Photochromic compound and articles containing the same
    1.
    发明授权
    Photochromic compound and articles containing the same 失效
    光致变色复合物和含有相同的物品

    公开(公告)号:US4637698A

    公开(公告)日:1987-01-20

    申请号:US635696

    申请日:1984-07-30

    CPC分类号: C07D498/20 G03C1/685

    摘要: Photochromic compounds represented by the graphic formula: ##STR1## wherein: (a) R.sub.1 is selected from the group consisting of C.sub.1 -C.sub.8 alkyl, phenyl, phen(C.sub.1 -C.sub.4) alkyl, allyl and mono- and di-substituted phenyl, said substituents being selected from C.sub.1 -C.sub.4 alkyl and C.sub.1 -C.sub.5 alkoxy;(b) R.sub.2 and R.sub.3 are each selected from the group consisting of C.sub.1 -C.sub.5 alkyl, phenyl, C.sub.1 -C.sub.4 alkyl and C.sub.1 -C.sub.5 alkoxy mono- and disubstituted phenyl, benzyl or combined to form a cyclic ring selected from the group consisting of an alicyclic ring containing from 6 to 8 carbon atoms (including the spiro carbon atom), norbornyl and adamantyl, and(c) R.sub.4 and R.sub.5 are each selected from the group consisting of hydrogen, C.sub.1 -C.sub.5 alkyl, halogen, C.sub.1 -C.sub.5 alkoxy, nitro, cyano and C.sub.1 -C.sub.8 alkoxycarbonylare described. Solvent systems which form photochromic compositions with the above compounds and articles containing the photochromic compound are described. The compound or compositions typically change from a colorless (nonexcited) or pale color, e.g., yellow, to blue after exposure to ultraviolet light.

    摘要翻译: 其中:(a)R 1选自C 1 -C 8烷基,苯基,苯基(C 1 -C 4)烷基,烯丙基和单取代和二取代的苯基,所述 取代基选自C 1 -C 4烷基和C 1 -C 5烷氧基; (b)R2和R3各自选自C1-C5烷基,苯基,C1-C4烷基和C1-C5烷氧基单取代和二取代的苯基,苄基或组合形成选自以下的环: 含有6至8个碳原子的脂环(包括螺碳原子),降冰片基和金刚烷基,和(c)R4和R5各自选自氢,C1-C5烷基,卤素,C1-C5烷氧基 ,硝基,氰基和C 1 -C 8烷氧基羰基。 描述了用上述化合物和含有光致变色化合物的制品形成光致变色组合物的溶剂体系。 化合物或组合物在暴露于紫外光后通常从无色(无激发)或淡色,例如黄色变为蓝色。

    Photochromic compound and articles containing the same
    2.
    发明授权
    Photochromic compound and articles containing the same 失效
    光致变色复合物和含有相同的物品

    公开(公告)号:US4720547A

    公开(公告)日:1988-01-19

    申请号:US826428

    申请日:1986-02-05

    CPC分类号: C07D498/20 G03C1/685

    摘要: Described are photochromic spiro[indoline-2,3'[3H] pyrido [3,2-f][1,4]-benzoxazine compounds having a C.sub.1 -C.sub.4 monohaloalkyl or C.sub.1 -C.sub.4 polyhaloalkyl substituent on the indoline ring, and their use in plastic hosts to impart a photochromic response thereto.

    摘要翻译: 描述了在二氢吲哚环上具有C1-C4单卤代烷基或C1-C4多卤烷基取代基的光致变色螺[二氢吲哚-2,3'[3 H]吡啶并[3,2-f] [1,4] - 苯并恶嗪化合物及其用途 在塑料主体中赋予光致变色响应。

    Dissolution rate modifiers for lift-off resists
    4.
    发明授权
    Dissolution rate modifiers for lift-off resists 失效
    用于剥离抗蚀剂的溶解速率调节剂

    公开(公告)号:US06303260B1

    公开(公告)日:2001-10-16

    申请号:US09540778

    申请日:2000-03-31

    IPC分类号: G03F7023

    CPC分类号: G03F7/0045 G03F7/094

    摘要: Compositions useful for a lift-off resist in a bilayer metal lift-off process, which comprise a mixture of at least one solvent, at least one polyglutarimide resin and an effective amount of at least one actinic-absorbing dissolution rate modifier having the formulae of (IA) or (IB): in which each R1 and R2 is selected from the group consisting of hydrogen, unsubstituted or substituted alkyl, alkoxy, nitro, halo, amide or hydroxy or a combination thereof, X is an aromatic group and R3 and R4 are selected from the group consisting of hydrogen, an unsubstituted or substituted alkyl or arylsulfonyl; each m is an integer from 1 to 5 and each n is an integer from 1 to 4.

