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1.发明申请Hollow Fibers, A Method of Manufacturing a Hollow Fiber Bundle, A Cylindrical Module of Hollow Fiber Membrane, and an Immersion Type Module of Hollow Fiber Membrane 审中-公开空心纤维，中空纤维束制造方法，中空纤维膜的圆柱形模块和中空纤维膜的浸入型模块公开(公告)号：US20090301959A1
公开(公告)日：2009-12-10
申请号：US11992734
申请日：2006-09-15
申请人： Yasuhiro Tada , Yasushi Ebihara , Masayuki Hino , Takafumi Kato , Toshiya Mizuno
发明人： Yasuhiro Tada , Yasushi Ebihara , Masayuki Hino , Takafumi Kato , Toshiya Mizuno
CPC分类号： B01D63/021 , B01D63/025 , B01D2313/08 , B01D2315/06 , Y10T29/49826 , Y10T428/13
摘要： The object of the invention is to provide: a hollow fiber bundle, a method of manufacturing the hollow fiber bundle, a cylindrical module of hollow fiber membrane, and an immersion type module of hollow fiber membrane wherein the hollow fibers are easy to apply scrubbing while maintaining specified intervals among the hollow fibers. A hollow fiber bundle bundling porous hollow fibers, including; hollow fibers 10 that are open at one side end and closed at the other side end; and a closed side potting 60 and an open side potting 50 plate shaped at right angles to the hollow fibers for securing the hollow fibers, in which through holes 30 are disposed on a circumference, the hollow fibers are bundled in a cylindrical shape inside the through holes and disposed with a specified circumferential interval adjacent each other in a circumferential direction and with a specified radial interval adjacent each other in a radial direction, the hollow fibers are bundled outside the through holes disposed at specified peripheral intervals wherein the hollow fibers are disposed with a specified peripheral interval adjacent each other in a peripheral direction in the shape surrounding the outside of the through holes and with a specified peripheral right angle interval adjacent each other in a right angle to the periphery.
摘要翻译： 本发明的目的是提供：中空纤维束，中空纤维束的制造方法，中空纤维膜的圆筒状模块和中空纤维膜的浸渍型组件，其中中空纤维易于进行洗涤，同时 在中空纤维之间保持指定的间隔。 中空纤维束捆扎多孔中空纤维，包括： 在一侧端部开口并在另一侧端部封闭的中空纤维10; 以及与中空纤维成直角成形的封闭侧封装件60和开口侧封装件50，用于固定中空纤维，其中通孔30设置在圆周上，中空纤维在圆形状内部被捆成圆柱形 在圆周方向上彼此相邻并且沿径向相邻的规定的径向间隔配置有规定的周向间隔，将中空纤维捆扎在以规定的周期间隔设置的通孔的外侧，中空纤维配置有 围绕通孔外部的形状的圆周方向相邻的规定的周边间隔和与周边成直角相邻的规定的周边直角间隔。
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2.发明申请Screen-Like Object Made of Hollow Fibers, a Method of Manufacturing a Hollow Fiber Bundle, a Cylindrical Module of Hollow Fiber Membrane, and an Immersion Type Module of Hollow Fiber Membrane 审中-公开由空心纤维制成的屏幕状物体，中空纤维束的制造方法，中空纤维膜的圆柱形模块和中空纤维膜的浸入型模块公开(公告)号：US20100224548A1
公开(公告)日：2010-09-09
申请号：US11992738
申请日：2006-09-15
CPC分类号： B01D63/021 , B01D63/02 , B01D63/043 , B01D2313/02 , B01D2313/14 , B01D2321/00
摘要： The object of the invention is to provide: a screen-like object made of hollow fibers, a method of manufacturing a hollow fiber bundle, a cylindrical module of hollow fiber membrane, and an immersion type module of hollow fiber membrane wherein the hollow fibers are easy to bundle while keeping fiber-to-fiber intervals. The screen-like object made of hollow fibers includes: porous hollow fibers 10 disposed parallel at even intervals, tapes 26 for tying together the hollow fibers respectively at both ends of the hollow fibers, and a water-soluble tape for tying together the hollow fibers at a position apart from both ends of the hollow fibers across the hollow fibers. The method of manufacturing a hollow fiber bundle includes: the steps of forming a screen-like object made of hollow fibers, sealing one end or both ends of the hollow fibers, winding up the screen-like object made of hollow fibers so as to bundle the hollow fibers, forming pottings for integrally securing both ends, respectively, of the wound-up screen-like object, and cutting the potting together with the hollow fibers along a plane at right angles to the hollow fibers to cut off a sealed end and to open the hollow fibers.
