公开(公告)号：US08182574B2

公开(公告)日：2012-05-22

申请号：US12730776

申请日：2010-03-24

申请人： Yoshiaki Takata ,  Hiroki Hirata ,  Jun-etsu Satoh ,  Yasuro Niidome ,  Sunao Yamada ,  Koji Nishioka ,  Hideya Kawasaki ,  Daigou Mizoguchi ,  Masanori Nagai ,  Masato Murouchi ,  Masaoki Ishihara

发明人： Yoshiaki Takata ,  Hiroki Hirata ,  Jun-etsu Satoh ,  Yasuro Niidome ,  Sunao Yamada ,  Koji Nishioka ,  Hideya Kawasaki ,  Daigou Mizoguchi ,  Masanori Nagai ,  Masato Murouchi ,  Masaoki Ishihara

IPC分类号： B22F9/24

CPC分类号： B22F9/24 ,  B22F1/0025 ,  B22F2999/00 ,  B82Y30/00 ,  C22C5/02 ,  C23C24/00 ,  C23C24/08 ,  Y10S977/899 ,  B22F1/0088 ,  B22F1/0085

摘要： The present invention provides metal fine particles which have selective wavelength absorption characteristics in a wavelength region from visible light to near infrared light, and have sharp absorption characteristics, and influences little the surrounding wavelength, and therefore, they yield tones having high chroma. The present invention provides metal fine particles wherein an aspect ratio is in a range from 1.1 to 8.0, a maximum absorption wavelength in plasmon absorption is in a range from 400 nm to 1,200 nm, and an absorption coefficient at a peak position of the maximum absorption wavelength is in a range from 6,000 to 20,000 L/mol·cm (measurement concentration: 1.6×10−4 mol/L, and solvent: water).

摘要翻译： 本发明提供在从可见光到近红外光的波长区域中具有选择性波长吸收特性的金属微粒，并且具有尖锐的吸收特性，并且影响周围波长很小，因此它们产生色度高的色调。 本发明提供金属细颗粒，其中纵横比在1.1至8.0的范围内，等离子体激元吸收中的最大吸收波长在400nm至1200nm的范围内，并且在最大吸收峰峰位置处的吸收系数 波长在6000〜20,000L / mol·cm（测定浓度：1.6×10 -4 mol / L，溶剂：水）的范围内。

公开(公告)号：US07976609B2

公开(公告)日：2011-07-12

申请号：US12704364

申请日：2010-02-11

申请人： Yasuro Niidome ,  Sunao Yamada ,  Koji Nishioka ,  Hideya Kawasaki ,  Hiroki Hirata ,  Daigou Mizoguchi ,  Yoshiaki Takata ,  Jun-etsu Satoh ,  Masaoki Ishihara ,  Masanori Nagai ,  Masato Murouchi

发明人： Yasuro Niidome ,  Sunao Yamada ,  Koji Nishioka ,  Hideya Kawasaki ,  Hiroki Hirata ,  Daigou Mizoguchi ,  Yoshiaki Takata ,  Jun-etsu Satoh ,  Masaoki Ishihara ,  Masanori Nagai ,  Masato Murouchi

IPC分类号： B22F9/24 ,  B82B3/00

CPC分类号： B22F1/0025 ,  B22F9/24 ,  B22F2999/00 ,  B82Y30/00 ,  C30B7/00 ,  C30B7/14 ,  C30B29/605 ,  Y10S977/762 ,  Y10S977/896 ,  B22F2202/11

摘要： A method for manufacturing metal nanorods includes: a step of adding a reducing agent to a metallic salt solution; a step of radiating light into the metallic salt solution containing the reducing agent; and a step of leaving the light-radiated metallic salt solution containing the reducing agent stationary in a dark place so as to grow metal nanorods. Metal nanorods can be also grown by forming a mixed solution by fractionating the above light-radiated metallic salt solution and mixing the fractionated metallic salt solution into a non-radiated metallic salt solution containing the reducing agent, or mixing a non-radiated metallic salt solution and the reducing agent into the above light-radiated metallic salt solution; and leaving the mixed solution stationary in a dark place so as to grow metal nanorods.

