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公开(公告)号：US08187439B2
公开(公告)日：2012-05-29
申请号：US12535939
申请日：2009-08-05
申请人： Yar-Ming Wang , Hong-Hsiang Kuo , Matthew J. O'Keefe , Surender Maddela , Thomas J. O'Keefe , Jane G. O'Keefe, legal representative
IPC分类号： C25D13/10
摘要： Mixed-metal automotive vehicle bodies-in-white comprising ferrous metal surfaces, zinc surfaces, aluminum alloy surfaces, and magnesium alloy surfaces are cleaned and immersed in an aqueous bath comprising an adhesion promoter and an aqueous electrocoat bath (the adhesion promoter may be in the electrocoat bath. The adhesion promoter, which may be a cerium salt, is selected to react with each metal in the body surfaces to form an oxide layer that provides corrosion resistance for the surface and adherence for the deposited polymeric paint coating. The body is cathodic in the electrocoat deposition.
摘要翻译： 将包含黑色金属表面，锌表面，铝合金表面和镁合金表面的混合金属机车车身清洁并浸入包含粘合促进剂和水性电泳浴的水浴中（粘合促进剂可以在 选择可以是铈盐的粘合促进剂与身体表面中的每种金属反应以形成氧化物层，其为表面提供耐腐蚀性并且对于沉积的聚合物涂料涂层的粘附性。身体是 在电泳沉积中阴极。
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公开(公告)号：US20110031126A1
公开(公告)日：2011-02-10
申请号：US12535939
申请日：2009-08-05
申请人： Yar-Ming Wang , Hong-Hsiang Kuo , Matthew J. O'Keefe , Surender Maddela , Thomas J. O'Keefe , Jane G. O'Keefe
发明人： Yar-Ming Wang , Hong-Hsiang Kuo , Matthew J. O'Keefe , Surender Maddela , Thomas J. O'Keefe , Jane G. O'Keefe
IPC分类号： C23C28/04
摘要： Mixed-metal automotive vehicle bodies-in-white comprising ferrous metal surfaces, zinc surfaces, aluminum alloy surfaces, and magnesium alloy surfaces are cleaned and immersed in an aqueous bath comprising an adhesion promoter and an aqueous electrocoat bath (the adhesion promoter may be in the electrocoat bath. The adhesion promoter, which may be a cerium salt, is selected to react with each metal in the body surfaces to form an oxide layer that provides corrosion resistance for the surface and adherence for the deposited polymeric paint coating. The body is cathodic in the electrocoat deposition.
摘要翻译： 将包含黑色金属表面，锌表面，铝合金表面和镁合金表面的混合金属机车车身清洁并浸入包含粘合促进剂和水性电泳浴的水浴中（粘合促进剂可以在 选择可以是铈盐的粘合促进剂与身体表面中的每种金属反应以形成氧化物层，其为表面提供耐腐蚀性并且对于沉积的聚合物涂料涂层的粘附性。身体是 在电泳沉积中阴极。
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公开(公告)号：US08192801B2
公开(公告)日：2012-06-05
申请号：US12362499
申请日：2009-01-30
申请人： Guangling Song , Yar-Ming Wang , Hong-Hsiang Kuo
发明人： Guangling Song , Yar-Ming Wang , Hong-Hsiang Kuo
IPC分类号： C25D13/00
CPC分类号： B05D7/142 , B05D2202/20 , C09D5/008 , C09D5/088 , C09D5/4438 , C23C22/83 , C25D13/04 , C25D13/14 , C25D13/20 , C25D13/22
摘要： Some articles such as automobile components that have been constructed from steel and/or aluminum alloy parts are now being fitted with magnesium parts whose surfaces may need to be protected against corrosion. To do this an e-coating pre-film may be formed on the part's magnesium surfaces by exposing it to a conventional e-coating emulsion. And there is no need to supply a current or potential to the part or component. Magnesium's high reactivity with acidic or neutral aqueous mediums is itself a sufficient driving force to facilitate the deposition of an e-coating pre-film. At the same time any steel or aluminum alloy parts will remain unaffected. The article with a protective e-coating pre-film formed solely on its magnesium surfaces may now be advanced through a paint-line that includes conventional processes aimed at treating the component's steel and aluminum alloy parts. The process may be practiced where the magnesium surface comprises a magnesium-containing conversion or anodized coating.
摘要翻译： 一些由钢和/或铝合金部件构成的汽车部件的物品现在配备了可能需要防止其表面腐蚀的镁部件。 为了做到这一点，可以通过将其暴露于常规的电泳涂布乳液，在该部件的镁表面上形成e涂层预膜。 并且不需要为零件或部件提供电流或电位。 镁与酸性或中性水性介质的高反应性本身是促进电镀膜预膜沉积的足够驱动力。 同时任何钢或铝合金零件都不会受到影响。 具有仅在其镁表面形成的保护性电镀涂层预薄膜的物品现在可以通过涂料线进行，其包括旨在处理组分的钢和铝合金部件的常规方法。 该方法可以在镁表面包含含镁转化或阳极化涂层的情况下进行。
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公开(公告)号：US07166205B2
公开(公告)日：2007-01-23
申请号：US10635210
申请日：2003-08-06
申请人： Hong-Hsiang Kuo , Yar-Ming Wang , Joseph C. Simmer , Hsai-Yin Lee
发明人： Hong-Hsiang Kuo , Yar-Ming Wang , Joseph C. Simmer , Hsai-Yin Lee
摘要： The present invention uses a two-step anodizing process to produce a colored anodized coating on the surface of an aluminum part. In accordance with this invention, a thin hard anodized coating layer is first formed on the surface of the aluminum part and then growing a softer a clear anodized coating layer on the surface of the aluminum part underneath the hard coat layer. The soft coat is essentially colorless and suitable for color finishing. This invention drastically improves the wear resistance of the aluminum part while maintaining a desired amount of clarity for effective electrolytic coloring.