摘要翻译： 本发明的目的是提供一种由中空纤维制成的丝网状物体，中空纤维束的制造方法，中空纤维膜的圆筒状模块以及中空纤维膜的浸渍型组件，其中中空纤维为 容易捆绑，同时保持纤维间隔。 由中空纤维制成的丝网状物体包括：以均匀间隔平行设置的多孔中空纤维10，用于将中空纤维分别与中空纤维的两端结合在一起的带26和用于将中空纤维捆扎在一起的水溶性带 在穿过中空纤维的中空纤维的两端分开的位置。 制造中空纤维束的方法包括：形成由中空纤维制成的丝网状物体，密封中空纤维的一端或两端的步骤，卷绕由中空纤维制成的丝网状物体，以便捆扎 中空纤维，分别形成用于一体地固定卷绕的丝网状物体的两端的盆栽，并且与中空纤维一起沿着与中空纤维成直角的平面切割灌封，以切断密封端，并且 打开中空纤维。
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3.发明申请公开(公告)号：US20090032455A1
公开(公告)日：2009-02-05
申请号：US12087080
申请日：2006-12-26
申请人： Yasuhiro Tada , Masayuki Hino , Yasushi Ebihara , Toshiya Mizuno
发明人： Yasuhiro Tada , Masayuki Hino , Yasushi Ebihara , Toshiya Mizuno
CPC分类号： B01D63/023 , B01D63/021 , B01D2323/42
摘要： An object of the present invention is to provide a potting agent that enables the reduction of crawling and ensures sufficient penetration between the porous hollow fibers in stationary potting. The potting agent of the present invention is a potting agent for fixing an end portion of a porous hollow fiber group composed of a plurality of porous hollow fibers, and contains a resin material and a filler. The content of the filler is equal to or less than the content of the filler at a rising point of a variation curve of viscosity of the potting agent to filler content.
摘要翻译： 本发明的目的是提供一种能够减少爬行并确保在固定灌封中的多孔中空纤维之间充分渗透的灌封剂。 本发明的灌封剂是用于固定由多根多孔中空纤维构成的多孔中空纤维团的端部的灌封剂，并且含有树脂材料和填料。 在灌封剂与填料含量的粘度变化曲线的上升点处，填料的含量等于或小于填料的含量。
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公开(公告)号：US20080078718A1
公开(公告)日：2008-04-03
申请号：US11630896
申请日：2005-06-27
申请人： Yasuhiro Tada , Shingo Taniguchi , Masayuki Hino , Takeo Takahashi , Kenichi Suzuki , Toshiya Mizuno
发明人： Yasuhiro Tada , Shingo Taniguchi , Masayuki Hino , Takeo Takahashi , Kenichi Suzuki , Toshiya Mizuno
CPC分类号： B01D71/34 , B01D67/0027 , B01D67/003 , B01D69/02 , B01D69/08 , B01D71/38 , B01D2323/20 , B01D2325/24 , B01D2325/30
摘要： A porous membrane for water treatment of the present invention is made of a resin composition containing 100 parts by weight of a polyvinylidene fluoride based resin, and 5 to 13 parts by weight of a polyvinyl alcohol based polymer having a degree of saponification of 10 to 80 mol %. The porous membrane has a permeation wetting tension of 38 to 72 mN/m, and a tensile strength of 7 to 20 MPa, and thus is characterized by having the excellent mechanical strength and wettability. This is a porous membrane for water treatment essentially containing the polyvinylidene fluoride based resin, which allows water treatment to be highly efficiently performed on raw water (river water, industrial waste water, and the like), in particular. The porous membrane is manufactured, firstly, by melt-extruding a mixture composition containing a polyvinylidene fluoride based resin, a polyvinyl alcohol based polymer, a plasticizer, and a solvent, and then by extracting the plasticizer and the solvent from the substance thus extruded.
