摘要:
A positive electrode active material having an average from 1 μm or lager to smaller than 5 μm and containing a large number of crystal grains being composed of lithium manganate of spinel structure containing lithium and manganese as constituent elements, whose crystallite size is 500 to 1,500 nm in powder X-ray diffraction pattern, and whose value of a lattice strain (η) of 0.05×10−3 to 0.9×10−3 in powder X-ray diffraction pattern, and whose D50/DBET ratio is 1 to 4 wherein the D50 (μm) is the median diameter of the positive electrode active material and the DBET (μm) is calculated from the BET specific surface area by using the following general formula (1). DBET=6/(d×S) (1) [Wherein d is the true density (g/cm3) of the positive electrode active material powder and S is BET specific surface area (m2/g) in the general formula (1).]
摘要:
A positive electrode active material comprising a large number of crystal grains composed of lithium manganate of spinel structure, wherein the large number of crystal grains contain primary particles of 3 to 20 μm in particle diameter by 70 areal % or more relative to all the crystal grains, the primary particles contain a component having a rectangular plane, and the ratio of the total area of all the rectangular planes to the total surface area of the primary particles is 0.5 to 5%.
摘要:
A positive electrode active material containing a large number of crystal grains which contain, by 70 areal % or more, primary particles of non-octahedral shape, having particle diameters of 5 to 20 μm, and composed of lithium manganate of spinel structure containing lithium and manganese as the constituent elements.
摘要:
The production method of the present invention includes (A) a raw material preparation step of preparing a raw material mixture containing at least a manganese compound; (B) a forming step of forming the raw material mixture prepared through the raw material preparation step into a compact having a longitudinal size L and a maximum size R as measured in a direction perpendicular to the longitudinal direction (i.e., in a thickness direction) such that L/R is 3 or more; (C) a firing step of firing the compact obtained through the forming step; and (D) a crushing step of crushing the fired compact obtained through the firing step.
摘要:
A positive electrode active material containing a large number of crystal grains which contain, by 70 areal % or more, primary particles of non-octahedral shape, having particle diameters of 5 to 20 μm, and composed of lithium manganate of spinel structure containing lithium and manganese as the constituent elements.
摘要:
A complex oxide and an oxide-ion conductor made of the complex oxide are provided. The complex oxide has a basic composition of (Sm1-xAx)(Al1-yBy)O3, wherein “A” represents at least one element selected from the group consisting of barium, strontium and calcium, “B” represents an element selected from the group consisting of magnesium, iron and cobalt, x is a value in a range of 0.10 to 0.30, and y is a value in a range of 0 to 0.30.
摘要翻译:提供由复合氧化物制成的复合氧化物和氧化物离子导体。 复合氧化物具有(Sm 1-x A A x S)(Al 1-y B a Y z)的基本组成 >)O 3,其中“A”表示选自钡,锶和钙中的至少一种元素,“B”表示选自镁,铁和钴的元素 ,x为0.10〜0.30的范围的值,y为0〜0.30的范围的值。
摘要:
Manufacturing sintered bodies having microstructures including microscopic grains having a grain diameter of less than 5 μm, intermediate grains having a grain diameter of 5 μm or more and less than 15 μm, and coarse grains having a grain diameter of 15 μm or more and 100 μm or less enables to obtain high electric characteristics. Chemical compounds including metal elements are mixed so that the ratio of the elements is a composition expressed by (Li, Na, K)(Nb, Ta)O3, the mixture is calcined and crushed to obtain calcined/crushed powder. The powder is sintered in a constant temperature keeping process wherein temperature is kept constantly at a predetermined temperature within a range from 800 to 900° C. for a predetermined period of time in a heating process, and then the powder is further sintered by raising temperature to firing temperature, thereby the piezoelectric materials having superior electric characteristics are manufactured.
摘要:
A carbon film laminate 1 having a porous substrate 6 formed of a plurality of particles and a carbon film 2 provided on a surface of the porous substrate 6, wherein the porous substrate 6 includes a surface layer 3 which is in contact with the carbon film 2 and which is formed of particles 3a having a mean particle size of 0.01 to 0.11 μm, and a porous body 5 formed of particles having a mean particle size differing from that of the particles 3a forming the surface layer 3. The invention provides a carbon film laminate which does not generate cracks and pinholes of the carbon film and which is suitable for producing thin film thereof.
摘要:
A piezoelectric/electrostrictive ceramic sintered body has a microstructure in which a matrix phase and an additional material phase having different compositions coexist and the additional material phase is dispersed in the matrix phase. A residual strain ratio of the additional material phase alone is larger than a residual strain ratio of the matrix phase alone. The matrix phase and the additional material phase have a composition in which a Mn compound containing Mn atoms of 0 parts by mole or more and 3 parts by mole or less and a Ba compound containing Ba atoms of 0 parts by mole or more and 1 part by mole or less are contained in a composite of 100 parts by mole represented by a general formula {Liy(Na1-xKx)1-y}a(Nb1-z-wTazSbw)O3, where a, x, y, z and w satisfy 0.9≦a≦1.2, 0.2≦x≦0.8, 0.0≦y≦0.2, 0≦z≦0.5 and 0≦w≦0.1, respectively.
摘要翻译:压电/电致伸缩陶瓷烧结体具有其中基体相和具有不同组成的附加材料相共存并且附加材料相分散在基体相中的微结构。 单独的附加材料相的残余应变比大于单独的基质相的残余应变比。 基体相和附加材料相的组成为:含有Mn原子的Mn化合物为0份摩尔以上且3份以下,Ba原子的Ba化合物为0份以上,1份以上 (Nb 1-x K x)1-y} a(Nb 1-z-w T z S b w)O 3表示的100份摩尔的复合物,其中a,x,y,z和w 分别满足0.9≦̸ a≦̸ 1.2,0.2≦̸ x≦̸ 0.8,0.0≦̸ y≦̸ 0.2,0& nlE; z≦̸ 0.5和0< nEE; w≦̸ 0.1。
摘要:
A piezoelectric/electrostrictive ceramic sintered body has a microstructure in which a matrix phase and an additional material phase having different compositions coexist and the additional material phase is dispersed in the matrix phase. A residual strain ratio of the additional material phase alone is larger than a residual strain ratio of the matrix phase alone. The matrix phase and the additional material phase have a composition in which a Mn compound containing Mn atoms of 0 parts by mol or more and 3 parts by mol or less and a Sr compound containing Sr atoms of 0 parts by mol or more and 1 part by mol or less are contained in a composite of 100 parts by mol represented by a general formula {Liy(Na1-xKx)1-y}a(Nb1-z-wTazSbw)O3, where a, x, y, z and w satisfy 0.9≦a≦1.2, 0.2≦x≦0.8, 0.0≦y≦0.2, 0≦z≦0.5 and 0≦w≦0.1, respectively.