Abstract:
A nitrile group-containing highly saturated copolymer rubber composition containing a nitrile group-containing highly saturated copolymer rubber (A) having a Mooney viscosity [ML1+4, 100° C.] of 50 to 200, a nitrile group-containing highly saturated copolymer rubber (B) having a Mooney viscosity [ML1+4, 100° C.] of 5 to 45, and staple fibers (C) having an average fiber length of 0.1 to 12 mm is provided. According to the present invention, a nitrile group-containing highly saturated copolymer rubber composition which can give cross-linked rubber which is extremely high in tensile stress and is excellent in low heat buildup property and has good workability can be provided.
Abstract:
A nitrile group-containing copolymer rubber containing β-ethylenically unsaturated nitrile monomer units in 10 to 60 wt % and having a weight average radius of gyration of 10 to 100 nm in range is provided. According to the present invention, a nitrile group-containing copolymer rubber excellent in processability and able to give cross-linked rubber excellent in normal physical properties can be provided.
Abstract:
A cross-linkable nitrile rubber composition including a nitrile rubber (a) containing 0.1 to 15 wt % of α,β-ethylenically unsaturated nitrile monomer units, 1 to 10 wt % of α,β-ethylenically unsaturated dicarboxylic acid monoester monomer units, 40 to 75 wt % of α,β-ethylenically unsaturated monocarboxylic acid ester monomer units, and 20 to 58.9 wt % of diene monomer units and/or α-olefin monomer units, and a polyamine-based cross-linking agent (b), wherein a ratio of content of the polyamine-based cross-linking agent (b) with respect to 100 parts by weight of the nitrile rubber (a) is 0.1 to 20 parts by weight is provided.
Abstract:
A nitrile copolymer latex composition containing a latex of a nitrile copolymer rubber (A) having α,β-ethylenically unsaturated nitrile monomer units in 10 to 75 wt %, conjugated diene monomer units in 5 to 89.9 wt %, and cationic monomer units and/or monomer units able to form cations in 0.1 to 20 wt %, an inorganic filler (B) having an aspect ratio of 30 to 2,000, and a plasticizer (C) having an SP value by the HOY method of 8 to 10.2 (cal/cm3)1/2, wherein a content of said plasticizer (C) is 0.1 to 200 parts by weight with respect to said nitrile copolymer rubber (A) as 100 parts by weight is provided.
Abstract:
A nitrile group-containing copolymer rubber includes an acrylonitrile unit (a), a monomer unit (b) of an α,β-ethylenically unsaturated nitrile monomer other than acrylonitrile, and a conjugated diene monomer unit (c) and having an iodine value of 120 or less, wherein the total content of the acrylonitrile unit (a) and the monomer unit (b) of an α,β-ethylenically unsaturated nitrile monomer other than acrylonitrile is 1 to 50% by weight in the total monomer units, and the content ratio of the acrylonitrile unit (a) and the monomer unit (b) of an α,β-ethylenically unsaturated nitrile monomer other than acrylonitrile is 10:90 to 90:10 in a weight ratio of “content of acrylonitrile unit (a): content of monomer unit (b) of α,β-ethylenically unsaturated nitrile monomer other than acrylonitrile”.
Abstract:
A method for producing a hydrogenated conjugated diene polymer latex includes: a hydrogenation step of dissolving or dispersing a hydrogenation catalyst containing a platinum group element in a latex of a conjugated diene polymer to hydrogenate a carbon-carbon unsaturated bond in the polymer; an insoluble complex formation step of complexing the platinum group element with a complexing agent to form an insoluble complex; and an insoluble complex removing step of continuously feeding the latex which has undergone the insoluble complex formation step to a centrifuge machine and continuously performing a centrifugation operation to continuously remove the insoluble complex from the latex and continuously discharge the insoluble complex out of the centrifuge machine. In the insoluble complex removal step the feed rate of the latex to the centrifuge machine is adjusted to 0.5 to 15 m3/hour, and the centrifugal force in the centrifugation operation is adjusted to 200 to 10,000 G.