摘要翻译： 本发明的水处理用多孔膜由含有100重量份聚偏二氟乙烯类树脂的树脂组合物和5〜13重量份皂化度为10〜80的聚乙烯醇系聚合物 mol％。 多孔膜的渗透润湿张力为38〜72mN / m，拉伸强度为7〜20MPa，其特征在于具有优异的机械强度和润湿性。 这是一种基本上含有聚偏二氟乙烯类树脂的水处理用多孔膜，特别是能够对原水（河水，工业废水等）高效地进行水处理。 首先，通过熔融挤出含有聚偏二氟乙烯系树脂，聚乙烯醇类聚合物，增塑剂和溶剂的混合物组合物，然后从由此挤出的物质中提取增塑剂和溶剂来制造多孔膜。
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5.发明授权公开(公告)号：US07780014B2
公开(公告)日：2010-08-24
申请号：US11578425
申请日：2005-04-07
申请人： Yasuhiro Tada , Takeo Takahashi , Masayuki Hino , Shingo Taniguchi , Kenichi Suzuki , Toshiya Mizuno
发明人： Yasuhiro Tada , Takeo Takahashi , Masayuki Hino , Shingo Taniguchi , Kenichi Suzuki , Toshiya Mizuno
CPC分类号： B01D71/34 , B01D67/0011 , B01D67/0018 , B01D67/0027 , B01D67/003 , B01D67/0088 , B01D69/02 , B01D69/08 , B01D2323/20 , B01D2323/48 , B01D2325/24 , B01D2325/32 , B01D2325/34 , D01D5/24 , D01F6/12
摘要： A composition is formed by blending a vinylidene fluoride resin having a relatively high molecular weight and an improved crystallinity represented by a difference Tm2−Tc of at most 32° C. between an inherent melting point Tm2 and a crystallization temperature Tc of the resin with a plasticizer and a good solvent for vinylidene fluoride resin, and the composition is melt-extruded into a hollow fiber-form. The hollow fiber-form extrudate is then cooled to be solidified from an outside thereof by introduction into cooling medium and subjected to extraction of the plasticizer and stretching, thereby forming a hollow fiber porous membrane of vinylidene fluoride resin characterized by co-presence of crystal oriented portion and crystal non-oriented portion recognizable by X-ray diffraction method. The resultant hollow fiber porous membrane of vinylidene fluoride resin has micro-pores of appropriate size and distribution, is excellent in mechanical strength represented by tensile strength and elongation at break and is useful as a water microfiltration membrane.
摘要翻译： 通过将具有相对较高分子量和改善的结晶度的偏二氟乙烯树脂与具有至少32℃的差Tm2-Tc表示的固有熔点Tm2和树脂的结晶温度Tc混合形成组合物， 增塑剂和偏氟乙烯树脂的良溶剂，并将组合物熔融挤出成中空纤维形式。 然后将中空纤维状挤出物从外部冷却，通过引入冷却介质中进行固化，并进行增塑剂的提取和拉伸，形成偏氟乙烯树脂的中空纤维多孔膜，其特征在于，以晶体取向共存 部分和晶体非取向部分可通过X射线衍射法识别。 得到的偏氟乙烯树脂中空纤维多孔膜具有适当尺寸和分布的微孔，机械强度优异，以拉伸强度和断裂伸长率为代表，可用作水微滤膜。
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6.发明申请Vinylidene Fluoride Resin Hollow Fiber Porous Membrane and Method for Production Thereof 审中-公开亚乙烯基氟树脂中空纤维多孔膜及其生产方法公开(公告)号：US20090261034A1
公开(公告)日：2009-10-22
申请号：US11991955
申请日：2006-09-12
CPC分类号： B01D71/34 , B01D63/024 , B01D67/0027 , B01D67/0086 , B01D69/02 , B01D69/08 , B01D69/087 , B01D2313/24 , B01D2323/12 , B01D2323/20 , C02F1/444 , D01D5/247 , D01F6/12
摘要： A hollow-fiber porous membrane comprising a hollow-fiber form of vinylidene fluoride resin and satisfying the following properties (A) and (B), is provided as a hollow-fiber porous membrane of vinylidene fluoride resin having an average pore size and a further uniform pore size distribution (A) and a large water permeation rate regardless of good efficiency of blocking minute particles (bacteria) (B), as represented by: (A) a ratio Pmax (1 m)/Pm of at most 4.0 between a maximum pore size Pmax (1 m) measured at a test length of 1 m according to the bubble point method and an average pore size Pm of 0.05-0.20 μm measured according to the half dry method; and (B) a ratio F (L=200 mm, v=70%)/PM2 of at least 3000 (m/day·μm2), wherein the ratio F (L=200 mm, v=70%)/Pm2 denotes a ratio between F (L=200 mm, v=70%) which is a value normalized to a porosity v=70% of a water permeation rate F (100 kPa, L=200 mm) measured at a test length L=200 mm under the conditions of a pressure difference of 100 kPa and a water temperature of 25° C. and a square Pm2 of an average pore size Pm. The hollow-fiber porous membrane is produced by a process, comprising: subjecting a stretched hollow-fiber porous membrane of vinylidene fluoride resin to at least two stages of relaxation treatment in a non-wetting environment.
