyl containing not more than 4 carbon atoms,R.sub.3 is C.sub.2 -C.sub.10 alkenyl which is substituted by one or more fluorine or bromine atoms or by one or more hydroxyl, cyano, nitro, --(Y).sub.m --CO--(Z).sub.n --R.sub.8, --SO.sub.2 --NR.sub.11 R.sub.12, --S(O).sub.p --C.sub.1 -C.sub.3 haloalkyl or --S(O).sub.n --C.sub.1 -C.sub.3 alkyl groups and which may additionally be substituted by one or more chlorine atoms,R.sub.4 is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkoxy,R.sub.5 is hydrogen, halogen, --NR.sub.13 R.sub.14, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.2 haloalkoxy,R.sub.6 is hydrogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy,X is oxygen or sulfur, andE is nitrogen or the methine group, andR.sub.7 is C.sub.1 -C.sub.4 alkyl which is substituted by halogen or C.sub.1 -C.sub.3 alkoxy or is C.sub.3 -C.sub.5 alkenyl,R.sub.8 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl or C.sub.2 -C.sub.6 alkoxyalkyl,R.sub.9, R.sub.10, R.sub.11, R.sub.12, R.sub.13 and R.sub.14, each independently of the other, are hydrogen or C.sub.1 -C.sub.3 alkyl,Q is oxygen, sulfur, the sulfinyl or sulfonyl bridge,Y is oxygen, sulfur or --NR.sub.16 --, wherein R.sub.16 is hydrogen or C.sub.1 -C.sub.3 alkyl,Z is oxygen, sulfur or --NR.sub.17 --, wherein R.sub.17 is hydrogen or C.sub.1 -C.sub.3 alkyl,m and n are each 0 or 1, andp is 0, 1 or 2, and to the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases.These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.

公开(公告)号：US4671819A

公开(公告)日：1987-06-09

申请号：US810010

申请日：1985-12-17

申请人： Willy Meyer ,  Konrad Oertle

发明人： Willy Meyer ,  Konrad Oertle

IPC分类号： C07D249/16 ,  A01N43/70 ,  A01N47/36 ,  C07C20060101 ,  C07C67/00 ,  C07C301/00 ,  C07C309/86 ,  C07C311/15 ,  C07C311/16 ,  C07C311/17 ,  C07C311/29 ,  C07C311/39 ,  C07C311/53 ,  C07C311/65 ,  C07C325/00 ,  C07C331/16 ,  C07C331/32 ,  C07D239/42 ,  C07D239/46 ,  C07D239/47 ,  C07D239/48 ,  C07D239/52 ,  C07D239/56 ,  C07D239/69 ,  C07D251/16 ,  C07D251/18 ,  C07D251/22 ,  C07D251/46 ,  C07D251/52 ,  C07D521/00

CPC分类号： C07C309/86 ,  A01N47/36 ,  C07C311/65 ,  C07D521/00

摘要： N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the formula I ##STR1## wherein A is 3,3,3-trifluoropropyl or 3,3-difluorobutyl,R.sup.1 is hydrogen, halogen, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, --CO--R.sup.6, --NR.sup.7 R.sup.8, --CO--NR.sup.9 R.sup.10 or --SO.sub.2 --NR.sup.11 R.sup.12,R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl or C.sub.1 -C.sub.4 -alkylsulfonyl,R.sup.3 and R.sup.4 independently of one another are each hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.2 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkylthio, C.sub.2 -C.sub.4 -alkoxyalkyl, C.sub.1 -C.sub.4 -alkoxy or --NR.sup.12 R.sup.13,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,R.sup.6 is C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.2 -C.sub.6 -alkoxyalkoxy, hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -haloalkyl,R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13 independently of one another are each hydrogen or C.sub.1 -C.sub.4 -alkyl,E is nitrogen, andZ is oxygen or sulfur;and also the salts of these compounds.

摘要翻译： 式I的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲其中A是3,3,3-三氟丙基或3,3-二氟丁基，R 1是氢，卤素，硝基，氰基，C 1 C 1-4烷基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4 - 烷基亚磺酰基，C 1 -C 4烷基磺酰基，-CO-R 6，-NR 7 R 8，-CO-NR 9 R 10或-SO 2 -NR 11 R 12，R 2是氢，卤素，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4烷基亚磺酰基或C 1 -C 4烷基磺酰基，R 3和R 4彼此独立地各自为氢， 卤素，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 2 -C 4卤代烷氧基，C 1 -C 4烷硫基，C 1 -C 4卤代烷硫基，C 2 -C 4烷氧基烷基，C 1 -C 4烷氧基或-NR 12 R 13， ，C 1 -C 4烷基或C 1 -C 4 - 烷氧基，R 6是C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷氧基，C 1 -C 4烷硫基，C 2 -C 6烷氧基烷氧基，氢，C 1 -C 4烷基或C 1 -C 4 卤代烷基，R7，R8，R9，R10，R11，R12和R13各自独立地为氢或C1-C4烷基，E为氮，Z为氧或硫; 以及这些化合物的盐。

