公开(公告)号：US20070142666A1

公开(公告)日：2007-06-21

申请号：US10588921

申请日：2005-02-07

申请人： Yoshiyuki Himeno ,  Akio Takeda ,  Seiichi Kawato ,  Wataru Ninomiya

发明人： Yoshiyuki Himeno ,  Akio Takeda ,  Seiichi Kawato ,  Wataru Ninomiya

IPC分类号： C07C61/08

CPC分类号： B01J23/40 ,  B01J21/18 ,  B01J23/44 ,  B01J31/0231 ,  B01J31/04 ,  B01J31/28 ,  B01J37/16 ,  C07C51/252 ,  C07C57/04

摘要： The object of the present invention is to provide a method for producing an α,β-unsaturated carboxylic acid in higher selectivity. The present invention resides in a method for producing an α,β-unsaturated carboxylic acid from an olefin or an α,β-unsaturated aldehyde in liquid phase by using a noble metal-containing catalyst and by causing a compound (A) having an acid dissociation exponent (pKa) of less than 4 to be present in the liquid phase.

摘要翻译： 本发明的目的是提供一种以更高选择性生产α，β-不饱和羧酸的方法。 本发明涉及一种通过使用含贵金属的催化剂，通过使具有酸的化合物（A）从液相中的烯烃或α，β-不饱和醛生成α，β-不饱和羧酸的方法， 解离指数（pKa）小于4存在于液相中。

公开(公告)号：US07498462B2

公开(公告)日：2009-03-03

申请号：US10588921

申请日：2005-02-07

申请人： Yoshiyuki Himeno ,  Akio Takeda ,  Seiichi Kawato ,  Wataru Ninomiya

发明人： Yoshiyuki Himeno ,  Akio Takeda ,  Seiichi Kawato ,  Wataru Ninomiya

IPC分类号： C07C57/04

CPC分类号： B01J23/40 ,  B01J21/18 ,  B01J23/44 ,  B01J31/0231 ,  B01J31/04 ,  B01J31/28 ,  B01J37/16 ,  C07C51/252 ,  C07C57/04

摘要： The object of the present invention is to provide a method for producing an α,β-unsaturated carboxylic acid in higher selectivity. The present invention resides in a method for producing an α,β-unsaturated carboxylic acid from an olefin or an α,β-unsaturated aldehyde in liquid phase by using a noble metal-containing catalyst and by causing a compound (A) having an acid dissociation exponent (pKa) of less than 4 to be present in the liquid phase.

摘要翻译： 本发明的目的是提供一种以更高选择性生产α，β-不饱和羧酸的方法。 本发明涉及一种通过使用含贵金属的催化剂，通过使具有酸的化合物（A）从液相中的烯烃或α，β-不饱和醛生成α，β-不饱和羧酸的方法， 解离指数（pKa）小于4存在于液相中。

公开(公告)号：US20080064899A1

公开(公告)日：2008-03-13

申请号：US11628215

申请日：2005-05-30

申请人： Seiichi Kawato ,  Akio Takeda ,  Yoshiyuki Himeno

发明人： Seiichi Kawato ,  Akio Takeda ,  Yoshiyuki Himeno

IPC分类号： C07C51/25

CPC分类号： C07C45/35 ,  C07C51/235 ,  C07C51/252 ,  C07C51/50 ,  C07C47/22 ,  C07C57/04

摘要： The present invention provides a method for producing an α,β-unsaturated carboxylic acid in high yield. In particular, the present invention resides in a method for producing an α,β-unsaturated carboxylic acid by oxidation of an olefin or an α,β-unsaturated aldehyde with molecular oxygen in liquid phase in the presence of a catalyst containing at least palladium, wherein at least one compound selected from the group consisting of p-methoxyphenol, 4,4′-dihydroxytetraphenylmethane, 1,1,1-tris(p-hydroxyphenyl)ethane, compounds having an N-oxyl group in the molecule and compounds having an N-nitrosyl group in the molecule is caused to be coexistent.