摘要翻译： 本发明使用两步阳极氧化方法在铝部件的表面上产生着色的阳极氧化涂层。 根据本发明，首先在铝部件的表面上形成薄的硬质阳极氧化涂层，然后在硬涂层下方的铝部件的表面上生长更柔软的透明阳极氧化涂层。 柔软的外套基本上是无色的，适合于彩色整理。 本发明大大提高了铝部件的耐磨性，同时保持有效电解着色所需的透明度。
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公开(公告)号：US07018521B2
公开(公告)日：2006-03-28
申请号：US09963625
申请日：2001-09-27
摘要： A method is disclosed for forming a clear anodized coating on an aluminum base alloy containing more than three percent by weight magnesium. The alloy surface to be anodized is treated with an aqueous solution of a mineral acid such as sulfuric acid (10 to 20%), nitric acid (10 to 30%) or phosphoric acid (40 to 80%) under the influence of a relatively low voltage direct current. This treatment suitably reduces the magnesium content of the surface layer and, subsequently, a relatively low current density anodization in sulfuric acid produces the clear coating. The clear coating may then be colored by known processes.
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公开(公告)号：US20050029115A1
公开(公告)日：2005-02-10
申请号：US10635210
申请日：2003-08-06
申请人： Hong-Hsiang Kuo , Yar-Ming Wang , Joseph Simmer , Hsai-Yin Lee
发明人： Hong-Hsiang Kuo , Yar-Ming Wang , Joseph Simmer , Hsai-Yin Lee
摘要： The present invention uses a two-step anodizing process to produce a colored anodized coating on the surface of an aluminum part. In accordance with this invention, a thin hard anodized coating layer is first formed on the surface of the aluminum part and then growing a softer a clear anodized coating layer on the surface of the aluminum part underneath the hard coat layer. The soft coat is essentially colorless and suitable for color finishing. This invention drastically improves the wear resistance of the aluminum part while maintaining a desired amount of clarity for effective electrolytic coloring.
摘要翻译： 本发明使用两步阳极氧化方法在铝部件的表面上产生着色的阳极氧化涂层。 根据本发明，首先在铝部件的表面上形成薄的硬质阳极氧化涂层，然后在硬涂层下方的铝部件的表面上生长更柔软的透明阳极氧化涂层。 柔软的外套基本上是无色的，适合于彩色整理。 本发明大大提高了铝部件的耐磨性，同时保持有效电解着色所需的透明度。
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公开(公告)号：US20050045487A1
公开(公告)日：2005-03-03
申请号：US10650204
申请日：2003-08-28
申请人： Sheila Kia , Hong-Hsiang Kuo , Yar-Ming Wang
发明人： Sheila Kia , Hong-Hsiang Kuo , Yar-Ming Wang
摘要： A process is disclosed for stabilizing certain colored anodized coating on aluminum articles against degradation by ultraviolet radiation. Anodized articles colored by an electrolytic or interference process can thereafter be stabilized by heat treating them at temperatures of the order of 350° F. for a period of an hour or so. The process is particularly useful for use on electrolytically colored, anodized vehicular external body panels made from suitably formable sheet metal aluminum alloys.
