公开(公告)号：US07622535B2

公开(公告)日：2009-11-24

申请号：US11089160

申请日：2005-03-24

申请人： Yorimichi Dairoku ,  Yoshio Irie ,  Shinichi Fujino ,  Yasuhiro Fujita ,  Kenji Tada ,  Hiroki Inoue ,  Makoto Nagasawa ,  Hirofumi Shibata

发明人： Yorimichi Dairoku ,  Yoshio Irie ,  Shinichi Fujino ,  Yasuhiro Fujita ,  Kenji Tada ,  Hiroki Inoue ,  Makoto Nagasawa ,  Hirofumi Shibata

IPC分类号： C08F2/00 ,  C08F236/00 ,  C08F20/06

CPC分类号： C08F6/006

摘要： The present invention relates to a method for continuous production of a water-absorbent resin by use of an continuous polymerization device having a charge part of a monomer aqueous solution; an endless belt on which the monomer and a hydropolymer formed are conveyed; and a discharge part of the hydropolymer, wherein the continuous polymerization device has side walls and a ceiling, and the space ratio in the device represented by the equation, “space ratio in the device=B/A”, is in the range of 1.2 to 20. In the equation, A is a maximum cross-sectional area (cm2) of the hydropolymer during the polymerization in the width direction of the endless belt, and B is a maximum cross-sectional area (cm2) of the space between the endless belt of the continuous polymerization device and the ceiling of the continuous polymerization device in the width direction of the endless belt.

摘要翻译： 本发明涉及使用具有单体水溶液的电荷部分的连续聚合装置连续制造吸水性树脂的方法; 输送单体和形成的氢化聚合物的环状带; 和氢化聚合物的排出部分，其中连续聚合装置具有侧壁和天花板，并且由等式“器件中的空间比= B / A”表示的器件中的空间比在1.2 在该方程式中，A是在环形带的宽度方向上的聚合期间的氢化聚合物的最大横截面积（cm2），B是在环状带的宽度方向上的最大横截面积（cm2） 连续聚合装置的环形带和连续聚合装置的天花板在环形带的宽度方向上。

公开(公告)号：US07265190B2

公开(公告)日：2007-09-04

申请号：US10691586

申请日：2003-10-24

申请人： Yorimichi Dairoku ,  Yasuhiro Fujita ,  Shinichi Fujino ,  Hirofumi Shibata ,  Kenji Tada ,  Yoshio Irie

发明人： Yorimichi Dairoku ,  Yasuhiro Fujita ,  Shinichi Fujino ,  Hirofumi Shibata ,  Kenji Tada ,  Yoshio Irie

IPC分类号： C08F2/04 ,  C08F2/32 ,  C08F20/06

CPC分类号： C08F2/01 ,  B01J14/00 ,  B01J19/24 ,  C08F220/06 ,  C08F222/1006 ,  Y10S526/918

摘要： There is disclosed a process to uniformly and rapidly carry out the mixing of a monomer liquid and a polymerization initiator and thus for the resulting polymer not to adhere to the inner surface of the piping or the inside of the apparatus in an art of producing a water-absorbent resin by continuously mixing the monomer liquid and the polymerization initiator together and thereby carrying out polymerization. This process comprises the steps of: (a) continuously supplying a monomer liquid 20 to such as a supply pipe 10 to continuously stir the monomer liquid 20 in the supply pipe 10 with such as a stirring apparatus 12; (b) causing a polymerization initiator 30 to join into a flow of the monomer liquid 20 being in a stirred state, thereby obtaining a mixed liquid 40 of the monomer liquid 20 and the polymerization initiator 30; and (c) continuously supplying the mixed liquid 40 from the supply pipe line 10 to a polymerization apparatus to cause the mixed liquid 40 to run a polymerization reaction.

