摘要:
Herein disclosed are apparatus and associated methods related to producing an enhanced surface area biochar product with a desired activation level based on receiving biochar into a processing vessel configured with multiple independently temperature-controlled chambers and counter-flow steam injection, controlling activation levels of the biochar by moving the biochar through the processing vessel and adjusting the temperature of the biochar by injecting steam into at least one temperature-controlled chamber of the processing vessel, recovering volatiles driven off through dehydration using a thermal oxidizer, cooling the biochar to a desired discharge temperature using steam and retention time, and discharging the activated biochar product. The processing vessel may be a calciner, a rotary calciner, or a kiln. Biochar may be heated or cooled to a desired thermochemical processing temperature depending on the temperature of the received biochar. Counter-flow saturated steam may sweep volatile gases to a thermal oxidizer using a vacuum system.
摘要:
Herein disclosed are apparatus and associated methods related to producing an enhanced surface area biochar product with a desired activation level based on receiving biochar into a processing vessel configured with multiple independently temperature-controlled chambers and counter-flow steam injection, controlling activation levels of the biochar by moving the biochar through the processing vessel and adjusting the temperature of the biochar by injecting steam into at least one temperature-controlled chamber of the processing vessel, recovering volatiles driven off through dehydration using a thermal oxidizer, cooling the biochar to a desired discharge temperature using steam and retention time, and discharging the activated biochar product. The processing vessel may be a calciner, a rotary calciner, or a kiln. Biochar may be heated or cooled to a desired thermochemical processing temperature depending on the temperature of the received biochar. Counter-flow saturated steam may sweep volatile gases to a thermal oxidizer using a vacuum system.
摘要:
The organic matter carbonization process is based on thermal treatment at high temperatures, under a controlled atmosphere, if possible in the absence of oxygen. The organic matter carbonization theory was expounded in this text, with emphasis on the thermodynamic aspects. It is shown in this exposition the important misfit between the endothermic and the exothermic carbonization stages, which hinders the use of the energy emitted during the exothermic stage by the brick kilns. Following there is a summary of the carbonization technique actual stage. The present invention relates to a method and plant for the thermal treatment of organic matter comprising independent reactors for the drying and pyrolysis of organic matter, and an independent reactor for the charcoal cooling. In this method the volatile products—non condensable gases and condensable pyrolytic vapors—are burned in an independent combustion chamber in order to supply the energy demanded by the process. In this way wood is not burned, and polluting substances are not emitted to the atmosphere. The method proposed by the present invention allows a precise control of the process in order to obtain the specified charcoal fixed carbon content; and a higher gravimetric yield, which gives an increase of the forest wood, either native or cultivated. In the independent pyrolysis and drying reactors proposed by the present invention, exiting flue gases from an external combustion chamber are driven to the drying reactor where the wood onto roll on buckets are heated and dried. Fuel gases emitted by the carbonizing wood are burned in the combustion chamber as an energy source. Inside the combustion chamber is placed a heat exchanger with the aim to reheat the pyrolytic gases. After reheated, these gases return to the carbonizing reactor in order to supply energy for the endothermic carbonizing step. The aim of this technique is to avoid the mixing of the fuel gases with the flue gases generated inside the combustion chamber, and to precisely control the carbonizing temperature. The present invention allows the production of intermediate products between wet wood and charcoal by halting the carbonization process at the desired stage in order to obtain anhydrous wood, char or, or high volatile content charcoal. The basic concepts of the process are: 1—Utilization of the emitted gases by the carbonizing wood as an energy source. 2—The stages of wood drying, wood pyrolysis and charcoal cooling are performed in independent reactors, inside which only one of these stages occurs. 3—Energy supply during the carbonizing endothermic stage of the pyrolysis by the gases emitted during this stage after reheated in a heat exchanger. Basically the present invention comprises the following equipments: 1—Reaction chambers inside which the process stages are performed. 2—An external combustion chamber. 3—A heat exchanger inside said combustion chamber. 4—A set of pipes. 5—A set of fans. 6—A loading system comprising roll on buckets.
