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公开(公告)号:US09085647B2
公开(公告)日:2015-07-21
申请号:US11597918
申请日:2005-05-31
申请人: Nobuya Saegusa , Shojiro Kuwahara
发明人: Nobuya Saegusa , Shojiro Kuwahara
IPC分类号: B32B27/08 , B29C47/00 , C08F212/08 , C08F220/14 , C08F220/18 , C08F8/04 , B32B27/30 , C08L33/10 , C08L33/08 , C08L25/08 , C08L33/12 , B29C47/06 , G02B6/122 , B29C47/04
CPC分类号: C08F8/04 , B29C47/0021 , B29C47/043 , B29C47/065 , B32B27/00 , B32B27/08 , B32B27/18 , B32B27/20 , B32B27/22 , B32B27/302 , B32B27/308 , B32B27/36 , B32B27/365 , B32B2250/03 , B32B2250/24 , B32B2250/44 , B32B2264/0235 , B32B2264/025 , B32B2264/102 , B32B2264/104 , B32B2264/12 , B32B2307/412 , B32B2307/546 , B32B2457/20 , B32B2551/00 , C08F212/08 , C08F220/14 , C08F220/18 , C08F2800/10 , C08F2810/50 , C08L25/08 , C08L33/08 , C08L33/10 , C08L33/12 , G02B6/1221 , Y10T428/31855
摘要: A thermoplastic transparent resin which is produced by hydrogenating 70% or more of aromatic double bonds of a copolymer. The copolymer is produced by polymerizing a monomer composition containing at least one (meth)acrylic ester monomer and at least one aromatic vinyl monomer and has a molar ratio (A/B) of from 1 to 4 wherein A is a molar amount of a constitutional unit derived from the (meth)acrylic ester monomer and B is a molar amount of a constitutional unit derived from the aromatic vinyl monomer. The thermoplastic transparent resin is suitable for the production of a molded article such as optical article having a good color tone because molding defect is less produced.
摘要翻译: 通过共聚物的70%以上的芳香族双键氢化而制造的热塑性透明树脂。 共聚物通过聚合含有至少一种(甲基)丙烯酸酯单体和至少一种芳族乙烯基单体的单体组合物而制备,并且摩尔比(A / B)为1至4,其中A为结构式 衍生自(甲基)丙烯酸酯单体的单元,B是衍生自芳族乙烯基单体的结构单元的摩尔量。 热塑性透明树脂适合于制造具有良好色调的模制品如光学制品,因为较少产生成型缺陷。
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公开(公告)号:US20080213606A1
公开(公告)日:2008-09-04
申请号:US11597918
申请日:2005-05-31
申请人: Nobuya Saegusa , Shojiro Kuwahara
发明人: Nobuya Saegusa , Shojiro Kuwahara
IPC分类号: B32B27/30 , C08F220/06
CPC分类号: C08F8/04 , B29C47/0021 , B29C47/043 , B29C47/065 , B32B27/00 , B32B27/08 , B32B27/18 , B32B27/20 , B32B27/22 , B32B27/302 , B32B27/308 , B32B27/36 , B32B27/365 , B32B2250/03 , B32B2250/24 , B32B2250/44 , B32B2264/0235 , B32B2264/025 , B32B2264/102 , B32B2264/104 , B32B2264/12 , B32B2307/412 , B32B2307/546 , B32B2457/20 , B32B2551/00 , C08F212/08 , C08F220/14 , C08F220/18 , C08F2800/10 , C08F2810/50 , C08L25/08 , C08L33/08 , C08L33/10 , C08L33/12 , G02B6/1221 , Y10T428/31855
摘要: A thermoplastic transparent resin which is produced by hydrogenating 70% or more of aromatic double bonds of a copolymer. The copolymer is produced by polymerizing a monomer composition containing at least one (meth)acrylic ester monomer and at least one aromatic vinyl monomer and has a molar ratio (A/B) of from 1 to 4 wherein A is a molar amount of a constitutional unit derived from the (meth)acrylic ester monomer and B is a molar amount of a constitutional unit derived from the aromatic vinyl monomer. The thermoplastic transparent resin is suitable for the production of a molded article such as optical article having a good color tone because molding defect is less produced.
摘要翻译: 通过共聚物的70%以上的芳香族双键氢化而制造的热塑性透明树脂。 共聚物通过聚合含有至少一种(甲基)丙烯酸酯单体和至少一种芳族乙烯基单体的单体组合物而制备,并且摩尔比(A / B)为1至4,其中A为结构式 衍生自(甲基)丙烯酸酯单体的单元,B为衍生自芳族乙烯基单体的结构单元的摩尔量。 热塑性透明树脂适合于制造具有良好色调的模制品如光学制品,因为较少产生成型缺陷。
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公开(公告)号:US20050176914A1
公开(公告)日:2005-08-11
申请号:US10998058
申请日:2004-11-29
CPC分类号: C08G63/82 , C08G63/672 , C08G63/85
摘要: In the invention, a polyester resin comprising dicarboxylic acid constitutional units and diol constitutional units wherein 5 to 60 mol % of the diol constitutional units has a cyclic acetal skeleton is produced by a process comprising an oligomerization step and a polymerization step. In the oligomerization step, an ester having a limited acid value is transesterified with a diol having a cyclic acetal skeleton in the presence of a basic compound to obtain an oligomer. The oligomer is then polymerized in the subsequent polymerization step to increase the molecular weight.
