Tin compounds
    1.
    发明授权
    Tin compounds 失效
    锡化合物

    公开(公告)号:US4374145A

    公开(公告)日:1983-02-15

    申请号:US301570

    申请日:1981-09-14

    IPC分类号: A01N55/04 C07F7/22 A01N59/16

    CPC分类号: A01N55/04 C07F7/2216

    摘要: The invention relates to organo-tin ammonium salts of the formula ##STR1## wherein each of R.sub.1, R.sub.2 and R.sub.3 is hydrogen, alkyl, unsubstituted or acylated haloalkyl, halohydroxyalkyl, hydroxyalkyl, dihaloalkyl, or epoxyalkyl; R.sub.4 is unsubstituted or acylated haloalkyl, halohydroxyalkyl, hydroxyalkyl, dihaloalkyl, epoxyalkyl or benzyl; R.sub.5 is C.sub.1 -C.sub.6 -alkyl, cyclohexyl or phenyl; each of R.sub.6 and R.sub.7 is halogen, C.sub.1 -C.sub.6 -alkyl, cyclohexyl or phenyl; and each of X.sub.1 to X.sub.4 is halogen.A process for the production of these compounds and their use in pest control are also described.

    摘要翻译: 本发明涉及下式的有机锡铵盐:其中R 1,R 2和R 3各自为氢,烷基,未取代或酰化卤代烷基,卤代羟烷基,羟基烷基,二卤代烷基或环氧烷基; R4是未取代的或酰化的卤代烷基,卤代羟烷基,羟基烷基,二卤代烷基,环氧烷基或苄基; R5是C1-C6-烷基,环己基或苯基; R 6和R 7各自为卤素,C 1 -C 6烷基,环己基或苯基; X 1〜X 4分别为卤素。 还描述了生产这些化合物的方法及其在害虫防治中的用途。

    Pesticidal triorgano-tin triazines
    2.
    发明授权
    Pesticidal triorgano-tin triazines 失效
    杀虫三有机锡三嗪

    公开(公告)号:US4390538A

    公开(公告)日:1983-06-28

    申请号:US297884

    申请日:1981-08-31

    摘要: The invention relates to triorgano-tin triazine compounds of the formula ##STR1## wherein X' is --S--Y--COOSn(R').sub.3, --O--Y--COOSn(R').sub.3 or --NH--Y--COOSn(R').sub.3, each of X" and X'" has the same meaning as X' or is halogen, (C.sub.1 -C.sub.6 alkyl).sub.2 N--, (C.sub.1 -C.sub.6 alkyl)--NH--, (C.sub.1 -C.sub.6 alky)--O-- or (C.sub.1 -C.sub.6 alkyl)--S--, Y is C.sub.1 -C.sub.6 alkylene, and the radicals R' can be the same or different and are C.sub.1 -C.sub.6 alkyl, bennzyl, phenyl or cycohexyl, each of which is unsubstituted or substituted.A process for the production of thee compounds, starting compounds suitable for this process, and the use of the compounds of formula I in pest control are also described.

    摘要翻译: 本发明涉及下式的三有机锡三嗪化合物,其中X'是-SY-COOSn(R')3,-OY-COOSn(R')3或-NH-Y-COOSn(R ')3,X“和X”'各自与X'相同或为卤素,(C1-C6烷基)2N-,(C1-C6烷基)-NH-,(C1-C6烷基)-O - 或(C 1 -C 6烷基)-S-,Y是C 1 -C 6亚烷基,并且基团R'可以相同或不同,是C 1 -C 6烷基,苯乙基,苯基或环己基,其各自是未取代或取代的。 还描述了生产化合物的方法,适用于该方法的起始化合物和式I化合物在害虫防治中的用途。

    Process for the production of methyl-alkyl tin dichlorides
    3.
    发明授权
    Process for the production of methyl-alkyl tin dichlorides 失效
    甲基 - 烷基二氯化锡的生产方法

    公开(公告)号:US4301085A

    公开(公告)日:1981-11-17

    申请号:US140404

    申请日:1980-04-14

    IPC分类号: C08K5/00 C07F7/22 C08K5/57

    CPC分类号: C07F7/2216

    摘要: A process for the production of compounds of the formula ICH.sub.3 (R)SnCl.sub.2 (I)wherein R is C.sub.4 -C.sub.20 alkyl, which process comprises reacting dimethyl tin dichloride and R-Cl, wherein R has the above meaning, in the presence of a catalyst of the formula IIR'(R").sub.3 M.sup..sym. X.sup..crclbar. (II)wherein R' is C.sub.1 -C.sub.20 alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkoxy, or is C.sub.7 -C.sub.20 aralkyl, the aryl moiety of which can be substituted by halogen or C.sub.1 -C.sub.4 alkoxy, R" has the same meaning as assigned to R' or is phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen, M.sup..sym. is a cation N, P or Sb, and X is an anion selected from the group consisting of chlorine, SnCl.sub.3, CH.sub.3 -SnCl.sub.4, (CH.sub.3).sub.2 SnCl.sub.3, SnCl.sub.5 or SbCl.sub.4.The compounds of the formula I are intermediates for obtaining stabilizers for halogen-containing thermoplastics.

