公开(公告)号：US08685573B2

公开(公告)日：2014-04-01

申请号：US13368359

申请日：2012-02-08

申请人： Yuki Okuda ,  Norio Iwayasu ,  Hidetoshi Honbou

发明人： Yuki Okuda ,  Norio Iwayasu ,  Hidetoshi Honbou

IPC分类号： H01M10/0562 ,  H01M6/18 ,  H01M4/131

CPC分类号： H01M6/181 ,  H01M2/0217 ,  H01M4/131 ,  H01M4/525 ,  H01M4/62 ,  H01M10/052 ,  H01M10/4235 ,  H01M2004/028 ,  Y02E60/122

摘要： Provided is a lithium ion rechargeable battery less suffering from swelling even when stored at high temperatures. Disclosed are a cathode active material, a cathode for a lithium ion rechargeable battery using the cathode active material, and a lithium ion rechargeable battery using the cathode. The cathode active material includes particles, each of the particles including a cathode material capable of intercalating and deintercalating lithium ions, and a film formed on at least part of surfaces of the particles. The film includes a compound represented by Chemical Formula (1). Examples of the compound represented by Chemical Formula (1) include lithium squarate and dilithium squarate. Preferably, the lithium ion rechargeable battery is a prismatic battery.

摘要翻译： 锂离子充电电池即使在高温下储存时也较少膨胀。 公开了阴极活性物质，使用阴极活性物质的锂离子二次电池用阴极和使用该阴极的锂离子二次电池。 阴极活性材料包括颗粒，每个颗粒包括能够嵌入和脱嵌锂离子的阴极材料，以及在颗粒的至少一部分表面上形成的膜。 该膜包括由化学式（1）表示的化合物。 由化学式（1）表示的化合物的实例包括方酸锂和方酸二锂。 优选地，锂离子可再充电电池是棱柱形电池。

公开(公告)号：US20120091403A1

公开(公告)日：2012-04-19

申请号：US13217497

申请日：2011-08-25

申请人： Yuki OKUDA ,  Norio Iwayasu ,  Jinbao Zhao ,  Hidetoshi Honbou

发明人： Yuki OKUDA ,  Norio Iwayasu ,  Jinbao Zhao ,  Hidetoshi Honbou

IPC分类号： H01B1/08 ,  C08B37/00 ,  C08F120/44

CPC分类号： H01B1/22 ,  C09D101/288 ,  C09D105/00 ,  C09D133/22 ,  H01M4/0404 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/505 ,  H01M4/62

摘要： The preparation of a slurry so as to exhibit no strong alkalinity not only needs a strict pH control, but also needs once dispersing a positive electrode material in water and the operation of drying after the treatment, and other operations, thereby leading to the complication of the operations and a decrease in the yield. In consideration of the above-mentioned problems, the present invention provides a method for producing a positive electrode plate for a lithium ion rechargeable battery, which exhibits less complication of the operations and less decrease in the yield and can prevent the gelation of a positive electrode material slurry. The above-mentioned problems can be solved by a positive electrode for a lithium ion rechargeable battery containing a positive electrode active material capable of absorbing/desorbing lithium ions, a nitrile group-containing polymer, and a binder.

摘要翻译： 浆料的制备不显示碱性，不仅需要严格的pH值控制，而且还需要将正极材料分散在水中，并在处理后进行干燥操作等操作，从而导致复合 操作和产量下降。 考虑到上述问题，本发明提供一种锂离子可再充电电池用正极板的制造方法，其操作的并发性较差，产率降低较少，能够防止正极的凝胶化 材料浆料。 上述问题可以通过包含能够吸收/解吸锂离子的正极活性物质的锂离子可再充电电池用正极，含腈基聚合物和粘合剂来解决。

