ADDITIVE FOR NON-AQUEOUS ELECTROLYTE AND SECONDARY BATTERY USING THE SAME
    1.
    发明申请
    ADDITIVE FOR NON-AQUEOUS ELECTROLYTE AND SECONDARY BATTERY USING THE SAME 有权
    添加非水电解质和使用相同的二次电池

    公开(公告)号:US20100099905A1

    公开(公告)日:2010-04-22

    申请号:US12649100

    申请日:2009-12-29

    IPC分类号: C07C255/45

    摘要: Disclosed is a compound represented by the following formula 1: wherein, each of R1˜R13 independently represents —H, —F, —Cl, —Br, —I, —OH, —SH, —COOH, —PO3H2, —NH2, —NO2, —O(CH2CH2O)nH (wherein, n is an integer of 1˜5), C1˜C12 alkyl group, C1˜C12 aminoalkyl group, C1˜C12 hydroxyalkyl group, C1˜C12 haloalkyl group, C2˜C12 alkenyl group, C1˜C12 alkoxy group, C1˜C12 alkylamino group, C1˜C12 dialkylamino group, C6˜C18 aryl group, C6˜C18 aminoaryl group, C6˜C18 hydroxyaryl group, C6˜C18 haloaryl group, C7˜C18 benzyl group, C7˜C18 aminobenzyl group, C7˜C18 hydroxybenzyl group, C7˜C18 halobenzyl group, or nitrile group (—CN); and at least one of R4˜R13 is nitrile group (—CN). A non-aqueous electrolyte comprising: (i) a lithium salt, (ii) a solvent, and (iii) a compound represented by formula 1; and a secondary battery comprising the non-aqueous electrolyte are also disclosed. When the compound represented by formula 1 is added to a non-aqueous electrolyte, it is possible to improve the safety of a secondary battery in an overcharged state.

    摘要翻译: 公开了由下式1表示的化合物:其中,R 1〜R 13各自独立地表示-H,-F,-Cl,-Br,-I,-OH,-SH,-COOH,-PO 3 H 2,-NH 2, -NO 2,-O(CH 2 CH 2 O)n H(其中n为1〜5的整数),C 1〜C 12烷基,C 1〜C 12氨基烷基,C 1〜C 12羟烷基,C 1〜C 12卤代烷基,C 2〜C 12烯基 基团,C 1〜C 12烷氧基,C 1〜C 12烷基氨基,C 1〜C 12二烷基氨基,C 6〜C 18芳基,C 6〜C 18氨基芳基,C 6〜C 18羟基芳基,C 6〜C 18卤代芳基,C 7〜C 18苄基, C 7〜C 18氨基苄基,C 7〜C 18羟基苄基,C 7〜C 18卤代苄基或腈基(-CN); 并且R 4〜R 13中的至少一个为腈基(-CN)。 一种非水电解质,其包含:(i)锂盐,(ii)溶剂,和(iii)由式1表示的化合物; 还公开了包含非水电解质的二次电池。 当将由式1表示的化合物加入到非水电解质中时,可以提高过充电状态的二次电池的安全性。

    ANODE ACTIVE MATERIAL WITH IMPROVED ELECTROCHEMICAL PROPERTIES AND ELECTROCHEMICAL DEVICE COMPRISING THE SAME
    3.
    发明申请
    ANODE ACTIVE MATERIAL WITH IMPROVED ELECTROCHEMICAL PROPERTIES AND ELECTROCHEMICAL DEVICE COMPRISING THE SAME 有权
    具有改进的电化学性质的阳极活性材料和包含其的电化学装置

    公开(公告)号:US20090289219A1

    公开(公告)日:2009-11-26

    申请号:US12535207

    申请日:2009-08-04

    IPC分类号: H01M4/04 B05D5/12

    摘要: Disclosed is an anode active material, comprising: (a) a carbonaceous material; and (b) a carbide coating layer partially or totally formed on a surface of the carbonaceous material, the carbide coating layer comprising at least one element selected from the group consisting of metals and metalloids. An anode obtained by using the anode active material and an electrochemical device comprising the anode are also disclosed. The carbonaceous material comprises a coating layer of metal-/metalloid-carbide obtained by treating it at high temperature under inert atmosphere, wherein the coating layer has increased interfacial boding force to the carbonaceous material and thus shows minimized reactivity to lithium. The carbonaceous material as anode active material can minimize the irreversible anode capacity needed for the formation of an SEI film during the first charge/discharge cycle, thereby providing high capacity, high efficiency and significantly improved anode qualities.

    摘要翻译: 公开了一种阳极活性材料,其包含:(a)碳质材料; 和(b)部分或全部形成在所述碳质材料的表面上的碳化物涂层,所述碳化物涂层包含选自金属和准金属的至少一种元素。 还公开了通过使用阳极活性材料获得的阳极和包括阳极的电化学装置。 含碳材料包括通过在惰性气氛下在高温下处理而获得的金属/ /类金刚石碳化物的涂层,其中涂层对碳质材料具有增加的界面粘合力,因此显示出对锂的反应性最小化。 作为阳极活性材料的碳质材料可以使在第一充电/放电循环期间形成SEI膜所需的不可逆阳极容量最小化,从而提供高容量,高效率和显着改善的阳极质量。