摘要翻译： 本发明提供以高产率生产α，β-不饱和羧酸的方法。 特别地，本发明在于一种通过在含有至少钯的催化剂存在下在液相中用分子氧氧化烯键或α，β-不饱和醛来生产α，β-不饱和羧酸的方法， 其中选自对甲氧基苯酚，4,4'-二羟基四苯基甲烷，1,1,1-三（对羟基苯基）乙烷中的至少一种化合物，分子中具有N-氧基的化合物和具有 分子中的N-亚硝酰基被共同存在。

公开(公告)号：US08088945B2

公开(公告)日：2012-01-03

申请号：US12965509

申请日：2010-12-10

申请人： Toshiya Yasukawa ,  Toshiki Matsui ,  Ken Ooyachi ,  Yoshiyuki Himeno ,  Wataru Ninomiya

发明人： Toshiya Yasukawa ,  Toshiki Matsui ,  Ken Ooyachi ,  Yoshiyuki Himeno ,  Wataru Ninomiya

IPC分类号： C07C51/14 ,  C07C51/16 ,  C07C51/235 ,  C07C249/00 ,  C07C251/00 ,  C07C259/00 ,  C07C291/00 ,  B01J23/00 ,  B01J23/42 ,  B01J23/44

CPC分类号： B01J37/0201 ,  B01J21/08 ,  B01J23/6445 ,  B01J23/6447 ,  B01J27/0576 ,  B01J35/002 ,  B01J37/16 ,  C07C45/34 ,  C07C45/35 ,  C07C51/252 ,  C07C47/21 ,  C07C47/232 ,  C07C47/22 ,  C07C57/04

摘要： Disclosed is a palladium-containing catalyst which enables to produce an α,β-unsaturated carboxylic acid in high selectivity from an olefin or an α,β-unsaturated aldehyde. Also disclosed are a method for producing such a catalyst and a method for producing an α,β-unsaturated carboxylic acid using such a catalyst. Specifically disclosed is a palladium-containing catalyst containing 0.001 to 0.25 mole of antimony element to 1 mole of palladium element or a palladium-containing catalyst containing palladium element which composes a metal, tellurium element, and bismuth element.

摘要翻译： 公开了一种能够从烯烃或α，β-不饱和醛以高选择性制备α，β-不饱和羧酸的含钯催化剂。 还公开了这种催化剂的制造方法和使用这种催化剂制造α，β-不饱和羧酸的方法。 具体公开的是含有0.001〜0.25摩尔锑元素与1摩尔钯元素或含有钯金属元素的含钯催化剂的含钯催化剂，所述钯元素构成金属，碲元素和铋元素。

公开(公告)号：US20070238903A1

公开(公告)日：2007-10-11

申请号：US11628214

申请日：2005-06-02

申请人： Wataru Ninomiya ,  Yoshiyuki Himeno ,  Yuji Fujimori

发明人： Wataru Ninomiya ,  Yoshiyuki Himeno ,  Yuji Fujimori

IPC分类号： B01J23/44 ,  C07C409/00

CPC分类号： B01J37/0203 ,  B01J21/08 ,  B01J21/18 ,  B01J23/44 ,  B01J27/0576 ,  B01J37/0205 ,  B01J37/16 ,  C07C45/34 ,  C07C45/35 ,  C07C45/36 ,  C07C51/252 ,  C07C47/21 ,  C07C47/22 ,  C07C47/232 ,  C07C57/04

摘要： The present invention provides: a palladium-containing catalyst which is used for highly selectively or highly productively producing an α,β-unsaturated aldehyde and an α,β-unsaturated carboxylic acid from an olefin or in that way producing an α,β-unsaturated carboxylic acid from an α,β-unsaturated aldehyde; a method for producing the catalyst; and a method for highly selectively or highly productively producing an α,β-unsaturated aldehyde and an α,β-unsaturated carboxylic acid from an olefin or in that way producing an α,β-unsaturated carboxylic acid from an α,β-unsaturated aldehyde. In particular, the present invention resides in a palladium-containing catalyst comprising 0.001 to 0.40 mole of tellurium metal to 1.0 mole of palladium metal. This catalyst can be preferably produced by a method having a step of reducing a compound containing palladium atom in its oxidized state and tellurium atom in its oxidized state by a reducing agent.

