公开(公告)号：US09731481B2

公开(公告)日：2017-08-15

申请号：US13697882

申请日：2011-05-17

申请人： Hiroki Oguro ,  Nobuyuki Koike ,  Yoshio Aoki ,  Kazuya Sato ,  Toshinari Aoki

发明人： Hiroki Oguro ,  Nobuyuki Koike ,  Yoshio Aoki ,  Kazuya Sato ,  Toshinari Aoki

IPC分类号： B32B27/08 ,  B32B27/30 ,  B32B27/36

CPC分类号： B32B27/308 ,  B32B27/08 ,  B32B27/365 ,  Y10T428/31507

摘要： A synthetic resin laminate for use for transparent substrate materials and transparent protective materials is excellent in interlayer adhesiveness, form stability in high-temperature and high humidity environments, surface hardness and impact resistance. The synthetic resin laminate has a vinyl copolymer resin (A) layer and a polycarbonate resin (B) layer, wherein layer (A) is directly laminated on one surface of layer (B), and in which (A) contains a (meth)acrylate structural unit (a) represented by a specific formula and an aliphatic vinyl structural unit (b) represented by a specific formula, the total proportion of the (meth)acrylate structural unit (a) and the aliphatic vinyl structural unit (b) is from 90 to 100 mol % relative to the total of all the structural units in (A), and the proportion of the (meth)acrylate structural unit (a) is from 65 to 80 mol % relative to the total of all the structural units in (A).

公开(公告)号：US20130059158A1

公开(公告)日：2013-03-07

申请号：US13697882

申请日：2011-05-17

申请人： Hiroki Oguro ,  Nobuyuki Koike ,  Yoshio Aoki ,  Kazuya Sato ,  Toshinari Aoki

发明人： Hiroki Oguro ,  Nobuyuki Koike ,  Yoshio Aoki ,  Kazuya Sato ,  Toshinari Aoki

IPC分类号： B32B27/30 ,  B32B27/36

CPC分类号： B32B27/308 ,  B32B27/08 ,  B32B27/365 ,  Y10T428/31507

摘要： A synthetic resin laminate for use for transparent substrate materials and transparent protective materials is excellent in interlayer adhesiveness, form stability in high-temperature and high humidity environments, surface hardness and impact resistance. The synthetic resin laminate has a vinyl copolymer resin (A) layer and a polycarbonate resin (B) layer, wherein layer (A) is directly laminated on one surface of layer (B), and in which (A) contains a (meth)acrylate structural unit (a) represented by a specific formula and an aliphatic vinyl structural unit (b) represented by a specific formula, the total proportion of the (meth)acrylate structural unit (a) and the aliphatic vinyl structural unit (b) is from 90 to 100 mol % relative to the total of all the structural units in (A), and the proportion of the (meth)acrylate structural unit (a) is from 65 to 80 mol % relative to the total of all the structural units in (A).

摘要翻译： 用于透明基板材料和透明保护材料的合成树脂层压板在层间粘合性，高温高湿环境下的形状稳定性，表面硬度和耐冲击性方面是优异的。 合成树脂层压体具有乙烯基共聚物树脂（A）层和聚碳酸酯树脂（B）层，其中层（A）直接层压在层（B）的一个表面上，其中（A）含有（甲基） 丙烯酸酯结构单元（a）和由特定式表示的脂族乙烯基结构单元（b），（甲基）丙烯酸酯结构单元（a）和脂族乙烯基结构单元（b）的总比例为 相对于（A）中的全部结构单元的总量为90〜100摩尔％，（甲基）丙烯酸酯结构单元（a）的比例相对于所有结构单元的总和为65〜80摩尔％ 在一个）。

