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1.发明授权
公开(公告)号：US5035991A
公开(公告)日：1991-07-30
申请号：US454254
申请日：1989-12-21
CPC分类号： B01F15/00207 , B01F15/00344 , G03C1/015 , B01F2215/0093
摘要： A control process and apparatus for the formation of silver halide grains comprising a mixer disposed outside of a reaction vessel containing an aqueous protective colloid solution and causing a nucleus formation (nucleation) and/or a crystal growth of silver halide grains. The process and apparatus further include: supplying an aqueous solution of a water-soluble silver salt, an aqueous solution of water-soluble halide(s), and an aqueous solution of a protective colloid to the mixer through supply conduits while controlling the flow rates of the solutions; mixing them while controlling the rotational speed of a stirrer of the mixer to form fine, silver halide grains; and immediately supplying the fine grains into the reaction vessel through a conduit connecting the mixer to the reaction vessel to perform the nucleus formation and/or the crystal growth of the silver halide grains in the reaction vessel. The control process and apparatus further comprise measuring the silver ion potential of the fine grains formed in the mixer or the silver ion potential in the reaction vessel with an electrode, and controlling the flow rate of at least one of the aqueous silver salt solution, the aqueous halide solution, and the aqueous protective colloid solution being added to the mixer, such that the measured value equals a predetermined value.
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公开(公告)号：US5270159A
公开(公告)日：1993-12-14
申请号：US454238
申请日：1989-12-21
CPC分类号： G03C1/025 , G03C1/015 , G03C2200/09
摘要： A process and apparatus for producing silver halide grains wherein by removing water, etc., from a liquid containing fine, silver halide grains formed in a mixer and being added to a reaction vessel, the yield of the silver halide grains grown in the reaction vessel per unit amount of the raw materials used is increased. Also, by removing a portion of the water, used for the dilution, from the liquid being added to the reaction before the addition thereof, the amount of diluting water effective for the formation of silver halide fine grains in the mixer is increased, to thereby form finer silver halide grains in the mixer.
摘要翻译： 一种制造卤化银颗粒的方法和装置，其中通过从混合物中形成的并且添加到反应容器中的含有细小的卤化银颗粒的液体除去水等，生成在反应容器中的卤化银颗粒的产率 每单位原料使用量增加。 此外，通过从添加到反应中的液体除去用于稀释的一部分水，在混合器中有效形成卤化银细粒的稀释水的量增加，从而 在混合器中形成更细的卤化银颗粒。
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公开(公告)号：US5213772A
公开(公告)日：1993-05-25
申请号：US454611
申请日：1989-12-21
摘要： An apparatus for forming silver halide grains comprises a reaction vessel for causing the nucleus formation and the crystal growth of silver halide grains. The apparatus further includes: a mixer disposed outside of the reaction vessel and having a high-speed stirring blade; conduits for supplying an aqueous solution of a water-soluble silver salt, an aqueous solution of water-soluble halide, and an aqueous protective colloid solution to the mixer while controlling the rotational speed of the high-speed stirring blade to form fine, silver halide grains; and a conduit for connecting the mixer to the reaction vessel for immediately supplying the fine grains in the mixer to the reaction vessel.
摘要翻译： 用于形成卤化银颗粒的装置包括用于使核形成和卤化银晶粒的晶体生长的反应容器。 该设备还包括：设置在反应容器外部并具有高速搅拌叶片的混合器; 用于将水溶性银盐的水溶液，水溶性卤化物的水溶液和水性保护胶体溶液供给到混合器中，同时控制高速搅拌叶片的转速以形成细的卤化银 谷物 以及用于将混合器连接到反应容器用于立即将混合器中的细粒供应到反应容器的导管。
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公开(公告)号：US5145768A
公开(公告)日：1992-09-08
申请号：US454243
申请日：1989-12-21
CPC分类号： G03C1/015 , G03C1/0051 , G03C2001/0153
摘要： A process of producing silver halide grains by disposing a mixer outside of a reaction vessel for causing a nucleus formation and/or a crystal growth of silver halide grains and containing an aqueous protective colloid solution. The process further includes the steps of: supplying an aqueous solution of a water-soluble silver salt, an aqueous solution of a water-soluble halide(s), and an aqueous solution of a protective colloid to the mixer while controlling the flow rates of the solutions; mixing them while controlling the rotational speed of a stirring blade of the mixer to form fine, silver halide grains; and immediately supplying the fine grains into the reaction vessel to perform the nucleus formation and/or the crystal growth of the silver halide grains in the reaction vessel. The silver halide fine grains thus formed in the mixer are quickly diluted with a liquid withdrawn from the reaction vessel and then the diluted mixture is supplied to the reaction vessel.
