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1.发明授权公开(公告)号：US06413488B1
公开(公告)日：2002-07-02
申请号：US09355067
申请日：2000-06-19
申请人： David Smith , David Benayoun , Claude Dezael
发明人： David Smith , David Benayoun , Claude Dezael
IPC分类号： B01D5350
CPC分类号： B01D53/523 , C01B17/0205 , C01B17/0456 , C01B17/05
摘要： A process and an apparatus are described for treatment of a gas containing hydrogen sulphide and sulphur dioxide, for example a Claus plant tail gas, in which the gas is brought into contact with an organic solvent (1) e.g. polyethylene glycol 400, containing a catalyst e.g. sodium salicylate, in at least one gas-liquid reactor-contactor (2) and a gas (20) substantially no longer containing hydrogen sulphide and sulphur dioxide is recovered. A single-phase solution (4) of solvent and sulphur is extracted from the reactor-contactor and a portion is cooled in at least one cooling zone (8) to obtain a suspension of sulphur crystals in the solvent, the crystallised sulphur is separated from the solvent in a separation zone (10), the sulphur-depleted solvent (14, 15) is recovered and recycled at least in part to the reactor-contactor (2), and the sulphur (13) is recovered.
摘要翻译： 描述了一种用于处理含有硫化氢和二氧化硫的气体的方法和装置，例如克劳斯植物尾气，其中气体与有机溶剂（1）接触。 聚乙二醇400，含有催化剂 在至少一个气液反应器 - 接触器（2）和基本上不再含有硫化氢和二氧化硫的气体（20）中回收水杨酸钠。 从反应器 - 接触器中提取溶剂和硫的单相溶液（4），并在至少一个冷却区（8）中冷却一部分，以获得溶剂中硫结晶的悬浮液，将结晶的硫从 分离区（10）中的溶剂，贫硫溶剂（14,15）被回收并至少部分地再循环到反应器 - 接触器（2）中，并回收硫（13）。
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2.发明授权Process for treating gas containing hydrogen sulfide and sulphur dioxide, comprising a step for depleting the recycled solvent in sulphur 失效用于处理含有硫化氢和二氧化硫的气体的方法，包括用于耗尽硫中的再循环溶剂的步骤
公开(公告)号：US5935547A
公开(公告)日：1999-08-10
申请号：US929445
申请日：1997-09-16
CPC分类号： C01B17/05 , B01D53/523
摘要： In a process for treating a gas containing hydrogen sulphide and sulphur dioxide, such as Claus plant tail gas, to substantially reduce emission of sulphur vapor in the treated gases, the process a characterized in that the gas is brought into contact with a solvent (5) in at least one gas-liquid reactor-contactor (2) and a gas (20) is recovered which is sent to a second reactor (102) where it is brought into contact with solvent (105), the solvent (105) being cooled by suitable means (190), to separate a portion of the sulphur from the solvent. The resultant solvent depleted in sulphur, contacts the gas (20) from the first reactor (2). The gas (120) from the second reactor is highly depleted in sulphur vapor. At least one of the reactors contains a catalyst. The solvent may be insoluble in water, e.g. dodecane, tridecane, naphtha, or soluble in water, e.g. glycerol, thiodiglycol, cyclohexanedimethylethanol, or an acid ester. The catalyst may comprise, e.g., alkaline salts of organic acids such as benzoic acid or salicylic acid.
摘要翻译： 在用于处理含有硫化氢和二氧化硫（例如克劳斯工厂尾气）的气体的方法中，基本上减少处理过的气体中的硫蒸气的排放，其特征在于气体与溶剂（5 ）回收至少一个气液反应器 - 接触器（2）和气体（20），将其送至第二反应器（102），在其中与溶剂（105）接触，溶剂（105）为 通过合适的方法（190）冷却，以将一部分硫与溶剂分离。 所产生的硫的溶剂与第一反应器（2）的气体（20）接触。 来自第二反应器的气体（120）高度耗尽硫蒸气。 至少一个反应器含有催化剂。 溶剂可能不溶于水，例如 十二烷，十三烷，石脑油或可溶于水，例如。 甘油，硫二甘醇，环己烷二甲基乙醇或酸酯。 催化剂可以包括例如有机酸的碱性盐，例如苯甲酸或水杨酸。
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3.发明授权Process for converting heavy petroleum residues to hydrogen and gaseous distillable hydrocarbons 失效将重质石油残渣转化为氢气和气态可馏分烃的方法
公开(公告)号：US4609456A
公开(公告)日：1986-09-02
申请号：US699540
申请日：1985-02-08
IPC分类号： C10G47/02 , B01J23/00 , B01J23/02 , B01J23/22 , B01J23/78 , B01J27/00 , B01J27/232 , C10G11/12 , C10G47/04 , C10G47/26 , B01J23/90 , C10J3/46
摘要： The invention concerns a process for converting heavy petroleum residues to hydrogen and to gaseous and distillable hydrocarbons, comprising the association of a step of hydropyrolysis (inside tube 3) with a step of catalytic steam-gasification of the formed coke (outside tube 3), characterized in that the hydropyrolysis step is performed in the presence of a solid supporting a carbon gasification catalyst circulating between the hydropyrolysis zone and the coke steam-gasification zone, said steam-gasification being performed in the absence of oxygen.The petroleum residue, hydrogen and steam are introduced respectively through lines 5, 6 and 7.The products are withdrawn through line 10. Heat may be supplied by the radiating tube 4.