公开(公告)号：US09657168B2

公开(公告)日：2017-05-23

申请号：US13642936

申请日：2011-05-02

申请人： Yoshio Aoki ,  Kazuya Sato ,  Hiroki Oguro ,  Nobuyuki Koike

发明人： Yoshio Aoki ,  Kazuya Sato ,  Hiroki Oguro ,  Nobuyuki Koike

IPC分类号： C08L33/00 ,  C08L33/12 ,  C08L25/14 ,  G11B7/2533 ,  C08F220/14

CPC分类号： C08L33/12 ,  C08F220/14 ,  C08L25/14 ,  G11B7/2533 ,  C08F212/08 ,  C08F210/14

摘要： To provide a highly transparent thermoplastic resin composition without requiring, for example, a special molecular design or incorporation of an additive, with the refractive index of the composition being readily controllable.The highly transparent and refractive-index-controllable thermoplastic resin composition can be produced by blending a thermoplastic resin (A) containing a structural unit derived from a (meth)acrylic acid ester monomer represented by a specific chemical formula and a structural unit derived from an aromatic vinyl monomer represented by a specific chemical formula, with a thermoplastic resin (B) obtained by hydrogenating aromatic double bonds of a thermoplastic resin which contains a structural unit derived from a (meth)acrylic acid ester monomer represented by a specific chemical formula and a structural unit derived from an aromatic vinyl monomer represented by a specific chemical formula.

公开(公告)号：US20130095337A1

公开(公告)日：2013-04-18

申请号：US13704827

申请日：2011-06-17

申请人： Kazuya Sato ,  Nobuyuki Koike ,  Hiroki Oguro ,  Yoshio Aoki

发明人： Kazuya Sato ,  Nobuyuki Koike ,  Hiroki Oguro ,  Yoshio Aoki

IPC分类号： B32B27/30 ,  B32B27/08

CPC分类号： B32B27/302 ,  B32B3/30 ,  B32B27/08 ,  B32B27/308 ,  B32B27/325 ,  B32B2307/412 ,  B32B2551/00 ,  Y10T428/31913

摘要： A thermoplastic resin laminate is a transparent substrate material or protective material which is excellent in transparency, birefringence, and pattern-formability. The laminate is a synthetic resin laminate formed of a methacrylic resin layer, and a vinyl copolymer resin layer laminated on one or both sides of the methacrylic resin layer. The vinyl copolymer resin contains a (meth)acrylate structural unit and an aliphatic vinyl structural unit represented by specific formulas. The ratio of the sum of the (meth)acrylate structural units and the aliphatic vinyl structural units is 90 to 100 mol % with respect to all the structural units that form the resin. The ratio by mole of the (meth)acrylate structural unit to the aliphatic vinyl structural unit is 65:35 to 85:15. The methacrylic resin contains a structural unit having no benzene ring in an amount of 90 mol % or more with respect to all the structural units.

摘要翻译： 热塑性树脂层叠体是透明性，双折射性和图案形成性优异的透明基材或保护材料。 层压体是由甲基丙烯酸系树脂层和层叠在甲基丙烯酸系树脂层的一面或两面上的乙烯基共聚物树脂层构成的合成树脂层叠体。 乙烯基共聚物树脂含有（甲基）丙烯酸酯结构单元和由特定式表示的脂族乙烯基结构单元。 相对于形成树脂的所有结构单元，（甲基）丙烯酸酯结构单元和脂族乙烯基结构单元之和的比率为90〜100摩尔％。 （甲基）丙烯酸酯结构单元与脂肪族乙烯基结构单元的摩尔比为65:35〜85:15。 相对于所有结构单元，甲基丙烯酸系树脂含有不含苯环的结构单元，其数量为90摩尔％以上。

公开(公告)号：US20130059980A1

公开(公告)日：2013-03-07

申请号：US13642936

申请日：2011-05-02

申请人： Yoshio Aoki ,  Kazuya Sato ,  Hiroki Oguro ,  Nobuyuki Koike

发明人： Yoshio Aoki ,  Kazuya Sato ,  Hiroki Oguro ,  Nobuyuki Koike

IPC分类号： C08L33/12

CPC分类号： C08L33/12 ,  C08F220/14 ,  C08L25/14 ,  G11B7/2533 ,  C08F212/08 ,  C08F210/14

摘要： To provide a highly transparent thermoplastic resin composition without requiring, for example, a special molecular design or incorporation of an additive, with the refractive index of the composition being readily controllable.The highly transparent and refractive-index-controllable thermoplastic resin composition can be produced by blending a thermoplastic resin (A) containing a structural unit derived from a (meth)acrylic acid ester monomer represented by a specific chemical formula and a structural unit derived from an aromatic vinyl monomer represented by a specific chemical formula, with a thermoplastic resin (B) obtained by hydrogenating aromatic double bonds of a thermoplastic resin which contains a structural unit derived from a (meth)acrylic acid ester monomer represented by a specific chemical formula and a structural unit derived from an aromatic vinyl monomer represented by a specific chemical formula.

