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    PROCESS FOR PREPARING END-MODIFIED VINYLIDENE FLUORIDE ELASTOMER
    1.
    发明申请
    PROCESS FOR PREPARING END-MODIFIED VINYLIDENE FLUORIDE ELASTOMER 有权
    制备末端改性的乙烯基氟化物弹性体的方法

    公开(公告)号：US20100292408A1

    公开(公告)日：2010-11-18

    申请号：US12863549

    申请日：2009-01-20

    申请人： Yuzo Komatsu ,  Haruhiko Mohri ,  Hirokazu Aoyama ,  Takanori Fukushima ,  Takuzo Aida

    发明人： Yuzo Komatsu ,  Haruhiko Mohri ,  Hirokazu Aoyama ,  Takanori Fukushima ,  Takuzo Aida

    IPC分类号： C08F114/22

    CPC分类号： C08C19/20 ,  C08F2/38 ,  C08F8/20 ,  C08F8/26 ,  C08F8/34 ,  C08F8/36 ,  C08F8/38 ,  C08F14/22 ,  C08F114/22 ,  C08F214/18 ,  C08F214/22 ,  C08F2810/40 ,  C08F214/28 ,  C08F8/12

    摘要： The present invention provides a preparation process for converting to a vinylidene fluoride elastomer having a group having sulfinic acid, sulfinic acid derivative, sulfonic acid or sulfonic acid derivative at one end or both ends of its trunk chain, and the preparation process provides a vinylidene fluoride elastomer having, at one end or both ends of its trunk chain, end groups represented by the formula: —CR1R2—CR3R4—SO2H, wherein R1 to R4 may be the same or different and each is hydrogen atom or fluorine atom, by allowing a vinylidene fluoride elastomer having, at one end or both ends of its trunk chain, end groups represented by the formula: —CR1R2—CR3R4—X1, wherein R1 to R4 are as defined above, X1 is bromine atom or iodine atom, to react with a sulfur compound represented by the formula: (M1)nH2−nS2O4, wherein M1 is a monovalent or divalent metal ion or ammonium ion, n is an integer of 0 to 2.

    摘要翻译： 本发明提供一种在其主链的一端或两端转化为具有亚磺酸，亚磺酸衍生物，磺酸或磺酸衍生物的基团的偏二氟乙烯弹性体的制备方法，其制备方法提供偏二氟乙烯 在其主链的一端或两端具有由下式表示的端基的弹性体：-CR1R2-CR3R4-SO2H，其中R1至R4可以相同或不同，各自为氢原子或氟原子，通过使 偏二氟乙烯弹性体在其主链的一端或两端具有由下式表示的端基：-CR1R2-CR3R4-X1，其中R1至R4如上定义，X​​1为溴原子或碘原子，与 由式（M1）nH2-nS2O4表示的硫化合物，其中M1是一价或二价金属离子或铵离子，n是0-2的整数。

    Process for preparing end-modified vinylidene fluoride elastomer
    2.
    发明授权
    Process for preparing end-modified vinylidene fluoride elastomer 有权
    制备端改性偏二氟乙烯弹性体的方法

    公开(公告)号：US08722809B2

    公开(公告)日：2014-05-13

    申请号：US12863549

    申请日：2009-01-20

    申请人： Yuzo Komatsu ,  Haruhiko Mohri ,  Hirokazu Aoyama ,  Takanori Fukushima ,  Takuzo Aida

    发明人： Yuzo Komatsu ,  Haruhiko Mohri ,  Hirokazu Aoyama ,  Takanori Fukushima ,  Takuzo Aida

    IPC分类号： C08F8/26 ,  C08F14/22 ,  C08C19/20 ,  C08F8/36

    CPC分类号： C08C19/20 ,  C08F2/38 ,  C08F8/20 ,  C08F8/26 ,  C08F8/34 ,  C08F8/36 ,  C08F8/38 ,  C08F14/22 ,  C08F114/22 ,  C08F214/18 ,  C08F214/22 ,  C08F2810/40 ,  C08F214/28 ,  C08F8/12

    摘要： The present invention provides a preparation process for converting to a vinylidene fluoride elastomer having a group having sulfinic acid, sulfinic acid derivative, sulfonic acid or sulfonic acid derivative at one end or both ends of its trunk chain, and the preparation process provides a vinylidene fluoride elastomer having, at one end or both ends of its trunk chain, end groups represented by the formula: —CR1R2—CR3R4—SO2H, wherein R1 to R4 may be the same or different and each is hydrogen atom or fluorine atom, by allowing a vinylidene fluoride elastomer having, at one end or both ends of its trunk chain, end groups represented by the formula: —CR1R2—CR3R4—X1, wherein R1 to R4 are as defined above, X1 is bromine atom or iodine atom, to react with a sulfur compound represented by the formula: (M1)nH2-nS2O4, wherein M1 is a monovalent or divalent metal ion or ammonium ion, n is an integer of 0 to 2.