摘要翻译： 提供一种中空纤维多孔膜，其包含中空纤维形式的偏氟乙烯树脂，并满足以下性质（A）和（B））作为平均孔径和另外的平均孔径的偏氟乙烯树脂的中空纤维多孔膜 均匀的孔径分布（A）和大的水渗透速率，而不管堵塞微小颗粒（细菌）（B）的良好效率，如下所示：（A）比值Pmax（1m）/ Pm在 根据泡点法测试的测试长度为1μm的最大孔径Pmax（1μm）和根据半干法测量的平均孔径Pm为0.05-0.20μm; 和（B）比例F（L = 200mm，v = 70％）/ PM2为至少3000（m / day.mum2），其中比率F（L = 200mm，v = 70％）/ Pm2表示 F（L = 200mm，v = 70％）之间的比率，其是在试验长度L = 200时测量的孔隙率v = 70％的渗透速率F（100kPa，L = 200mm）的归一化值 压力差为100kPa，水温为25℃的条件下为平均孔径Pm的平方Pm2。 中空纤维多孔膜通过以下方法制造，该方法包括：使偏氟乙烯树脂的拉伸中空纤维多孔膜在非润湿环境中进行至少两个阶段的松弛处理。
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7.发明申请Vinylidene Fluoride Resin Hollow Filament Porous Membrane, Water Filtration Method Using the Same, and Process for Producing Said Vinylidene Fluoride Resin Hollow Filament Porous Membrane 审中-公开亚乙烯基氟化物树脂空心丝多孔膜，使用其的水过滤方法以及用于生产所述偏氟乙烯树脂中空丝多孔膜的方法公开(公告)号：US20090206035A1
公开(公告)日：2009-08-20
申请号：US11884371
申请日：2006-02-09
申请人： Takeo Takahashi , Yasuhiro Tada , Kenichi Suzuki , Masayuki Hino , Shingo Taniguchi , Toshiya Mizuno
发明人： Takeo Takahashi , Yasuhiro Tada , Kenichi Suzuki , Masayuki Hino , Shingo Taniguchi , Toshiya Mizuno
CPC分类号： B01D69/02 , B01D67/0018 , B01D69/08 , B01D71/34 , B01D2323/20 , B01D2325/022 , B01D2325/24
摘要： A hollow-fiber porous membrane, comprising a hollow fiber-form porous membrane in a network texture of vinylidene fluoride resin showing a pore size distribution in a direction of its membrane thickness including an outer surface-average pore size P1 as measured by a scanning electron microscope and a membrane layer-average pore size P2 as measured by half-dry method giving a ratio P1/P2 of at least 2.5. The hollow-fiber porous membrane is excellent in long-term water filtration performance including efficiency of regeneration by air scrubbing. The hollow-fiber porous membrane is produced through a process, wherein a mixture of vinylidene fluoride resin, a plasticizer and a good solvent for vinylidene fluoride resin, is melt-extruded in a hollow-fiber film and cooled and formed into a solidified film within a cooling medium containing at least a certain proportion of a good solvent for vinylidene fluoride resin.
