公开(公告)号：US07790917B2

公开(公告)日：2010-09-07

申请号：US12298260

申请日：2007-04-24

申请人： Yasunari Okada ,  Hajime Ito ,  Hideki Yamane ,  Nobuaki Matsumoto

发明人： Yasunari Okada ,  Hajime Ito ,  Hideki Yamane ,  Nobuaki Matsumoto

IPC分类号： C07C69/34 ,  C08D303/12

CPC分类号： C08F290/06 ,  C08F222/1006 ,  C08F290/061 ,  C08F290/064 ,  C08G59/186

摘要： The present invention provides an adamantyl group containing epoxy-modified (meth)acrylate and a resin composition containing it which are imparted by transparency, optical characteristics such as (durable) light resistance and the like, heat-resistance, and good mechanical properties.For example, they are an adamantyl group containing epoxy-modified (meth)acrylate having the following general formula (I) and a composition containing it. In the formula, R1 represents a hydrogen atom or a methyl group, and R2 represents a halogen atom or an aliphatic hydrocarbon group which may contain a hetero atom. Plural R2 may be the same or different, and m represents an integer of 0 to 4 and n represents an integer of 0 or more.

摘要翻译： 本发明提供含有环氧改性（甲基）丙烯酸金刚烷基和含有它的树脂组合物，它们由透明性，耐光性等光学特性赋予耐热性和良好的机械性能。 例如，它们是含有具有以下通式（I）的环氧改性（甲基）丙烯酸酯和含有它的组合物的金刚烷基。 在该式中，R 1表示氢原子或甲基，R 2表示卤素原子或可含有杂原子的脂肪族烃基。 多个R2可以相同或不同，m表示0〜4的整数，n表示0以上的整数。

公开(公告)号：US20090062481A1

公开(公告)日：2009-03-05

申请号：US12279772

申请日：2007-02-01

申请人： Hajime Ito ,  Yasunari Okada ,  Hideki Yamane ,  Nobuaki Matsumoto

发明人： Hajime Ito ,  Yasunari Okada ,  Hideki Yamane ,  Nobuaki Matsumoto

IPC分类号： C08L63/00 ,  C07D305/06 ,  C07D303/12

CPC分类号： C07D303/30 ,  C07D305/06 ,  C08G59/24 ,  C08G59/42

摘要： To provide an adamantane derivative, a compound having an adamantane skeleton, compositions containing them that can provide a cured product having excellent optical properties such as transparency and light resistance, long-term heat resistance and electric characteristics such as dielectric permittivity, and optical electronic members using the compositions.An adamantane derivative represented by the general formula (I), a compound with an adamantane skeleton represented by the general formula (VII) or (VIII), compositions containing them, and optical electronic members using the resin compositions. In the formulas, W represents, for example, a hydrogen atom, X represents, for example, a group represented by the general formula (II), Y represents a group represented by the formula (V) or (VI), R1 represents a methyl group or an ethyl group, R2 represents a C1 to C10 hydrocarbon group which may contain O or S, m is an integer of 2 to 4, k is an integer of 0 to (16−m) and p and q are each an integer of 1 to 5.

摘要翻译： 为了提供金刚烷衍生物，具有金刚烷骨架的化合物，含有它们的组合物可以提供具有优异的光学性质如透明性和耐光性，长期耐热性和电特性如介电常数的固化产物和光学电子部件 使用组合物。 由通式（I）表示的金刚烷衍生物，具有由通式（VII）或（VIII）表示的金刚烷骨架的化合物，含有它们的组合物和使用该树脂组合物的光学电子部件。 在该式中，W表示例如氢原子，X表示例如由通式（II）表示的基团，Y表示由式（V）或（VI）表示的基团，R1表示 甲基或乙基，R2表示可以含有O或S的C1〜C10烃基，m为2〜4的整数，k为0〜（16-m）的整数，p和q各自为 1〜5的整数。

