Supported catalyst, method of preparing the same, and fuel cell using the same
    1.
    发明申请
    Supported catalyst, method of preparing the same, and fuel cell using the same 有权
    负载催化剂,其制备方法和使用其的燃料电池

    公开(公告)号:US20070270305A1

    公开(公告)日:2007-11-22

    申请号:US11708600

    申请日:2007-02-21

    IPC分类号: B01J31/00

    摘要: A method of preparing a supported catalyst, the method comprising mixing a first catalytic metal precursor and a first solvent to obtain a first catalytic metal precursor mixture; mixing a carbon support for catalyst and the first catalytic metal precursor mixture, and drying the mixture to obtain a primary supported catalyst precursor; subjecting the primary supported catalyst precursor to a hydrogen reduction heat treatment, to obtain a primary supported catalyst; mixing the primary supported catalyst and a polyhydric alcohol to obtain a primary supported catalyst mixture; mixing a second catalytic metal precursor and a second solvent to obtain a second catalytic metal precursor mixture; mixing the primary supported catalyst mixture and the second catalytic metal precursor mixture to obtain a secondary supported catalyst precursor mixture; and adjusting the pH of the secondary supported catalyst precursor mixture, and then heating the secondary supported catalyst precursor mixture to obtain a supported catalyst, a supported catalyst prepared by the method, an electrode comprising the supported catalyst, and a fuel cell including the electrode are provided. A supported catalyst having a desired amount of loaded catalytic metal particles can be obtained by preparing a primary supported catalyst containing catalytic metal particles that are obtained by a primary gas phase reduction reaction of a portion of the final loading amount of catalytic metal, and reducing the remaining portion of the catalytic metal by a secondary liquid phase reduction reaction. The supported catalyst contains catalytic metal particles having a very small average particle size, which are uniformly distributed on a carbon support at a high concentration, and thus exhibits maximal catalyst activity. A fuel cell produced using the supported catalyst has improved efficiency.

    摘要翻译: 一种制备负载型催化剂的方法,所述方法包括混合第一催化金属前体和第一溶剂以获得第一催化金属前体混合物; 混合催化剂用碳载体和第一催化金属前体混合物,干燥混合物得到主要负载型催化剂前体; 对初级负载催化剂前体进行氢还原热处理,得到主要负载型催化剂; 将主要负载型催化剂和多元醇混合,得到主要负载型催化剂混合物; 混合第二催化金属前体和第二溶剂以获得第二催化金属前体混合物; 将主要负载的催化剂混合物和第二催化金属前体混合物混合,得到二次负载催化剂前体混合物; 调节二次负载型催化剂前体混合物的pH,然后加热二次负载型催化剂前体混合物,得到负载型催化剂,通过该方法制备的负载催化剂,包含负载型催化剂的电极和包含该电极的燃料电池 提供。 具有所需量的负载的催化金属颗粒的负载型催化剂可以通过制备含有催化金属颗粒的主负载催化剂获得,所述催化金属颗粒是通过催化金属的最终负载量的一部分一次气相还原反应获得的, 催化金属的剩余部分通过二次液相还原反应。 载体催化剂含有平均粒径非常小的催化金属颗粒,其以高浓度均匀分布在碳载体上,因此表现出最大的催化剂活性。 使用负载型催化剂制造的燃料电池具有提高的效率。

    Supported catalyst, method of preparing the same, and fuel cell using the same
    2.
    发明授权
    Supported catalyst, method of preparing the same, and fuel cell using the same 有权
    负载催化剂,其制备方法和使用其的燃料电池

    公开(公告)号:US07994088B2

    公开(公告)日:2011-08-09

    申请号:US11708600

    申请日:2007-02-21

    摘要: A method of preparing a supported catalyst, a supported catalyst prepared by the method, and a fuel cell using the supported catalyst. In particular, a method of preparing a supported catalyst by preparing a primary supported catalyst containing catalytic metal particles that are obtained by a primary gas phase reduction reaction of a portion of the final loading amount of a catalytic metal, and reducing the remaining portion of the catalytic metal by a secondary liquid phase reduction reaction using the primary supported catalyst. The supported catalyst contains catalytic metal particles having a very small average particle size, which are uniformly distributed on a carbon support at a high concentration, and thus exhibits maximal catalyst activity. A fuel cell produced using the supported catalyst has improved efficiency.