    摘要翻译: 制备式I CH 3(R)SnCl 2(I)的化合物的方法,其中R是C 4 -C 20烷基,该方法包括使二氯化二甲基锡和R-Cl反应,其中R具有上述含义,在 式II R'(R“)3M(+)X( - )(II)的催化剂其中R'是未被取代或被C 1 -C 4烷氧基取代的C 1 -C 20烷基,或者是C 7 -C 20芳烷基, 其可以被卤素或C 1 -C 4烷氧基取代,R“具有与R'相同的含义,或者是未被取代或被C 1 -C 4烷基,C 1 -C 4烷氧基或卤素取代的苯基,M(+)​​是阳离子N ,P或Sb,X为选自氯,SnCl 3,CH 3 -SiCl 4,(CH 3)2 SnCl 3,SnCl 5或SbCl 4的阴离子。 式I化合物是用于获得含卤素热塑性塑料的稳定剂的中间体。

    Melamine derivatives as stabilizers for chloride-containing polymers
    5.
    发明授权
    Melamine derivatives as stabilizers for chloride-containing polymers 失效
    三聚氰胺衍生物作为含氯化聚合物的稳定剂

    公开(公告)号:US5272192A

    公开(公告)日:1993-12-21

    申请号:US867090

    申请日:1992-04-13

    摘要: Compositions containinga) a chlorine-containing polymer,b) 0.01 to 1% by weight, relative to the chlorine-containing polymer, of a compound of the formula I and/or its hydrochloride, ##STR1## in which R is C.sub.6 -C.sub.20 alkyl, C.sub.3 -C.sub.20 alkyl interrupted by 1 to 5 oxygen atoms, C.sub.1 -C.sub.20 alkyl substituted by 1 to 5 OH, C.sub.3 -C.sub.20 alkenyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.4 alkyl-substituted C.sub.3 -C.sub.8 cycloalkyl, C.sub.7 -C.sub.11 phenylalkyl, C.sub.7 -C.sub.11 phenylalkyl which is substituted on the phenyl by 1 to 3 radicals, these radicals, independently of one another, being hydroxyl, chlorine, C.sub.1 -C.sub.4 alkyl, methoxy or ethoxy, or R is furthermore a group of the formula IIa or IIb, ##STR2## in which X is C.sub.1 -C.sub.20 alkyloxy, C.sub.1 -C.sub.20 alkylthio, phenyloxy, phenylthio, benzyloxy or benzylthio, and R.sub.1, R.sub.2 and R.sub.3, independently of one another, are hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.1 -C.sub.20 alkyloxy, C.sub.1 -C.sub.20 alkythio, C.sub.2 -C.sub.12 alkyloxycarbonyl, C.sub.2 -C.sub.12 alkanoyl, phenyl, phenyloxy, phenylthio, hydroxyl, mercapto or chlorine, andc) 0.01 to 5% by weight, relative to the chlorine-containing polymer, of an Me(II) carboxylate and/or Me(II)-phenolate, in which Me(II) is Ba, Ca, Mg, Cd or Zn.Some of the compounds of the formula I are novel.

    摘要翻译: 包含a)含氯聚合物的组合物,b)相对于含氯聚合物,式I和/或其盐酸盐化合物的0.01至1重量%,其中R为 C 1 -C 20烷基,被1至5个氧原子间隔的C 3 -C 20烷基,被1至5个OH,C 3 -C 20烯基,C 3 -C 8环烷基,C 1 -C 4烷基取代的C 3 -C 8环烷基,C 7 -C 11苯基烷基,C 7 -C 11苯基烷基取代的C 1 -C 20烷基, 在苯基上被1至3个基团取代,这些基团彼此独立地是羟基,氯,C 1 -C 4烷基,甲氧基或乙氧基,或R另外是式IIa或IIb的基团, )其中X为C 1 -C 20烷氧基,C 1 -C 20烷硫基,苯氧基,苯硫基,苄氧基或苄硫基,R 1,R 2和R 3彼此独立地为氢,C 1 -C 20烷基,C 1 -C 20烷氧基, C 1 -C 20链炔基,C 2 -C 12烷氧基羰基,C 2 -C 12烷酰基,苯基,苯氧基,苯硫基,羟基,巯基或氯,和c)0.01至5重量% Me(II)羧酸盐和/或Me(I​​I) - 酚盐的含氯聚合物,其中Me(II)是Ba,Ca,Mg,Cd或Zn。 一些式I的化合物是新的。

    Organotin compounds, and their use
    6.
    发明授权
    Organotin compounds, and their use 失效
    有机锡化合物及其用途

    公开(公告)号:US4327016A

    公开(公告)日:1982-04-27

    申请号:US145417

    申请日:1980-05-01

    CPC分类号: C07F7/2268 C08K5/58

    摘要: Compounds of the formula ##STR1## wherein each R independently is hydrogen or C.sub.1 -C.sub.4 alkyl, Y is the --OR' or --S--R" group, in which R' is C.sub.12 -C.sub.16 alkyl and R" is C.sub.8 -C.sub.20 alkyl, C.sub.2 -C.sub.20 alkenyl, C.sub.6 -C.sub.20 aryl or C.sub.7 -C.sub.20 aralkyl, m is an integer from 1 to 6, and n is 1 or 2. These compounds are stabilizers for halogen-containing thermoplastics.