摘要翻译： 提供高度透明的热塑性树脂组合物，而不需要例如特殊的分子设计或添加剂的结合，组合物的折射率容易控制。 高透明度和折射率可控的热塑性树脂组合物可以通过将含有由特定化学式表示的（甲基）丙烯酸酯单体的结构单元和衍生自具体化学式的结构单元的热塑性树脂（A） 与通过氢化包含由特定化学式表示的（甲基）丙烯酸酯单体的结构单元的热塑性树脂的芳香族双键而获得的热塑性树脂（B）和由具体化学式表示的（甲基）丙烯酸酯单体） 衍生自由特定化学式表示的芳族乙烯基单体的结构单元。

公开(公告)号：US20130183537A1

公开(公告)日：2013-07-18

申请号：US13814323

申请日：2011-08-22

申请人： Kazuya Sato ,  Katsuyuki Murai ,  Nobuyuki Koike ,  Hiroki Oguro

发明人： Kazuya Sato ,  Katsuyuki Murai ,  Nobuyuki Koike ,  Hiroki Oguro

IPC分类号： B32B27/08

CPC分类号： B32B27/08 ,  B32B7/12 ,  B32B27/302 ,  B32B27/308 ,  B32B2250/24 ,  B32B2255/10 ,  B32B2255/26 ,  B32B2270/00 ,  B32B2307/4026 ,  B32B2307/408 ,  B32B2307/412 ,  B32B2307/546 ,  B32B2307/584 ,  B32B2307/71 ,  B32B2307/712 ,  B32B2457/20 ,  G02B1/105 ,  G02B1/14 ,  Y10T428/31928

摘要： The invention provides a synthetic resin laminate having a thermoplastic resin (A) layer and a thermoplastic resin (B) layer provided on each side of the thermoplastic resin (A) layer, the thermoplastic resin (A) having a styrene structural unit content of 65 to 90 mol % with respect to all the structural units forming the resin, characterized in that the thermoplastic resin (B) is a (meth)acrylic acid ester-styrene copolymer resin which is predominantly formed of a (meth)acrylic acid ester structural unit (a) represented by formula (1) and a styrene structural unit, and which has a ratio by mole of (meth)acrylic acid ester structural unit (a) to styrene structural unit of 70:30 to 84:16. The synthetic resin laminate is excellent in transparency, anti-warpage property, interlayer adhesion, adhesion to a hard coat layer formed from a photosensitive hard coating material, scratch resistance, and weather resistance.

摘要翻译： 本发明提供一种具有热塑性树脂（A）层和在热塑性树脂（A）层的每一侧设置的热塑性树脂（B）层）的合成树脂层压体，所述热塑性树脂（A）的苯乙烯结构单元含量为65 相对于形成树脂的所有结构单元为90摩尔％，其特征在于，热塑性树脂（B）是（甲基）丙烯酸酯 - 苯乙烯共聚物树脂，其主要由（甲基）丙烯酸酯结构单元 （a）表示的苯乙烯结构单元和苯乙烯结构单元，（甲基）丙烯酸酯结构单元（a）与苯乙烯结构单元的摩尔比为70:30〜84:16。 合成树脂层叠体的透明性，抗翘曲性，层间粘合性，与感光性硬涂层材料形成的硬涂层的粘附性，耐刮擦性和耐候性优异。

