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公开(公告)号：US4554187A
公开(公告)日：1985-11-19
申请号：US622936
申请日：1984-06-21
IPC分类号： C08L83/06 , C08J3/03 , C08K5/5419 , C08K5/57 , C08L83/00 , C08L83/04 , C09D183/04 , C09D183/06 , D06M15/643 , B05D3/02
摘要： A silicone emulsion which can be converted into an elastomeric product under ambient conditions by eliminating and evaporating water and alcohol or carboxylic acid, comprising by weight approximately(A) 100 parts of a hydroxyl-terminated polydiorganosiloxane having a molecular weight of at least about 50,000,(B) 1 to 400 parts of a low molecular weight, reactive acyloxy or alkoxy-functional silicone resin,(C) 0.1 to 20 parts of a catalytic compound,(D) 0 to 200 parts of a thixotropic filler and(E) 0 to 200 parts by weight of a non-thixotropic filler, the silicone emulsion having a solids content of about 20 to 85% by weight. The emulsion is especially suited for coatings and sealants.
摘要翻译： 硅氧烷乳液，其可在环境条件下通过除去和蒸发水和醇或羧酸而转化成弹性体产物，所述水和醇或羧酸的重量约为（A）100份分子量为至少约50,000的羟基封端的聚二有机硅氧烷， （B）1〜400份低分子量反应性酰氧基或烷氧基官能的有机硅树脂，（C）0.1〜20份催化剂，（D）0〜200份触变性填料和（E）0 至200重量份的非触变性填料，所述硅氧烷乳液具有约20至85重量％的固体含量。 该乳液特别适用于涂料和密封剂。
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公开(公告)号：US4855473A
公开(公告)日：1989-08-08
申请号：US47963
申请日：1987-05-08
摘要： The present invention relates to the preparation of organooxychlorosilanes. They are produced by reacting the corresponding chlorosilane with an alcohol in the presence of a catalyst system consisting of hydrogen chloride and a cocatalyst.
摘要翻译： 本发明涉及有机氧氯硅烷的制备。 它们通过在由氯化氢和助催化剂组成的催化剂体系的存在下使相应的氯代硅烷与醇反应制备。
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3.发明授权Polyorganosiloxane compositions which harden into elastomers at room temperature 失效在室温下硬化成弹性体的聚有机硅氧烷组合物
公开(公告)号：US4588770A
公开(公告)日：1986-05-13
申请号：US622946
申请日：1984-06-21
CPC分类号： C08L83/04 , C08G77/16 , Y10S528/901
摘要： A silicone composition which is stable in the absence of moisture but which in the presence of water will cure at room temperature to an elastomer, comprising a polyorganosiloxane having reactive end groups, a polyester and a thickening filler.
摘要翻译： 在没有水分的情况下是稳定的但在水存在下可以在室温下固化的弹性体的硅氧烷组合物，其包含具有反应性端基的聚有机硅氧烷，聚酯和增稠填料。
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公开(公告)号：US4585849A
公开(公告)日：1986-04-29
申请号：US654996
申请日：1984-09-26
CPC分类号： C08K5/54 , C08G77/14 , C08G77/16 , C08G77/26 , Y10S528/901
摘要： In a polydiorganosilixane composition which is capable of storage in the absence of moisture and can be cured at ambient temperature under the action of water or moisture to give elastomers, the composition comprising a diorganosiloxane having reactive terminal groups, a diorganosilane having groups which are sensitive to hydrolysis, a cross-linking agent, and optionally fillers which have a thixotropic effect, condensation catalysts and/or other known auxiliaries, the improvement which comprises employing as the silane (a) a silane of the formulaRR.sup.1 Si(NR.sup.2 R.sup.3).sub.2plus (b) an organosilane of the formulaRSi (O--N.dbd.R.sup.4).sub.3in whichR, R.sup.1, R.sup.2 and R.sup.3 each independently is alkyl, aryl, aralkyl and vinyl groups, orR.sup.2 and R.sup.3 together can be an alkanediyl radical having up to 8 C atoms or hydrogen, andR.sup.4 is an R.sup.2 R.sup.3 C group having up to 8 C atoms. The composition cures at room temperature in the presence of moisture to elastomers of desirable physical properties.
摘要翻译： 在聚二有机硅烷组合物中，其能够在不存在水分的情况下储存并且可以在环境温度下在水或水分的作用下固化，得到弹性体，该组合物包含具有反应性末端基团的二有机硅氧烷，具有对 水解，交联剂和任选具有触变效应的填料，缩合催化剂和/或其它已知的助剂，其改进包括使用式（a）式（I）的硅烷：（式中，R 1，R 2，R 3）2加上（b ）式RSi（ON = R4）3的有机硅烷，其中R，R 1，R 2和R 3各自独立地是烷基，芳基，芳烷基和乙烯基，或者R 2和R 3一起可以是具有至多8个C原子的烷二基 或氢，R4是具有至多8个C原子的R 2 R 3 C基团。 组合物在室温下在湿气存在下固化成具有所需物理性能的弹性体。
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公开(公告)号：US4720530A
公开(公告)日：1988-01-19
申请号：US880622
申请日：1986-07-01
IPC分类号： C08L83/00 , C08K3/00 , C08K5/00 , C08K5/09 , C08K5/5465 , C08K5/56 , C08L83/04 , C08L83/06 , C08G77/06
摘要： Improved polyorganosiloxane compositions which can be stored with the exclusion of moisture and harden on access to moisture are disclosed. These compositions contain, 100 parts by weight of an .alpha.,.omega.-dihdyroxypolydimethylsiloxane, 0 to 100 parts by weight of an .alpha.,.omega.-bis(trimethylsiloxy)polydimethylsiloxane plasticizer, 1 to 10 parts by weight of an oximinosilane, 5 to 250 parts by weight of a reinforcing or non-reinforcing filler or a filler mixture, 0.01 to 1 part by weight of a tin catalyst, 0.05 to 2.5 parts by weight of an aminoalkylalkoxysilane and 0.5 to 2.5 parts by weight of an accelerator chosen from alkyl or alkenyl carboxylic acids or silane derivatives of such carboxylic acids.
摘要翻译： 公开了改进的聚有机硅氧烷组合物，其可以排除潮湿并在获得水分时变硬而储存。 这些组合物含有100重量份的α，ω-二羟基聚二甲基硅氧烷，0〜100重量份的α，ω-双（三甲基甲硅烷氧基）聚二甲基硅氧烷增塑剂，1〜10重量份的肟基硅烷，5〜250重量份 增强或非增强填料或填料混合物的重量，0.01至1重量份的锡催化剂，0.05至2.5重量份的氨基烷基烷氧基硅烷和0.5至2.5重量份的促进剂，其选自烷基或烯基羧酸 这些羧酸的酸或硅烷衍生物。
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