摘要翻译： 一种中空纤维多孔膜，其包含在偏二氟乙烯树脂的网状结构中的中空纤维状多孔膜，其表现出通过扫描电子测量的包括外表面平均孔径P1的膜厚度方向上的孔径分布 显微镜和通过半干法测量的膜层平均孔径P2，其比值P1 / P2至少为2.5。 中空纤维多孔膜的长期水过滤性能优异，包括通过空气洗涤再生的效率。 中空纤维多孔膜通过以下方法制造，其中偏二氟乙烯树脂，增塑剂和偏二氟乙烯树脂的良溶剂的混合物在中空纤维膜中熔融挤出并冷却并形成固化膜 含有至少一定比例的偏二氟乙烯树脂的良溶剂的冷却介质。
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8.发明申请公开(公告)号：US20070241050A1
公开(公告)日：2007-10-18
申请号：US11578425
申请日：2005-04-07
申请人： Yasuhiro Tada , Takeo Takahashi , Masayuki Hino , Shingo Taniguchi , Kenichi Suzuki , Toshiya Mizuno
发明人： Yasuhiro Tada , Takeo Takahashi , Masayuki Hino , Shingo Taniguchi , Kenichi Suzuki , Toshiya Mizuno
CPC分类号： B01D71/34 , B01D67/0011 , B01D67/0018 , B01D67/0027 , B01D67/003 , B01D67/0088 , B01D69/02 , B01D69/08 , B01D2323/20 , B01D2323/48 , B01D2325/24 , B01D2325/32 , B01D2325/34 , D01D5/24 , D01F6/12
摘要： A composition is formed by blending a vinylidene fluoride resin having a relatively high molecular weight and an improved crystallinity represented by a difference Tm2−Tc of at most 32° C. between an inherent melting point Tm2 and a crystallization temperature Tc of the resin with a plasticizer and a good solvent for vinylidene fluoride resin, and the composition is melt-extruded into a hollow fiber-form. The hollow fiber-form extrudate is then cooled to be solidified from an outside thereof by introduction into cooling medium and subjected to extraction of the plasticizer and stretching, thereby forming a hollow fiber porous membrane of vinylidene fluoride resin characterized by co-presence of crystal oriented portion and crystal non-oriented portion recognizable by X-ray diffraction method. The resultant hollow fiber porous membrane of vinylidene fluoride resin has micro-pores of appropriate size and distribution, is excellent in mechanical strength represented by tensile strength and elongation at break and is useful as a water microfiltration membrane.
摘要翻译： 通过将具有相对较高分子量和改进的结晶度的偏二氟乙烯树脂混合在一起，通过将不同Tm 2 -Tc表示为至多32℃的固有熔点Tm 2和树脂的结晶温度Tc之间的混合物形成组合物 用增塑剂和偏氟乙烯树脂的良溶剂，将组合物熔融挤出成中空纤维形式。 然后将中空纤维状挤出物从外部冷却，通过引入冷却介质中进行固化，并进行增塑剂的提取和拉伸，形成偏氟乙烯树脂的中空纤维多孔膜，其特征在于，以晶体取向共存 部分和晶体非取向部分可通过X射线衍射法识别。 得到的偏氟乙烯树脂中空纤维多孔膜具有适当尺寸和分布的微孔，机械强度优异，以拉伸强度和断裂伸长率为代表，可用作水微滤膜。
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9.发明申请Holow-Fiber Porous Water Filtration Membrane of Vinyldene Fluoride Resin and Process for Producing the Same 有权乙烯基氟树脂的水性纤维多孔水过滤膜及其制备方法公开(公告)号：US20070215540A1
公开(公告)日：2007-09-20
申请号：US11629350
申请日：2005-06-08
申请人： Yasuhiro Tada , Takeo Takahashi , Masayuki Hino , Shingo Taniguchi , Kenichi Suzuki , Toshiya Mizuno
发明人： Yasuhiro Tada , Takeo Takahashi , Masayuki Hino , Shingo Taniguchi , Kenichi Suzuki , Toshiya Mizuno
CPC分类号： B01D69/08 , B01D67/0011 , B01D67/0018 , B01D67/0027 , B01D67/003 , B01D69/02 , B01D71/34 , B01D2323/20 , B01D2325/24 , B01D2325/30 , B01D2325/32 , B01D2325/34 , Y10T428/249978
摘要： A hollow fiber-form porous membrane of vinylidene fluoride resin having a high crystallinity as represented by a crystal melting enthalpy of at least 58 J/g is produced by forming a composition of a vinylidene fluoride resin having a relatively high weight-average molecular weight of at least 3×105 blended with a plasticizer and a good solvent for vinylidene fluoride resin, melt-extruding the composition into a hollow fiber-form film, and solidifying the film by cooling it from an outside thereof by contact with a cooling liquid inert to vinylidene fluoride resin while crystallizing the vinylidene fluoride resin at an appropriately moderate speed. The resultant hollow fiber-form porous membrane is excellent in mechanical strength represented by tensile strength and elongation at break, and also excellent in chemical resistance, thus being effectively used as a water micro-filtration membrane.
