Ion exchange materials for use in a 213Bi generator
    3.
    发明授权
    Ion exchange materials for use in a 213Bi generator 失效
    用于213Bi发电机的离子交换材料

    公开(公告)号:US07211231B2

    公开(公告)日:2007-05-01

    申请号:US10354929

    申请日:2003-01-30

    IPC分类号: C01B25/26 C01G56/00

    CPC分类号: G21G4/08 Y10S423/07

    摘要: A bismuth-213 generator comprising an insoluble composition having the general formula Zr(Phosponate)x(HPO4)2−x.nH2O, wherein x is between 0 and 2; and n is the number of waters of hydration; and wherein cations of radioactive isotopes selected from radium, actinium and combinations thereof are immobilized on the composition. The value of x may be between about 0.2 and about 1. The phosphonate may be n-phosphonomethyl-miniodiacetic acid (PMIDA), wherein x may be between about 0.1 and about 1.9. The phosphonate may be one or more phosphonate having the formula: H2O3P—(CH2)a—N—((CH2)bCO2H)—((CH2)cCO2H), wherein a, b, and c are numbers from 1 to 3 that may or may not be equal. The value of x may also be between about 0.1 and 1.9.

    摘要翻译: 一种铋-213发生器,其包含具有通式Zr(磷酸酯)x(HPO 2)2-x N)的不溶性组合物。 > 2 O,其中x在0和2之间; n是水合水的数量; 并且其中选自镭,锕及其组合的放射性同位素的阳离子固定在组合物上。 x的值可以在约0.2和约1之间。膦酸酯可以是正膦酰基甲基 - 次碘酸(PMIDA),其中x可以在约0.1和约1.9之间。 膦酸酯可以是一种或多种具有下式的膦酸酯:<?in-line-formula description =“In-line Formulas”end =“lead”?> H (CH 2)2 - ((CH 2)2)b - 2 H) - ((CH 2)2 CO 2 H),<β在线公式描述=“ 在线公式“end =”tail“?>其中a,b和c是可以相同也可以不相等的从1到3的数字。 x的值也可以在约0.1和1.9之间。

    Method for labeling DNA and RNA
    4.
    发明授权
    Method for labeling DNA and RNA 有权
    标记DNA和RNA的方法

    公开(公告)号:US07208269B2

    公开(公告)日:2007-04-24

    申请号:US10057753

    申请日:2002-01-23

    IPC分类号: C12Q1/68

    摘要: A method for fragmenting and labeling nucleic acids is provided. The method comprises maintaining double- and single-stranded nucleic acid molecules in an aerobic or an anaerobic atmosphere, contacting the molecules with hydrogen peroxide and radical generating coordination complexes for a time and at concentrations sufficient to produce aldehyde moieties on the molecules, reacting the aldehyde moieties with amine to produce a condensation product, and labeling the condensation product.

    摘要翻译: 提供了一种分离和标记核酸的方法。 该方法包括在需氧或厌氧环境中保持双链和单链核酸分子,使分子与过氧化氢和产生自由基的配位络合物接触一段时间并且足以在分子上产生醛部分的浓度,使醛 部分与胺反应以产生缩合产物,并标出缩合产物。

    Redox shuttles for overcharge protection of lithium batteries
    6.
    发明授权
    Redox shuttles for overcharge protection of lithium batteries 有权
    锂离子电池过充电保护的氧化还原穿梭

    公开(公告)号:US07851092B2

    公开(公告)日:2010-12-14

    申请号:US11366891

    申请日:2006-03-01

    IPC分类号: H01M1/40

    摘要: The present invention is generally related to electrolytes containing novel redox shuttles for overcharge protection of lithium-ion batteries. The redox shuttles are capable of thousands hours of overcharge tolerance and have a redox potential at about 3-5.5 V vs. Li and particularly about 4.4-4.8 V vs. Li. Accordingly, in one aspect the invention provides electrolytes comprising an alkali metal salt; a polar aprotic solvent; and a redox shuttle additive that is an aromatic compound having at least one aromatic ring with four or more electronegative substituents, two or more oxygen atoms bonded to the aromatic ring, and no hydrogen atoms bonded to the aromatic ring; and wherein the electrolyte solution is substantially non-aqueous. Further there are provided electrochemical devices employing the electrolyte and methods of making the electrolyte.

    摘要翻译: 本发明通常涉及含有用于锂离子电池的过充电保护的新的氧化还原梭的电解质。 氧化还原梭能够承受数千小时的过充电容忍,并且具有约3-5.5V相对于Li的氧化还原电位,特别是约4.4-4.8V对Li的氧化还原电位。 因此,一方面,本发明提供了包含碱金属盐的电解质; 极性非质子溶剂; 以及氧化还原穿梭添加剂,其是具有至少一个具有四个或更多个电负性取代基的芳环的芳族化合物,两个或更多个与芳环键合的氧原子,并且没有与芳环键合的氢原子; 并且其中所述电解质溶液基本上是非水的。 还提供了采用电解质的电化学装置和制备电解质的方法。

    Lithium-ion batteries with intrinsic pulse overcharge protection
    9.
    发明授权
    Lithium-ion batteries with intrinsic pulse overcharge protection 有权
    具有固有脉冲过充保护的锂离子电池

    公开(公告)号:US08367253B2

    公开(公告)日:2013-02-05

    申请号:US11345947

    申请日:2006-02-02

    IPC分类号: H01M6/16 H01M4/13

    摘要: The present invention relates in general to the field of lithium rechargeable batteries, and more particularly relates to the positive electrode design of lithium-ion batteries with improved high-rate pulse overcharge protection. Thus the present invention provides electrochemical devices containing a cathode comprising at least one primary positive material and at least one secondary positive material; an anode; and a non-aqueous electrolyte comprising a redox shuttle additive; wherein the redox potential of the redox shuttle additive is greater than the redox potential of the primary positive material; the redox potential of the redox shuttle additive is lower than the redox potential of the secondary positive material; and the redox shuttle additive is stable at least up to the redox potential of the secondary positive material.

    摘要翻译: 本发明一般涉及锂可充电电池领域,更具体地涉及具有改进的高速率脉冲过充电保护的锂离子电池的正电极设计。 因此,本发明提供了含有包含至少一种初级正材料和至少一种次级正材料的阴极的电化学装置; 阳极; 和含有氧化还原穿梭添加剂的非水电解质; 其中所述氧化还原穿梭添加剂的氧化还原电位大于所述初级正材料的氧化还原电位; 氧化还原穿梭添加剂的氧化还原电位低于次级正材料的氧化还原电位; 并且氧化还原穿梭添加剂至少达到次级正材料的氧化还原电位稳定。