摘要翻译: 在本发明中,通过包括低聚步骤和聚合步骤的方法制备包含二羧酸结构单元的聚酯树脂和其中5至60mol%的二醇结构单元具有环状缩醛骨架的二醇结构单元。 在低聚步骤中,在碱性化合物的存在下,将具有有限酸值的酯与具有环状缩醛骨架的二醇酯交换,得到低聚物。 然后在随后的聚合步骤中聚合低聚物以增加分子量。
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公开(公告)号:US07183362B2
公开(公告)日:2007-02-27
申请号:US10998058
申请日:2004-11-29
CPC分类号: C08G63/82 , C08G63/672 , C08G63/85
摘要: In the invention, a polyester resin comprising dicarboxylic acid constitutional units and diol constitutional units wherein 5 to 60 mol % of the diol constitutional units has a cyclic acetal skeleton is produced by a process comprising an oligomerization step and a polymerization step. In the oligomerization step, an ester having a limited acid value is transesterified with a diol having a cyclic acetal skeleton in the presence of a basic compound to obtain an oligomer. The oligomer is then polymerized in the subsequent polymerization step to increase the molecular weight.
摘要翻译: 在本发明中,通过包括低聚步骤和聚合步骤的方法制备包含二羧酸结构单元的聚酯树脂和其中5至60mol%的二醇结构单元具有环状缩醛骨架的二醇结构单元。 在低聚步骤中,在碱性化合物的存在下,将具有有限酸值的酯与具有环状缩醛骨架的二醇酯交换,得到低聚物。 然后在随后的聚合步骤中聚合低聚物以增加分子量。
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公开(公告)号:US20110244242A1
公开(公告)日:2011-10-06
申请号:US13060835
申请日:2009-08-24
申请人: Hiroki Oguro , Nobuyuki Koike , Nobuya Saegusa , Toshinari Aoki
发明人: Hiroki Oguro , Nobuyuki Koike , Nobuya Saegusa , Toshinari Aoki
IPC分类号: B32B27/00
CPC分类号: B32B27/30 , B32B7/12 , B32B27/08 , B32B27/36 , C08F8/04 , C08F212/08 , Y10T428/31507 , C08F220/14
摘要: Provided is a thermoplastic resin laminate including: a thermoplastic transparent resin (A) layer; a thermoplastic resin (B) layer formed of a methyl methacrylate-styrene copolymer and/or an acrylonitrile-styrene copolymer; and a thermoplastic resin (C) layer formed of a polycarbonate-based resin, the (B) layer being laminated on one surface, or each of both surfaces, of the (C) layer, and the (A) layer being laminated on the surface of the (B) layer, in which the thermoplastic transparent resin (A) includes a vinyl copolymer resin containing a (meth)acrylate constituent unit (a) and an aliphatic vinyl constituent unit (b) each having a specific structure at a molar ratio between the (meth)acrylate constituent unit (a) and the aliphatic vinyl constituent unit (b) of 15:85 to 85:15. The thermoplastic resin laminate has such characteristics as to be excellent in, for example, weather resistance against high-temperature, high-humidity environments, abrasion resistance, and interlayer adhesion, and is used, as a transparent substrate material or a transparent protective material, for an optical product, and in particular, portable display devices such as portable phone terminals, portable electronic game devices, and PDA's.
摘要翻译: 本发明提供一种热塑性树脂层压体,它包括:热塑性透明树脂(A)层; 由甲基丙烯酸甲酯 - 苯乙烯共聚物和/或丙烯腈 - 苯乙烯共聚物形成的热塑性树脂(B)层; 和由(C)层和层叠在所述(C)层上的所述(A)层的一个表面或两个表面层叠的所述(B)层,由聚碳酸酯类树脂形成的热塑性树脂(C) (B)层,其中热塑性透明树脂(A)包含含有(甲基)丙烯酸酯结构单元(a)的乙烯基共聚物树脂和脂族乙烯基构成单元(b) (甲基)丙烯酸酯结构单元(a)和脂族乙烯基构成单元(b)之间的比例为15:85至85:15。 热塑性树脂层叠体具有例如耐高温,高湿度环境的耐候性,耐磨性和层间粘合性优异的特征,作为透明基材或透明保护材料, 用于光学产品,特别是诸如便携式电话终端,便携式电子游戏设备和PDA的便携式显示设备。
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