POSITIVE ELECTRODE ACTIVE MATERIAL AND LITHIUM SECONDARY BATTERY
    1.
    发明申请
    POSITIVE ELECTRODE ACTIVE MATERIAL AND LITHIUM SECONDARY BATTERY 审中-公开
    正极电极活性材料和锂二次电池

    公开(公告)号:US20100330429A1

    公开(公告)日:2010-12-30

    申请号:US12819465

    申请日:2010-06-21

    IPC分类号: H01M4/50 H01M4/90

    摘要: A positive electrode active material having an average from 1 μm or lager to smaller than 5 μm and containing a large number of crystal grains being composed of lithium manganate of spinel structure containing lithium and manganese as constituent elements, whose crystallite size is 500 to 1,500 nm in powder X-ray diffraction pattern, and whose value of a lattice strain (η) of 0.05×10−3 to 0.9×10−3 in powder X-ray diffraction pattern, and whose D50/DBET ratio is 1 to 4 wherein the D50 (μm) is the median diameter of the positive electrode active material and the DBET (μm) is calculated from the BET specific surface area by using the following general formula (1). DBET=6/(d×S)  (1) [Wherein d is the true density (g/cm3) of the positive electrode active material powder and S is BET specific surface area (m2/g) in the general formula (1).]

    摘要翻译: 平均1μm以上且小于5μm的正极活性物质,其含有大量的结晶粒子,所述晶体由以锂和锰为构成元素的尖晶石结构的锰酸锂构成,微晶尺寸为500〜1500nm 在粉末X射线衍射图中,其粉末X射线衍射图中的晶格应变值(&egr)为0.05×10 -3〜0.9×10 -3,D50 / DBET比为1〜4,其中 D50(μm)是正极活性物质的中值粒径,使用以下通式(1)从BET比表面积算出DBET(μm)。 DBET = 6 /(d×S)(1)其中,d为正极活性物质粉末的真密度(g / cm 3),S为通式(1)中的BET比表面积(m2 / g) 。]

    METHOD FOR PRODUCING SPINEL-TYPE LITHIUM MANGANATE
    4.
    发明申请
    METHOD FOR PRODUCING SPINEL-TYPE LITHIUM MANGANATE 审中-公开
    生产螺旋型锰酸锰的方法

    公开(公告)号:US20110311435A1

    公开(公告)日:2011-12-22

    申请号:US13165233

    申请日:2011-06-21

    IPC分类号: C01G45/12

    CPC分类号: C01G45/1242

    摘要: The production method of the present invention includes (A) a raw material preparation step of preparing a raw material mixture containing at least a manganese compound; (B) a forming step of forming the raw material mixture prepared through the raw material preparation step into a compact having a longitudinal size L and a maximum size R as measured in a direction perpendicular to the longitudinal direction (i.e., in a thickness direction) such that L/R is 3 or more; (C) a firing step of firing the compact obtained through the forming step; and (D) a crushing step of crushing the fired compact obtained through the firing step.

    摘要翻译: 本发明的制造方法包括(A)至少含有锰化合物的原料混合物的制备工序, (B)将通过原料制备工序制备的原料混合物形成为在与长度方向垂直的方向(即厚度方向)上测量的纵向尺寸L和最大尺寸R的压块的成形步骤, 使得L / R为3以上; (C)煅烧通过成形步骤获得的压块的烧制步骤; 和(D)破碎通过烧成工序得到的烧结体的粉碎工序。

    Piezoelectric/electrostrictive ceramics sintered body
    9.
    发明授权
    Piezoelectric/electrostrictive ceramics sintered body 有权
    压电/电致伸缩陶瓷烧结体

    公开(公告)号:US08414791B2

    公开(公告)日:2013-04-09

    申请号:US12965947

    申请日:2010-12-13

    IPC分类号: H01L41/18

    摘要: A piezoelectric/electrostrictive ceramic sintered body has a microstructure in which a matrix phase and an additional material phase having different compositions coexist and the additional material phase is dispersed in the matrix phase. A residual strain ratio of the additional material phase alone is larger than a residual strain ratio of the matrix phase alone. The matrix phase and the additional material phase have a composition in which a Mn compound containing Mn atoms of 0 parts by mole or more and 3 parts by mole or less and a Ba compound containing Ba atoms of 0 parts by mole or more and 1 part by mole or less are contained in a composite of 100 parts by mole represented by a general formula {Liy(Na1-xKx)1-y}a(Nb1-z-wTazSbw)O3, where a, x, y, z and w satisfy 0.9≦a≦1.2, 0.2≦x≦0.8, 0.0≦y≦0.2, 0≦z≦0.5 and 0≦w≦0.1, respectively.

    摘要翻译: 压电/电致伸缩陶瓷烧结体具有其中基体相和具有不同组成的附加材料相共存并且附加材料相分散在基体相中的微结构。 单独的附加材料相的残余应变比大于单独的基质相的残余应变比。 基体相和附加材料相的组成为:含有Mn原子的Mn化合物为0份摩尔以上且3份以下,Ba原子的Ba化合物为0份以上,1份以上 (Nb 1-x K x)1-y} a(Nb 1-z-w T z S b w)O 3表示的100份摩尔的复合物,其中a,x,y,z和w 分别满足0.9≦̸ a≦̸ 1.2,0.2≦̸ x≦̸ 0.8,0.0≦̸ y≦̸ 0.2,0& nlE; z≦̸ 0.5和0< nEE; w≦̸ 0.1。

    Piezoelectric/electrostrictive ceramics sintered body
    10.
    发明授权
    Piezoelectric/electrostrictive ceramics sintered body 有权
    压电/电致伸缩陶瓷烧结体

    公开(公告)号:US08034249B2

    公开(公告)日:2011-10-11

    申请号:US12830625

    申请日:2010-07-06

    IPC分类号: C04B35/00 C04B35/495

    摘要: A piezoelectric/electrostrictive ceramic sintered body has a microstructure in which a matrix phase and an additional material phase having different compositions coexist and the additional material phase is dispersed in the matrix phase. A residual strain ratio of the additional material phase alone is larger than a residual strain ratio of the matrix phase alone. The matrix phase and the additional material phase have a composition in which a Mn compound containing Mn atoms of 0 parts by mol or more and 3 parts by mol or less and a Sr compound containing Sr atoms of 0 parts by mol or more and 1 part by mol or less are contained in a composite of 100 parts by mol represented by a general formula {Liy(Na1-xKx)1-y}a(Nb1-z-wTazSbw)O3, where a, x, y, z and w satisfy 0.9≦a≦1.2, 0.2≦x≦0.8, 0.0≦y≦0.2, 0≦z≦0.5 and 0≦w≦0.1, respectively.

    摘要翻译: 压电/电致伸缩陶瓷烧结体具有其中基体相和具有不同组成的附加材料相共存并且附加材料相分散在基体相中的微结构。 单独的附加材料相的残余应变比大于单独的基质相的残余应变比。 基体相和附加材料相具有Mn含量为0摩尔%以上且3摩尔份以下的Mn化合物和Sr原子数为0摩尔份以上的Sr化合物和1份 以上,通式{Liy(Na1-xKx)1-y} a(Nb1-z-wTazSbw)O3表示的100份摩尔的复合物中含有1摩尔以下,其中a,x,y,z和w 分别满足0.9≦̸ a≦̸ 1.2,0.2≦̸ x≦̸ 0.8,0.0≦̸ y≦̸ 0.2,0& nlE; z≦̸ 0.5和0< nEE; w≦̸ 0.1。