摘要翻译： 本发明涉及将重质石油残余物转化为氢气和气态和可馏出烃的方法，其包括加氢热解步骤（管3内）与成形焦炭（外管3）的催化蒸汽气化步骤的关联， 其特征在于，所述加氢热解步骤在支持在所述加氢热解区和所述焦炭蒸汽 - 气化区之间循环的碳气化催化剂的固体存在下进行，所述蒸汽气化在不存在氧的情况下进行。 石油渣，氢气和蒸汽分别通过管线5,6和7引入。产物通过管线10排出。热量可以由辐射管4供应。
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公开(公告)号：US4044114A
公开(公告)日：1977-08-23
申请号：US641223
申请日：1975-12-16
CPC分类号： C01B17/05 , B01D53/8615 , C01B17/0408 , C01B17/0456
摘要： Process for purifying a gas containing hydrogen sulfide and sulfur dioxide, comprising substantially removing sulfur dioxide, absorbing hydrogen sulfide on a solid contact mass, intermittently regenerating said mass by means of an oxygen-containing gas, so as to produce a gas containing sulfur dioxide, and reacting the latter gas with hydrogen sulfide to produce sulfur.
摘要翻译： 用于纯化含有硫化氢和二氧化硫的气体的方法，包括基本上除去二氧化硫，在固体接触物质上吸收硫化氢，通过含氧气体间歇地再生所述物质，以产生含有二氧化硫的气体， 并使后者的气体与硫化氢反应产生硫。
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公开(公告)号：US5458675A
公开(公告)日：1995-10-17
申请号：US209498
申请日：1994-03-04
申请人： Jean Morlec , Christine Travers , Claude Dezael
发明人： Jean Morlec , Christine Travers , Claude Dezael
CPC分类号： B01D53/8668 , B01D53/0407 , B01D2253/1085 , B01D2253/25 , B01D2257/30 , B01D2257/40 , B01D2257/50 , B01D2257/90 , B01D2257/93 , B01D2259/4009 , B01D2259/402 , B01D53/02 , B01J2219/30238
摘要： The invention concerns a process for the treatment of ventilation air containing malodorous gases, e.g., styrene, involving:1. An adsorption step onto a hydrophobic zeolite containing, for example, platinum and/or palladium,2. A combustion-desorption step wherein hot gases pass over the impregnated zeolite in order to desorb the gas, e.g., styrene and burn it on the zeolite,in which the zeolite is encased in small tetrahedral-shaped containers.
摘要翻译： 本发明涉及一种处理包含恶臭气体（例如苯乙烯）的通风空气的方法，涉及：1.对含有例如铂和/或钯的疏水性沸石的吸附步骤2.一种燃烧 - 脱附步骤，其中热 气体通过浸渍的沸石以便解吸气体，例如苯乙烯并将其燃烧在沸石上，其中沸石被包裹在小的四面体形状的容器中。
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公开(公告)号：US4310497A
公开(公告)日：1982-01-12
申请号：US230174
申请日：1981-01-30
CPC分类号： B01D53/52 , C01B17/508
摘要： A process for purifying a gas containing hydrogen sulfide, wherein said gas is admixed with oxygen and contacted with a carbon mass of specific surface higher than 50 m2/g and containing at least one oxide and/or sulfate of iron and/or copper, at a temperature from 20.degree. to 170.degree. C., the operating conditions being so selected as to avoid a substantial oxidation of said mass and said mass being periodically regenerated by heating to 200.degree.-300.degree. C. in the presence of oxygen, the regenerating conditions being such as to avoid a substantial oxidation of the carbon mass.
摘要翻译： 一种纯化含有硫化氢的气体的方法，其中所述气体与氧气混合并与特定表面积高于50m2 / g并且含有至少一种铁和/或铜的氧化物和/或硫酸盐的碳质量块接触， 温度为20℃至170℃，选择操作条件以避免所述物质的实质氧化，并且所述物质通过在氧气存在下加热至200-300℃来定期再生，再生 条件是为了避免碳质量的显着氧化。
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7.发明授权Process for removing H.sub.2 S and CO.sub.2 from gases and regenerating the adsorbing solution 失效从气体中除去H {HD 2 {B S和CO（HD 2 {B）并再生吸附溶液的方法
公开(公告)号：US4163043A
公开(公告)日：1979-07-31
申请号：US889803
申请日：1978-03-24
IPC分类号： B01D53/52 , B01D53/77 , C01B17/52 , C01C1/22 , C01D1/04 , C01D1/20 , C01G3/00 , C01G3/12 , C02F1/58 , B01D53/34
摘要： H.sub.2 S and CO.sub.2 from a waste gas are absorbed in an ammoniacal or alkali metal hydroxide solution. The resultant sodium, potassium or ammonium sulfide solution is reacted with pulverized copper oxide and the resultant copper sulfide precipitate is separated and the resultant solution of increased sodium hydroxide, potassium hydroxide or ammonia content is recycled as absorbent for hydrogen sulfide and CO.sub.2. The copper sulfide is roasted to form recyclable copper oxide and product sulfur dioxide.
