摘要:
1-butene based polymer satisfying following requirements (1″) to (4″) provides formed product having low stickiness, superior flexibility and transparency. (1″) Crystalline resin having melting point (Tm−P), not observed or in the range of 0 to 100° C., wherein said melting point defined as the peak top of the peak observed in the highest temperature zone of the melting heat absorption curve obtained by heating a sample of said polymer at a rate of 10° C./minute using Differential Scanning Calorimeter (DSC), after melting said sample in advance at 190° for 5 minutes under nitrogen atmosphere, followed by cooling it to −10° C. at a rate of 5° C./minutes, and keeping it at −10° C. for 5 minutes. (2″) Stereoregularity index {(mmmm)/(mmrr+rmmr)} is at most 20. (3″) Molecular weight distribution (Mw/Mn) measured by Gel Permeation Chromatography (GPC) method is at most 4.0. (4″) Weight average molecular weight (Mw) measured by GPC method is in the range of 10,000 to 1,000,000.
摘要:
A propylenic polymer according to the present invention or a composition thereof have an excellent melt flowability and contains a less amount of stickiness-causing components, and also has a low modulus and is pliable, and is capable of providing a transparent molded article, thus being useful as a substitute for a pliable vinyl chloride resin. In addition, a molded article made therefrom exhibits an excellent heat seal performance at a low temperature, and is excellent in terms of transparency and rigidity. Specifically, it has an isotactic pentad fraction (mmmm), which indicates a stereoregulariry, of 30 to 80%, a molecular weight distribution (Mw/Mn) of 3.5 or less and an intrinsic viscosity [η] of 0.8 to 5 dl/g.
摘要翻译:根据本发明的丙烯聚合物或其组合物具有优异的熔体流动性并且含有较少量的粘着性成分,并且还具有低模量和柔韧性,并且能够提供透明模制品,因此是 可用作柔性氯乙烯树脂的替代物。 此外,由其制成的模制品在低温下表现出优异的热封性能,并且在透明性和刚性方面优异。 具体地说,其具有30至80%的立体有规配比的全同立构五单元组分数(mmmm),3.5或更小的分子量分布(Mw / Mn)和特性粘度η为0.8至5dl / g 。
摘要:
A propylenic polymer according to the present invention or a composition thereof have an excellent melt flowability and contains a less amount of stickiness-causing components, and also has a low modulus and is pliable, and is capable of providing a transparent molded article, thus being useful as a substitute for a pliable vinyl chloride resin. In addition, a molded article made therefrom exhibits an excellent heat seal performance at a low temperature, and is excellent in terms of transparency and rigidity. Specifically, it has an isotactic pentad fraction (mmmm), which indicates a stereoregulariry, of 30 to 80%, a molecular weight distribution (Mw/Mn) of 3.5 or less and an intrinsic viscosity [η] of 0.8 to 5 dl/g.
摘要翻译:根据本发明的丙烯聚合物或其组合物具有优异的熔体流动性并且含有较少量的粘着性成分,并且还具有低模量和柔韧性,并且能够提供透明模制品,因此是 可用作柔性氯乙烯树脂的替代物。 此外,由其制成的模制品在低温下表现出优异的热封性能,并且在透明性和刚性方面优异。 具体地说,其具有30至80%的立构规整性的全同立构五单元组分数(mmmm),3.5或更小的分子量分布(Mw / Mn)和特性粘度η为0.8至5dl / g 。
摘要:
A propylenic polymer according to the present invention or a composition thereof have an excellent melt flowability and contains a less amount of stickiness-causing components, and also has a low modulus and is pliable, and is capable of providing a transparent molded article, thus being useful as a substitute for a pliable vinyl chloride resin. In addition, a molded article made therefrom exhibits an excellent heat seal performance at a low temperature, and is excellent in terms of transparency and rigidity. Specifically, it has an isotactic pentad fraction (mmmm), which indicates a stereoregulariry, of 30 to 80%, a molecular weight distribution (Mw/Mn) of 3.5 or less and an intrinsic viscosity [η] of 0.8 to 5 dl/g.
摘要翻译:根据本发明的丙烯聚合物或其组合物具有优异的熔体流动性并且含有较少量的粘着性成分,并且还具有低模量和柔韧性,并且能够提供透明模制品,因此是 可用作柔性氯乙烯树脂的替代物。 此外,由其制成的模制品在低温下表现出优异的热封性能,并且在透明性和刚性方面优异。 具体地说,其具有30至80%的立构规整性的全同立构五单元组分数(mmmm),3.5或更小的分子量分布(Mw / Mn)和特性粘度η为0.8至5dl / g 。
摘要:
A propylenic polymer according to the present invention or a composition thereof have an excellent melt flowability and contains a less amount of stickiness-causing components, and also has a low modulus and is pliable, and is capable of providing a transparent molded article, thus being useful as a substitute for a pliable vinyl chloride resin. In addition, a molded article made therefrom exhibits an excellent heat seal performance at a low temperature, and is excellent in terms of transparency and rigidity. Specifically, it has an isotactic pentad fraction (mmmm), which indicates a stereoregulariry, of 30 to 80%, a molecular weight distribution (Mw/Mn) of 3.5 or less and an intrinsic viscosity [η] of 0.8 to 5 dl/g.
