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    Modified polymers prepared with lanthanide-based catalysts
    3.
    发明申请
    Modified polymers prepared with lanthanide-based catalysts 有权

    公开(公告)号：US20060025539A1

    公开(公告)日：2006-02-02

    申请号：US11243874

    申请日：2005-10-05

    申请人： Yoichi Ozawa ,  H. Miller ,  Koji Masaki

    发明人： Yoichi Ozawa ,  H. Miller ,  Koji Masaki

    IPC分类号： C08C19/22 ,  C08F8/30

    CPC分类号： C08C19/44 ,  C08F136/04 ,  C08L19/006 ,  C08F4/545

    摘要： A method for preparing a functionalized polymer comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, where said pseudo-living polymer is characterized by having greater than about 85 percent of the polymer in the cis microstructure and less than about 3 percent of the polymer is in the 1,2- or 3,4-microstructure, and reacting the pseudo-living polymer with at least one functionalizing agent defined by the formula (I) or (II) where Z is a substituent that will react or interact with organic or inorganic fillers; R1 is a single bond or a divalent organic group; R2 is a monovalent organic group or a divalent organic group that forms a cyclic organic group with R13 or R14; R3 is a single bond, a divalent organic group, or a trivalent organic group that forms a cyclic organic group with R4 or R5; R13 is a single bond, a divalent organic group, or a trivalent organic group that forms a cyclic organic group with R2 or R14; R4 is a monovalent organic group or a divalent organic group that forms a cyclic organic group with R3 or R5; R14 is a monovalent organic group or a divalent organic group that forms a cyclic organic group with R2 or R13; and R5 is a monovalent organic group or a divalent organic group that forms a cyclic organic group with R3 or R4; with the proviso that each group attached to the imino carbon is attached via a carbon atom and R1, R2 R3, R4, R5, R13, R14 and Z are substituents that will not protonate a pseudo-living polymer.

    Process for producing conjugated diene polymer, conjugated diene polymer, and rubber composition
    4.
    发明授权
    Process for producing conjugated diene polymer, conjugated diene polymer, and rubber composition 有权
    用于制备共轭二烯聚合物，共轭二烯聚合物和橡胶组合物的方法

    公开(公告)号：US08153723B2

    公开(公告)日：2012-04-10

    申请号：US12096263

    申请日：2006-12-05

    申请人： Takahiro Nakamura ,  Kouichirou Tani ,  Ryouji Tanaka ,  Takuo Sone ,  Toshihiro Tadaki ,  Junko Kurazumi ,  Koji Masaki ,  Yoichi Ozawa

    发明人： Takahiro Nakamura ,  Kouichirou Tani ,  Ryouji Tanaka ,  Takuo Sone ,  Toshihiro Tadaki ,  Junko Kurazumi ,  Koji Masaki ,  Yoichi Ozawa

    IPC分类号： C08L9/00 ,  C08F4/44

    CPC分类号： C08L9/00 ,  C08F36/04 ,  C08K3/013 ,  C08F4/545

    摘要： A process for simply and inexpensively producing a conjugated diene polymer with a narrow molecular weight distribution and a high cis-bond content at a low cost is provided. The process comprises a polymerization step, wherein a conjugated diene polymer having a cis-1,4-bond content of 98.5 mass % or more and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) measured by gel permeation chromatography of 2.5 or less is obtained by carrying out a polymerization reaction in conjugated diene compounds using a catalyst composition containing a rare earth element-containing compound or a reaction product of the rare earth element-containing compound with a Lewis base, an aluminoxane and/or organoaluminum compound, and an iodine-containing compound.

    摘要翻译： 提供了一种以低成本简单且廉价地制备具有窄分子量分布和高顺式键含量的共轭二烯聚合物的方法。 该方法包括聚合步骤，其中顺式-1,4-键含量为98.5质量％以上的共轭二烯聚合物和重均分子量（Mw）与数均分子量（Mw）的比（Mw / Mn） 通过凝胶渗透色谱法测定的重量（Mn）为2.5以下，通过使用含有含稀土元素化合物的催化剂组合物或含稀土元素化合物的反应产物与共轭二烯化合物的反应， 路易斯碱，铝氧烷和/或有机铝化合物，以及含碘化合物。

    Lanthanide-based catalyst composition for the manufacture of polydienes
    5.
    发明授权
    Lanthanide-based catalyst composition for the manufacture of polydienes 有权
    用于制造聚二烯的镧系元素的催化剂组合物

    公开(公告)号：US06699813B2

    公开(公告)日：2004-03-02

    申请号：US10287205

    申请日：2002-11-04

    申请人： Steven Luo ,  Yoichi Ozawa ,  Koji Masaki ,  David Lawson

    发明人： Steven Luo ,  Yoichi Ozawa ,  Koji Masaki ,  David Lawson

    IPC分类号： B01D3100

    CPC分类号： C08F36/04 ,  Y10S526/943 ,  C08F4/7098 ,  C08F4/545

    摘要： A catalyst composition that is the combination of or the reaction product of ingredients comprising (a) an lanthanide compound, (b) an alkylating agent, (c) a nickel-containing compound, and optionally (d) a halogen-containing compound, with the proviso that the halogen-containing compound must be present where none of the lanthanide compound, the alkylating agent, and the nickel-containing compound contain a labile halogen atom.

