摘要:
A disk-like nanoparticle includes a core layer that comprises a cross-linked multi-vinyl substituted aromatic hydrocarbon and a shell layer that comprises tri-block copolymer chains, each having a first, a second, and a third block. The first and third blocks of the tri-block copolymer chains comprise vinyl aromatic monomer units and are crosslinked with the core. The second block comprises conjugated diene monomer units and comprises a top and bottom axial surface of the disk-like nanoparticle. In the case of a nanoparticle having A-B-C tri-block copolymer chains, the third block comprises a top and bottom axial surface of the disk-like nanoparticle.
摘要:
The present invention provides polymeric nanoparticles comprising triblock and optionally diblock copolymer chains. The architecture of the polymeric nanoparticles may be controlled, resulting in nanoparticles having non-spherical shapes. The present invention also provides a method of preparing the polymeric nanoparticles and a rubber article such as a tire manufactured from a formulation comprising the polymer nanoparticles.
摘要:
This disclosure relates to a block interpolymer comprising at least one diene block and at least one butyl block, wherein the at least one butyl block comprises residue from a functionalizing agent on at least one end adjacent to the diene block(s). The disclosure also relates to methods of making such block interpolymers. Also disclosed is a rubber composition comprising: (a) a block interpolymer comprising at least one diene block and at least one butyl block, and (b) a filler, wherein said at least one butyl block comprises residue from a functionalizing agent on at least one end adjacent to said diene block(s).
摘要:
A macromolecule including a polymer and a polyhedral radical chemically bonded to a terminus of the polymer provides numerous processing and performance advantages. Further functionalization of this macromolecule also is described as being advantageous in certain circumstances. Methods of providing, functionalizing, and utilizing the macromolecule also are provided.
摘要:
Compositions and methods are included for preparing a hairy polymeric nanoparticle including first and second shell block polymer arms are at least partially phase-separated and surround a polymeric core. One type of polymeric arm can have a greater polarity than the other type(s) of polymeric arms. A rubber composition including the hairy nanoparticles is also provided.
摘要:
The present invention provides polymeric nanoparticles comprising triblock and optionally diblock copolymer chains. The architecture of the polymeric nanoparticles may be controlled, resulting in nanoparticles having non-spherical shapes. The present invention also provides a method of preparing the polymeric nanoparticles and a rubber article such as a tire manufactured from a formulation comprising the polymer nanoparticles.
摘要:
Compositions and methods are included for preparing a hairy polymeric nanoparticle including first and second shell block polymer arms are at least partially phase-separated and surround a polymeric core. One type of polymeric arm can have a greater polarity than the other type(s) of polymeric arms. A rubber composition including the hairy nanoparticles is also provided.
摘要:
A macromolecule including a polymer and a polyhedral radical chemically bonded to a terminus of the polymer provides numerous processing and performance advantages. Further functionalization of this macromolecule also is described as being advantageous in certain circumstances. Methods of providing, functionalizing, and utilizing the macro-molecule also are provided.
摘要:
This disclosure relates to a block interpolymer comprising at least one diene block and at least one butyl block, wherein the at least one butyl block comprises residue from a functionalizing agent on at least one end adjacent to the diene block(s). The disclosure also relates to methods of making such block interpolymers. Also disclosed is a rubber composition comprising: (a) a block interpolymer comprising at least one diene block and at least one butyl block, and (b) a filler, wherein said at least one butyl block comprises residue from a functionalizing agent on at least one end adjacent to said diene block(s).
摘要:
A macromolecule including a polymer and a polyhedral radical chemically bonded to a terminus of the polymer provides numerous processing and performance advantages. Further functionalization of this macromolecule also is described as being advantageous in certain circumstances. Methods of providing, functionalizing, and utilizing the macro-molecule also are provided.