摘要翻译： 通过在反应容器的外部设置混合器以产生卤化银颗粒的核形成和/或晶体生长并含有水性保护胶体溶液来生产卤化银颗粒的方法。 该方法还包括以下步骤：将水溶性银盐的水溶液，水溶性卤化物的水溶液和保护胶体的水溶液加入到混合器中，同时控制流动速率 解决方案; 混合它们同时控制混合器的搅拌叶片的旋转速度以形成细小的卤化银颗粒; 并立即将细粒供给到反应容器中，以进行反应容器内的卤化银颗粒的核形成和/或结晶生长。 在混合器中形成的卤化银细颗粒用从反应容器中取出的液体迅速稀释，然后将稀释的混合物供入反应容器。
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公开(公告)号：US5104785A
公开(公告)日：1992-04-14
申请号：US452651
申请日：1989-12-19
CPC分类号： G03C1/015 , C01G5/02 , G03C2001/0153
摘要： A process of forming silver halide grains which comprises disposing a mixer outside of a reaction vessel for causing the nucleus formation and crystal growth of silver halide grains. The process further includes the steps of: supplying an aqueous solution of a water-soluble silver salt, an aqueous solution of a water-soluble halide, and an aqueous protective colloid solution into the mixer to form fine, silver halide grains therein; immediately supplying the fine grains into the reaction vessel; and performing the nucleus formation and crystal growth of the silver halide grains in the reaction vessel. The formation of the fine grains is controlled by controlling the flow rates of the solutions being supplied to the mixer and the r.p.m. of a stirrer provided in the mixer.
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6.发明授权Method and apparatus for forming silver halide emulsion particles and method for forming fine particles 失效用于形成卤化银乳剂颗粒的方法和设备及形成细颗粒的方法公开(公告)号：US06858381B2
公开(公告)日：2005-02-22
申请号：US10420926
申请日：2003-04-23
申请人： Yasunori Ichikawa , Katsuhisa Ohzeki , Fumiko Shiraishi , Tetsurou Mitsui , Shigeharu Urabe , Nobuo Nishida , Kenichi Harashima
发明人： Yasunori Ichikawa , Katsuhisa Ohzeki , Fumiko Shiraishi , Tetsurou Mitsui , Shigeharu Urabe , Nobuo Nishida , Kenichi Harashima
CPC分类号： B01F5/0256 , B01F2215/0409 , B01J19/26 , G03C1/015 , Y10S423/09 , Y10S423/11 , Y10T137/87603 , Y10T137/87652
摘要： The mixing state of static mixing is optimized, so that it is possible to form silver halide emulsion particles in small sizes with an excellent mono-dispersion characteristic. An aqueous solution of haloid salt is blown out from a first nozzle into a mixing chamber as a rectilinear flow of turbulent flow, and before eddy viscosity formed when the rectilinear flow is blown out from the first nozzle of a small diameter to the mixing chamber of a greater diameter reaches a maximum, or before a maximum flow speed of the rectilinear flow is reduced to {fraction (1/10)} or below, an aqueous solution of silver nitrate is blown out from a second nozzle as a crossflow of turbulent flow which crosses the rectilinear flow at a substantially right angle and is entrained by the rectilinear flow, so that the two solutions are allowed to mix and react with each other instantaneously, and a liquid resulting from the mixing and reaction is discharged from a discharge duct.
摘要翻译： 优化静态混合的混合状态，从而可以形成具有优异的单分散特性的小尺寸的卤化银乳剂颗粒。 将卤素盐的水溶液从第一喷嘴吹入混合室，作为湍流的直线流动，并且在直线流从小直径的第一喷嘴吹送到混合室的混合室之前形成的涡流粘度 更大的直径达到最大值，或者在直线流量的最大流速降低到{分数（1/10或更低）之前，硝酸银的水溶液从第二喷嘴吹出，作为湍流的交叉流， 直线流以基本上直角流动并被直线流动夹带，使得两种溶液瞬间混合和反应，并且从混合和反应产生的液体从排出管排出。
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7.发明授权Method for making silver halide emulsion, photosensitive materials using the same, and methods of recording images using the photosensitive materials 失效制备卤化银乳剂的方法，使用其的感光材料以及使用感光材料记录图像的方法
公开(公告)号：US5264338A
公开(公告)日：1993-11-23
申请号：US953782
申请日：1992-09-30
申请人： Shigeharu Urabe , Shunichi Aida
发明人： Shigeharu Urabe , Shunichi Aida
摘要： A method of preparing a superfine grain emulsion with a grain size of 0.05 .mu.m or less is provided, which includes mixing aqueous solutions of a water-soluble silver salt and a water-soluble halide with vigorous stirring inside a closed mixing device furnished with an agitator, where the solutions are fed into the device simultaneously and continuously, in the presence of at least one of a high molecular compound and a substance capable of adsorbing to silver halide, each of which has a physical retardance value of at least 40 as determined by PAGI method, and immediately expelling the newly-formed grains from the mixing device. Another method includes mixing the aqueous solutions in a mixing device as described above, immediately expelling the newly-formed grains from the device, and mixing the expelled grains with at least one of the above-described high molecular compound and substance. The silver halide photographic materials utilizing the superfine grain emulsion are suitable for holographic image-recording and image-recording with electron beam, lasers, and so on.
