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公开(公告)号：US07018738B2
公开(公告)日：2006-03-28
申请号：US10262438
申请日：2002-10-01
申请人： Yukiko Morioka , Masaharu Satoh , Shigeyuki Iwasa , Jiro Iriyama , Kentaro Nakahara , Masahiro Suguro
发明人： Yukiko Morioka , Masaharu Satoh , Shigeyuki Iwasa , Jiro Iriyama , Kentaro Nakahara , Masahiro Suguro
IPC分类号： H01M4/60 , C08G73/06 , C01D241/52
CPC分类号： H01M4/137 , H01M2/0207 , H01M4/60 , H01M4/608 , H01M10/052 , H01M10/0525
摘要： An electrode including a compound acting as an electrode active material and represented by a general formula (1) having a diazine N,N′-dioxide structure. A novel battery with the higher specific density and the excellent charge and discharge stability can be provided by incorporating the electrode having the compound represented by the general formula (1). [General Formula 1]
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2.发明授权Electrode active material and electrode using the electrode active material and battery using the electrode 失效电极活性材料和电极使用电极活性物质和电池使用电极公开(公告)号：US07476465B2
公开(公告)日：2009-01-13
申请号：US10504916
申请日：2003-02-18
申请人： Yukiko Morioka , Masahiro Suguro , Kentaro Nakahara , Jiro Iriyama , Shigeyuki Iwasa , Masaharu Satoh
发明人： Yukiko Morioka , Masahiro Suguro , Kentaro Nakahara , Jiro Iriyama , Shigeyuki Iwasa , Masaharu Satoh
IPC分类号： H01M4/60 , C07D241/36 , C08G73/06
CPC分类号： H01M4/60 , C07D241/44 , H01M4/606 , H01M10/052
摘要： An object of the present invention is to provide a battery which is high in capacity density and superior in stability. An electrode containing a compound having a diazine-N,N′-dioxide structure shown by a general formula (1) described below as an electrode active material is used, where x, y, x′, and y′ independently shows integer numbers of 0 or more respectively, and the order of condensation of diazine rings and benzene rings may be alternate or random. One of substituents R1, R2, R3, R4, Ra, Rb, Rc, and Rd shows a part of main chain or side chain of oligomer or polymer, and the other independently shows hydrogen atom, halogen atom, or a specific group.
摘要翻译： 本发明的目的是提供一种容量密度高，稳定性优异的电池。 使用含有下述通式（1）所示的二嗪-N，N'-二氧化物结构的化合物作为电极活性物质的电极，其中x，y，x'和y'独立地表示 0以上，并且二嗪环和苯环的缩合顺序可以是交替的或随机的。 取代基R 1，R 2，R 3，R 4，R a，R b，R c和R d中的一个表示低聚物或聚合物的主链或侧链的一部分，另外独立地表示氢原子，卤素原子或特定基团。
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公开(公告)号：US08728662B2
公开(公告)日：2014-05-20
申请号：US12303592
申请日：2007-06-04
申请人： Masahiro Suguro , Shigeyuki Iwasa , Yuki Kusachi , Jiro Iriyama , Yukiko Morioka , Kentaro Nakahara , Sadahiko Miura
发明人： Masahiro Suguro , Shigeyuki Iwasa , Yuki Kusachi , Jiro Iriyama , Yukiko Morioka , Kentaro Nakahara , Sadahiko Miura
CPC分类号： H01M4/60 , C08F216/125 , C08F216/1458 , H01M4/602
摘要： Disclosed is a polyradical compound which can be used as an electrode active material for at least one of a positive electrode and a negative electrode. The polyradical compound has a repeating unit represented by general formula (1) and is crosslinked using a bifunctional crosslinking agent having two polymerizing groups in the molecule represented by general formula (2), wherein R1 to R3 each independently represent hydrogen or methyl group; R4 to R7 each independently represent C1 to C3 alkyl group; X represents single bond, linear, branched or cyclic C1 to C15 alkylenedioxy group, alkylene group, phenylenedioxy group, phenylene group or structure represented by general formula (3); and R8 to R13 each independently represent hydrogen or methyl group, and k represents an integer of 2 to 5.
