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    Preparation of phenylacetaldehydes
    3.
    发明授权
    Preparation of phenylacetaldehydes 失效
    苯乙醛的制备

    公开(公告)号：US4990684A

    公开(公告)日：1991-02-05

    申请号：US378984

    申请日：1989-07-12

    申请人： Wolfgang Hoelderich ,  Norbert Goetz ,  Leopold Hupfer

    发明人： Wolfgang Hoelderich ,  Norbert Goetz ,  Leopold Hupfer

    IPC分类号： C07C45/51 ,  C07C45/52 ,  C07C45/54 ,  C07C45/58

    CPC分类号： C07C45/58 ,  C07C45/512 ,  C07C45/513 ,  C07C45/52 ,  C07C45/54 ,  Y02P20/582

    摘要： Phenylacetaldehydes of the general formula I ##STR1## where each of R.sup.1 to R.sup.5 is independently of the others hydrogen, halogen, unsubstituted or halogen-substituted alkyl, alkenyl, alkoxyl, alkylthio or cycloalkyl, are prepared by converting glycidic esters of the general formula II ##STR2## where each of R.sup.1 to R.sup.5 is as defined above and R.sup.6 is tertbutyl or i-propyl, in the presence of zeolites and/or phosphates and/or phosphoric or boric acid on a carrier material and/or acidic metal oxides as catalysts.

    摘要翻译： 通式Ⅰ（I）的苯基乙醛通过将式（I）的缩水甘油酯转化成其中R1至R5各自独立地为氢，卤素，未取代或卤素取代的烷基，烯基，烷氧基，烷硫基或环烷基， 在载体材料上的沸石和/或磷酸盐和/或磷酸或硼酸存在下，通式II（II）其中R 1至R 5各自如上所定义，R 6为叔丁基或异丙基，和/ 或酸性金属氧化物作为催化剂。

    Preparation of vinyl ethers
    4.
    发明授权
    Preparation of vinyl ethers 失效
    乙烯的制备

    公开(公告)号：US5130435A

    公开(公告)日：1992-07-14

    申请号：US565180

    申请日：1990-08-09

    申请人： Wolfgang Hoelderich ,  Norbert Goetz ,  Leopold Hupfer

    发明人： Wolfgang Hoelderich ,  Norbert Goetz ,  Leopold Hupfer

    IPC分类号： C07C41/28

    CPC分类号： C07C41/28 ,  Y02P20/582

    摘要： Vinyl ethers of the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are identical to or different from one another, each being hydrogen, straight-chain or branched alkyl or alkenyl of up to 12 carbon atoms, cycloalkyl or cycloalkylene of from 5 to 8 carbon atoms, aryl, alkylaryl, alkenylaryl, aralkyl and aralkenyl of from 6 to 16 carbon atoms, halogen-substituted aryl or heterocyclyl, and in addition the radicals R.sup.1 and R.sup.2 or R.sup.1 and R.sup.3, together with the carbon atom to which they are bonded, can form a cycloalkane, cycloalkene or a heterocycle, and R.sup.4 is alkyl, alkylaryl or aralkyl, are prepared by eliminating an alcohol from an acetal/ketal of the formula ##STR2## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each as defined above, in the presence of a phosphate of zeolite structure and/or a precipitated phosphate of the elements B, Zr, Ce or Fe and/or phosphoric acid or boric acid on carrier material and/or acidic undoped metal oxide as catalyst, the reaction being preferably carried out in the gas phase.

    摘要翻译： 式中，R 1，R 2和R 3彼此相同或不同的乙烯基醚，各自为氢，直至12个碳原子的直链或支链烷基或烯基，5至8的环烷基或亚环烷基 碳原子，芳基，烷基芳基，烯基芳基，芳烷基和具有6至16个碳原子的芳烯基，卤素取代的芳基或杂环基，此外基团R 1和R 2或R 1和R 3与它们所键合的碳原子一起 可以形成环烷烃，环烯烃或杂环，并且R 4是烷基，烷基芳基或芳烷基，通过从式（I）的缩醛/缩酮中除去醇来制备，其中R 1，R 2，R 3和R 4各自如上所定义 在载体材料和/或酸性未掺杂的金属氧化物作为催化剂的沸石结构的磷酸盐和/或元素B，Zr，Ce或Fe和/或磷酸或硼酸的沉淀磷酸盐存在下，反应为 优选在气相中进行。

    Preparation of vinyl ethers
    5.
    发明授权
    Preparation of vinyl ethers 失效
    乙烯基醚的制备

    公开(公告)号：US4891451A

    公开(公告)日：1990-01-02

    申请号：US213589

    申请日：1988-06-30

    申请人： Wolfgang Hoelderich ,  Norbert Goetz ,  Leopold Hupfer

    发明人： Wolfgang Hoelderich ,  Norbert Goetz ,  Leopold Hupfer

    IPC分类号： C07C41/28

    CPC分类号： C07C41/28 ,  C07C2101/14 ,  Y02P20/582

    摘要： Vinyl ethers of the formula (I) ##STR1## where R.sup.1 to R.sup.3 are identical or different and are each hydrogen, a straight-chain or branched alkyl or alkenyl radical of not more than 12 carbon atoms, halogen-substituted alkyl, a cycloalkyl or cycloalkenyl radical of 5 to 8 carbon atoms, an aryl, alkylaryl, alkenylaryl, aralkyl or aralkenyl radical of 6 to 16 carbon atoms, halogen-substituted aryl or a heterocyclic radical and furthermore R.sup.1 and R.sup.2 or R.sup.1 and R.sup.3, together with the carbon atom to which they are bonded, may form a cycloalkane, cycloalkene or heterocyclic structure, and R.sup.4 is alkyl, alkylaryl or aralkyl, are prepared by a process in which an alcohol is eliminated from an acetal or ketal of the formula (II) ##STR2## where R.sup.1 to R.sup.4 have the above meanings, in the presence of borosilicate and/or iron silicate zeolites as catalysts.