公开(公告)号：US08084650B2

公开(公告)日：2011-12-27

申请号：US12160534

申请日：2007-01-19

申请人： Yasunari Okada ,  Hajime Ito ,  Hideki Yamane ,  Nobuaki Matsumoto

发明人： Yasunari Okada ,  Hajime Ito ,  Hideki Yamane ,  Nobuaki Matsumoto

IPC分类号： C07C39/17 ,  C08L63/00 ,  B32B27/38

CPC分类号： C07C39/17 ,  C07C37/16 ,  C07C37/20 ,  C07C2603/74 ,  C07D301/28 ,  C07D303/30 ,  C08G59/24 ,  C08G59/4215 ,  C08G59/4223 ,  C08G59/621 ,  G03F7/038 ,  Y10T428/1073 ,  Y10T428/31511

摘要： Disclosed is an adamantane derivative which provides a cured product excellent in optical characteristics such as transparency and light resistance, long-term heat resistance, electrical characteristics such as and dielectric constant, and low water absorption. Also disclosed are a resin composition containing the adamantane derivative, a sealing agent for electronic circuits, optical electronic member, semiconductor device and copper-clad laminate all using the resin composition, and a radiation-sensitive resin composition which contains the above-mentioned adamantane derivative as a crosslinking agent. Specifically disclosed are an adamantane derivative represented by the formula (I-1) below, a resin composition containing the adamantane derivative, a sealing agent for electronic circuits, optical electronic member, semiconductor device and copper-clad laminate, all using the resin composition, and a radiation-sensitive resin composition which contains the above-mentioned adamantane derivative as a crosslinking agent.

摘要翻译： 公开了一种金刚烷衍生物，其提供了透光性，耐光性，长期耐热性，电特性如介电常数，低吸水性等光学特性优异的固化物。 还公开了含有金刚烷衍生物，电子电路用密封剂，光电子元件，半导体器件和覆铜层压板的树脂组合物，其全部使用该树脂组合物，以及含有上述金刚烷衍生物的辐射敏感性树脂组合物 作为交联剂。 具体公开了以下式（I-1）表示的金刚烷衍生物，含有金刚烷衍生物的树脂组合物，电子电路用密封剂，光电子部件，半导体装置和覆铜层压板，全部使用树脂组合物， 以及含有上述金刚烷衍生物作为交联剂的辐射敏感性树脂组合物。

公开(公告)号：US08017800B2

公开(公告)日：2011-09-13

申请号：US12831763

申请日：2010-07-07

申请人： Yasunari Okada ,  Hajime Ito ,  Hideki Yamane ,  Nobuaki Matsumoto

发明人： Yasunari Okada ,  Hajime Ito ,  Hideki Yamane ,  Nobuaki Matsumoto

IPC分类号： C07C69/732

CPC分类号： C08F290/06 ,  C08F222/1006 ,  C08F290/061 ,  C08F290/064 ,  C08G59/186

摘要： The present invention provides an adamantyl group containing epoxy-modified (meth)acrylate and a resin composition containing it which are imparted by transparency, optical characteristics such as (durable) light resistance and the like, heat-resistance, and good mechanical properties.For example, they are an adamantyl group containing epoxy-modified (meth)acrylate having the following general formula (I) and a composition containing it. In the formula, R1 represents a hydrogen atom or a methyl group, and R2 represents a halogen atom or an aliphatic hydrocarbon group which may contain a hetero atom. Plural R2 may be the same or different, and m represents an integer of 0 to 4 and n represents an integer of 0 or more.

摘要翻译： 本发明提供含有环氧改性（甲基）丙烯酸金刚烷基和含有它的树脂组合物，它们由透明性，耐光性等光学特性赋予耐热性和良好的机械性能。 例如，它们是含有具有以下通式（I）的环氧改性（甲基）丙烯酸酯和含有它的组合物的金刚烷基。 在该式中，R 1表示氢原子或甲基，R 2表示卤素原子或可含有杂原子的脂肪族烃基。 多个R2可以相同或不同，m表示0〜4的整数，n表示0以上的整数。

公开(公告)号：US20100298491A1

公开(公告)日：2010-11-25

申请号：US12160534

申请日：2007-01-19

申请人： Yasunari Okada ,  Hajime Ito ,  Hideki Yamane ,  Nobuaki Matsumoto

发明人： Yasunari Okada ,  Hajime Ito ,  Hideki Yamane ,  Nobuaki Matsumoto

IPC分类号： C08L63/00 ,  C07D303/12 ,  C07C39/10

CPC分类号： C07C39/17 ,  C07C37/16 ,  C07C37/20 ,  C07C2603/74 ,  C07D301/28 ,  C07D303/30 ,  C08G59/24 ,  C08G59/4215 ,  C08G59/4223 ,  C08G59/621 ,  G03F7/038 ,  Y10T428/1073 ,  Y10T428/31511