    摘要翻译: 制备载体催化剂的方法,通过该方法制备的负载催化剂和使用负载型催化剂的燃料电池。 特别是制备负载型催化剂的方法,该方法是通过制备含有催化金属颗粒的主载体催化剂,所述催化剂金属颗粒是通过催化金属的最终负载量的一部分的一次气相还原反应获得的,并且还原剩余部分 催化金属通过使用主要负载催化剂的二次液相还原反应。 载体催化剂含有平均粒径非常小的催化金属颗粒,其以高浓度均匀分布在碳载体上,因此表现出最大的催化剂活性。 使用负载型催化剂制造的燃料电池具有提高的效率。

    Catalyst coated membrane, membrane electrode assembly containing the same, method of producing the same, and fuel cell including the membrane electrode assembly
    3.
    发明申请
    Catalyst coated membrane, membrane electrode assembly containing the same, method of producing the same, and fuel cell including the membrane electrode assembly 审中-公开
    催化剂涂膜,含有其的膜电极组件,其制造方法和包括膜电极组件的燃料电池

    公开(公告)号:US20070269699A1

    公开(公告)日:2007-11-22

    申请号:US11708599

    申请日:2007-02-21

    IPC分类号: H01M8/10

    摘要: A catalyst coated membrane (CCM) comprising an anode catalyst layer having a first catalyst layer composed of a non-supported catalyst and a second catalyst layer composed of a supported catalyst, a cathode catalyst layer composed of a supported catalyst, and an electrolyte membrane interposed between the anode catalyst layer and a cathode catalyst layer, the first catalyst layer of the anode catalyst layer being disposed adjacent to the electrolyte membrane; a membrane electrode assembly (MEA) comprising the catalyst coated membrane; a method of preparing the membrane electrode assembly; and a fuel cell comprising the membrane electrode assembly, are provided. The CCM, which comprises a bilayered anode catalyst layer including the first catalyst layer composed of a non-supported catalyst and the second catalyst layer composed of a supported catalyst, exhibits reduced electrical resistance and interfacial resistance, and has increased catalyst availability. The use of the CCM and an MEA having the same results in a decrease in the interfacial resistance between the electrodes and the electrolyte membrane, a decrease in the amount of the catalyst used in the electrode catalyst layer, and a decrease in the thickness deviation in the electrode layers. The fuel cell employing the MEA exhibits maximal activity of the supported catalyst, and has improved cell characteristics such as output voltage, output density, efficiency, and the like.

    摘要翻译: 一种催化剂涂覆膜(CCM),其包括具有由非负载型催化剂构成的第一催化剂层和由负载型催化剂构成的第二催化剂层的阳极催化剂层,由负载型催化剂构成的阴极催化剂层和插入 在阳极催化剂层和阴极催化剂层之间,阳极催化剂层的第一催化剂层设置在电解质膜附近; 包含所述催化剂涂覆膜的膜电极组件(MEA) 一种制备膜电极组件的方法; 以及包括膜电极组件的燃料电池。 包含由非载体催化剂构成的第一催化剂层和由负载型催化剂构成的第二催化剂层的双层阳极催化剂层的CCM显示出降低的电阻和界面电阻,并且提高了催化剂的可利用性。 使用具有相同结果的CCM和MEA在电极和电解质膜之间的界面电阻降低,电极催化剂层中使用的催化剂量的减少以及厚度偏差的降低 电极层。 使用MEA的燃料电池显示出负载型催化剂的最大活性,并且具有改善的电池特性,例如输出电压,输出密度,效率等。

    Supported catalyst and method of preparing the same
    4.
    发明授权
    Supported catalyst and method of preparing the same 有权
    负载催化剂及其制备方法

    公开(公告)号:US07867940B2

    公开(公告)日:2011-01-11

    申请号:US11334472

    申请日:2006-01-19

    摘要: A method of preparing a supported catalyst includes dissolving a cation exchange polymer in alcohol to prepare a solution containing cation exchange polymer; mixing the cation exchange polymer containing solution with a catalytic metal precursor or a solution containing catalytic metal precursor; heating the mixture after adjusting its pH to a predetermined range; adding a reducing agent to the resultant and stirring the solution to reduce the catalytic metal precursor; mixing the resultant with a catalyst support; adding a precipitating agent to the resultant to form precipitates; and filtering and drying the precipitates. The method of preparing a supported catalyst can provide a highly dispersed supported catalyst containing catalytic metal particles with a reduced average size regardless of the type of catalyst support, which provides better catalytic activity than conventional catalysts at the same loading amount of catalytic metal.