公开(公告)号：US20140170448A1

公开(公告)日：2014-06-19

申请号：US14125822

申请日：2011-06-13

申请人： Norio Iwayasu ,  Hidetoshi Honbou

发明人： Norio Iwayasu ,  Hidetoshi Honbou

IPC分类号： H01M10/42

CPC分类号： H01M10/4235 ,  H01M2/345 ,  H01M4/13 ,  H01M4/62 ,  H01M10/0525 ,  H01M10/0567 ,  H01M2200/20 ,  Y02T10/7011

摘要： A lithium-ion secondary battery having a positive electrode capable of occluding and releasing lithium ions, a negative electrode capable of occluding and releasing lithium ions, a separator interposed between the positive electrode and the negative electrode, an electrolytic solution, and a current breaking mechanism that works in response to the rise of the battery's internal pressure, wherein the electrolytic solution is incorporated with an aromatic compound and the positive electrode is incorporated with a carbon dioxide gas generating agent which is represented by the formula AxCO3 or AyHCO3. It is highly responsive to overcharging owing to the current breaking mechanism attached thereto which activates in the early stage of overcharging. Therefore, it exhibits high battery performance as well as high safety in the case of overcharging.

摘要翻译： 具有能够吸留和释放锂离子的正极的锂离子二次电池，能够吸留和释放锂离子的负极，介于正极和负极之间的隔膜，电解液和电流断路机构 其响应于电池内部压力的升高而起作用，其中电解溶液与芳族化合物结合，并且正极与由式AxCO 3或AyHCO 3表示的二氧化碳气体发生剂结合。 由于其附带的电流断路机构在过充电的早期阶段激活，对过充电是高度响应的。 因此，在过充电的情况下，它具有高电池性能以及高安全性。

公开(公告)号：US20110189550A1

公开(公告)日：2011-08-04

申请号：US12858484

申请日：2010-08-18

申请人： Jinbao ZHAO ,  Norio Iwayasu ,  Yuki Okuda ,  Hidetoshi Honbo

发明人： Jinbao ZHAO ,  Norio Iwayasu ,  Yuki Okuda ,  Hidetoshi Honbo

IPC分类号： H01M10/052 ,  C08F220/30 ,  C08F218/08

CPC分类号： H01M10/0567

摘要： An overcharge inhibitor is provided which increases an internal resistance of a battery, being electropolymerized by reaction with a positive electrode at a high potential in overcharging.The overcharge inhibitor is produced by using a polymer containing a polymerizable monomer as a repeating unit. The polymerizable monomer has a functional group that is electropolymerized at a potential of 4.3 to 5.5 V based on a lithium metal reference.

摘要翻译： 提供了一种过充电抑制剂，其增加电池的内阻，通过与过电压的高电位的正极反应进行电聚合。 过充电抑制剂通过使用含有聚合性单体作为重复单元的聚合物来制造。 可聚合单体具有基于锂金属参考电位聚合在4.3至5.5V的电位的官能团。

公开(公告)号：US08735004B2

公开(公告)日：2014-05-27

申请号：US12858484

申请日：2010-08-18

申请人： Jinbao Zhao ,  Norio Iwayasu ,  Yuki Okuda ,  Hidetoshi Honbo

发明人： Jinbao Zhao ,  Norio Iwayasu ,  Yuki Okuda ,  Hidetoshi Honbo

IPC分类号： H01M10/056 ,  H01M10/0567 ,  H01M10/0568

CPC分类号： H01M10/0567

摘要： An overcharge inhibitor is provided which increases an internal resistance of a battery, being electropolymerized by reaction with a positive electrode at a high potential in overcharging.The overcharge inhibitor is produced by using a polymer containing a polymerizable monomer as a repeating unit. The polymerizable monomer has a functional group that is electropolymerized at a potential of 4.3 to 5.5 V based on a lithium metal reference.