摘要： Disclosed is an adamantane derivative which provides a cured product excellent in optical characteristics such as transparency and light resistance, long-term heat resistance, electrical characteristics such as and dielectric constant, and low water absorption. Also disclosed are a resin composition containing the adamantane derivative, a sealing agent for electronic circuits, optical electronic member, semiconductor device and copper-clad laminate all using the resin composition, and a radiation-sensitive resin composition which contains the above-mentioned adamantane derivative as a crosslinking agent. Specifically disclosed are an adamantane derivative represented by the formula (I-1) below, a resin composition containing the adamantane derivative, a sealing agent for electronic circuits, optical electronic member, semiconductor device and copper-clad laminate, all using the resin composition, and a radiation-sensitive resin composition which contains the above-mentioned adamantane derivative as a crosslinking agent.

摘要翻译： 公开了一种金刚烷衍生物，其提供了透光性，耐光性，长期耐热性，电特性如介电常数，低吸水性等光学特性优异的固化物。 还公开了含有金刚烷衍生物，电子电路用密封剂，光电子元件，半导体器件和覆铜层压板的树脂组合物，其全部使用该树脂组合物，以及含有上述金刚烷衍生物的辐射敏感性树脂组合物 作为交联剂。 具体公开了以下式（I-1）表示的金刚烷衍生物，含有金刚烷衍生物的树脂组合物，电子电路用密封剂，光电子部件，半导体装置和覆铜层压板，全部使用树脂组合物， 以及含有上述金刚烷衍生物作为交联剂的辐射敏感性树脂组合物。

公开(公告)号：US20090099326A1

公开(公告)日：2009-04-16

申请号：US12298836

申请日：2007-04-20

申请人： Yasunari Okada ,  Hideki Yamane ,  Hajime Ito ,  Nobuaki Matsumoto

发明人： Yasunari Okada ,  Hideki Yamane ,  Hajime Ito ,  Nobuaki Matsumoto

IPC分类号： C08F214/18 ,  C07C35/44 ,  C07C69/753 ,  C08G65/22 ,  C07D303/18

CPC分类号： C07C31/44 ,  C07C69/653 ,  C07C2603/74 ,  C07D301/24 ,  C07D305/06 ,  C08F220/24 ,  C08F222/1006

摘要： To provide a polymerizable group-containing and fluorine-containing adamantane derivative capable of affording a cured product having good heat resistance, good mechanical properties such as mar resistance and a low refractive index, a resin composition containing such a polymerizable group-containing adamantane derivative, and a fluorine-containing adamantane derivative which is useful as a reaction intermediate used for the production of the polymerizable group-containing and fluorine-containing adamantane derivative.Specifically provided are a fluorine-containing adamantane derivative represented by the general formula (I) below, a polymerizable group-containing and fluorine-containing adamantane derivative represented by the general formula (II) below, and a resin composition containing such a polymerizable group-containing and fluorine-containing adamantane derivative. In the formula, R1 and R2 are each a hydrogen atom, for example, n is an integer of 0 or more, X1 is a polymerizable group represented by the formula (III-a), for example, Y is a hydrogen atom, for example, s and t are each an integer of 1 to 15, and u is an integer of 0 to 14, with the proviso that s+t+u=16.

摘要翻译： 为了提供能够提供具有良好耐热性，良好机械性能如耐磨性和低折射率的固化产物的含可聚合基团的含氟金刚烷衍生物，含有这种含聚合基团的金刚烷衍生物的树脂组合物， 以及可用作制备含聚合基团和含氟金刚烷衍生物的反应中间体的含氟金刚烷衍生物。 具体地提供由以下通式（I）表示的含氟金刚烷衍生物，下述通式（II）表示的可聚合基团的含氟金刚烷衍生物和含有这样的聚合性基团的树脂组合物， 含氟和金属金刚烷衍生物。 在该式中，R 1和R 2各自为氢原子，例如n为0以上的整数，X 1为式（III-a）表示的聚合性基团，例如，Y为氢原子，作为 例如，s和t分别为1〜15的整数，u为0〜14的整数，条件是s + t + u = 16。