摘要:
The propylene polymer of the invention is transparent and has good low-temperature heat-sealability and scratch resistance, and is favorable to wrapping and packaging films. (1) The polymer has a melting point, Tm (° C.), measured through differential scanning calorimetry, of 110≦Tm≦140; (2) its heat of fusion &Dgr;H (J/g) and melting point Tm (° C.) satisfy &Dgr;H≧0.45×Tm+22; (3) the half-value width Th (° C.) of the peak top of its elution curve obtained in programmed-temperature fractionation is Th≦5; and (4) its intrinsic viscosity [&eegr;] (dl/g) measured in a solvent of tetralin at 135° C. falls between 0.5 and 5.
摘要:
A propylenic polymer according to the present invention or a composition thereof have an excellent melt flowability and contains a less amount of stickiness-causing components, and also has a low modulus and is pliable, and is capable of providing a transparent molded article, thus being useful as a substitute for a pliable vinyl chloride resin. In addition, a molded article made therefrom exhibits an excellent heat seal performance at a low temperature, and is excellent in terms of transparency and rigidity. Specifically, it has an isotactic pentad fraction (mmmm), which indicates a stereoregularity, of 30 to 80%, a molecular weight distribution (Mw/Mn) of 3.5 or less and an intrinsic viscosity [η] of 0.8 to 5 dl/g.
摘要翻译:根据本发明的丙烯聚合物或其组合物具有优异的熔体流动性并且含有较少量的粘着性成分,并且还具有低模量和柔韧性,并且能够提供透明模制品,因此是 可用作柔性氯乙烯树脂的替代物。 此外,由其制成的模制品在低温下表现出优异的热封性能,并且在透明性和刚性方面优异。 具体地说,其具有立构规整性的全同立构五单元组分数(mmmm)为30〜80%,分子量分布(Mw / Mn)为3.5以下,特性粘度η为0.8〜5dl / g 。
摘要:
1-butene based polymer satisfying following requirements (1″) to (4″) provides formed product having low stickiness, superior flexibility and transparency. (1″) Crystalline resin having melting point (Tm−P), not observed or in the range of 0 to 100° C., wherein said melting point defined as the peak top of the peak observed in the highest temperature zone of the melting heat absorption curve obtained by heating a sample of said polymer at a rate of 10° C./minute using Differential Scanning Calorimeter (DSC), after melting said sample in advance at 190° for 5 minutes under nitrogen atmosphere, followed by cooling it to −10° C. at a rate of 5° C./minutes, and keeping it at −10° C. for 5 minutes. (2″) Stereoregularity index {(mmmm)/(mmrr+rmmr)} is at most 20. (3″) Molecular weight distribution (Mw/Mn) measured by Gel Permeation Chromatography (GPC) method is at most 4.0. (4″) Weight average molecular weight (Mw) measured by GPC method is in the range of 10,000 to 1,000,000.
摘要:
The propylene polymer of the present invention satisfies (1) a 25° C. hexane soluble content (H25) of 0-80 wt %; and (2) either no melting temperature (Tm) measurable by differential scanning calorimetry (DSC), or a melting temperature (Tm) satisfying, if measurable by DSC, the following relationship: ΔH≧3×(Tm−120) wherein ΔH is a melting endotherm (J/g). The propylene homopolymer of the present invention satisfies (1) a meso pentad fraction (mmmm) of 30-60 mol %; (2) a racemic pentad fraction (rrrr) satisfying the following relationship: [rrrr/(1−mmmm)]≦0.1; (3) a fraction (W25) eluted at a temperatures up to 25° C. by temperature-programmed chromatography, of from 20-100 wt %; and, (4) a pentad fraction (rmrm) of more than 2.5 mol %. The propylene copolymer of the present invention satisfies (1) a stereoregularity index (P) of 55-90 mol % as determined by 13C-NMR measurement; and (2) a fraction (W25) eluted at a temperatures up to 25° C. by temperature-programmed chromatography, of from 20-100 wt %.
摘要:
A polypropylene-based calendered or injection-molded article satisfying the requirements of (1) having a tensile modulus TM of 5 MPa or higher and (2) having, when measured by a differential scanning calorimeter (DSC), no melting point or a melting point Tm (° C.) satisfying the formula: TM≧5×Tm−450, is less tacky and excellent in flexibility and transparency. Such a polypropylene-based calendered or injection-molded article is produced from a propylene polymer satisfying the requirements of (1) having a component soluble in a 25° C. hexane in a content H25 of 0 to 80% by weight; (2) having, when measured by a differential scanning calorimeter (DSC), no melting point or a melting point Tm (° C.) satisfying the formula: &Dgr;H≧6×(Tm−140) wherein &Dgr;H is a melting endotherm (J/g); and (3) having an intrinsic viscosity [&eegr;] of 1 to 3 dl/g as measured at 135° C. in tetralin.