摘要翻译： 本发明提供：一种含钯催化剂，其用于从烯烃高度选择性或高产率地生产α，β-不饱和醛和α，β-不饱和羧酸，或以这种方式产生α，β-不饱和的 羧酸从α，β-不饱和醛; 催化剂的制造方法; 以及用于从烯烃高度选择性地或高效地生产α，β-不饱和醛和α，β-不饱和羧酸的方法，或以这种方式从α，β-不饱和醛生产α，β-不饱和羧酸的方法 。 特别地，本发明涉及一种含钯催化剂，其包含0.001至0.40摩尔的碲金属至1.0摩尔的钯金属。 该催化剂可以优选通过还原剂还原含有氧化态的钯原子的化合物和其氧化态的碲原子的方法来制造。

公开(公告)号：US20090023952A1

公开(公告)日：2009-01-22

申请号：US11816584

申请日：2006-02-17

申请人： Toshiya Yasukawa ,  Toshiki Matsui ,  Ken Ooyachi ,  Yoshiyuki Himeno ,  Wataru Ninomiya

发明人： Toshiya Yasukawa ,  Toshiki Matsui ,  Ken Ooyachi ,  Yoshiyuki Himeno ,  Wataru Ninomiya

IPC分类号： C07C51/16 ,  B01J23/44 ,  B01J27/057 ,  B01J23/64

CPC分类号： B01J37/0201 ,  B01J21/08 ,  B01J23/6445 ,  B01J23/6447 ,  B01J27/0576 ,  B01J35/002 ,  B01J37/16 ,  C07C45/34 ,  C07C45/35 ,  C07C51/252 ,  C07C47/21 ,  C07C47/232 ,  C07C47/22 ,  C07C57/04

摘要： Disclosed is a palladium-containing catalyst which enables to produce an α,β-unsaturated carboxylic acid in high selectivity from an olefin or an α,β-unsaturated aldehyde. Also disclosed are a method for producing such a catalyst and a method for producing an α,β-unsaturated carboxylic acid using such a catalyst. Specifically disclosed is a palladium-containing catalyst containing 0.001 to 0.25 mole of antimony element to 1 mole of palladium element or a palladium-containing catalyst containing palladium element which composes a metal, tellurium element, and bismuth element.

摘要翻译： 公开了一种能够从烯烃或α，β-不饱和醛以高选择性产生α，β-不饱和羧酸的含钯催化剂。 还公开了制备这种催化剂的方法和使用这种催化剂生产α，β-不饱和羧酸的方法。 具体公开的是含有0.001〜0.25摩尔锑元素与1摩尔钯元素或含有钯金属元素的含钯催化剂的含钯催化剂，其构成金属，碲元素和铋元素。