公开(公告)号：US07960483B2

公开(公告)日：2011-06-14

申请号：US12279772

申请日：2007-02-01

申请人： Hajime Ito ,  Yasunari Okada ,  Hideki Yamane ,  Nobuaki Matsumoto

发明人： Hajime Ito ,  Yasunari Okada ,  Hideki Yamane ,  Nobuaki Matsumoto

IPC分类号： C08G59/06 ,  C08G59/42 ,  C08G59/50 ,  C08G59/62 ,  C08L63/00 ,  F21V7/04

CPC分类号： C07D303/30 ,  C07D305/06 ,  C08G59/24 ,  C08G59/42

摘要： An adamantane derivative of formula (I), a compound of formula (VII) or (VIII), compositions containing them, and optical electronic members using the resin compositions. In the formulas, W represents, for example, a hydrogen atom, X is bonded to a bridge-head adamantane carbon and represents, for example, a group of represented by the general formula (II), Y represents a group of formula (V) or (VI), R1 represents a methyl group or an ethyl group, R2 represents a C1 to C10 hydrocarbon group which may contain O or S, m is an integer of 2 to 4, k is an integer of 0 to (16−m) and p and q are each an integer of 1 to 5.

摘要翻译： 式（I）的金刚烷衍生物，式（VII）或（VIII）的化合物，含有它们的组合物和使用该树脂组合物的光学电子部件。 在该式中，W表示例如氢原子，X与桥头金刚烷碳键合，表示例如由通式（II）表示的基团，Y表示式（V ）或（VI）中，R1表示甲基或乙基，R2表示可含有O或S的C1〜C10烃基，m为2〜4的整数，k为0〜 m），p和q各自为1〜5的整数。

公开(公告)号：US20090099330A1

公开(公告)日：2009-04-16

申请号：US12298260

申请日：2007-04-24

申请人： Yasunari Okada ,  Hajime Ito ,  Hideki Yamane ,  Nobuaki Matsumoto

发明人： Yasunari Okada ,  Hajime Ito ,  Hideki Yamane ,  Nobuaki Matsumoto

IPC分类号： C08G59/02 ,  C07D303/12

CPC分类号： C08F290/06 ,  C08F222/1006 ,  C08F290/061 ,  C08F290/064 ,  C08G59/186

摘要： The present invention provides an adamantyl group containing epoxy-modified (meth)acrylate and a resin composition containing it which are imparted by transparency, optical characteristics such as (durable) light resistance and the like, heat-resistance, and good mechanical properties.For example, they are an adamantyl group containing epoxy-modified (meth)acrylate having the following general formula (I) and a composition containing it. In the formula, R1 represents a hydrogen atom or a methyl group, and R2 represents a halogen atom or an aliphatic hydrocarbon group which may contain a hetero atom. Plural R2 may be the same or different, and m represents an integer of 0 to 4 and n represents an integer of 0 or more.

摘要翻译： 本发明提供含有环氧改性（甲基）丙烯酸金刚烷基和含有它的树脂组合物，它们由透明性，耐光性等光学特性赋予耐热性和良好的机械性能。 例如，它们是含有具有以下通式（I）的环氧改性（甲基）丙烯酸酯和含有它的组合物的金刚烷基。 在该式中，R 1表示氢原子或甲基，R 2表示卤素原子或可含有杂原子的脂肪族烃基。 多个R2可以相同或不同，m表示0〜4的整数，n表示0以上的整数。

