摘要:
The invention provides a means for greatly saving the thermal energy consumption in the dehydrating distillation of an aqueous solution of a carboxylic acid such as acetic acid by use of an azeotropically distilling entrainer boiling at a lower temperature than the carboxylic acid and immiscible with water. The improvement proposed by the invention comprises taking at least a part of the entrainer phase separated from the condensate coming from the column top or at least a part of the side-cut fluid abstracted from the refluxing fluid inside the column, evaporating the thus taken fluid into vapor and introducing the vapor into the distillation column at a stage for the introduction of the starting feed or below.
摘要:
Proposed is a novel and very efficient method for the preparation of an N-vinyl compound such as N-vinyl-2-pyrrolidone and N-vinyl-N-ethyl acetamide by the thermal decomposition of an N-(.alpha.-acyloxyethyl) compound which is a novel compound obtained by the addition reaction between an NH group-containing compound such as 2-pyrrolidone and N-ethyl acetamide and a vinyl carboxylate, e.g., vinyl acetate, in the presence of an alkali, e.g. alkali metal hydroxide. The reaction mixture after completion of this addition reaction as such, i.e. without isolating the N-(.alpha.-acyloxyethyl) compound, such as N-(.alpha.-acetoxyethyl)-2-pyrrolidone and N-(.alpha.-acetoxyethyl)-N-ethyl acetamide, is heated to effect in situ formation of the desired N-vinyl compound which can then be isolated by distillation under reduced pressure in a very high overall yield.
摘要:
Proposed are an N-(.alpha.-acyloxyethyl) compound, e.g., (N-(.alpha.-acetoxyethyl)-2-pyrrolidone, which is a novel compound and can be converted into an industrially very important N-vinyl compound, e.g., N-vinyl-2-pyrrolidone, by a thermal decomposition reaction under relatively mild conditions as well as a method for the preparation of such an N-(.alpha.-acyloxyethyl) compound. The N-(.alpha.-acyloxyethyl) compound can be synthesized in a high yield by the addition reaction of an NH group-containing compound, e.g., 2-pyrrolidone, with a vinyl carboxylate, e.g., vinyl acetate, in the presence of an alkaline compound such as alkali metal hydroxides.
摘要:
A novel and effective catalyst system is provided for application in the preparation of alkenyl esters of carboxylic acids by transesterification reaction. The catalyst system consists of a palladium compound as the main ingredient and a cocatalyst formed of an alkali metal compound and a copper compound, at least one of which is a halide. The catalyst ingredients are adsorbed on a solid catalyst carrier, so that repeated use of the combined catalyst or a continuous operation of the reaction can easily be facilitated.
摘要:
A polyester resin composition having an equivalent spherical diameter of 1 mm to 50 mm, a degree of crystallization of not less than 65% and less than 99%, an intrinsic viscosity of not more than 0.7 dl/g and a cyclic trimer content of not more than 0.4% by weight. This polymer resin composition has an excellent color tone, causes no significant viscosity lowering or viscosity rise, and can withstand a process which is exposed to a long-term thermal history. A polyester resin composition having a viscosity suitable for extrusion in a general-purpose manner, a production process thereof, and a polyester film are also provided.
摘要:
Disclosed is a video signal processing apparatus applicable to various LCD panels. This video signal processing apparatus includes a format converting unit which converts first-format image data into second-format image data, a point sequential converting unit which converts the second-format image data into point sequenced data, a resizing unit which resizes the point sequenced data, a line memory which stores the resized point sequenced data, and an output control unit which controls to continuously read out the point sequenced data from the line memory.
摘要:
An image processor which forms a composite image of at least two images includes a storage unit which stores first and second image data, and a display unit which reads and displays the stored first and second image data in modes adapted to display forms of the first and second image data. The image processor also includes an image-signal forming unit which forms image signals representing a composite image of the stored first and second image data for display on a television monitor and a liquid crystal display panel.
摘要:
A polyester composition includes a ligand capable of coordinating to a metal or metal ion, wherein the ligand includes at least one donor atom selected from the group consisting of a nitrogen atom, a sulfur atom, and an oxygen atom. Consequently, it is possible to inactivate a metal catalyst which adversely affects heat resistance. As a result, it is possible to obtain polyester compositions and films having excellent heat resistance, colorability, and weathering resistance. Moreover, in the process of producing a polyester, by separating and recovering a catalyst by adding a ligand which is capable of coordinating to a metal or metal ion and which includes at least one donor atom selected from the group consisting of a nitrogen atom, a sulfur atom, and an oxygen atom, it is possible to improve the heat resistance of the polyester composition.
摘要:
An image processor which forms a composite image of at least two images includes a storage unit which stores first and second image data, and a display unit which reads and displays the stored first and second image data in modes adapted to display forms of the first and second image data. The image processor also includes an image-signal forming unit which forms image signals representing a composite image of the stored first and second image data for display on a television monitor and a liquid crystal display panel.
摘要:
A microscope apparatus has a sample table for supporting a sample and being mounted to undergo movement in a horizontal direction. A line sensor acquires a line image for each of a series of measuring positions of the sample in accordance with movement of the sample at a constant speed by one measuring width of the line sensor in the horizontal direction. An image processing device produces an image of the sample based on the line images acquired by the line sensor. A focusing device has a light-projecting member for projecting light onto the sample at a position forward of a leading side of an imaging range of the line sensor in the horizontal direction to prevent light reflected by the sample as a result of the projected light from being incident on and interfering with the line images acquired by the line sensor.