摘要翻译： 金属纳米棒的制造方法包括：向金属盐溶液中添加还原剂的工序; 将光照射到含有还原剂的金属盐溶液中的步骤; 以及将含有还原剂的光照射的金属盐溶液静置在黑暗处，以便生长金属纳米棒的步骤。 金属纳米棒也可以通过将上述光照的金属盐溶液分级分离并将分级的金属盐溶液混合到含有还原剂的非辐射金属盐溶液中，或混合未辐射的金属盐溶液 并将还原剂加入上述光照金属盐溶液中; 并将混合溶液静置在黑暗的地方，以便生长金属纳米棒。

公开(公告)号：US20100229684A1

公开(公告)日：2010-09-16

申请号：US12730776

申请日：2010-03-24

申请人： Yoshiaki Takata ,  Hiroki Hirata ,  Jun-etsu Satoh ,  Yasuro Niidome ,  Sunao Yamada ,  Koji Nishioka ,  Hideya Kawasaki ,  Daigou Mizoguchi ,  Masanori Nagai ,  Masato Murouchi ,  Masaoki Ishihara

发明人： Yoshiaki Takata ,  Hiroki Hirata ,  Jun-etsu Satoh ,  Yasuro Niidome ,  Sunao Yamada ,  Koji Nishioka ,  Hideya Kawasaki ,  Daigou Mizoguchi ,  Masanori Nagai ,  Masato Murouchi ,  Masaoki Ishihara

IPC分类号： B22F9/18 ,  C25D1/00

CPC分类号： B22F9/24 ,  B22F1/0025 ,  B22F2999/00 ,  B82Y30/00 ,  C22C5/02 ,  C23C24/00 ,  C23C24/08 ,  Y10S977/899 ,  B22F1/0088 ,  B22F1/0085

摘要： The present invention provides metal fine particles which have selective wavelength absorption characteristics in a wavelength region from visible light to near infrared light, and have sharp absorption characteristics, and influences little the surrounding wavelength, and therefore, they yield tones having high chroma. The present invention provides metal fine particles wherein an aspect ratio is in a range from 1.1 to 8.0, a maximum absorption wavelength in plasmon absorption is in a range from 400 nm to 1,200 nm, and an absorption coefficient at a peak position of the maximum absorption wavelength is in a range from 6,000 to 20,000 L/mol·cm (measurement concentration: 1.6×10−4 mol/L, and solvent: water).

摘要翻译： 本发明提供在从可见光到近红外光的波长区域中具有选择性波长吸收特性的金属微粒，并且具有尖锐的吸收特性，并且影响周围波长很小，因此它们产生色度高的色调。 本发明提供金属细颗粒，其中纵横比在1.1至8.0的范围内，等离子体激元吸收中的最大吸收波长在400nm至1200nm的范围内，并且在最大吸收峰峰位置处的吸收系数 波长在6000〜20,000L / mol·cm（测定浓度：1.6×10 -4 mol / L，溶剂：水）的范围内。

公开(公告)号：US20100143184A1

公开(公告)日：2010-06-10

申请号：US12704364

申请日：2010-02-11

申请人： Yasuro Niidome ,  Sunao Yamada ,  Koji Nishioka ,  Hideya Kawasaki ,  Hiroki Hirata ,  Daigou Mizoguchi ,  Yoshiaki Takata ,  Jun-etsu Satoh ,  Masaoki Ishihara ,  Masanori Nagai ,  Masato Murouchi

发明人： Yasuro Niidome ,  Sunao Yamada ,  Koji Nishioka ,  Hideya Kawasaki ,  Hiroki Hirata ,  Daigou Mizoguchi ,  Yoshiaki Takata ,  Jun-etsu Satoh ,  Masaoki Ishihara ,  Masanori Nagai ,  Masato Murouchi

IPC分类号： B22F9/16 ,  C22C5/02

CPC分类号： B22F1/0025 ,  B22F9/24 ,  B22F2999/00 ,  B82Y30/00 ,  C30B7/00 ,  C30B7/14 ,  C30B29/605 ,  Y10S977/762 ,  Y10S977/896 ,  B22F2202/11

摘要： A method for manufacturing metal nanorods includes: a step of adding a reducing agent to a metallic salt solution; a step of radiating light into the metallic salt solution containing the reducing agent; and a step of leaving the light-radiated metallic salt solution containing the reducing agent stationary in a dark place so as to grow metal nanorods. Metal nanorods can be also grown by forming a mixed solution by fractionating the above light-radiated metallic salt solution and mixing the fractionated metallic salt solution into a non-radiated metallic salt solution containing the reducing agent, or mixing a non-radiated metallic salt solution and the reducing agent into the above light-radiated metallic salt solution; and leaving the mixed solution stationary in a dark place so as to grow metal nanorods.