公开(公告)号：US20080306298A1

公开(公告)日：2008-12-11

申请号：US11719461

申请日：2005-11-14

申请人： Yoshiyuki Himeno ,  Wataru Ninomiya ,  Ken Ooyachi

发明人： Yoshiyuki Himeno ,  Wataru Ninomiya ,  Ken Ooyachi

IPC分类号： C07C51/25 ,  B01J23/44

CPC分类号： B01J37/086 ,  B01J21/08 ,  B01J23/44 ,  B01J37/16 ,  C07C51/252 ,  C07C57/04

摘要： The present invention provides: a palladium-containing supported catalyst which is used for producing an α,β-unsaturated carboxylic acid from an olefin or an α,β-unsaturated aldehyde in high selectivity; a method for manufacturing the catalyst; and a method for producing an α,β-unsaturated carboxylic acid in high selectivity. In particular, the present invention resides in a method for manufacturing a palladium-containing supported catalyst for producing an α,β-unsaturated carboxylic acid from an olefin or an α,β-unsaturated aldehyde, comprising the step of reducing palladium oxide contained in a catalyst precursor wherein at least the palladium oxide is supported on a carrier. By using such a palladium-containing supported catalyst, an α,β-unsaturated carboxylic acid is produced through liquid-phase oxidation of an olefin or an α,β-unsaturated aldehyde with molecular oxygen.

摘要翻译： 本发明提供：一种用于以高选择性从烯烃或α，β-不饱和醛生产α，β-不饱和羧酸的含钯载体催化剂; 催化剂的制造方法; 以及以高选择性制备α，β-不饱和羧酸的方法。 特别地，本发明涉及一种制备用于由烯烃或α，β-不饱和醛生产α，β-不饱和羧酸的含钯负载型催化剂的方法，其包括将还原氧化钯 催化剂前体，其中至少将氧化钯负载在载体上。 通过使用这种含钯载体催化剂，通过烯烃或α，β-不饱和醛与分子氧的液相氧化产生α，β-不饱和羧酸。

公开(公告)号：US08389760B2

公开(公告)日：2013-03-05

申请号：US13291732

申请日：2011-11-08

申请人： Toshiya Yasukawa ,  Toshiki Matsui ,  Ken Ooyachi ,  Yoshiyuki Himeno ,  Wataru Ninomiya

发明人： Toshiya Yasukawa ,  Toshiki Matsui ,  Ken Ooyachi ,  Yoshiyuki Himeno ,  Wataru Ninomiya

IPC分类号： C07C51/16 ,  C07C51/235 ,  C07C51/14 ,  C07C249/00 ,  C07C251/00 ,  C07C259/00 ,  C07C291/00 ,  B01J23/00 ,  B01J23/42 ,  B01J23/44

CPC分类号： B01J37/0201 ,  B01J21/08 ,  B01J23/6445 ,  B01J23/6447 ,  B01J27/0576 ,  B01J35/002 ,  B01J37/16 ,  C07C45/34 ,  C07C45/35 ,  C07C51/252 ,  C07C47/21 ,  C07C47/232 ,  C07C47/22 ,  C07C57/04

摘要： Disclosed is a palladium-containing catalyst which enables to produce an α,β-unsaturated carboxylic acid in high selectivity from an olefin or an α,β-unsaturated aldehyde. Also disclosed are a method for producing such a catalyst and a method for producing an α,β-unsaturated carboxylic acid using such a catalyst. Specifically disclosed is a palladium-containing catalyst containing 0.001 to 0.25 mole of antimony element to 1 mole of palladium element or a palladium-containing catalyst containing palladium element which composes a metal, tellurium element, and bismuth element.

摘要翻译： 公开了一种能够从烯烃或α，β-不饱和醛以高选择性制备α，β-不饱和羧酸的含钯催化剂。 还公开了这种催化剂的制造方法和使用这种催化剂制造α，β-不饱和羧酸的方法。 具体公开的是含有0.001〜0.25摩尔锑元素与1摩尔钯元素或含有钯金属元素的含钯催化剂的含钯催化剂，其构成金属，碲元素和铋元素。

公开(公告)号：US07446223B2

公开(公告)日：2008-11-04

申请号：US11628214

申请日：2005-06-02

申请人： Wataru Ninomiya ,  Yoshiyuki Himeno ,  Yuji Fujimori

发明人： Wataru Ninomiya ,  Yoshiyuki Himeno ,  Yuji Fujimori

IPC分类号： C07C51/14 ,  C07C51/16 ,  C07C45/34

CPC分类号： B01J37/0203 ,  B01J21/08 ,  B01J21/18 ,  B01J23/44 ,  B01J27/0576 ,  B01J37/0205 ,  B01J37/16 ,  C07C45/34 ,  C07C45/35 ,  C07C45/36 ,  C07C51/252 ,  C07C47/21 ,  C07C47/22 ,  C07C47/232 ,  C07C57/04