摘要翻译： 来自废气的H 2 S和CO 2被吸收在氨或碱金属氢氧化物溶液中。 所得的硫化钠，硫化钾或硫化铵溶液与粉碎的氧化铜反应，分离得到的硫化铜沉淀物，所得到的氢氧化钠，氢氧化钾或氨含量的溶液作为硫化氢和CO 2的吸收剂再循环。 硫化铜被焙烧以形成可回收的氧化铜和产物二氧化硫。
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8.发明授权Process for converting sulfitic solutions by means of ammonium bisulfate with SO.sub.2 production 失效通过具有“2”生产的三聚氰胺转换硫酸溶液的方法
公开(公告)号：US4146579A
公开(公告)日：1979-03-27
申请号：US840947
申请日：1977-10-11
摘要： This process avoids the disadvantages of admixing hot molten ammonium bisulfate with ammonium sulfites solutions. Overflowing hot molten ammonium bisulfate is admixed with a stream of aqueous ammonium bisulfate solution, said solution being preferably circulated in a closed loop. A portion of the resulting solution is then used to acidify the ammonium sulfites solution.
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公开(公告)号：US3943228A
公开(公告)日：1976-03-09
申请号：US419383
申请日：1973-11-27
摘要： Sulfur dioxide and ammonia remaining in waste-gas after partial purification thereof, for example by means of ammonia or ammonium sulfite solutions, are withdrawn from said gas by washing with a diluted aqueous solution of ammonium sulfate; the resulting ammonium sulfite containing solution is oxidized thereafter either by means of air or in an electrochemical cell.
摘要翻译： 通过用氨或亚硫酸铵溶液的部分纯化后残留在废气中的二氧化硫和氨通过用稀释的硫酸铵水溶液洗涤从所述气体中排出; 所得到的含亚硫酸铵的溶液随后通过空气或电化学电池被氧化。
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10.发明授权Desulphurizing catalytic composition and its use in removing hydrogen sulphide and sulphur dioxide from a gas 有权脱硫催化剂组合物及其从气体中除去硫化氢和二氧化硫的用途公开(公告)号：US06627108B1
公开(公告)日：2003-09-30
申请号：US09688388
申请日：2000-10-17
申请人： Claude Dezael , Fabrice Lecomte
发明人： Claude Dezael , Fabrice Lecomte
IPC分类号： C09K300
CPC分类号： B01D53/523 , C01B17/05
摘要： A desulphurizing composition for the treatment of CLAUS plant tail gases, comprises: an organic solvent A with a boiling point of more than 200° C. at atmospheric pressure; a catalyst composition B of at least one alkali- or alkaline-earth salt (S) of an organic monoacid or an organic polyacid which has at least one dissociation constant value (pK) in the range 2.2 to 8 such as formic acid, acetic acid, ascorbic acid, fumaric acid, maleic acid, malonic acid, oxalic acid, tartaric acid, benzoic acid, salicyclic acid, and sulphosalicyclic acid; at least one complexing agent (C) such as an alkali or alkaline-earth salt or a ferrous or ferric salt of a mono- or poly-aminocarboxylic acid, citric acid, a sulphocyanide ion, a ferrocyanide ion, a ferricyanide ion, a phosphate ion, a pyrophosphate ion, a fluoride ion and/or a thiosulphate ion; and water (W), in the following proportions by weight: S=0.1% to 30%; C=0.001% to 30%; W=balance.
摘要翻译： 一种用于处理CLAUS植物尾气的脱硫组合物，包括：在大气压下沸点大于200℃的有机溶剂A;至少一种碱金属或碱土金属盐（S ）有机一元酸或有机多酸，其具有至少一个解离常数值（pK）在2.2至8的范围内，例如甲酸，乙酸，抗坏血酸，富马酸，马来酸，丙二酸，草酸，酒石酸 酸，苯甲酸，水杨酸和磺基脂环酸; 至少一种络合剂（C）如碱金属或碱土金属盐或单或多氨基羧酸，柠檬酸，亚砷氰酸根离子，亚铁氰化物离子，铁氰化物离子，磷酸根离子的亚铁或铁盐 离子，焦磷酸根离子，氟离子和/或硫代硫酸根离子; 和水（W），以下列重量比：S = 0.1％至30％; C = 0.001％至30％; W =余量。
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