    摘要翻译: 制备负载型催化剂的方法包括将阳离子交换聚合物溶解在醇中以制备含有阳离子交换聚合物的溶液; 将含阳离子交换聚合物的溶液与催化金属前体或含有催化金属前体的溶液混合; 将其pH调节至预定范围后加热混合物; 向所得物中加入还原剂并搅拌溶液以还原催化金属前体; 将所得物与催化剂载体混合; 向所得物中加入沉淀剂形成析出物; 并过滤并干燥沉淀物。 制备负载型催化剂的方法可以提供高分散的载体催化剂,其含有平均尺寸较小的催化金属颗粒,而不管催化剂载体的类型如何,这在催化金属的相同负载量下提供比常规催化剂更好的催化活性。

    Fuel composition for fuel cell and fuel cell using the same
    5.
    发明申请
    Fuel composition for fuel cell and fuel cell using the same 有权
    用于燃料电池和使用其的燃料电池的燃料组成

    公开(公告)号:US20070148515A1

    公开(公告)日:2007-06-28

    申请号:US11635031

    申请日:2006-12-07

    IPC分类号: H01M8/10 C10L1/16

    摘要: Provided is a fuel composition for a fuel cell including a first fuel which generates protons and electrons, and hydrogen gas. Also, provided is a fuel cell using the fuel composition. Using the fuel composition for a fuel cell, catalyst activation can be increased. Also, a fuel cell having high efficiency and excellent performance can be prepared using the fuel composition.

    摘要翻译: 本发明提供一种燃料电池用燃料组合物,其包括产生质子和电子的第一燃料和氢气。 此外,提供了使用燃料组合物的燃料电池。 使用燃料电池用燃料组合物可以提高催化剂活化。 此外,可以使用燃料组合物来制备具有高效率和优异性能的燃料电池。

    Fuel composition for fuel cell and fuel cell using the same
    7.
    发明授权
    Fuel composition for fuel cell and fuel cell using the same 有权
    用于燃料电池和使用其的燃料电池的燃料组成

    公开(公告)号:US07976993B2

    公开(公告)日:2011-07-12

    申请号:US11635031

    申请日:2006-12-07

    IPC分类号: H01M8/06

    摘要: Provided is a fuel composition for a fuel cell including a first fuel which generates protons and electrons, and hydrogen gas. Also, provided is a fuel cell using the fuel composition. Using the fuel composition for a fuel cell, catalyst activation can be increased. Also, a fuel cell having high efficiency and excellent performance can be prepared using the fuel composition.

    摘要翻译: 本发明提供一种燃料电池用燃料组合物,其具有产生质子和电子的第一燃料和氢气。 此外,提供了使用燃料组合物的燃料电池。 使用燃料电池用燃料组合物可以提高催化剂活化。 此外,可以使用燃料组合物来制备具有高效率和优异性能的燃料电池。

    CATALYST USED TO FORM FUEL CELL AND FUEL CELL USING THE SAME
    8.
    发明申请
    CATALYST USED TO FORM FUEL CELL AND FUEL CELL USING THE SAME 审中-公开
    用于形成燃料电池和燃料电池的催化剂

    公开(公告)号:US20080107956A1

    公开(公告)日:2008-05-08

    申请号:US11690341

    申请日:2007-03-23

    摘要: A catalyst, a method of preparing the catalyst, and a fuel cell using the catalyst. The catalyst includes a catalyst metal particle, and a porous coating layer of a conductive ceramic material disposed on the surface of the catalyst metal particle. The catalyst has a methanol tolerance index of 80%, or more, a smaller particle size than a commercially available Pt-black catalyst manufactured through a polyol process. The catalyst can include a PT catalyst metal particle that is surface treated, or coated, with a conductive ceramic ATO. The catalyst has an excellent ORR activity in the presence of methanol, and an enhanced tolerance with respect to methanol. A fuel cell, including an electrode manufactured using the catalyst, has a high energy density and a high fuel efficiency.