摘要翻译： 提供了一种过充电抑制剂，其增加电池的内阻，通过与过电压的高电位的正极反应进行电聚合。 过充电抑制剂通过使用含有聚合性单体作为重复单元的聚合物来制造。 可聚合单体具有基于锂金属参考电位聚合在4.3至5.5V的电位的官能团。

公开(公告)号：US08765310B2

公开(公告)日：2014-07-01

申请号：US13094902

申请日：2011-04-27

申请人： Jinbao Zhao ,  Norio Iwayasu ,  Yuuki Okuda ,  Hidetoshi Honbo

发明人： Jinbao Zhao ,  Norio Iwayasu ,  Yuuki Okuda ,  Hidetoshi Honbo

IPC分类号： H01M6/04 ,  H01M6/16 ,  H01M10/056

CPC分类号： H01M10/052 ,  H01M10/0567 ,  H01M2300/0022 ,  Y02T10/7011

摘要： A nonaqueous electrolytic solution which may suppress the overcharge of a battery and a nonaqueous electrolyte secondary battery using the solution are provided. The overcharge of the battery is suppressed by undergoing the electrolytic polymerization in the solution when the battery is overcharged, and simultaneously more effectively suppressed by increasing the internal resistance of the battery. The nonaqueous electrolytic solution comprises a polymer which undergoes the electrolytic polymerization in the range of 4.3V or more to 5.5V or less at the lithium metal standard voltage, having a repeating unit represented by the formula (1), an electrolytic salt and a nonaqueous solvent. [where, A is a functional group which undergoes the electrolytic polymerization in the range of 4.3V or more to 5.5V or less at the lithium metal standard voltage, R and R′ are each independently an hydrogen atom or a methyl group]

摘要翻译： 提供了可以抑制电池的过充电的非水电解液和使用该溶液的非水电解质二次电池。 当电池过充电时，通过在溶液中进行电解聚合来抑制电池的过充电，并且通过增加电池的内阻同时更有效地抑制电池的过充电。 非水电解液包含在锂金属标准电压下进行4.3V以上且5.5V以下的电解聚合的聚合物，具有式（1）表示的重复单元，电解质盐和非水性 溶剂。 [其中，A是以锂金属标准电压在4.3V以上至5.5V以下的范围内进行电解聚合的官能团，R和R'各自独立地为氢原子或甲基]

公开(公告)号：US08518580B2

公开(公告)日：2013-08-27

申请号：US12712624

申请日：2010-02-25

申请人： Norio Iwayasu

发明人： Norio Iwayasu

IPC分类号： H01M6/16 ,  H01M6/24

CPC分类号： H01M10/0567

摘要： There is provided a lithium ion secondary battery which suppresses overcharge while keeping battery characteristics. The lithium ion secondary, batter, has positive and negative electrodes facing each other via a separator and being filled with an electrolytic solution with a supporting electrolyte dissolved in a non-aqueous solvent, wherein the electrolytic solution contains overcharge inhibitor.

摘要翻译： 提供一种锂离子二次电池，其在保持电池特性的同时抑制过充电。 锂离子二次电池具有通过隔板相对的正极和负极，并且填充有溶解在非水溶剂中的支持电解质的电解液，其中电解液含有过充电抑制剂。

公开(公告)号：US20120142880A1

公开(公告)日：2012-06-07

申请号：US13313041

申请日：2011-12-07

申请人： Norio Iwayasu ,  Jinbao Zhao ,  Hidetoshi Honbo

发明人： Norio Iwayasu ,  Jinbao Zhao ,  Hidetoshi Honbo

IPC分类号： H01M10/42 ,  C08F12/18 ,  C08F14/06 ,  C08F20/24 ,  H01M10/056 ,  C08F12/16

CPC分类号： H01M10/052 ,  H01M10/0565 ,  H01M10/0567

摘要： In a lithium secondary battery, an overcharge inhibitor is used which includes polymerizable compounds or a polymer, or both as an active component, the polymerizable compounds including a first polymerizable compound having an aromatic functional group and a polymerizable functional group, and a second polymerizable compound having a halogen-containing functional group and a polymerizable functional group, and the polymer including a polymer having the halogen-containing functional group, the aromatic functional group, and residues of the polymerizable functional groups. The present invention allows the lithium secondary battery to form a radical-trapping polymer layer on the cathode upon overcharge.