摘要翻译： 通过形成具有至少58J / g的结晶熔融焓所表示的具有高结晶度的偏氟乙烯树脂的中空纤维状多孔膜通过形成具有相对高的重均分子量的偏二氟乙烯树脂 与增塑剂和用于偏二氟乙烯树脂的良溶剂共混至少3×10 5，将组合物熔融挤出成中空纤维形式的膜，并通过接触从其外部冷却来固化该膜 与偏二氟乙烯树脂呈惰性的冷却液体，同时以适度适度的速度使偏氟乙烯树脂结晶。 得到的中空纤维状多孔质膜以拉伸强度和断裂伸长率为代表的机械强度优异，耐化学性优异，因此有效地用作水微滤膜。
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10.发明授权Vinylidene fluoride based resin porous hollow yarn and method for production thereof 有权偏二氟乙烯系树脂多孔中空丝及其制造方法公开(公告)号：US07569145B2
公开(公告)日：2009-08-04
申请号：US10574111
申请日：2004-09-24
申请人： Yasuhiro Tada , Takeo Takahashi , Masayuki Hino , Toshiya Mizuno , Kosuke Abe
发明人： Yasuhiro Tada , Takeo Takahashi , Masayuki Hino , Toshiya Mizuno , Kosuke Abe
CPC分类号： B01D67/002 , B01D67/0027 , B01D67/003 , B01D67/0088 , B01D69/02 , B01D69/08 , B01D71/34 , B01D2323/20 , B01D2325/12 , B01D2325/20 , D01F6/12
摘要： There is provided a porous hollow fiber of vinylidene fluoride resin which has a water permeation rate that is large per fiber and little dependent on the length, has a large treatment capacity per volume of a filtering module, and is therefore suitable as a microfilter element. That is, a porous hollow fiber, comprising a vinylidene fluoride resin having a weight-average molecular weight of at least 3×105, having a water permeation rate F (m3/m2·day) measured at a pressure difference of 100 kPa and at a water temperature of 25° C. in a range of test length L=0.2-0.8 (m) and expressed in a linear relationship with the test length L of: F=C·L+F0 (formula 1) and satisfying requirements (a)-(d) shown below: (a) a average slope C (/day) of: −20≦C≦0, (b) an intercept (basic permeability) F0 (m3/m2·day) of: F0≧30, (c) a relation between F0 (m3/m2·day) and an average pore diameter P (μm) according to half-dry method of F0/P≧300, and (d) an outer diameter of at most 3 mm.
摘要翻译： 提供了一种偏氟乙烯树脂的多孔中空纤维，其具有每纤维的水渗透速率大，并且几乎不依赖于长度，每个体积的过滤组件具有大的处理能力，因此适合作为微过滤器元件。 也就是说，一种多孔中空纤维，其包含重均分子量为至少3×10 5的偏二氟乙烯树脂，其具有在100千帕的压力差下测得的水渗透速率F（m3 / m2.day） 在测试长度L = 0.2-0.8（m）的范围内，温度为25℃，并且与试验长度L呈线性关系：F = C.L + F0（式1）并满足要求（a） （d）如下所示：（a）平均斜率C（/天）：-20 <= C <= 0，（b）截距（基本渗透率）F0（m3 / m2.day）：F0> = 30，（c）根据F0 / P> = 300的半干法，F0（m3 / m2.day）与平均孔径P（母）之间的关系，（d）最大外径 3毫米。
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