摘要翻译： 金属纳米棒的制造方法包括：向金属盐溶液中添加还原剂的工序; 将光照射到含有还原剂的金属盐溶液中的步骤; 以及将含有还原剂的光照射的金属盐溶液静置在黑暗处，以便生长金属纳米棒的步骤。 金属纳米棒也可以通过将上述光照的金属盐溶液分级分离并将分级的金属盐溶液混合到含有还原剂的非辐射金属盐溶液中，或混合未辐射的金属盐溶液 并将还原剂加入上述光照金属盐溶液中; 并将混合溶液静置在黑暗的地方，以便生长金属纳米棒。

公开(公告)号：US07691176B2

公开(公告)日：2010-04-06

申请号：US10556498

申请日：2004-05-13

申请人： Yasuro Niidome ,  Sunao Yamada ,  Koji Nishioka ,  Hideya Kawasaki ,  Hiroki Hirata ,  Yoshiaki Takata ,  Jun-etsu Satoh ,  Daigou Mizoguchi ,  Masaoki Ishihara ,  Masanori Nagai ,  Masato Murouchi

发明人： Yasuro Niidome ,  Sunao Yamada ,  Koji Nishioka ,  Hideya Kawasaki ,  Hiroki Hirata ,  Yoshiaki Takata ,  Jun-etsu Satoh ,  Daigou Mizoguchi ,  Masaoki Ishihara ,  Masanori Nagai ,  Masato Murouchi

IPC分类号： B22F9/22 ,  B01J13/00 ,  B82B3/00

CPC分类号： B22F1/0025 ,  B22F9/24 ,  B22F2999/00 ,  B82Y30/00 ,  C30B7/00 ,  C30B7/14 ,  C30B29/605 ,  Y10S977/762 ,  Y10S977/896 ,  B22F2202/11

摘要： A method for manufacturing metal nanorods includes: a step of adding a reducing agent to a metallic salt solution; a step of radiating light into the metallic salt solution containing the reducing agent; and a step of leaving the light-radiated metallic salt solution containing the reducing agent stationary in a dark place so as to grow metal nanorods. Metal nanorods can be also grown by forming a mixed solution by fractionating the above light-radiated metallic salt solution and mixing the fractionated metallic salt solution into a non-radiated metallic salt solution containing the reducing agent, or mixing a non-radiated metallic salt solution and the reducing agent into the above light-radiated metallic salt solution; and leaving the mixed solution stationary in a dark place so as to grow metal nanorods.

摘要翻译： 金属纳米棒的制造方法包括：向金属盐溶液中添加还原剂的工序; 将光照射到含有还原剂的金属盐溶液中的步骤; 以及将含有还原剂的光照射的金属盐溶液静置在黑暗处，以便生长金属纳米棒的步骤。 金属纳米棒也可以通过将上述光照的金属盐溶液分级分离并将分级的金属盐溶液混合到含有还原剂的非辐射金属盐溶液中，或混合未辐射的金属盐溶液 并将还原剂加入上述光照金属盐溶液中; 并将混合溶液静置在黑暗的地方，以便生长金属纳米棒。

公开(公告)号：US20060266157A1

公开(公告)日：2006-11-30

申请号：US10570523

申请日：2004-09-02

申请人： Yoshiaki Takata ,  Hiroki Hirata ,  Jun-etsu Satoh ,  Yasuro Niidome ,  Sunao Yamada ,  Koji Nishioka ,  Hideya Kawasaki ,  Daigou Mizoguchi ,  Masanori Nagai ,  Masato Murouchi ,  Masaoki Ishihara

发明人： Yoshiaki Takata ,  Hiroki Hirata ,  Jun-etsu Satoh ,  Yasuro Niidome ,  Sunao Yamada ,  Koji Nishioka ,  Hideya Kawasaki ,  Daigou Mizoguchi ,  Masanori Nagai ,  Masato Murouchi ,  Masaoki Ishihara

IPC分类号： B22F9/24 ,  C22C5/02

CPC分类号： B22F9/24 ,  B22F1/0025 ,  B22F2999/00 ,  B82Y30/00 ,  C22C5/02 ,  C23C24/00 ,  C23C24/08 ,  Y10S977/899 ,  B22F1/0088 ,  B22F1/0085

摘要： The present invention provides metal fine particles which have selective wavelength absorption characteristics in a wavelength region from visible light to near infrared light, and have sharp absorption characteristics, and influences little the surrounding wavelength, and therefore, they yield tones having high chroma. The present invention provides metal fine particles wherein an aspect ratio is in a range from 1.1 to 8.0, a maximum absorption wavelength in plasmon absorption is in a range from 400 nm to 1,200 nm, and an absorption coefficient at a peak position of the maximum absorption wavelength is in a range from 6,000 to 20,000 L/mol·cm (measurement concentration: 1.6×10−4 mol/L, and solvent:water).