    摘要翻译: 用于双层金属剥离方法中的剥离抗蚀剂的组合物,其包含至少一种溶剂,至少一种聚戊二酰亚胺树脂和有效量的至少一种光化吸收溶解速率改性剂的混合物,其具有式 (IA)或(IB):其中每个R 1和R 2选自氢,未取代或取代的烷基,烷氧基,硝基,卤素,酰胺或羟基或其组合,X为芳基,R3和 R4选自氢,未取代或取代的烷基或芳基磺酰基; m为1〜5的整数,n为1〜4的整数。

    Poly-hydroxy aromatic dissolution modifiers for lift-off resists
    6.
    发明授权
    Poly-hydroxy aromatic dissolution modifiers for lift-off resists 失效
    用于剥离抗蚀剂的聚羟基芳族溶解改性剂

    公开(公告)号:US06395449B1

    公开(公告)日:2002-05-28

    申请号:US09540791

    申请日:2000-03-31

    IPC分类号: G03C172

    CPC分类号: G03F7/094

    摘要: Compositions useful for a lift-off resist in a bilayer metal lift-off process which comprise a mixture of at least one solvent, at least one polyglutarimide resin and an effective amount of at least one dissolution rate modifier selected from a group consisting of 2,3,4,2′,3′,4′-hexahydroxybenzophenone; hexahydroxyspirobiindane; 2,4,2′,4′-tetrahydroxybenzophenone; 1,1,1-tris-hydroxyphenylethane; 1,7-bis-(hydroxy-3-methoxyphenyl)-1,6-heptadiene-3,5-dione and at least one arylsulfonate ester of these poly-hydroxy aromatic compounds.

    摘要翻译: 用于双层金属剥离方法中的剥离抗蚀剂的组合物,其包含至少一种溶剂,至少一种聚戊二酰亚胺树脂和有效量的至少一种溶解速率改性剂的混合物,所述溶解速率改性剂选自2, 3,4,2',3',4'-六羟基二苯甲酮; 六羟基苯乙酮 2,4,2',4'-四羟基二苯甲酮; 1,1,1-三羟基苯乙烷; 1,1-双 - (羟基-3-甲氧基苯基)-1,6-庚二烯-3,5-二酮和这些多羟基芳族化合物的至少一种芳基磺酸酯。

    Method for preparing variable-light transmittance article
    8.
    发明授权
    Method for preparing variable-light transmittance article 失效
    制备可变透光制品的方法

    公开(公告)号:US5021196A

    公开(公告)日:1991-06-04

    申请号:US554321

    申请日:1990-07-16

    IPC分类号: C08K5/00 G02B1/04

    CPC分类号: G02B1/041 C08K5/0041

    摘要: Variable-transmittance articles, such as an ophthalmic lens, are prepared by applying to or incorporating within the article a combination of two (or more) organic photochromic substances exhibiting different activated absorption maxima within the matrix in which the substances are incorporated. One organic photochromic substance has an absorption maximum within the range of between greater than 590 and about 700 nanometers. The other organic photochromic substance exhibits at least one absorption maximum and preferably two absorption maxima, within the range of between about 400 and less than 590 nanometers. The organic photochromic substances are used in a proportion to achieve a near neutral coloring of the article. The article may also be tinted with a light compatible tint (dye) to achieve a more neutral color when the photochromic substances are activated.

    摘要翻译: 可变透射物品,例如眼科镜片,是通过在物品内掺入物质的基质内施用或并入物品中的两种(或更多种)表现出不同的活化吸收最大值的有机光致变色物质的组合来制备的。 一种有机光致变色物质的吸收最大值在大于590和约700纳米之间的范围内。 另一种有机光致变色物质在约400至小于590纳米的范围内表现出至少一个吸收最大值,优选两个最大吸收。 有机光致变色物质以一定比例使用以实现制品的近中性着色。 当光致变色物质被激活时,该物品也可以着色有浅色相容的色调(染料)以获得更中性的颜色。

    Variable-light transmittance article and method for preparing same
    9.
    发明授权
    Variable-light transmittance article and method for preparing same 失效
    可变透光制品及其制备方法

    公开(公告)号:US4968454A

    公开(公告)日:1990-11-06

    申请号:US147430

    申请日:1988-01-25

    CPC分类号: C08K5/0041 G02B1/041

    摘要: Variable-transmittance articles, such as an ophthalmic lens, are prepared by applying to or incorporating within the article a combination of two (or more) organic photochromic substances exhibiting different activated absorption maxima within the matrix in which the substances are incorporated. One organic photochromic substance has an absorption maximum within the range of between greater than 590 and about 700 nanometers. The other organic photochromic substance exhibits at least one absorption maximum and preferably two absorption maxima, within the range of between about 400 and less than 500 nanometers. The organic photochromic substances are used in a proportion to achieve a near neutral coloring of the article. The article may also be tinted with a light compatible tint (dye) to achieve a more neutral color when the photochromic substances are activated.

    摘要翻译: 可变透射物品,例如眼科镜片,是通过在物品内掺入物质的基质内施用或并入物品中的两种(或更多种)表现出不同的活化吸收最大值的有机光致变色物质的组合来制备的。 一种有机光致变色物质的吸收最大值在大于590和约700纳米之间的范围内。 另一种有机光致变色物质在约400至小于500纳米的范围内表现出至少一个吸收最大值,优选两个最大吸收。 有机光致变色物质以一定比例使用以实现制品的近中性着色。 当光致变色物质被激活时,该物品也可以着色有浅色相容的色调(染料)以获得更中性的颜色。