摘要翻译： 公开了一种均匀且快速地进行单体液体和聚合引发剂的混合的方法，因此在生产水的技术中所得聚合物不粘附到管道或设备内部的内表面 通过将单体液体和聚合引发剂连续混合在一起，从而进行聚合。 该方法包括以下步骤：（a）将单体液体20连续地供给到供给管10，以通过搅拌装置12连续地搅拌供给管10中的单体液20; （b）使聚合引发剂30接合到处于搅拌状态的单体液体20的流动中，从而得到单体液20和聚合引发剂30的混合液40; 和（c）将混合液40从供给管线10连续供给聚合装置，使混合液40进行聚合反应。

公开(公告)号：US20050215734A1

公开(公告)日：2005-09-29

申请号：US11089160

申请日：2005-03-24

申请人： Yorimichi Dairoku ,  Yoshio Irie ,  Shinichi Fujino ,  Yasuhiro Fujita ,  Kenji Tada ,  Hiroki Inoue ,  Makoto Nagasawa ,  Hirofumi Shibata

发明人： Yorimichi Dairoku ,  Yoshio Irie ,  Shinichi Fujino ,  Yasuhiro Fujita ,  Kenji Tada ,  Hiroki Inoue ,  Makoto Nagasawa ,  Hirofumi Shibata

IPC分类号： C08F6/00 ,  C08F8/00 ,  C08F2/00

CPC分类号： C08F6/006

摘要： The present invention relates to a method for continuous production of a water-absorbent resin by use of an continuous polymerization device having a charge part of a monomer aqueous solution; an endless belt on which the monomer and a hydropolymer formed are conveyed; and a discharge part of the hydropolymer, wherein the continuous polymerization device has side walls and a ceiling, and the space ratio in the device represented by the equation, “space ratio in the device=B/A”, is in the range of 1.2 to 20. In the equation, A is a maximum cross-sectional area (cm2) of the hydropolymer during the polymerization in the width direction of the endless belt, and B is a maximum cross-sectional area (cm2) of the space between the endless belt of the continuous polymerization device and the ceiling of the continuous polymerization device in the width direction of the endless belt.

摘要翻译： 本发明涉及使用具有单体水溶液的电荷部分的连续聚合装置连续制造吸水性树脂的方法; 输送单体和形成的氢化聚合物的环状带; 和氢化聚合物的排出部分，其中连续聚合装置具有侧壁和天花板，并且由等式“器件中的空间比= B / A”表示的器件中的空间比在1.2 在等式中，A是在环形带的宽度方向上的聚合期间的氢化聚合物的最大横截面积（cm 2），B是最大横截面积 连续聚合装置的环形带与连续聚合装置的天花板之间的距离（cm 2）在环形带的宽度方向上。

公开(公告)号：US07694900B2

公开(公告)日：2010-04-13

申请号：US10829706

申请日：2004-04-22

申请人： Yoshio Irie ,  Yorimichi Dairoku ,  Yasuhiro Fujita ,  Kenji Tada ,  Hirofumi Shibata

发明人： Yoshio Irie ,  Yorimichi Dairoku ,  Yasuhiro Fujita ,  Kenji Tada ,  Hirofumi Shibata

IPC分类号： B02C1/00 ,  B02C23/18

CPC分类号： B29C47/762 ,  B29C47/0004 ,  B29C47/0011 ,  B29C47/10 ,  B29C47/1027 ,  B29C47/1063 ,  B29C47/1072 ,  B29K2995/0092 ,  C08J3/124 ,  C08J2300/14

摘要： A method for disintegrating a hydrate polymer characterized by disintegrating a hydrate polymer having a solid content in the range of 50-70 wt. % with a screw extruder while supplying 0.1-30 parts by weight of water per 100 parts by weight of the polymer to the extruder. Since the product of disintegration is prevented from inducing mutual adhesion, it does not form masses of conglomeration when it is dried.

摘要翻译： 一种水合物聚合物的分解方法，其特征在于将固体成分在50〜70重量％范围内的水合物聚合物分解。 ％，同时向挤出机中加入每100重量份聚合物0.1-30重量份的水。 由于防止分解产物引起相互粘合，所以当其干燥时不会形成团聚体。

公开(公告)号：US20070123658A1

公开(公告)日：2007-05-31

申请号：US10572565

申请日：2004-09-17

申请人： Kazushi Torii ,  Hirofumi Shibata ,  Taku Iwamura ,  Yoshio Irie ,  Yorimichi Dairoku ,  Yoshiro Mitsukami ,  Sayaka Machida

发明人： Kazushi Torii ,  Hirofumi Shibata ,  Taku Iwamura ,  Yoshio Irie ,  Yorimichi Dairoku ,  Yoshiro Mitsukami ,  Sayaka Machida