摘要翻译： 公开了可用作正电极和负电极中的至少一种的电极活性材料的多元化合物。 多元化合物具有由通式（1）表示的重复单元，并且使用在通式（2）表示的分子中具有两个聚合基团的双官能交联剂进行交联，其中R 1至R 3各自独立地表示氢或甲基; R4至R7各自独立地表示C1至C3烷基; X表示单键，直链，支链或环状的C1至C15亚烷基二氧基，亚烷基，亚苯基二氧基，亚苯基或由通式（3）表示的结构; R 8〜R 13各自独立地表示氢或甲基，k表示2〜5的整数。
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公开(公告)号：US20100255372A1
公开(公告)日：2010-10-07
申请号：US12303592
申请日：2007-06-04
申请人： Masahiro Suguro , Shigeyuki Iwasa , Yuki Kusachi , Jiro Iriyama , Yukiko Morioka , Kentaro Nakahara , Sadahiko Miura
发明人： Masahiro Suguro , Shigeyuki Iwasa , Yuki Kusachi , Jiro Iriyama , Yukiko Morioka , Kentaro Nakahara , Sadahiko Miura
IPC分类号： H01M4/60 , C08F226/06
CPC分类号： H01M4/60 , C08F216/125 , C08F216/1458 , H01M4/602
摘要： Disclosed is a polyradical compound which can be used as an electrode active material for at least one of a positive electrode and a negative electrode. The polyradical compound has a repeating unit represented by general formula (1) and is crosslinked using a bifunctional crosslinking agent having two polymerizing groups in the molecule represented by general formula (2), wherein R1 to R3 each independently represent hydrogen or methyl group; R4 to R7 each independently represent C1 to C3 alkyl group; X represents single bond, linear, branched or cyclic C1 to C15 alkylenedioxy group, alkylene group, phenylenedioxy group, phenylene group or structure represented by general formula (3); and R8 to R13 each independently represent hydrogen or methyl group, and k represents an integer of 2 to 5.
摘要翻译： 公开了可用作正电极和负电极中的至少一种的电极活性材料的多元化合物。 多元化合物具有由通式（1）表示的重复单元，并且使用在通式（2）表示的分子中具有两个聚合基团的双官能交联剂进行交联，其中R 1至R 3各自独立地表示氢或甲基; R4至R7各自独立地表示C1至C3烷基; X表示单键，直链，支链或环状的C1至C15亚烷基二氧基，亚烷基，亚苯基二氧基，亚苯基或由通式（3）表示的结构; R 8〜R 13各自独立地表示氢或甲基，k表示2〜5的整数。
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公开(公告)号：US20080297350A1
公开(公告)日：2008-12-04
申请号：US12093559
申请日：2006-12-04
申请人： Shigeyuki Iwasa , Yukiko Morioka , Masahiro Suguro , Yuki Kusachi , Jiro Iriyama , Kentaro Nakahara , Sadahiko Miura
发明人： Shigeyuki Iwasa , Yukiko Morioka , Masahiro Suguro , Yuki Kusachi , Jiro Iriyama , Kentaro Nakahara , Sadahiko Miura
IPC分类号： G08B13/22
CPC分类号： H01M4/60 , G06K19/0702 , G06K19/07749 , H01M2/08 , H01M2/1066 , H01M2/1094 , H01M4/604 , H01M6/40 , H01M10/052 , H01M10/425 , H01M10/486
摘要： To provide an RFID tag including therein a lightweight, thin, reusable by charging, and foldable power source. In an RFID tag including an IC module 2, an antenna 3, and a power source and with a thickness of 0.9 mm or less, there is included an organic radical battery with a thickness of 0.7 mm or less as the power source.
摘要翻译： 通过充电和可折叠的电源来提供其中包括重量轻，可重复使用的RFID标签。 在包括IC模块2，天线3和电源并且厚度为0.9mm或更小的RFID标签中，包括厚度为0.7mm或更小的有机自由基电池作为电源。
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公开(公告)号：US07226697B2
公开(公告)日：2007-06-05
申请号：US10473158
申请日：2002-04-03
IPC分类号： H01M4/60
CPC分类号： H01M4/137 , H01M4/60 , H01M4/608 , H01M10/052 , H01M2004/028
摘要： A charge storage device such as a battery, wherein a positive electrode comprises a nitroxyl compound having a structure of a nitroxyl cation moiety represented by formula (I) in an oxidized state while having a structure of a nitroxyl radical moiety represented by formula (II) in a reduced state and a reaction represented by reaction formula (A) in which an electron is transferred between these states is used as a positive electrode reaction. The charge storage device can have a higher energy density and can be used at a large current.