公开(公告)号：US20110244242A1

公开(公告)日：2011-10-06

申请号：US13060835

申请日：2009-08-24

申请人： Hiroki Oguro ,  Nobuyuki Koike ,  Nobuya Saegusa ,  Toshinari Aoki

发明人： Hiroki Oguro ,  Nobuyuki Koike ,  Nobuya Saegusa ,  Toshinari Aoki

IPC分类号： B32B27/00

CPC分类号： B32B27/30 ,  B32B7/12 ,  B32B27/08 ,  B32B27/36 ,  C08F8/04 ,  C08F212/08 ,  Y10T428/31507 ,  C08F220/14

摘要： Provided is a thermoplastic resin laminate including: a thermoplastic transparent resin (A) layer; a thermoplastic resin (B) layer formed of a methyl methacrylate-styrene copolymer and/or an acrylonitrile-styrene copolymer; and a thermoplastic resin (C) layer formed of a polycarbonate-based resin, the (B) layer being laminated on one surface, or each of both surfaces, of the (C) layer, and the (A) layer being laminated on the surface of the (B) layer, in which the thermoplastic transparent resin (A) includes a vinyl copolymer resin containing a (meth)acrylate constituent unit (a) and an aliphatic vinyl constituent unit (b) each having a specific structure at a molar ratio between the (meth)acrylate constituent unit (a) and the aliphatic vinyl constituent unit (b) of 15:85 to 85:15. The thermoplastic resin laminate has such characteristics as to be excellent in, for example, weather resistance against high-temperature, high-humidity environments, abrasion resistance, and interlayer adhesion, and is used, as a transparent substrate material or a transparent protective material, for an optical product, and in particular, portable display devices such as portable phone terminals, portable electronic game devices, and PDA's.

摘要翻译： 本发明提供一种热塑性树脂层压体，它包括：热塑性透明树脂（A）层; 由甲基丙烯酸甲酯 - 苯乙烯共聚物和/或丙烯腈 - 苯乙烯共聚物形成的热塑性树脂（B）层; 和由（C）层和层叠在所述（C）层上的所述（A）层的一个表面或两个表面层叠的所述（B）层，由聚碳酸酯类树脂形成的热塑性树脂（C） （B）层，其中热塑性透明树脂（A）包含含有（甲基）丙烯酸酯结构单元（a）的乙烯基共聚物树脂和脂族乙烯基构成单元（b） （甲基）丙烯酸酯结构单元（a）和脂族乙烯基构成单元（b）之间的比例为15:85至85:15。 热塑性树脂层叠体具有例如耐高温，高湿度环境的耐候性，耐磨性和层间粘合性优异的特征，作为透明基材或透明保护材料， 用于光学产品，特别是诸如便携式电话终端，便携式电子游戏设备和PDA的便携式显示设备。

公开(公告)号：US07078477B2

公开(公告)日：2006-07-18

申请号：US10875230

申请日：2004-06-25

申请人： Hiroki Oguro ,  Shuta Kihara ,  Tsuyoshi Bito

发明人： Hiroki Oguro ,  Shuta Kihara ,  Tsuyoshi Bito

IPC分类号： C08G73/10 ,  C08G69/26

CPC分类号： C08G73/1028 ,  C08G73/1032

摘要： In the process of the present invention, a solvent-soluble polyimide is produced by polycondensing at least one tetracarboxylic acid component with at least one diamine component in a solvent in the presence of a tertiary amine. The tetracarboxylic acid component is selected from the group consisting of tetracarboxylic dianhydrides represented by the following formula 1: wherein R is as defined in the specification, and tetracarboxylic acids and their derivatives represented by the following formula 2: wherein R and Y1 to Y4 are as defined in the specification. Unlike the conventional techniques using an excessively large amount of a chemical imidation agent such as acetic anhydride and a chemical imidation catalyst such as triethylamine, in the process of the present invention, the solvent-soluble polyimide having a high polymerization degree is easily produced in a solvent with good productivity by using only a catalytic amount of the tertiary amine.

摘要翻译： 在本发明的方法中，溶剂可溶性聚酰亚胺通过在至少一种二羧酸组分与至少一种二胺组分在溶剂中在叔胺存在下缩聚来制备。 四羧酸成分选自由下式1表示的四羧酸二酐：其中R如说明书中所定义，和由下式2表示的四羧酸及其衍生物：其中R和Y 1 到Y 4是在说明书中定义的。 与使用过量的化学酰亚胺化剂如乙酸酐和化学酰亚胺化催化剂如三乙胺的常规技术不同，在本发明的方法中，具有高聚合度的溶剂可溶性聚酰亚胺容易在 溶剂，通过仅使用催化量的叔胺具有良好的生产率。