IPC分类号： C08F120/02

CPC分类号： C08J3/245 ,  A61L15/60 ,  B01J20/261 ,  B01J2220/68 ,  C08F20/06 ,  C08J2333/00

摘要： An object of the present invention is to provide a water absorbent having excellent gel properties and showing excellent properties when used in a water-absorbing material of a sanitary/hygienic material such as paper diaper. Moreover, another object of the present invention is to provide a water absorbent which is safe and excellent in liquid permeability, and in which an amount of liquid permeability improver for improving the liquid permeability is reduced. The water absorbent is made from a water-absorbing resin prepared by a specific polymerization method and having a high degree of cross-linking, a high liquid holding property and a high gel strength (its swelling pressure of gel layer of is 35 kdyne/cm2 or more). This water absorbent is further processed to have a particular particle size distribution (95 wt % or more of its particles are less than 850ƒÊm but not less than 106ƒÊm, and logarithmic standard deviation (ƒĐƒÄ) is in a range of 0.25 to 0.45) and then surface cross-linked. After that, a liquid permeability improver is added therein.

摘要翻译： 本发明的目的是提供一种具有优异凝胶性能的吸水剂，并且当用于诸如纸尿布的卫生/卫生材料的吸水材料时显示出优异的性能。 此外，本发明的另一个目的是提供一种安全且透液性优异的吸水剂，并且其中用于提高液体渗透性的液体渗透性改进剂的量减少。 吸水剂由具有高交联度，高液体保持性和高凝胶强度（凝胶层的溶胀压力为35kDyne / cm2）的特定聚合方法制成的吸水性树脂 或者更多）。 该吸水剂被进一步处理以具有特定的粒度分布（其颗粒的95重量％以上小于850微米但不小于106微米，对数标准偏差（fDfÄ）在0.25至0.45的范围内），然后 表面交联。 之后，加入液体渗透性改进剂。

公开(公告)号：US07803880B2

公开(公告)日：2010-09-28

申请号：US10572565

申请日：2004-09-17

申请人： Kazushi Torii ,  Hirofumi Shibata ,  Taku Iwamura ,  Yoshio Irie ,  Yorimichi Dairoku ,  Yoshiro Mitsukami ,  Sayaka Machida

发明人： Kazushi Torii ,  Hirofumi Shibata ,  Taku Iwamura ,  Yoshio Irie ,  Yorimichi Dairoku ,  Yoshiro Mitsukami ,  Sayaka Machida

IPC分类号： C08F20/02

CPC分类号： C08J3/245 ,  A61L15/60 ,  B01J20/261 ,  B01J2220/68 ,  C08F20/06 ,  C08J2333/00

摘要： An object of the present invention is to provide a water absorbent having excellent gel properties and showing excellent properties when used in a water-absorbing material of a sanitary/hygienic material such as paper diaper. Moreover, another object of the present invention is to provide a water absorbent which is safe and excellent in liquid permeability, and in which an amount of liquid permeability improver for improving the liquid permeability is reduced. The water absorbent is made from a water-absorbing resin prepared by a specific polymerization method and having a high degree of cross-linking, a high liquid holding property and a high gel strength (its swelling pressure of gel layer of is 35 kdyne/cm2 or more). This water absorbent is further processed to have a particular particle size distribution (95 wt % or more of its particles are less than 850ƒÊm but not less than 106ƒÊm, and logarithmic standard deviation (ƒĐƒÄ) is in a range of 0.25 to 0.45) and then surface cross-linked. After that, a liquid permeability improver is added therein.

摘要翻译： 本发明的目的是提供一种具有优异凝胶性能的吸水剂，并且当用于诸如纸尿布的卫生/卫生材料的吸水材料时显示出优异的性能。 此外，本发明的另一个目的是提供一种安全且透液性优异的吸水剂，其中用于提高液体渗透性的液体渗透性改进剂的量减少。 吸水剂由具有高交联度，高液体保持性和高凝胶强度（凝胶层的溶胀压力为35kDyne / cm2）的特定聚合方法制成的吸水性树脂 或者更多）。 该吸水剂被进一步处理以具有特定的粒度分布（其颗粒的95重量％或更多小于850度，但不小于106度，对数标准偏差（ƒðƒÄ）在0.25至0.45的范围内），然后 表面交联。 之后，加入液体渗透性改进剂。