    摘要翻译： 本发明提供一种在其主链的一端或两端转化为具有亚磺酸，亚磺酸衍生物，磺酸或磺酸衍生物的基团的偏二氟乙烯弹性体的制备方法，其制备方法提供偏二氟乙烯 在其主链的一端或两端具有由下式表示的端基的弹性体：-CR1R2-CR3R4-SO2H，其中R1至R4可以相同或不同，各自为氢原子或氟原子，通过使 偏二氟乙烯弹性体在其主链的一端或两端具有由下式表示的端基：-CR1R2-CR3R4-X1，其中R1至R4如上定义，X​​1为溴原子或碘原子，与 由式（M1）nH2-nS2O4表示的硫化合物，其中M1是一价或二价金属离子或铵离子，n是0-2的整数。

    Process for preparing heteroaromatic ring compound having N-Rf group
    5.
    发明授权
    Process for preparing heteroaromatic ring compound having N-Rf group 有权
    制备具有N-Rf基团的杂芳环化合物的方法

    公开(公告)号：US08252944B2

    公开(公告)日：2012-08-28

    申请号：US13350498

    申请日：2012-01-13

    申请人： Yuzo Komatsu ,  Haruhiko Mohri ,  Hirokazu Aoyama

    发明人： Yuzo Komatsu ,  Haruhiko Mohri ,  Hirokazu Aoyama

    IPC分类号： C07D233/54 ,  C07D233/60

    CPC分类号： C07D207/325 ,  C07D209/08 ,  C07D209/20 ,  C07D231/12 ,  C07D233/56 ,  C07D233/60 ,  C07D233/64 ,  C07D249/08 ,  C07D473/00 ,  C07D473/08

    摘要： There is provided a preparation process in which a N—H group of a heteroaromatic ring compound having a N—H group in its ring is converted directly to a N—Rf group at a high reaction efficiency without using a catalyst. The preparation process is a process for preparing a compound comprising a heteroaromatic ring structure having a N—Rf group (—Rf is a fluorine-containing organic group) in its ring and is characterized in that the heteroaromatic ring compound having a N—H group in its ring is allowed to react with fluoroalkene in the absence of an alkali metal.

    摘要翻译： 提供了一种制备方法，其中在其环中具有N-H基团的杂芳环化合物的N-H基团在不使用催化剂的情况下以高反应效率直接转化为N-Rf基团。 制备方法是在环中制备包含具有N-Rf基（-Rf为含氟有机基团）的杂芳环结构的化合物的方法，其特征在于具有N-H基的杂芳环化合物 在不存在碱金属的情况下使其与氟代烯烃反应。

    Actuator element
    6.
    发明授权
    Actuator element 有权
    执行元件

    公开(公告)号：US08123983B2

    公开(公告)日：2012-02-28

    申请号：US12161275

    申请日：2007-01-22

    申请人： Yuzo Komatsu ,  Keiko Hirata ,  Haruhiko Mohri ,  Hirokazu Aoyama

    发明人： Yuzo Komatsu ,  Keiko Hirata ,  Haruhiko Mohri ,  Hirokazu Aoyama

    IPC分类号： H01B1/00

    CPC分类号： H01B1/122 ,  C08K5/0008 ,  C08K5/3445 ,  C08K7/24 ,  C09D127/12 ,  H02N11/006 ,  Y10S310/80

    摘要： An ion-conducting layer for an actuator element including (I) a fluorine-containing polymer having a functional group and (II) an ionic liquid. The functional group is selected from —OH, —COOH, —COOR, —CN, iodine atom, epoxy group and (meth)acryloyl group, and is contained in a side chain and/or at an end of a trunk chain of the fluorine-containing polymer. Also disclosed is an electrode layer including (I) the fluorine-containing polymer having a functional group, (II) an ionic liquid and (III) an electroconductive nano-filler. Also disclosed is an actuator element including the ion-conducting layer and at least two electrode layers formed on the surfaces of the ion-conducting layer and insulated from one another, in which flection or deformation can be caused by applying an electric potential between the electrode layers.