摘要翻译： 在锂二次电池中，使用包含可聚合化合物或聚合物或两者作为活性组分的包含具有芳族官能团和可聚合官能团的第一可聚合化合物的可聚合化合物的过充电抑制剂和第二可聚合化合物 具有含卤官能团和可聚合官能团的聚合物，并且该聚合物包括具有含卤官能团的聚合物，芳族官能团和可聚合官能团的残基。 本发明允许锂二次电池在过充电时在阴极上形成自由基捕获聚合物层。

公开(公告)号：US20120121947A1

公开(公告)日：2012-05-17

申请号：US13296268

申请日：2011-11-15

申请人： Norio Iwayasu ,  Jinbao Zhao ,  Hidetoshi Honbo ,  Shinji Yamada

发明人： Norio Iwayasu ,  Jinbao Zhao ,  Hidetoshi Honbo ,  Shinji Yamada

IPC分类号： H01M10/44 ,  C08F212/32 ,  C08F220/28 ,  H01M10/0564

CPC分类号： C08F212/32 ,  C08F212/08 ,  H01M10/052 ,  H01M10/0565 ,  H01M10/0569 ,  H01M2300/0085 ,  C08F220/14 ,  C08F2220/285

摘要： To provide a functional material which forms a high-resistance layer to interrupt an electric current, thereby ensuring the safety of a battery during overcharge.A polymerizable compound including a polymerizable functional group having an aromatic functional group, a polymerizable compound including a polymerizable functional group having a highly polar functional group, and a polymerizable compound including a polymerizable functional group having a less polar functional group, or a polymer obtained by polymerizing these polymerizable compounds are added into an electrolytic solution of a lithium secondary battery.

摘要翻译： 提供形成高电阻层以中断电流的功能材料，从而确保过充电期间电池的安全性。 包含具有芳香族官能团的聚合性官能团的聚合性化合物，具有高极性官能团的聚合性官能团的聚合性化合物和具有极性低官能团的聚合性官能团的聚合性化合物， 聚合这些可聚合化合物被加入到锂二次电池的电解液中。

公开(公告)号：US07230057B2

公开(公告)日：2007-06-12

申请号：US10717645

申请日：2003-11-21

申请人： Takefumi Okumura ,  Shin Nishimura ,  Norio Iwayasu ,  Shoichi Yokoyama ,  Takeshi Yabe

发明人： Takefumi Okumura ,  Shin Nishimura ,  Norio Iwayasu ,  Shoichi Yokoyama ,  Takeshi Yabe

IPC分类号： C08F130/06 ,  C07F5/04

CPC分类号： H01M10/0565 ,  C07F5/04 ,  C08F30/06 ,  C08G65/328 ,  C08G79/08 ,  H01B1/122 ,  H01M6/181 ,  H01M10/0525

摘要： An object of the present invention is to provide a boron-containing compound capable of forming an ion-conductive polyelectrolyte having high ion-conductive properties, and a polymer of said compound. According to the present invention, there are provided a polymerizable boron-containing compound of (formula 1), a polymer thereof, a polymer of a compound of (formula 2) and a compound of (formula 3), and a polyelectrolyte for electrochemical device comprising either of these polymers and at least one electrolyte salt:

摘要翻译： 本发明的目的是提供一种能够形成具有高离子传导性的离子传导性聚电解质的含硼化合物和所述化合物的聚合物。 根据本发明，提供了（式1）的聚合性含硼化合物，其聚合物，（式2）化合物和（式3）化合物的聚合物和电化学装置用聚电解质 包括这些聚合物中的任一种和至少一种电解质盐：