    摘要翻译: 催化剂,制备催化剂的方法和使用该催化剂的燃料电池。 催化剂包括催化剂金属颗粒和设置在催化剂金属颗粒表面上的导电陶瓷材料的多孔涂层。 与通过多元醇法制造的市售Pt-black催化剂相比,催化剂的甲醇耐受指数为80%以上,粒径小。 催化剂可以包括用导电陶瓷ATO进行表面处理或涂覆的PT催化剂金属颗粒。 该催化剂在甲醇存在下具有优异的ORR活性,并且相对于甲醇具有增强的耐受性。 包括使用该催化剂制造的电极的燃料电池具有高能量密度和高燃料效率。

    Anode for fuel cell, manufacturing method thereof, and fuel cell including the same
    9.
    发明授权
    Anode for fuel cell, manufacturing method thereof, and fuel cell including the same 有权
    燃料电池用阳极及其制造方法以及包含该阳极的燃料电池

    公开(公告)号:US07910259B2

    公开(公告)日:2011-03-22

    申请号:US11445340

    申请日:2006-06-02

    IPC分类号: H01M8/14

    摘要: A method of manufacturing an anode for a fuel cell including: performing an acid treatment for a carbon-based compound; washing the resultant obtained from the acid treatment with water and then performing a freeze-drying (lyophilization) process; forming a microporous diffusion layer by dispersing the lyophilized resultant in a solvent, coating the dispersed resultant on a porous carbon support, and drying; and forming a catalyst layer on top of the microporous diffusion layer, an anode for a fuel cell obtained according to the method herein, and a fuel cell using the same. An anode having improved efficiency on liquid fuel diffusion can be obtained when using the fuel diffusion layer including the microporous diffusion layer formed of the carbon-based compounds obtained after an acid treatment and a freeze-drying process according to the present invention. A fuel cell having improved performance can be manufactured by using such an anode.

    摘要翻译: 一种制造燃料电池用阳极的方法,包括:对碳系化合物进行酸处理; 用水洗涤从酸处理得到的结果,然后进行冷冻干燥(冷冻干燥)处理; 通过将冻干的产物分散在溶剂中形成微孔扩散层,将分散的产物涂布在多孔碳载体上并干燥; 以及在微多孔扩散层的顶部形成催化剂层,根据本文方法得到的燃料电池用阳极和使用该催化剂的燃料电池。 当使用包括由根据本发明的酸处理和冷冻干燥处理之后获得的碳基化合物形成的微孔扩散层的燃料扩散层时,可以获得提高液体燃料扩散效率的阳极。 可以通过使用这种阳极来制造具有改进性能的燃料电池。

    Supported catalyst, electrode using the supported catalyst and fuel cell including the electrode
    10.
    发明申请
    Supported catalyst, electrode using the supported catalyst and fuel cell including the electrode 有权
    负载催化剂,使用负载催化剂的电极和包括电极的燃料电池

    公开(公告)号:US20070059585A1

    公开(公告)日:2007-03-15

    申请号:US11445333

    申请日:2006-06-02

    IPC分类号: H01M4/96 H01M4/92 B01J21/18

    摘要: Provided are a supported catalyst, an electrode including the same, and a fuel cell using the electrode. The supported catalyst includes a carbon-based catalyst support and metal catalyst particles having an average diameter of 3.5 to 5 nm and an amount of 80 to 90 parts by weight based on 100 parts by weight of the supported catalyst in a multi-layer structure adsorbed on a surface of the carbon-based catalyst support. In the supported catalyst of the present invention, as small metal catalyst particles with an average diameter of 3.5 to 5 nm are dispersed with high concentration, high dispersion, and the multi-layer structure, catalytic efficiency is increased. A fuel cell having improved energy density and fuel efficiency characteristics can be prepared using an electrode formed using the supported catalyst.

    摘要翻译: 提供了一种负载型催化剂,包括该催化剂的电极和使用该电极的燃料电池。 载体催化剂包括碳基催化剂载体和平均直径为3.5至5nm的金属催化剂颗粒和基于100重量份吸附的多层结构中的负载型催化剂的量为80至90重量份的金属催化剂载体 在碳基催化剂载体的表面上。 在本发明的负载型催化剂中,作为平均粒径为3.5〜5nm的小金属催化剂粒子以高浓度,高分散性,多层结构分散,催化效率提高。 可以使用使用负载的催化剂形成的电极来制备具有改善的能量密度和燃料效率特性的燃料电池。