公开(公告)号：US4961021A

公开(公告)日：1990-10-02

申请号：US304213

申请日：1989-01-31

申请人： Hiroki Oguro ,  Nobutaka Okuyama ,  Masaki Nakahara

发明人： Hiroki Oguro ,  Nobutaka Okuyama ,  Masaki Nakahara

IPC分类号： H01J29/76 ,  H01J29/70 ,  H04N9/28

CPC分类号： H01J29/705 ,  H01J2229/5687

摘要： The disclosed relates to a convergence apparatus to be used for a single electron gun type cathode-ray tube, and relates to a convergence yoke to be used for the convergence apparatus. Each of two magnetic poles for generating a bipolar magnetic field is constituted by a first one of a plurality of core protrusions located on a horizontal or vertical axis and at least one pair of second ones of the plurality of core protrusions located at positions equiangularly and symmetrically deviated from the horizontal or vertical axis, and a ratio of an ampere turn of the coil wound on each of at least one pair of second core protrusions to an ampere turn of the coil wound on the first core protrusion is suitably changed. A firt magnetic auxiliary plate and a second magnetic auxiliary plate are provided on a first core protrusion constituting each of a first pair of magnetic poles and on a second core protrusion constituting each of a second pair of magnetic poles respectively. Each of the first and second magnetic auxiliary plates has a fork end projected along an axis perpendicular to a horizontal axis as well as a vertical axis. The first and second magnetic auxiliary plates have respective widths existing within an angular range symmetrically deviated by 45.degree. from the horizontal axis and within an angular range symmetrically deviated by 45.degree. from the vertical axis respectively. Each of the first and second magnetic auxiliary plates has a substantially Y-shaped and axisymmetrical form.

摘要翻译： 所公开的涉及用于单电子枪式阴极射线管的会聚装置，涉及用于会聚装置的会聚磁轭。 用于产生双极磁场的两个磁极中的每一个由位于水平轴或垂直轴上的多个芯突起中的第一个和位于等轴对称的位置中的至少一对第二个芯突起中的至少一对构成 卷绕在至少一对第二芯突起中的每一个上的线圈的安培匝数与卷绕在第一芯突起上的线圈的安匝数的比率适当地改变。 在构成第一对磁极中的每一个的第一芯突起上和分别构成第二对磁极中的每一个的第二芯突起上设置有一个空隙磁辅助板和一第二磁辅助板。 第一和第二磁辅助板中的每一个具有沿着垂直于水平轴线和垂直轴线的轴线突出的叉端。 第一和第二磁性辅助板具有相对于与水平轴对称偏离45°并在与垂直轴对称偏离45°的角度范围内的相对宽度。 第一和第二磁辅助板中的每一个具有大致Y形和轴对称的形式。

公开(公告)号：US4725763A

公开(公告)日：1988-02-16

申请号：US911422

申请日：1986-09-25

申请人： Nobutaka Okuyama ,  Toshiharu Shimizu ,  Hiroki Oguro

发明人： Nobutaka Okuyama ,  Toshiharu Shimizu ,  Hiroki Oguro

IPC分类号： H01J29/70 ,  H01J29/50

CPC分类号： H01J29/705 ,  H01J29/707 ,  H01J2229/5687

摘要： A convergence correcting device for correcting mis-convergence of a cathode ray tube having in-line electron guns and, at the same time, correcting coma at the top and bottom of the screen, the device comprising pole pieces provided for the outermost electron beams for producing 4-pole magnetic fields used for convergence correction, a convergence yoke for applying the magnetic fields to the pole pieces, a convergence coil wound on the convergence yoke, a coil for producing a coma correcting magnetic field which cancels a leakage flux created between the right and left pole pieces by the vertical deflection coil, and current sources for supply currents to the coils.

摘要翻译： 一种用于校正具有直列电子枪的阴极射线管的误会聚并且同时校正屏幕顶部和底部的彗差的会聚校正装置，该装置包括为最外面的电子束提供的极片，用于 产生用于会聚校正的4极磁场，用于将磁场施加到磁极片的会聚磁轭，卷绕在会聚磁轭上的会聚线圈，用于产生彗差校正磁场的线圈，其消除在 垂直偏转线圈的右极和左极片，以及线圈供电电流的电流源。