利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

24 条记录 (耗时 0.026 秒)

    Pyrethroids and their use for controlling pests
    2.
    发明授权
    Pyrethroids and their use for controlling pests 失效
    拟除虫菊酯及其用于防治害虫的用途

    公开(公告)号：US4870100A

    公开(公告)日：1989-09-26

    申请号：US940649

    申请日：1986-12-11

    申请人： Bernd Wolf ,  Hans Theobald ,  Rainer Becker ,  Norbert Goetz ,  Walter Himmele ,  Rudolf Kropp

    发明人： Bernd Wolf ,  Hans Theobald ,  Rainer Becker ,  Norbert Goetz ,  Walter Himmele ,  Rudolf Kropp

    IPC分类号： A01N43/08 ,  A01N43/10 ,  A01N53/00 ,  A01N53/04 ,  A01N53/08 ,  C07C249/00 ,  C07D261/04 ,  C07D307/40 ,  C07D307/42 ,  C07D307/45 ,  C07D307/46 ,  C07D307/54 ,  C07D409/12

    CPC分类号： C07D307/42 ,  A01N43/08 ,  A01N53/00 ,  C07D261/04 ,  C07D307/46

    摘要： 2-benzylfuryl compounds of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are identical or different substituents and are each hydrogen, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, haloalkylthio, alkenyl or haloalkenyl, each of not more than 6 carbon atoms, n being 1, 2 or 3 where R.sup.3 is not hydrogen, and R.sup.4 and R.sup.5 are each hydrogen or alkyl of not more than 6 carbon atoms, R is --CHO or CHR.sup.6 OA, R.sup.6 is hydrogen, cyano, alkyl, alkenyl, haloalkenyl or alkynyl, each of not more than 6 carbon atoms, or carboxamide, and A is either hydrogen or a radical of an acid typical for pyrethroids, with the proviso that R.sup.2 is not hydrogen, chlorine, bromine, methyl or methoxy when R.sup.1 is hydrogen or methyl and R.sup.3 and A are each hydrogen, and furthermore with the proviso that R.sup.1 and R.sup.2 are not methyl when A is a radical of tetramethylcyclopropanecarboxylic acid, and finally with the proviso that R.sup.2 is not methyl, chlorine, bromine or methoxy and R.sup.1 and R.sup.3 are not hydrogen when A is a radical of chrysanthemumic acid, their preparation and their use as intermediates for crop protection agents or as crop protection agents.

    摘要翻译： 通式I（I）的2-苄基呋喃基化合物，其中R 1，R 2和R 3是相同或不同的取代基，并且各自为氢，卤素，烷基，卤代烷基，烷氧基，卤代烷氧基，卤代烷硫基，烯基或卤代烯基， 大于6个碳原子，n为1,2或3，其中R3不是氢，R4和R5各自为氢或不超过6个碳原子的烷基，R为-CHO或CHR6OA，R6为氢，氰基，烷基 ，烯基，卤代烯基或炔基，各自不超过6个碳原子，或甲酰胺，A是氢或拟除虫菊酯典型的酸的基团，条件是R2不是氢，氯，溴，甲基或甲氧基 当R 1为氢或甲基且R 3和A各自为氢时，此外，当A为四甲基环丙烷羧酸基时，R 1和R 2不为甲基，最后条件是R 2不为甲基，氯，溴或 甲氧基，当A是基团时，R 1和R 3不是氢 菊花酸，它们的制备及其作为作物保护剂的中间体或作为作物保护剂的用途。

    Preparation of 5-(2,2,2-trihaloethyl)-dialkyl-tetrahydrofuran-2-ones
    4.
    发明授权
    Preparation of 5-(2,2,2-trihaloethyl)-dialkyl-tetrahydrofuran-2-ones 失效
    制备5-（2,2,2-三卤代乙基） - 二烷基 - 四氢呋喃-2-酮

    公开(公告)号：US4320062A

    公开(公告)日：1982-03-16

    申请号：US178171

    申请日：1980-08-14

    申请人： Rudolf Kropp ,  Martin Fischer ,  Klaus Halbritter

    发明人： Rudolf Kropp ,  Martin Fischer ,  Klaus Halbritter

    IPC分类号： C07D307/30 ,  C07D307/33 ,  C07D307/32

    CPC分类号： C07D307/33 ,  C07D307/30

    摘要： Preparation of 5-(2,2,2-trihaloethyl)-4,4-dialkyl-tetrahydro-furan-2-ones of the formula I ##STR1## where R.sup.1 and R.sup.2 are each alkyl of 1 to 4 carbon atoms and X is halogen, by reacting a carboxylic acid amide of the formula II ##STR2## where R.sup.3 and R.sup.4 are each alkyl of 1 to 4 carbon atoms, aralkyl of 7 to 9 carbon atoms or aryl of 6 to 10 carbon atoms or together with the nitrogen on which they are present as substituents form a 5-membered or 6-membered saturated ring which may contain a second hetero-atom, with a carbon tetrahalide of the formula IIICX.sub.4 (III)to give an iminium salt of the formula IV ##STR3## and subsequently hydrolyzing this iminium salt; and novel iminium salts of the formula IV.