公开(公告)号：US4759793A

公开(公告)日：1988-07-26

申请号：US30529

申请日：1987-03-27

申请人： Willy Meyer ,  Konrad Oertle

发明人： Willy Meyer ,  Konrad Oertle

IPC分类号： C07D249/16 ,  A01N43/70 ,  A01N47/36 ,  C07C20060101 ,  C07C67/00 ,  C07C301/00 ,  C07C309/86 ,  C07C311/15 ,  C07C311/16 ,  C07C311/17 ,  C07C311/29 ,  C07C311/39 ,  C07C311/53 ,  C07C311/65 ,  C07C325/00 ,  C07C331/16 ,  C07C331/32 ,  C07D239/42 ,  C07D239/46 ,  C07D239/47 ,  C07D239/48 ,  C07D239/52 ,  C07D239/56 ,  C07D239/69 ,  C07D251/16 ,  C07D251/18 ,  C07D251/22 ,  C07D251/46 ,  C07D251/52 ,  C07D521/00 ,  A01N43/54

CPC分类号： C07C309/86 ,  A01N47/36 ,  C07C311/65 ,  C07D521/00

摘要： N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the formula I ##STR1## wherein A is 3,3,3-trifluoropropyl or 3,3-difluorobutyl,R.sup.1 is hydrogen, halogen, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, --CO-R.sup.6, --NR.sup.7 R.sup.8, --CO--NR.sup.9 R.sup.10 or --SO.sub.2 --NR.sup.11 R.sup.12,R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl or C.sub.1 -C.sub.4 -alkylsulfonyl,R.sup.3 and R.sup.4 independently of one another are each hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.2 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkylthio, C.sub.2 -C.sub.4 -alkoxyalkyl, C.sub.1 -C.sub.4 -alkoxy or --NR.sup.12 R.sup.13,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,R.sup.6 is C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.2 -C.sub.6 -alkoxyalkoxy, hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -haloalkyl,R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13 independently of one another are each hydrogen or C.sub.1 -C.sub.4 -alkyl,E is nitrogen or the methine bridge, andZ is oxygen or sulfur;and also the salts of these compounds.

摘要翻译： 式I的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲其中A是3,3,3-三氟丙基或3,3-二氟丁基，R 1是氢，卤素，硝基，氰基，C 1 C 1-4烷基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4 - 烷基亚磺酰基，C 1 -C 4烷基磺酰基，-CO-R 6，-NR 7 R 8，-CO-NR 9 R 10或-SO 2 -NR 11 R 12，R 2是氢，卤素，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4烷基亚磺酰基或C 1 -C 4烷基磺酰基，R 3和R 4彼此独立地各自为氢， 卤素，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 2 -C 4卤代烷氧基，C 1 -C 4烷硫基，C 1 -C 4卤代烷硫基，C 2 -C 4烷氧基烷基，C 1 -C 4烷氧基或-NR 12 R 13， ，C 1 -C 4烷基或C 1 -C 4 - 烷氧基，R 6是C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷氧基，C 1 -C 4 - 烷硫基，C 2 -C 6 - 烷氧基烷氧基，氢，C 1 -C 4烷基或C 1 -C 4 卤代烷基，R 7，R 8，R 9，R 10，R 11，R 12和R 13各自独立地为氢或C 1 -C 4烷基，E为氮或次甲基桥，Z为氧或硫; 以及这些化合物的盐。

公开(公告)号：US4832736A

公开(公告)日：1989-05-23

申请号：US130487

申请日：1987-12-09

申请人： Rolf Schurter ,  Konrad Oertle

发明人： Rolf Schurter ,  Konrad Oertle

IPC分类号： A01N53/06 ,  A01N43/40 ,  A01N55/00 ,  A01N57/18 ,  A01N57/24 ,  C07D213/64 ,  C07D213/643 ,  C07F7/08 ,  C07F9/58

CPC分类号： C07D213/643 ,  A01N43/40 ,  A01N55/00 ,  A01N57/24 ,  C07F7/0812 ,  C07F9/582

摘要： New 3-fluoropyridyl-2-oxy-phenoxy derivatives are disclosed which have a herbicidal and plant growth inhibiting action. They correspond to the formula ##STR1## wherein X is halogen or trifluoromethyl,G is a C.sub.1 -C.sub.3 -alkylene chain which can be mono- or disubstituted by methyl or phenyl,m is zero or one,R.sup.12 and K.sup.13 are each C.sub.1 -C.sub.6 -alkyl andR.sup.17 is hydrogen, C.sub.1 -C.sub.2 -alkyl or methoxymethyl.These compounds are suitable for the selective control of weeds in crops of cultivated plants, or for the reduction of the growth of grasses.

摘要翻译： 公开了具有除草和植物生长抑制作用的新的3-氟吡啶基-2-氧基 - 苯氧基衍生物。 它们对应于式（I）其中X是卤素或三氟甲基，G是可被甲基或苯基单或双取代的C1-C3-亚烷基链，m是0或1，R12和 K13各自为C1-C6-烷基，R17为氢，C1-C2-烷基或甲氧基甲基。 这些化合物适合于选择性地控制栽培植物作物中的杂草，或者减少草的生长。