摘要:
A selenium-containing aqueous stream may be used as a quenching water stream and optionally a cutting water stream in a delayed coking process to effectuate the removal of selenium from the selenium-containing aqueous stream resulting in the formation of a selenium-coke product. In addition, selenium may be concentrated in selenium-containing stripped sour water streams by recycling the stream in one or more hydroprocessing units and one or more sour water stripper units and subsequently removed by using a portion of the selenium-containing stripped sour water stream as a quenching water stream and optionally a cutting water stream in a delayed coking process.
摘要:
Cooling water for cooling coke in a coking drum is charged into the interior of the coking drum from a plurality of orifices located on the lateral surfaces of the coking drum so as to uniformly distribute the cooling effect provided by the cooling water.
摘要:
Methods and apparatus for compact and easily maintainable waste reformation. Some embodiments include a rotary oven reformer adapted and configured to provide synthesis gas from organic waste. Some embodiments include a rotary oven with simplified operation both as to reformation of the waste, usage of the synthesized gas and other products, and easy removal of the finished waste products, preferably in a unit of compact size for use in austere settings. Yet other embodiments include Fischer-Tropsch reactors of synthesized gas. Some of these reactors include heat exchanging assemblies that provide self-cleaning effects, efficient utilization of waste heat, and ease of cleaning.
摘要:
The present technology is generally directed to coal charging systems used with coke ovens. In some embodiments, a coal charging system includes a charging head having opposing wings that extend outwardly from the charging head, leaving an open pathway through which coal may be directed toward side edges of the coal bed. In other embodiments, an extrusion plate is positioned on a rearward face of the charging head and oriented to engage and compress coal as the coal is charged along a length of the coking oven. In other embodiments, charging plates extend outwardly from inward faces of opposing wings.
摘要:
The present technology is generally directed to methods of increasing coke production rates for coke ovens. In some embodiments, a coal charging system includes a false door system with a false door that is vertically oriented to maximize an amount of coal being charged into the oven. A lower extension plate associated with embodiments of the false door is selectively, automatically extended beyond a lower end portion of the false door in order to extend an effective length of the false door. In other embodiments an extension plate may be coupled with an existing false door having an angled front surface to provide the existing false door with a vertically oriented face.
摘要:
A closed system for gaining sellable petroleum coke pieces out of solidified petroleum coke in a coke drum unit, comprises a coke drum unit containing solidified petroleum coke; a coke crushing unit for crushing petroleum coke into sellable petroleum coke pieces; a closed slurry pipe leading petroleum coke slurry to a closed slurry pit; a dewatering bin unit for receiving petroleum coke slurry from the slurry pit, for collecting the sellable petroleum coke pieces and for leading filtered water and petroleum coke fines out of it; a closed drain water pit, separate from the slurry pit, for receiving the filtered water and the petroleum coke fines from the dewatering bin unit; a water settling tank receiving the filtered water and the petroleum coke from the drain water pit and for separating the petroleum coke fines from the water such that the petroleum coke fines collect in the bottom part of the water settling tank, and for leading the petroleum coke fines into the slurry pit where they mix with the petroleum coke slurry; a clean water tank for receiving the purified water from the upper part of the water settling tank; and a removal unit for removing the sellable petroleum coke pieces from the dewatering bin unit.
摘要:
A process and apparatus for improving the production of coke having a high volatile combustible material content are disclosed. The process may include, for example: heating a coker feedstock to a coking temperature to produce a heated coker feedstock; contacting the heated coker feedstock with a quench medium to reduce a temperature of the heated coker feedstock and produce a quenched feedstock; feeding the quenched feedstock to a coking drum; subjecting the quenched feedstock to thermal cracking in the coking drum to (a) crack a portion of the quenched feedstock to produce a cracked vapor product, and (b) produce a coke product having a volatile combustible material (VCM) concentration in the range from about 13% to about 50% by weight, as measured by ASTM D3175.