    摘要翻译： 一种用于致动器元件的离子传导层，包括（I）具有官能团的含氟聚合物和（II）离子液体。 官能团选自-OH，-COOH，-COOR，-CN，碘原子，环氧基和（甲基）丙烯酰基，并且包含在氟的主链的侧链和/或末端 含聚合物。 还公开了一种电极层，其包括（I）具有官能团的含氟聚合物，（II）离子液体和（III）导电纳米填料。 还公开了一种致动器元件，其包括离子传导层和形成在离子传导层的表面上并彼此绝缘的至少两个电极层，其中可以通过在电极之间施加电位而引起弯曲或变形 层。

    PROCESS FOR PREPARING HETEROAROMATIC RING COMPOUND HAVING N-Rf GROUP
    9.
    发明申请
    PROCESS FOR PREPARING HETEROAROMATIC RING COMPOUND HAVING N-Rf GROUP 有权
    制备具有N-Rf基团的异构环化合物的方法

    公开(公告)号：US20100222598A1

    公开(公告)日：2010-09-02

    申请号：US12159439

    申请日：2006-12-11

    申请人： Yuzo Komatsu ,  Haruhiko Mohri ,  Hirokazu Aoyama

    发明人： Yuzo Komatsu ,  Haruhiko Mohri ,  Hirokazu Aoyama

    IPC分类号： C07D233/68

    CPC分类号： C07D207/325 ,  C07D209/08 ,  C07D209/20 ,  C07D231/12 ,  C07D233/56 ,  C07D233/60 ,  C07D233/64 ,  C07D249/08 ,  C07D473/00 ,  C07D473/08

    摘要： There is provided a preparation process in which a N—H group of a heteroaromatic ring compound having a N—H group in its ring is converted directly to a N—Rf group at a high reaction efficiency without using a catalyst. The preparation process is a process for preparing a compound comprising a heteroaromatic ring structure having a N—Rf group (—Rf is a fluorine-containing organic group) in its ring and is characterized in that the heteroaromatic ring compound having a N—H group in its ring is allowed to react with fluoroalkene in the absence of an alkali metal.

    摘要翻译： 提供了一种制备方法，其中在其环中具有N-H基团的杂芳环化合物的N-H基团在不使用催化剂的情况下以高反应效率直接转化为N-Rf基团。 制备方法是在环中制备包含具有N-Rf基（-Rf为含氟有机基团）的杂芳环结构的化合物的方法，其特征在于具有N-H基的杂芳环化合物 在不存在碱金属的情况下使其与氟代烯烃反应。

    ACTUATOR ELEMENT
    10.
    发明申请
    ACTUATOR ELEMENT 有权
    执行元件

    公开(公告)号：US20100164330A1

    公开(公告)日：2010-07-01

    申请号：US12161275

    申请日：2007-01-22

    申请人： Yuzo Komatsu ,  Keiko Hirata ,  Haruhiko Mohri ,  Hirokazu Aoyama

    发明人： Yuzo Komatsu ,  Keiko Hirata ,  Haruhiko Mohri ,  Hirokazu Aoyama

    IPC分类号： H01L41/193 ,  H01L41/18

    CPC分类号： H01B1/122 ,  C08K5/0008 ,  C08K5/3445 ,  C08K7/24 ,  C09D127/12 ,  H02N11/006 ,  Y10S310/80

    摘要： There is provided an actuator element which can be driven at low voltages, is operated stably in air and in vacuo with a quick response, exhibits a large degree of displacement and a large displacement force, has high mechanical strength including flexibility, thus giving long-term durability for repeated use, can be produced by a very simple method, can be formed into a small size because of a simple structure, and can be put into practical use in wide applications. The actuator element is comprised of an ion-conducting layer for an actuator element comprising (I) a fluorine-containing polymer having functional group and (II) an ionic liquid, in which the fluorine-containing polymer having functional group is a polymer having functional group selected from the group consisting of —OH, —COOH, —COOR, —CN, iodine atom, epoxy group and (meth)acryloyl group in a polymer side chain and/or at an end of a polymer trunk chain, and an electrode layer comprising (I) the fluorine-containing polymer having functional group, (II) an ionic liquid and (III) an electroconductive nano-filler.

    摘要翻译： 提供了可以在低电压下驱动的致动器元件，在空气中和在真空中以快速响应稳定地操作，表现出大的位移和大的位移力，具有高的机械强度，包括柔性， 反复使用的长期耐用性可以通过非常简单的方法制造，由于结构简单而可以形成小尺寸，并且可以广泛应用于实际应用中。 致动器元件包括用于致动器元件的离子传导层，其包括（I）具有官能团的含氟聚合物和（II）离子液体，其中具有官能团的含氟聚合物是具有官能团的聚合物 在聚合物侧链和/或聚合物主链的末端选自-OH，-COOH，-COOR，-CN，碘原子，环氧基和（甲基）丙烯酰基的基团，和电极 层（I）具有官能团的含氟聚合物，（II）离子液体和（III）导电纳米填料。