    摘要翻译: 其中每个R独立地是氢或C 1 -C 4烷基,Y是-OR'或-S-R“基团,其中R'是C 12 -C 16烷基,R”是C 8 -C 16烷基, C20烷基,C2-C20烯基,C6-C20芳基或C7-C20芳烷基,m为1至6的整数,n为1或2.这些化合物为含卤素热塑性塑料的稳定剂。

    Coordination-polymeric triethanolamineperchlorato(triflato)metal inner complexes as additives for synthetic polymers
    7.
    发明授权
    Coordination-polymeric triethanolamineperchlorato(triflato)metal inner complexes as additives for synthetic polymers 有权
    配位聚合三乙醇胺(triflato)金属内复合物作为合成聚合物的添加剂

    公开(公告)号:US07741390B2

    公开(公告)日:2010-06-22

    申请号:US11964671

    申请日:2007-12-26

    IPC分类号: C08K5/34 C08G73/02

    摘要: Stabilizer system for chlorinated polymers, especially PVC, comprising at least one coordination-polymeric triethanolamineperchlorato(triflato)metal inner complex comprising the monomer unit of the formula (A) The stabilizer system may additionally comprise substituted cyanoacetylureas or/and 6-aminouracils or/and 3-aminocrotonic esters or/and hydantoins or/and monomeric or polymeric dihydropyridines or alkaline earth metal hydroxides or/and hydrotalcites or/and dawsonites or/and zeolites or/and glycidyl compounds or/and cyanamides or/and cyanoguanidines or/and melamines. In addition, phosphites or/and sterically hindered amines or/and NOR-HALS compounds may be present.

    摘要翻译: 用于氯化聚合物,特别是PVC的稳定剂体系包含至少一种包含式(A)的单体单元的配位聚合的三乙醇胺三(三氟甲基)金属内复合物。稳定剂体系可以另外包含取代的氰基乙酰脲或/和6-氨基尿嘧啶或/和 3-氨基巴豆酸酯或/和乙内酰脲或/和单体或聚合二氢吡啶或碱土金属氢氧化物或/和水滑石或/和片钠铝石或/和沸石或/和缩水甘油基化合物或/和氰酰胺或/和氰胍胺或/和三聚氰胺。 此外,可能存在亚磷酸酯或/和空间位阻胺或/和NOR-HALS化合物。

    COORDINATION-POLYMERIC TRIETHANOLAMINEPERCHLORATO(TRIFLATO)METAL INNER COMPLEXES AS ADDITIVES FOR SYNTHETIC POLYMERS
    9.
    发明申请
    COORDINATION-POLYMERIC TRIETHANOLAMINEPERCHLORATO(TRIFLATO)METAL INNER COMPLEXES AS ADDITIVES FOR SYNTHETIC POLYMERS 有权
    作为合成聚合物的添加剂的协调 - 聚合三乙醇胺金属(三氟化硫)金属内部复合物

    公开(公告)号:US20090131564A1

    公开(公告)日:2009-05-21

    申请号:US11964671

    申请日:2007-12-26

    IPC分类号: C08L27/06

    摘要: Stabilizer system for chlorinated polymers, especially PVC, comprising at least one coordination-polymeric triethanolamineperchlorato(triflato)metal inner complex comprising the monomer unit of the formula (A) The stabilizer system may additionally comprise substituted cyanoacetylureas or/and 6-aminouracils or/and 3-aminocrotonic esters or/and hydantoins or/and monomeric or polymeric dihydropyridines or alkaline earth metal hydroxides or/and hydrotalcites or/and dawsonites or/and zeolites or/and glycidyl compounds or/and cyanamides or/and cyanoguanidines or/and melamines. In addition, phosphites or/and sterically hindered amines or/and NOR-HALS compounds may be present.

    摘要翻译: 用于氯化聚合物,特别是PVC的稳定剂体系包含至少一种包含式(A)的单体单元的配位聚合的三乙醇胺三(三氟甲基)金属内复合物。稳定剂体系可以另外包含取代的氰基乙酰脲或/和6-氨基尿嘧啶或/和 3-氨基巴豆酸酯或/和乙内酰脲或/和单体或聚合二氢吡啶或碱土金属氢氧化物或/和水滑石或/和片钠铝石或/和沸石或/和缩水甘油基化合物或/和氰酰胺或/和氰胍胺或/和三聚氰胺。 此外,可能存在亚磷酸酯或/和空间位阻胺或/和NOR-HALS化合物。