摘要翻译： 一种电池等电荷存储装置，其特征在于，正极具有由式（I）表示的硝酰氧基阳离子结构的氧化态的硝酰化合物，同时具有由式（II）表示的硝酰基部分的结构， 在其中电子在这些状态之间转移的反应式（A）表示的还原状态和反应使用作为正极反应。 电荷存储装置可以具有更高的能量密度并且可以在大电流下使用。
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公开(公告)号：US07544441B2
公开(公告)日：2009-06-09
申请号：US10492943
申请日：2002-10-18
IPC分类号： H01M4/60
CPC分类号： H01M4/60 , H01M4/137 , H01M4/602 , H01M4/606 , H01M10/052
摘要： A secondary battery is provided which has a high energy density, a high capacity, an excellent stability in charge-discharge cycle as well as an excellent safety. The secondary battery comprises at least a positive electrode, a negative electrode and an electrolyte, wherein an active material of at least one of the positive and negative electrodes includes at least one compound selected from the group consisting of radical compounds represented by the formula (1) or the formula (3): (in the formula (1), X1 and X2 each independently represent a group represented by the formula (3), alkoxyl group, halogen atom, hydroxyl group or cyano group, and R1˜R8 each independently represent hydrogen atom or alkyl group.) (in the formula (3), R10 represents alkyl group or substituted or unsubstituted phenyl group.)
摘要翻译： 提供二次电池，其具有高能量密度，高容量，在充放电循环中具有优异的稳定性以及优异的安全性。 二次电池至少包括正电极，负电极和电解质，其中正极和负极中的至少一个的活性材料包括至少一种选自由式（1）表示的自由基化合物的化合物 ）或式（3）:(式（1）中，X1和X2各自独立地表示由式（3）表示的基团，烷氧基，卤素原子，羟基或氰基，R1〜R8各自独立地表示 表示氢原子或烷基）（式（3）中，R 10表示烷基或取代或未取代的苯基）
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8.发明授权Power storage device having a nitroxyl polymer in a cathode and a lithium or lithium alloy anode 有权具有在阴极中的硝酰基聚合物和锂或锂合金阳极的蓄电装置公开(公告)号：US09443661B2
公开(公告)日：2016-09-13
申请号：US10597518
申请日：2004-12-17
CPC分类号： H01G9/155 , H01M4/137 , H01M4/386 , H01M4/387 , H01M4/405 , H01M4/60 , H01M4/602 , H01M10/052 , Y02E60/122 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： An object of the present invention is to provide a power storage device with excellent cycle property, employing a cathode containing a nitroxyl polymer. To attain the object in the present invention, in the power storage device employing a cathode comprising a nitroxyl polymer, a lithium or lithium alloy anode is used as an anode active material and the cathode is in direct contact with the anode.
摘要翻译： 本发明的目的是提供一种具有优异的循环性能的蓄电装置，其中使用含有硝酰基聚合物的阴极。 为了实现本发明的目的，在使用包含硝酰基聚合物的阴极的蓄电装置中，使用锂或锂合金阳极作为负极活性物质，阴极与阳极直接接触。
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公开(公告)号：US20080226986A1
公开(公告)日：2008-09-18
申请号：US10597517
申请日：2004-12-17
IPC分类号： H01M4/60
CPC分类号： H01G9/155 , H01M4/137 , H01M4/1399 , H01M4/60 , H01M4/602 , H01M4/624 , H01M4/661 , H01M4/663 , H01M4/667 , H01M10/052 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： An object of the present invention is to provide a power storage device with low internal resistance, employing a cathode containing a nitroxyl polymer. To attain the object in the present invention, in the power storage device employing a cathode comprising a nitroxyl polymer, a cathode collector having a conductive auxiliary layer comprising carbon as a main component formed and integrated on an aluminum electrode is used.
摘要翻译： 本发明的目的是提供一种具有低内阻的蓄电装置，其使用含有硝酰基聚合物的阴极。 为了实现本发明的目的，在使用包含硝酰基聚合物的阴极的蓄电装置中，使用在铝电极上形成并整合在碳上作为主要成分的导电性辅助层的阴极集电体。
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公开(公告)号：US20080213669A1
公开(公告)日：2008-09-04
申请号：US10597518
申请日：2004-12-17
CPC分类号： H01G9/155 , H01M4/137 , H01M4/386 , H01M4/387 , H01M4/405 , H01M4/60 , H01M4/602 , H01M10/052 , Y02E60/122 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： An object of the present invention is to provide a power storage device with excellent cycle property, employing a cathode containing a nitroxyl polymer. To attain the object in the present invention, in the power storage device employing a cathode comprising a nitroxyl polymer, a lithium or lithium alloy anode is used as an anode active material and the cathode is in direct contact with the anode.
摘要翻译： 本发明的目的是提供一种具有优异的循环性能的蓄电装置，其中使用含有硝酰基聚合物的阴极。 为了实现本发明的目的，在使用包含硝酰基聚合物的阴极的蓄电装置中，使用锂或锂合金阳极作为负极活性物质，阴极与阳极直接接触。
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