摘要:
A family of functionalized polymers is provided capable of forming membranes having exceptional OH− ionic conductivity as well as advantageous mechanical properties, which may be applied to membranes including such polymers for use in, e.g., AEMFC/HEMFC fuel cells. Preferred functional groups include a quaternary phosphonium, and the polymer may specifically be (tris(2,4,6-trimethoxyphenyl) phosphine)3 functionalized phosphonium polysulfone hydroxide, ECL-PVBC-QPOH, or QPOH based on any of the commercial polumers including polycarbonate (PC), poly(2,6-dimethyl-1,4-phenylene oxide) (PPO), polyetherimine (PEI), poly(ether sulfone) (PES), poly(phenylene sulfoxide) PPS, poly(ether ether ketone) (PEEK), or polybenzimidazole (PBI), polyvinyl chloride (PVC). An ionomer membrane may include polysulfone based TPQPOH, ECL-PVBC-QPOH, and/or PPO.
摘要:
A compound including a cation of the following structure is provided (1), wherein Q is selected from the group consisting of polymer residues and substituted or unsubstituted alkyl groups, and R is H or a polymer residue. A membrane including the above cation, and electrochemical devices employing this membrane, are also provided.
摘要:
A method for controlling the operation of a wind turbine may generally include monitoring a current yaw position of a nacelle of the wind turbine, wherein the current yaw position is located within one of a plurality of yaw sectors defined for the nacelle. In addition, the method may include monitoring a wind-dependent parameter of the wind turbine and determining a variance of the wind-dependent parameter over time, wherein the variance is indicative of variations in a wind parameter associated with the wind turbine. Moreover, the method may include determining at least one curtailed operating setpoint for the wind turbine when the variance exceeds a predetermined variance threshold, wherein the curtailed operating setpoint(s) is determined based at least in part on historical wind data for the yaw sector associated with the current yaw position.