摘要翻译： 公开了一种用于稳定铝制品上的某些彩色阳极氧化涂层以防紫外线照射降解的方法。 然后通过电解或干涉工艺着色的阳极氧化物品可以通过在约350°F的温度下热处理一个小时左右的时间来稳定。 该方法特别适用于由合适可成形的金属铝合金制成的电解着色阳极氧化车辆外壳板上。
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公开(公告)号：US20050031856A1
公开(公告)日：2005-02-10
申请号：US10336959
申请日：2003-01-06
申请人： Hong-Hsiang Kuo , Yar-Ming Wang , Sheila Kia
发明人： Hong-Hsiang Kuo , Yar-Ming Wang , Sheila Kia
IPC分类号： B32B3/26 , B32B15/00 , B32B15/20 , C22C20060101 , C25D5/34 , C25D11/02 , C25D11/04 , C25D11/08 , C25D11/12 , C25D11/22
CPC分类号： C25D11/04 , C25D11/08 , C25D11/12 , C25D11/22 , Y10T428/12667 , Y10T428/12736 , Y10T428/12764 , Y10T428/12993 , Y10T428/249977 , Y10T428/24999 , Y10T428/265
摘要： An anodized aluminum alloy comprises an aluminum alloy comprising magnesium in an amount greater than 3 weight percent based on the total weight of the aluminum alloy; and a clear porous oxide layer having a thickness greater than about 5 micrometers disposed on and into a surface of the aluminum alloy, wherein the anodized aluminum alloy has a surface gloss value greater than about 40 gloss units as measured on a gloss meter at dual illumination angles of 60° and 85°. An anodizing process comprises immersing an aluminum alloy workpiece comprising greater than 3 weight percent magnesium based on a total weight of the aluminum alloy into an anodizing solution comprising about 10 to about 25 weight percent sulfuric acid maintained at a temperature of about 18° C. to about 22° C.; applying a first direct electric current density less than or equal to about 5 amperes per square foot for a period of time sufficient to produce an oxide layer at a thickness of at least about 5 micrometers on and into a surface of the aluminum alloy workpiece; and applying a subsequent direct electric current density greater than or equal to about 10 amperes per square foot for a period of time sufficient to produce a final oxide thickness of about 10 micrometers to about 25 micrometers, wherein the oxide layer is clear and the aluminum alloy workpiece has a gloss value greater than 40 gloss units as measured by a gloss meter at dual illumination angles of 60° and 85°.
摘要翻译： 阳极氧化铝合金包括铝合金，其包含基于铝合金总重量大于3重量％的镁; 以及设置在铝合金表面上并具有厚度大于约5微米的透明多孔氧化物层，其中所述阳极氧化铝合金具有大于约40光泽度的表面光泽度，其在双重照度下在光泽度计上测量 角度为60°和85°。 阳极氧化方法包括将包含大于3重量％镁的铝合金工件浸入基于铝合金的总重量的阳极氧化溶液中，所述阳极氧化溶液包含保持在约18℃温度下的约10至约25重量％的硫酸， 约22°C。 施加小于或等于约5安培/平方英尺的第一直流电流密度足以产生至少约5微米厚度的铝合金工件的表面上的氧化物层; 以及施加大于或等于约10安培/平方英尺的随后的直流电流密度足以产生约10微米至约25微米的最终氧化物厚度的时间段，其中所述氧化物层是透明的，并且所述铝合金 工件的光泽值大于40度光泽度，通过光泽计在60°和85°的双照度下测量。
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9.发明申请ELECTROCOATING INTERNAL SURFACES OF A METALLIC SUBSTRATE USING A WIRELESS ELECTRODE 有权使用无线电极对金属基材的内部表面进行电化学处理公开(公告)号：US20120175256A1
公开(公告)日：2012-07-12
申请号：US12987457
申请日：2011-01-10
申请人： Hua-Tzu Fan , Yar-Ming Wang , Hong-Hsiang Kuo
发明人： Hua-Tzu Fan , Yar-Ming Wang , Hong-Hsiang Kuo
IPC分类号： C25D13/14
摘要： A system for electro-coating a metallic substrate includes a DC power supply, a primary electrode, and a wireless auxiliary electrode. The primary electrode transmits electrical current through electrolyte fluid when energized by the power supply. The auxiliary electrode is within the drain hole, and receives the current from the fluid at one end. The auxiliary electrode boosts the calibrated voltage at the opposite end near the drain hole. In a method for depositing thin film material onto the internal surfaces, the wireless auxiliary electrode is positioned in the drain hole, and the calibrated voltage is applied from the DC power supply to the primary electrode. Electrical current transmitted through the fluid is received at the first end of the auxiliary electrode. The calibrated voltage is boosted in proximity to the drain hole at the second end of the same auxiliary electrode. A wireless auxiliary electrode assembly is also provided.
摘要翻译： 用于电镀金属基底的系统包括直流电源，初级电极和无线辅助电极。 当电源供电时，主电极通过电解质流体传输电流。 辅助电极位于排水孔内，并在一端接受来自流体的电流。 辅助电极在靠近排水孔的相对端增强校准电压。 在用于在内表面上沉积薄膜材料的方法中，无线辅助电极位于排水孔中，并且校准的电压从直流电源施加到初级电极。 通过流体传输的电流在辅助电极的第一端被接收。 校准电压在相同辅助电极的第二端附近的排水孔附近升压。 还提供无线辅助电极组件。
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公开(公告)号：US07122107B2
公开(公告)日：2006-10-17
申请号：US10650204
申请日：2003-08-28
摘要： A process is disclosed for stabilizing certain colored anodized coating on aluminum articles against degradation by ultraviolet radiation. Anodized articles colored by an electrolytic or interference process can thereafter be stabilized by heat treating them at temperatures of the order of 350° F. for a period of an hour or so. The process is particularly useful for use on electrolytically colored, anodized vehicular external body panels made from suitably formable sheet metal aluminum alloys.
摘要翻译： 公开了一种用于稳定铝制品上的某些彩色阳极氧化涂层以防紫外线照射降解的方法。 然后通过电解或干涉工艺着色的阳极氧化物品可以通过在约350°F的温度下热处理一个小时左右的时间来稳定。 该方法特别适用于由合适可成形的金属铝合金制成的电解着色阳极氧化车辆外壳板上。
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