摘要翻译： 提供了一种制备粒度为0.05μm或更小的超微粒乳剂的方法，其包括在密闭混合装置内混合水溶性银盐和水溶性卤化物的水溶液，同时剧烈搅拌， 搅拌器，其中溶液在高分子化合物和能够吸附到卤化银的物质中的至少一种的存在下同时且连续地进料到装置中，每个物质的物理延迟值至少为40，如所确定的 通过PAGI方法，立即从混合装置排出新形成的颗粒。 另一种方法包括将水溶液混合在如上所述的混合装置中，立即从装置中排出新形成的颗粒，并将排出的颗粒与至少一种上述高分子化合物和物质混合。 利用超细颗粒乳剂的卤化银照相材料适用于全息图像记录和电子束，激光等的图像记录。
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8.发明授权
公开(公告)号：US5238796A
公开(公告)日：1993-08-24
申请号：US788536
申请日：1991-11-06
申请人： Yoichi Maruyama , Shigeharu Urabe
发明人： Yoichi Maruyama , Shigeharu Urabe
CPC分类号： G03C1/0051 , G03C1/16 , G03C1/18 , G03C2001/0056
摘要： A silver halide photographic emulsion containing tabular silver halide grains which have an aspect ratio of 2 or more and in which dislocations are localized in a center portion of each grain. The tabular silver halide grains have a thickness of less than 0.5 .mu.m and a diameter of 0.3 .mu.m or more and account for at least 50% of a total projected area of the silver halide grains. This emulsion has a high sensitivity and good reciprocity characteristics. In a photographic light-sensitive material having at least two light-sensitive silver halide emulsion layers having different color sensitivities on a support, the above tabular silver halide photographic emulsion and at least one type of a coupler which is coupled with an oxidant of a color developing agent to develop a color are added to at least one of the emulsion layers, thereby obtaining a photographic light-sensitive material having a high sensitivity and good reciprocity characteristics.
摘要翻译： 含有长宽比为2以上并且位错位于每个颗粒的中心部分的片状卤化银颗粒的卤化银照相乳剂。 片状卤化银颗粒的厚度小于0.5μm，直径为0.3μm以上，占卤化银颗粒总投影面积的至少50％。 该乳液具有高灵敏度和良好的互易性。 在具有至少两个在载体上具有不同颜色敏感度的感光卤化银乳剂层的照相感光材料中，上述片状卤化银照相乳剂和至少一种与颜色氧化剂偶联的成色剂 向至少一个乳剂层中添加显影剂以显色，从而获得具有高灵敏度和良好的互易性特征的照相感光材料。
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公开(公告)号：US5045443A
公开(公告)日：1991-09-03
申请号：US206141
申请日：1988-06-13
申请人： Shigeharu Urabe
发明人： Shigeharu Urabe
CPC分类号： G03C1/0051 , G03C1/16 , G03C1/18 , G03C1/26 , G03C2001/03511 , G03C2001/03517 , G03C2001/03535 , G03C2001/03558
摘要： A silver halide photographic emulsion comprising a dispersant and silver halide grains, at least 50% of the total projected area of the silver halide grains being occupied by tabular grains having an average aspect ratio of 2 or more, the tabular grains comprising opposing parallel major faces consisting of a (1 1 1) face, and at least 30% of the tabular grains having an indentation or space in the central portion of the major faces thereof.
摘要翻译： 包含分散剂和卤化银颗粒的卤化银照相乳剂，所述卤化银颗粒的总投影面积的至少50％占平均纵横比为2或更大的片状颗粒，所述片状颗粒包含相对的平行主面 由（111）面构成，并且至少30％的片状颗粒在其主面的中心部分具有凹陷或空间。
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公开(公告)号：US4879208A
公开(公告)日：1989-11-07
申请号：US298446
申请日：1989-01-18
申请人： Shigeharu Urabe
发明人： Shigeharu Urabe
CPC分类号： G03C1/0051 , G03C1/18
摘要： A process for manufacturing uniform silver halide grains, which comprises the steps of:(A) providing a mixer vessel and a reactor vessel, the mixer vessel being separate from the reactor vessel and the reactor vessel having contained therein an aqueous protective colloid solution and in which silver halide grains are grown;(B) feeding an aqueous water-soluble silver salt solution, an aqueous water-soluble halide solution and an aqueous protective colloid solution into the mixer vessel;(C) forming a fine silver halide grain-containing solution by mixing the thus fed solutions in the mixer vessel;(D) immediately feeding the thus formed fine silver halide grain-containing solution into the reactor vessel; and(E) stirring said solution in the reactor vessel to grow uniform silver halide grains therein. By prohibiting the addition of the silver ions and the halide ions to the reactor vessel i the form of aqueous solutions, and the addition of the aqueous protective colloid solution containing the silver halide grains from the reactor vessel to the mixer vessel, formation and growth of uniform silver halide grains is achieved. An apparatus for performing the process of the present invention is also disclosed herein.
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