    摘要翻译： 制备式I（I）的5-（2,2,2-三卤代乙基）-4,4-二烷基 - 四氢 - 呋喃-2-酮其中R 1和R 2各自为1至4个碳原子的烷基 并且X是卤素，通过使式II的羧酰胺（II）其中R3和R4各自为1至4个碳原子的烷基，7至9个碳原子的芳烷基或6至10个碳原子的芳基 或与它们作为取代基存在的氮一起形成可含有第二杂原子的5元或6元饱和环与式III CX4（III）的四卤化碳，得到 （IV）并随后水解该亚胺鎓盐; 和式IV的新型亚胺盐。

    Preparation of 2,4,6-trimethylbenzoic acid
    7.
    发明授权
    Preparation of 2,4,6-trimethylbenzoic acid 失效
    制备2,4,6-三甲基苯甲酸

    公开(公告)号：US5296636A

    公开(公告)日：1994-03-22

    申请号：US10058

    申请日：1993-01-28

    申请人： Wolfgang Siegel ,  Rudolf Kropp ,  Jochen Schroeder

    发明人： Wolfgang Siegel ,  Rudolf Kropp ,  Jochen Schroeder

    IPC分类号： C07C45/46 ,  C07C51/29 ,  C07C51/16 ,  C07C45/00

    CPC分类号： C07C45/46 ,  C07C51/29

    摘要： A process for the preparation of 2,4,6-trimethylbenzoic acid of the formula I ##STR1## in which .alpha.-chloro-2,4,6-trimethylacetophenone is reacted with an alkali hydroxide solution and chlorine in the presence of a phase-transfer catalyst at a temperature ranging from 0.degree. to 150.degree. C. and a pressure ranging from 0.01 to 50 bar, and a process for the preparation of 2,4,6-trimethylbenzoic acid I, in which .alpha.-chloro-2.4.6-trimethylacetophenone of the formula II ##STR2## is reacted with 1,3,5-trimethylbenzene and chloroacetyl chloride in the presence of a catalyst at a temperature ranging from 0.degree. to 150.degree. C. and a pressure ranging from 0.01 to 50 bar, the catalyst used being an iron oxide.

    摘要翻译： 制备式I的2,4,6-三甲基苯甲酸（I）的方法，其中α-氯-2,4,6-三甲基苯乙酮与碱金属氢氧化物溶液和氯在存在下反应 在0〜150℃的温度和0.01〜50巴的压力范围内的相转移催化剂，以及制备2,4,6-三甲基苯甲酸I的方法，其中α-氯 - 在催化剂存在下，在0℃至150℃的温度范围内，使式II（II）的2.4.6-三甲基苯乙酮与1,3,5-三甲基苯和氯乙酰氯反应， 使用的催化剂为0.01至50巴，所述催化剂为氧化铁。

    Process for the preparation of a salt of 1-(.gamma.-halopropyl)-1,2,3,4-.beta.-carbolines
    9.
    发明授权
    Process for the preparation of a salt of 1-(.gamma.-halopropyl)-1,2,3,4-.beta.-carbolines 失效
    制备1-（γ-卤代丙基）-1,2,3,4-β-咔啉盐的方法

    公开(公告)号：US4565870A

    公开(公告)日：1986-01-21

    申请号：US519508

    申请日：1983-08-02

    申请人： Rudolf Kropp

    发明人： Rudolf Kropp

    IPC分类号： A61K31/435 ,  A61P9/00 ,  A61P25/00 ,  C07D471/04

    CPC分类号： C07D471/04

    摘要： Salts of 1,2,3,4-tetrahydro-.beta.-carbolines of the formula I ##STR1## where R is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or trifluoromethyl, x is halogen and n is an integer from 2 to 5, and their preparation are described. The compounds are intermediates for the preparation of pharmacologically active substances.

    摘要翻译： 式I的1,2,3,4-四氢-β-咔啉的盐其中R是氢，卤素，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基或三氟甲基，x是卤素和 n为2〜5的整数，对其制备进行说明。 这些化合物是制备药理活性物质的中间体。