摘要:
The present invention relates to an aqueous blocked polyurethaneurea dispersion which is obtainable by reacting at least one polyisocyanate, one blocking agent for isocyanate groups, one polyamine having at least one carboxyl and/or carboxylate group, and water. Additionally provided by the invention are a coating composition comprising the aqueous blocked polyurethaneurea dispersion, the use of the aqueous blocked polyurethaneurea dispersion or of the coating composition for producing a coating, a coating obtainable using the aqueous blocked polyurethaneurea dispersion or the coating composition, and a method for producing the aqueous blocked polyurethaneurea dispersion.
摘要:
The invention concerns a compound of formula (I) in which m is to 0 or 1 Iso is the (poly)isocyanate radical (after elimination of an isocyanate function); R10 is selected among: a negative charge; a hydrocarbon-based radical (i.e. a residue containing hydrogen and carbon atoms) having a carbon as it binding point [i.e. the atom carrying the open bond]; R11 is selected among a negative charge. The invention is applicable to organic synthesis.
摘要:
The present invention relates to a process for preparing leather by (I) tanning a pelt with (a) an aldehyde, or (b) a bisulphite-blocked polyisocyanate; (II) optionally, retanning the pelt with (a) a polyaspartic acid, a salt of a polyaspartic acid, a polyaspartic acid anhydride, or a mixture thereof, and/or (b) a polyaspartamide; (III) dressing the resultant product by (a) bottoming the product with a polyurethane and one or more natural bottoming assistants, and (b) applying a polyurethane and/or polyesteramide finish; and (IV) optionally, aftertreating the resultant dressed leather with a leather preservative.
摘要:
This invention relates to a process for the preparation of aqueous emulsions of blocked (poly)isocyanates, this process comprising the steps consisting successively in: a) placing an isocyanate composition containing free isocyanate functions in contact with at least one blocking agent A in the presence of a surfactant B and an aqueous phase, the said isocyanate composition being added gradually to a stock containing at least some of the aqueous phase and at least some of the blocking agent; and optionally, b) subjecting the mixture obtained to a shear (speed gradient) of greater than 1000 s−1, preferably greater than 20,000 s−1 and less than 1,000,000 s−1, preferably less than 200,000 s−1, and c) repeating step b), optionally after step a) has been repeated, until a stable emulsion is obtained whose particles have a Sauter diameter of greater than 0.1 μm, preferably 0.2 μm, and less than 5 μm, preferably less than 2 μm, and a dispersion width of less than 5 μm.
摘要:
Microcapsules having a hydrophobic core material and capsule walls formed by the reaction of water-insoluble polyamines with water-soluble bisulphite adducts of polyisocyanates, a process for the production thereof which is characterized in that a mixture of a hydrophobic core material and water-insoluble polyamines is emulsified in water or in an aqueous protective colloid solution to the required particle size, water-soluble bisulphite adducts of polyisocyanates in the form of powders or aqueous solutions are added and the mixture is left to react to completion at temperatures of from 1.degree. to 140.degree. C., and applications thereof.
摘要:
A polyisocyanate modified with sulphamic acid and a mixture thereof, the preparation method thereof, and the use thereof in the production of polyurethane, especially as a cross-linking ingredient in the field of aqueous coatings and adhesives containing groups that are capable of reacting with isocyanate groups.
摘要:
An insulated structure is formed by injection of a foamed thermal-insulating material created by foaming into a space between a plastic board and metal plate with a disposition of copper pipes. A non-halogenated organophosphorus compound having a molecular weight over 150 as an additive with an OH group as a functional group is mixed with the raw materials of the foamed thermal-insulating material including polyol, a foam stabilizer, a catalyst, a foaming agent having at least one component of hydrocarbon, and an organic polyisocyanates. By adding a non-halogenated organophosphorus compound, which has a molecular weight over 150 as an additive with an OH group as a functional group, the burning rate of the foamed thermal-insulating material becomes the same as that of the foamed thermal-insulating material which uses CFC11 as a foaming agent. Also, the possibilities of phosphor corrosion by free ionization to copper pipes, which are disposed inside of the insulated structure, are eliminated and phosphorus transfer to the plastic board and worries of food contamination are also eliminated.
摘要:
The invention concerns a compound of formula (I) 1 in which m is to 0 or 1 Iso is the (poly)isocyanate radical (after elimination of an isocyanate function); R10 is selected among: a negative charge; a hydrocarbon-based radical (i.e. a residue containing hydrogen and carbon atoms) having a carbon as it binding point nulli.e. the atom carrying the open bondnull; R11 is selected among a negative charge. The invention is applicable to organic synthesis.
摘要:
In an example, a process of forming a flame-retardant polyurethane material includes chemically reacting a polyisocyanate (that includes at least three isocyanate groups) with a phosphonate that includes at least one hydroxyl group to form a polyisocyanate-phosphonate compound. The process also includes forming a mixture that includes the polyisocyanate-phosphonate compound and a polyol. The process further includes polymerizing the mixture to form a flame-retardant polyurethane material.