公开(公告)号：US08497226B2

公开(公告)日：2013-07-30

申请号：US12805685

申请日：2010-08-13

申请人： Kazushi Torii ,  Hirofumi Shibata ,  Taku Iwamura ,  Yoshio Irie ,  Yorimichi Dairoku ,  Yoshiro Mitsukami ,  Sayaka Machida

发明人： Kazushi Torii ,  Hirofumi Shibata ,  Taku Iwamura ,  Yoshio Irie ,  Yorimichi Dairoku ,  Yoshiro Mitsukami ,  Sayaka Machida

IPC分类号： B01J20/26 ,  C08F20/06

CPC分类号： C08J3/245 ,  A61L15/60 ,  B01J20/261 ,  B01J2220/68 ,  C08F20/06 ,  C08J2333/00

摘要： An object of the present invention is to provide a water absorbent having excellent gel properties and showing excellent properties when used in a water-absorbing material of a sanitary/hygienic material such as paper diaper. Moreover, another object of the present invention is to provide a water absorbent which is safe and excellent in liquid permeability, and in which an amount of liquid permeability improver for improving the liquid permeability is reduced. The water absorbent is made from a water-absorbing resin prepared by a specific polymerization method and having a high degree of cross-linking, a high liquid holding property and a high gel strength (its swelling pressure of gel layer of is 35 kdyne/cm2 or more). This water absorbent is further processed to have a particular particle size distribution (95 wt % or more of its particles are less than 850ƒÊm but not less than 106ƒÊm, and logarithmic standard deviation (ƒĐƒÄ) is in a range of 0.25 to 0.45) and then surface cross-linked. After that, a liquid permeability improver is added therein.

摘要翻译： 本发明的目的是提供一种具有优异凝胶性能的吸水剂，并且当用于诸如纸尿布的卫生/卫生材料的吸水材料时显示出优异的性能。 此外，本发明的另一个目的是提供一种安全且透液性优异的吸水剂，其中用于提高液体渗透性的液体渗透性改进剂的量减少。 吸水剂由具有高交联度，高液体保持性和高凝胶强度（凝胶层的溶胀压力为35kDyne / cm2）的特定聚合方法制成的吸水性树脂 或者更多）。 该吸水剂被进一步处理以具有特定的粒度分布（其颗粒的95重量％以上小于850微米但不小于106微米，对数标准偏差（fDfÄ）在0.25至0.45的范围内），然后 表面交联。 之后，加入液体渗透性改进剂。

公开(公告)号：US20100308263A1

公开(公告)日：2010-12-09

申请号：US12805685

申请日：2010-08-13

申请人： Kazushi Torii ,  Hirofumi Shibata ,  Taku Iwamura ,  Yoshio Irie ,  Yorimichi Dairoku ,  Yoshiro Mitsukami ,  Sayaka Machida

发明人： Kazushi Torii ,  Hirofumi Shibata ,  Taku Iwamura ,  Yoshio Irie ,  Yorimichi Dairoku ,  Yoshiro Mitsukami ,  Sayaka Machida

IPC分类号： B01J20/26 ,  C08F120/06

CPC分类号： C08J3/245 ,  A61L15/60 ,  B01J20/261 ,  B01J2220/68 ,  C08F20/06 ,  C08J2333/00

摘要： An object of the present invention is to provide a water absorbent having excellent gel properties and showing excellent properties when used in a water-absorbing material of a sanitary/hygienic material such as paper diaper. Moreover, another object of the present invention is to provide a water absorbent which is safe and excellent in liquid permeability, and in which an amount of liquid permeability improver for improving the liquid permeability is reduced. The water absorbent is made from a water-absorbing resin prepared by a specific polymerization method and having a high degree of cross-linking, a high liquid holding property and a high gel strength (its swelling pressure of gel layer of is 35 kdyne/cm2 or more). This water absorbent is further processed to have a particular particle size distribution (95 wt % or more of its particles are less than 850ƒÊm but not less than 106ƒÊm, and logarithmic standard deviation (ƒĐƒÄ) is in a range of 0.25 to 0.45) and then surface cross-linked. After that, a liquid permeability improver is added therein.