    摘要翻译： 式（I）的乙烯基醚其中R 1至R 3相同或不同并且各自为氢，不超过12个碳原子的直链或支链烷基或烯基，卤素取代的烷基， 5至8个碳原子的环烷基或环烯基，6至16个碳原子的芳基，烷基芳基，烯基芳基，芳烷基或芳烯基，卤素取代的芳基或杂环基，此外R1和R2或R1和R3连同 其键合的碳原子可以通过其中从式（II）的缩醛或缩酮中除去醇的方法制备环烷烃，环烯烃或杂环结构，并且R 4是烷基，烷基芳基或芳烷基， 在有硼硅酸盐和/或铁硅酸盐沸石作为催化剂的情况下，R1至R4具有上述含义的图像（II）。

    Preparation of pyridines
    7.
    发明授权
    Preparation of pyridines 失效
    吡啶的制备

    公开(公告)号：US5081247A

    公开(公告)日：1992-01-14

    申请号：US449401

    申请日：1989-12-19

    申请人： Wolfgang Hoelderich ,  Norbert Goetz

    发明人： Wolfgang Hoelderich ,  Norbert Goetz

    IPC分类号： C07D213/08 ,  C07D213/09 ,  C07D213/14

    CPC分类号： C07D213/08 ,  C07D213/14 ,  Y02P20/582

    摘要： Pyridines of the formula ##STR1## where the individual radicals R.sup.1 may be identical or different and are each hydrogen or an aliphatic radical are prepared by reactinga) a 2-alkoxy-2,3-dihydro-4H-pyran of the formula ##STR2## or b) a glutaraldehyde of the formula ##STR3## where R.sup.1 has the abovementioned meansings and R.sup.2 is an aliphatic radical, with ammonia in the presence of an acidic, solid catalyst.

    摘要翻译： 其中各个基团R 1可以相同或不同并且各自为氢或脂族基团的式（Ⅺ）的吡啶通过使a）2-烷氧基-2,3-二氢-4H-吡喃与 式（II）或b）在酸性固体催化剂的存在下，氨与式（III）的戊二醛，其中R 1具有上述含义并且R 2是脂族基团。

    Preparation of .alpha.-ketocarboxylic esters
    9.
    发明授权
    Preparation of .alpha.-ketocarboxylic esters 失效
    α-酮羧酸酯的制备

    公开(公告)号：US4968831A

    公开(公告)日：1990-11-06

    申请号：US323861

    申请日：1989-03-15

    申请人： Norbert Goetz ,  Wolfgang Hoelderich ,  Leopold Hupfer

    发明人： Norbert Goetz ,  Wolfgang Hoelderich ,  Leopold Hupfer

    IPC分类号： C07C67/313 ,  C07C69/738 ,  C07C69/76

    CPC分类号： C07C67/313 ,  C07C69/738

    摘要： .alpha.-Ketocarboxylic esters ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are identical to or different from one another and are each hydrogen or straight-chain or branched alkyl, alkenyl, hydroxyl, alkoxy cycloalkyl or halogen and R.sup.6 is unbranched lower alkyl, are prepared by reacting glycidic esters of the formula ##STR2## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each as defined above, in the presence of zeolites or phosphates and/or phosphoric acid or boric acid on a carrier material and/or acidic metal oxides as catalysts and are used for preparing phenylacetic esters.

    摘要翻译： α-酮羧酸酯，其中R 1，R 2，R 3，R 4和R 5彼此相同或不同，各自为氢或直链或支链烷基，烯基，羟基，烷氧基环烷基或卤素，R6为未分支的 烷基，通过在载体上的沸石或磷酸盐和/或磷酸或硼酸的存在下使式（I）的缩水甘油酯反应来制备，其中R 1，R 2，R 3，R 4，R 5和R 6各自如上所定义 材料和/或酸性金属氧化物作为催化剂，并用于制备苯乙酸酯。

    Preparation of substituted pyridines
    10.
    发明授权
    Preparation of substituted pyridines 失效
    取代吡啶的制备

    公开(公告)号：US4960894A

    公开(公告)日：1990-10-02

    申请号：US278362

    申请日：1988-12-01

    申请人： Wolfgang Hoelderich ,  Norbert Goetz

    发明人： Wolfgang Hoelderich ,  Norbert Goetz

    IPC分类号： C07D213/12 ,  C07D213/50 ,  C07D213/80

    CPC分类号： C07D213/80 ,  C07D213/12 ,  C07D213/50

    摘要： Preparation of substituted pyridines of the general formula (I) ##STR1## by the reaction of acrolein and ammonia with alkanals or ketones of the general formula (II), the acetals of the alkanals,R.sup.2 --CO--CH.sub.2 --CO--R.sup.1 IIwhere R.sup.1 is hydrogen or an alkyl of from 1 to 12 carbon atoms, cycloalkyl, aryl, or arylalkyl and R.sup.2 is an alkyl or alkoxy radical; the reaction is carried out in the presence of zeolites.

    摘要翻译： 通过丙烯醛和氨与通式（II）的链烷或酮的反应制备通式（I）的取代吡啶，其中链烷醛，R2-CO-CH2-CO- R1Ⅱ其中R1是氢或1至12个碳原子的烷基，环烷基，芳基或芳基烷基，R2是烷基或烷氧基; 反应在沸石存在下进行。