摘要翻译： 本发明提供在从可见光到近红外光的波长区域中具有选择性波长吸收特性的金属微粒，并且具有尖锐的吸收特性，并且影响周围波长很小，因此它们产生色度高的色调。 本发明提供金属细颗粒，其中纵横比在1.1至8.0的范围内，等离子体激元吸收中的最大吸收波长在400nm至1200nm的范围内，并且在最大吸收峰峰位置处的吸收系数 波长在6000至20,000L / mol.cm（测量浓度：1.6×10 -4 mol / L）和溶剂：水的范围内。

公开(公告)号：US20060196309A1

公开(公告)日：2006-09-07

申请号：US10556498

申请日：2004-05-13

申请人： Yasuro Niidome ,  Sunao Yamada ,  Koji Nishioka ,  Hideya Kawasaki ,  Hiroki Hirata ,  Yoshiaki Takata ,  Jun-etsu Satoh ,  Daigou Mizoguchi ,  Masaoki Ishihara ,  Masanori Nagai ,  Masato Murouchi

发明人： Yasuro Niidome ,  Sunao Yamada ,  Koji Nishioka ,  Hideya Kawasaki ,  Hiroki Hirata ,  Yoshiaki Takata ,  Jun-etsu Satoh ,  Daigou Mizoguchi ,  Masaoki Ishihara ,  Masanori Nagai ,  Masato Murouchi

IPC分类号： B22F9/24

CPC分类号： B22F1/0025 ,  B22F9/24 ,  B22F2999/00 ,  B82Y30/00 ,  C30B7/00 ,  C30B7/14 ,  C30B29/605 ,  Y10S977/762 ,  Y10S977/896 ,  B22F2202/11

摘要： A method for manufacturing metal nanorods includes: a step of adding a reducing agent to a metallic salt solution; a step of radiating light into the metallic salt solution containing the reducing agent; and a step of leaving the light-radiated metallic salt solution containing the reducing agent stationary in a dark place so as to grow metal nanorods. Metal nanorods can be also grown by forming a mixed solution by fractionating the above light-radiated metallic salt solution and mixing the fractionated metallic salt solution into a non-radiated metallic salt solution containing the reducing agent, or mixing a non-radiated metallic salt solution and the reducing agent into the above light-radiated metallic salt solution; and leaving the mixed solution stationary in a dark place so as to grow metal nanorods.

摘要翻译： 金属纳米棒的制造方法包括：向金属盐溶液中添加还原剂的工序; 将光照射到含有还原剂的金属盐溶液中的步骤; 以及将含有还原剂的光照射的金属盐溶液静置在黑暗处，以便生长金属纳米棒的步骤。 金属纳米棒也可以通过将上述光照的金属盐溶液分级分离并将分级的金属盐溶液混合到含有还原剂的非辐射金属盐溶液中，或混合未辐射的金属盐溶液 并将还原剂加入上述光照金属盐溶液中; 并将混合溶液静置在黑暗的地方，以便生长金属纳米棒。

公开(公告)号：US20080166259A1

公开(公告)日：2008-07-10

申请号：US11885434

申请日：2006-03-01

申请人： Tsuyoshi Kijima ,  Hideya Kawasaki

发明人： Tsuyoshi Kijima ,  Hideya Kawasaki

IPC分类号： C22C5/00 ,  C22C5/02 ,  C22C5/06 ,  C22C5/04

CPC分类号： B22F1/0018 ,  B01J23/38 ,  B01J35/0013 ,  B01J37/0215 ,  B01J37/03 ,  B22F1/0055 ,  B22F9/24 ,  B22F2001/0033 ,  B22F2998/00 ,  B82Y30/00 ,  C25B11/0473 ,  H01M4/885 ,  H01M4/92 ,  H01M2008/1095 ,  B22F1/0025

摘要： It is aimed at creating noble metal nanoparticles having novel shapes, sizes, and arrangements usable for catalysts, electrodes, and the like.Micelles made into rod-like shapes having semicylindrical cross-sections are formed on a carrier substrate in a self-creating manner and immobilized thereon; noble metal ions are added and diffused in the micelles to complex the micelles with noble metal ions; and a reducing agent is subsequently caused to act thereon to progress a reductive reaction of noble metal within the immobilized micelles as reaction fields, thereby growing single crystalline noble metal ultrathin-film nanoparticles on the carrier substrate by utilizing the fixed micelles having the shapes as templates, respectively.

摘要翻译： 其目的在于制备具有新型形状，尺寸和可用于催化剂，电极等的布置的贵金属纳米颗粒。 制成具有半圆柱形横截面的棒状形状的胶束以自制方式形成在载体基板上并固定在其上; 添加贵金属离子并将其扩散到胶束中，以与贵金属离子配合胶束; 随后使还原剂作用于其上以进行作为反应场的固定化胶束内的贵金属的还原反应，从而通过利用形状为模板的固定胶束在载体基材上生长单晶贵金属超薄膜纳米颗粒 ， 分别。