摘要翻译： 本发明的目的是提供一种具有优异凝胶性能的吸水剂，并且当用于诸如纸尿布的卫生/卫生材料的吸水材料时显示出优异的性能。 此外，本发明的另一个目的是提供一种安全且透液性优异的吸水剂，其中用于提高液体渗透性的液体渗透性改进剂的量减少。 吸水剂由具有高交联度，高液体保持性和高凝胶强度（凝胶层的溶胀压力为35kDyne / cm2）的特定聚合方法制成的吸水性树脂 或者更多）。 该吸水剂被进一步处理以具有特定的粒度分布（其颗粒的95重量％或更多小于850度，但不小于106度，对数标准偏差（ƒðƒÄ）在0.25至0.45的范围内），然后 表面交联。 之后，加入液体渗透性改进剂。

公开(公告)号：US20120305842A1

公开(公告)日：2012-12-06

申请号：US13467236

申请日：2012-05-09

申请人： Kazushi Torii ,  Hirofumi Shibata ,  Kazuki Kimura ,  Yasuhisa Nakashima ,  Motohiro Imura ,  Hiroko Ueda ,  Katsuyuki Wada

发明人： Kazushi Torii ,  Hirofumi Shibata ,  Kazuki Kimura ,  Yasuhisa Nakashima ,  Motohiro Imura ,  Hiroko Ueda ,  Katsuyuki Wada

IPC分类号： C08L35/02

CPC分类号： A61L15/60 ,  A61L15/18 ,  B01J20/103 ,  B01J20/26 ,  B01J20/261 ,  B01J20/267 ,  B01J2220/46 ,  B01J2220/68 ,  C08K3/36 ,  C08L101/14 ,  Y10T428/253

摘要： A water absorbing agent of the present invention has an internal crosslinking structure obtained by polymerization of a water-soluble unsaturated monomer. The agent satisfies conditions (a) to (d): (a) the agent contains water-insoluble inorganic particles at an amount of from 10 ppm to 1,900 ppm inclusive; (b) the agent contains 5 mass % or less particles which have such a size that they can pass through a sieve having a mesh opening size of 150 μm; (c) the agent has an absorbency against a pressure of 4.83 kPa (AAP) of 18 g/g or more; and (d) the water-insoluble inorganic particles reside on a surface of the water absorbing resin or near the surface.

摘要翻译： 本发明的吸水剂具有通过聚合水溶性不饱和单体获得的内部交联结构。 该试剂满足条件（a）至（d）：（a）该试剂含有10ppm至1,900ppm含量的水不溶性无机颗粒; （b）该试剂含有5质量％以下的粒径，使其能够通过网孔大小为150μm的筛子; （c）该试剂具有相对于4.83kPa（AAP）的压力为18g / g以上的吸收性; 和（d）水不溶性无机颗粒驻留在吸水树脂的表面上或表面附近。

公开(公告)号：US5748274A

公开(公告)日：1998-05-05

申请号：US406484

申请日：1995-03-20

申请人： Osamu Taniguchi ,  Shinjiro Okada ,  Yutaka Inaba ,  Hitoshi Shindo ,  Hirofumi Shibata

发明人： Osamu Taniguchi ,  Shinjiro Okada ,  Yutaka Inaba ,  Hitoshi Shindo ,  Hirofumi Shibata

IPC分类号： G02F1/1339 ,  G02F1/133 ,  G02F1/1337 ,  G02F1/1343 ,  G02F1/137 ,  G02F1/141 ,  G09F9/35 ,  G02F1/13

CPC分类号： G02F1/1337 ,  G02F1/141 ,  G02F1/133784 ,  G02F1/13394 ,  G02F1/134336

摘要： A liquid crystal device comprising a pair of parallel base plates and a ferroelectric liquid crystal disposed between the base plates. One of the pair of parallel base plates is provided with a plurality of stepwise elevations disposed in the form of stripes, and has been implemented with a uniaxial orientation treatment in a direction parallel to the edges of the stepwise elevations. The stepwise elevation may be formed by a transparent electrode alone or in combination with an alignment control film disposed thereon. Because of the above features, alignment defects liable to develop from the edges of the elevations are removed.

摘要翻译： 一种液晶装置，包括一对平行基板和设置在基板之间的铁电液晶。 一对平行基板中的一个设置有以条纹形式设置的多个逐步升降，并且已经在平行于阶梯高度的边缘的方向上以单轴取向处理来实现。 可以通过单独的透明电极或与其上配置的取向控制膜组合来形成逐步升高。 由于上述特征，从高度边缘容易产生的对准缺陷被去除。