公开(公告)号：US07939682B2

公开(公告)日：2011-05-10

申请号：US12063685

申请日：2006-08-11

申请人： Yasunari Okada ,  Hideki Yamane ,  Nobuaki Matsumoto

发明人： Yasunari Okada ,  Hideki Yamane ,  Nobuaki Matsumoto

IPC分类号： C07D493/00

CPC分类号： C07D407/12 ,  C07C43/196 ,  C07C69/653 ,  C07C2603/74 ,  C07D303/28 ,  C08F222/1006 ,  G03F7/0007 ,  G03F7/091

摘要： Provided are a polymerizable group-containing and fluorine-containing adamantane derivative capable of affording a cured product having good heat resistance, good mechanical properties such as surface hardness and a low refractive index, a resin composition containing such a polymerizable group-containing adamantane derivative, and a fluorine-containing adamantane derivative which is useful as a reaction intermediate used for the production of the polymerizable group-containing and fluorine-containing adamantane derivative. Specifically provided are a fluorine-containing adamantane derivative represented by the general formula (I) below, a polymerizable group-containing and fluorine-containing adamantane derivative represented by the general formula (II) below, and a resin composition containing such a polymerizable group-containing and fluorine-containing adamantane derivative. In the formulas, X1 and X2 each represent OH or NH2, a, b and c each represent an integer of 0 or more and a+b+c≧1, for example a=b=0 and c=1, Z3 represents, for example, —C2H4—, s and t each represent an integer of 1 to 15, u represents an integer of 0 to 14, s+t+u=16, for example s=2, t=14, u=0, and X3 represents, for example, —O—CO—CH═CH2.

摘要翻译： 提供能够提供具有良好耐热性，良好机械性能如表面硬度和低折射率的固化产物的含可聚合基团的含氟金刚烷衍生物，含有这种含聚合基团的金刚烷衍生物的树脂组合物， 以及可用作制备含聚合基团和含氟金刚烷衍生物的反应中间体的含氟金刚烷衍生物。 具体地提供由以下通式（I）表示的含氟金刚烷衍生物，下述通式（II）表示的可聚合基团的含氟金刚烷衍生物和含有这样的聚合性基团的树脂组合物， 含氟和金属金刚烷衍生物。 式中，X 1和X 2各自表示OH或NH 2，a，b和c各自表示0以上的整数，a + b +c≥1，例如a = b = 0，c = 1，Z 3表示 例如-C 2 H 4 - ，s和t各自表示1〜15的整数，u表示0〜14的整数，s + t + u = 16，例如s = 2，t = 14，u = 0， X3表示例如-O-CO-CH = CH2。

公开(公告)号：US20100048757A1

公开(公告)日：2010-02-25

申请号：US12447308

申请日：2007-10-24

申请人： Yasunari Okada ,  Hideki Yamane ,  Katsuki Ito ,  Nobuaki Matsumoto

发明人： Yasunari Okada ,  Hideki Yamane ,  Katsuki Ito ,  Nobuaki Matsumoto

IPC分类号： C08F2/46 ,  C07C69/54 ,  C08L31/02

CPC分类号： G03F7/027 ,  C07C67/08 ,  C07C69/54 ,  C07C2603/74 ,  C08F20/20 ,  C08F20/28

摘要： Disclosed herein is an adamantane derivative represented by the following general formula (I): (wherein R represents a hydrogen atom, a fluorine atom, a methyl group or a trifluoromethyl group; Y represents a hydrogen atom, a hydroxyl group, ═O formed by two Ys together, a carboxyl group, or a hydrocarbon group having 1 to 20 carbon atoms or a cyclic hydrocarbon group having 3 to 20 carbon atoms; m is 13 and n is 3, or m is 12 and n is 4; and p is an integer of one or more), a production method thereof, a resin composition containing the adamantane derivative, and a cured product thereof. The present invention provides a cured product advantageous as various coating agents, a microlens, a film condenser, a colored composition for a liquid crystal color filter, a pattern organizer formed in nanoimprinting, and the like, having transparency, heat resistance, good mechanical properties, low volume shrinkage, and low coefficient of linear expansion, as well as liquid adamantyl group-containing (meth)acrylates to produce the cured product, the production method thereof, and the resin composition.

摘要翻译： 本文公开了由以下通式（I）表示的金刚烷衍生物：其中R表示氢原子，氟原子，甲基或三氟甲基; Y表示氢原子，羟基，由式 两个Y一起，一个羧基或一个碳原子数1〜20的烃基或碳原子数3〜20的环状烃基，m为13，n为3，m为12，n为4，p为 1个以上的整数），其制造方法，含有金刚烷衍生物的树脂组合物及其固化物。 本发明提供了作为各种涂布剂，微透镜，薄膜冷凝器，液晶滤色器着色组合物，纳米压印等形成的图案组织器等有利的固化产物，具有透明性，耐热性，良好的机械性能 ，低体积收缩率和低的线性膨胀系数，以及含有金刚烷基的（甲基）丙烯酸酯以制备固化产物，其制备方法和树脂组合物。