摘要： The present invention provides: a palladium-containing catalyst which is used for highly selectively or highly productively producing an α,β-unsaturated aldehyde and an α,β-unsaturated carboxylic acid from an olefin or in that way producing an α,β-unsaturated carboxylic acid from an α,β-unsaturated aldehyde; a method for producing the catalyst; and a method for highly selectively or highly productively producing an α,β-unsaturated aldehyde and an α,β-unsaturated carboxylic acid from an olefin or in that way producing an α,β-unsaturated carboxylic acid from an α,β-unsaturated aldehyde. In particular, the present invention resides in a palladium-containing catalyst comprising 0.001 to 0.40 mole of tellurium metal to 1.0 mole of palladium metal. This catalyst can be preferably produced by a method having a step of reducing a compound containing palladium atom in its oxidized state and tellurium atom in its oxidized state by a reducing agent.

摘要翻译： 本发明提供：一种含钯催化剂，其用于从烯烃高度选择性或高产率地生产α，β-不饱和醛和α，β-不饱和羧酸，或以这种方式产生α，β-不饱和的 羧酸从α，β-不饱和醛; 催化剂的制造方法; 以及用于从烯烃高度选择性地或高效地生产α，β-不饱和醛和α，β-不饱和羧酸的方法，或以这种方式从α，β-不饱和醛生产α，β-不饱和羧酸的方法 。 特别地，本发明涉及一种含钯催化剂，其包含0.001至0.40摩尔的碲金属至1.0摩尔的钯金属。 该催化剂可以优选通过还原剂还原含有氧化态的钯原子的化合物和其氧化态的碲原子的方法来制造。

公开(公告)号：US20120053363A1

公开(公告)日：2012-03-01

申请号：US13291732

申请日：2011-11-08

申请人： Toshiya YASUKAWA ,  Toshiki Matsui ,  Ken Ooyachi ,  Yoshiyuki Himeno ,  Wataru Ninomiya

发明人： Toshiya YASUKAWA ,  Toshiki Matsui ,  Ken Ooyachi ,  Yoshiyuki Himeno ,  Wataru Ninomiya

IPC分类号： C07C57/03

CPC分类号： B01J37/0201 ,  B01J21/08 ,  B01J23/6445 ,  B01J23/6447 ,  B01J27/0576 ,  B01J35/002 ,  B01J37/16 ,  C07C45/34 ,  C07C45/35 ,  C07C51/252 ,  C07C47/21 ,  C07C47/232 ,  C07C47/22 ,  C07C57/04

摘要： Disclosed is a palladium-containing catalyst which enables to produce an α,β-unsaturated carboxylic acid in high selectivity from an olefin or an α,β-unsaturated aldehyde. Also disclosed are a method for producing such a catalyst and a method for producing an α,β-unsaturated carboxylic acid using such a catalyst. Specifically disclosed is a palladium-containing catalyst containing 0.001 to 0.25 mole of antimony element to 1 mole of palladium element or a palladium-containing catalyst containing palladium element which composes a metal, tellurium element, and bismuth element.

摘要翻译： 公开了一种能够从烯烃或α，β-不饱和醛以高选择性制备α，β-不饱和羧酸的含钯催化剂。 还公开了这种催化剂的制造方法和使用这种催化剂制造α，β-不饱和羧酸的方法。 具体公开的是含有0.001〜0.25摩尔锑元素与1摩尔钯元素或含有钯金属元素的含钯催化剂的含钯催化剂，所述钯元素构成金属，碲元素和铋元素。