    摘要翻译： 一种催化剂组合物，其是成分的组合或成分的反应产物，其包含（a）镧系元素化合物，（b）烷基化剂，（c）含镍化合物和任选（d）含卤素化合物与 条件是必须存在镧系化合物，烷化剂和含镍化合物中不含有不稳定卤素原子的卤素化合物。

    Modified polymers prepared with lanthanide-based catalysts
    7.
    发明授权
    Modified polymers prepared with lanthanide-based catalysts 有权
    用镧系元素催化剂制备的改性聚合物

    公开(公告)号：US07671136B2

    公开(公告)日：2010-03-02

    申请号：US11243874

    申请日：2005-10-05

    申请人： Yoichi Ozawa ,  H. Jerrold Miller ,  Koji Masaki

    发明人： Yoichi Ozawa ,  H. Jerrold Miller ,  Koji Masaki

    IPC分类号： C08F8/30

    CPC分类号： C08C19/44 ,  C08F136/04 ,  C08L19/006 ,  C08F4/545

    摘要： A functionalized polymer prepared by a process comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, the polymer having greater than about 85 percent in the 1,4-cis microstructure and less than about 3 percent in the 1,2- or 3,4-microstructure, and reacting the pseudo-living polymer with at least one functionalizing agent defined by the formula (I) or (II): where Z is a substituent that will react or interact with organic or inorganic fillers; with the proviso that each group attached to the imino carbon is attached via a carbon atom and R1, R2, R3, R4, R5, R13, R14 and Z are substituents that will not protonate a pseudo-living polymer.

    摘要翻译： 通过包括以下步骤制备的官能化聚合物的方法，所述方法包括通过使共轭二烯单体与镧系元素基催化剂聚合来制备假活性聚合物，所述聚合物在1,4-顺式显微组织中具有大于约85％且小于约3 在1,2-或3,4-微结构中的百分比，并使假活性聚合物与由式（I）或（II）定义的至少一种官能化试剂反应：其中Z是将与 有机或无机填料; 条件是通过碳原子连接到亚氨基碳上的每个基团，并且R 1，R 2，R 3，R 4，R 5，R 13，R 14和Z是不会使假活性聚合物质子化的取代基。

    PROCESS FOR PRODUCING CONJUGATED DIENE POLYMER, CONJUGATED DIENE POLYMER, AND RUBBER COMPOSITION
    10.
    发明申请
    PROCESS FOR PRODUCING CONJUGATED DIENE POLYMER, CONJUGATED DIENE POLYMER, AND RUBBER COMPOSITION 有权
    生产聚合二烯聚合物，共混二烯聚合物和橡胶组合物的方法

    公开(公告)号：US20120142851A1

    公开(公告)日：2012-06-07

    申请号：US13371780

    申请日：2012-02-13

    申请人： Takahiro NAKAMURA ,  Kouichirou Tani ,  Ryouji Tanaka ,  Takuo Sone ,  Toshihiro Tadaki ,  Junko Kurazumi ,  Koji Masaki ,  Yoichi Ozawa

    发明人： Takahiro NAKAMURA ,  Kouichirou Tani ,  Ryouji Tanaka ,  Takuo Sone ,  Toshihiro Tadaki ,  Junko Kurazumi ,  Koji Masaki ,  Yoichi Ozawa

    IPC分类号： C08L9/00 ,  C08F36/04 ,  C08K3/04 ,  C08F4/12 ,  C08K3/36

    CPC分类号： C08L9/00 ,  C08F36/04 ,  C08K3/013 ,  C08F4/545

    摘要： A process for simply and inexpensively producing a conjugated diene polymer with a narrow molecular weight distribution and a high cis-bond content at a low cost is provided. The process comprises a polymerization step, wherein a conjugated diene polymer having a cis-1,4-bond content of 98.5 mass % or more and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) measured by gel permeation chromatography of 2.5 or less is obtained by carrying out a polymerization reaction in conjugated diene compounds using a catalyst composition containing a rare earth element-containing compound or a reaction product of the rare earth element-containing compound with a Lewis base, an aluminoxane and/or organoaluminum compound, and an iodine-containing compound.

    摘要翻译： 提供了一种以低成本简单且廉价地制备具有窄分子量分布和高顺式键含量的共轭二烯聚合物的方法。 该方法包括聚合步骤，其中顺式-1,4-键含量为98.5质量％以上的共轭二烯聚合物和重均分子量（Mw）与数均分子量（Mw）的比（Mw / Mn） 通过凝胶渗透色谱法测定的重量（Mn）为2.5以下，通过使用含有含稀土元素化合物的催化剂组合物或含稀土元素化合物的反应产物与共轭二烯化合物的反应， 路易斯碱，铝氧烷和/或有机铝化合物，以及含碘化合物。