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    Process for sulfiding an additive-containing catalyst
    1.
    发明授权
    Process for sulfiding an additive-containing catalyst 有权
    用于硫化含添加剂的催化剂的方法

    公开(公告)号：US06753291B2

    公开(公告)日：2004-06-22

    申请号：US09829638

    申请日：2001-04-10

    申请人： Sonja Eijsbouts ,  Frans Lodewijk Plantenga ,  Pierre Dufresne ,  Franck Labruyere ,  Leendert Arie Gerritsen

    发明人： Sonja Eijsbouts ,  Frans Lodewijk Plantenga ,  Pierre Dufresne ,  Franck Labruyere ,  Leendert Arie Gerritsen

    IPC分类号： B01J2702

    CPC分类号： B01J31/0254 ,  B01J23/85 ,  B01J27/188 ,  B01J31/0202 ,  B01J31/0205 ,  B01J31/0218 ,  B01J31/0237 ,  B01J37/20 ,  C10G45/08 ,  C10G2300/705

    摘要： The present invention pertains to a process for sulfiding a catalyst composition comprising at least one hydrogenation metal component of Group VI and/or Group VIII of the Periodic Table, and an organic additive wherein the catalyst composition is first contacted with an organic liquid, followed by the catalyst being contacted with hydrogen and a sulfur-containing compound in the gaseous phase, wherein less than about 40%, preferably less than about 35%, more preferably less than about 25%, most preferably less than about 15%, of the sulfur present in the sulfided catalyst is added with the organic liquid. The process of the present invention makes it possible to use additive-containing catalysts without loss of activity in units which cannot effect gas phase start-up or are required to carry out a pressure test. The organic liquid may be a hydrocarbon with a boiling range of about 150-500° C., preferably gasoline, white spirit, diesel, gas oil, mineral lube oil, or white oil. The step of contacting the catalyst with hydrogen and a sulfur-containing compound may take place in one step at a temperature of about 150-450° C. It may also take place in two steps, with the first step being performed at a temperature which is lower than that of the second step, with the first step being carried out at a temperature of about 100-250° C. and the second step at a temperature of about 150-450° C.

    摘要翻译： 本发明涉及一种硫化催化剂组合物的方法，该催化剂组合物包含至少一种元素周期表第VI族和/或第Ⅷ族氢化金属组分和一种有机添加剂，其中催化剂组合物首先与有机液体接触， 催化剂在气相中与氢气和含硫化合物接触，其中少于约40％，优选小于约35％，更优选小于约25％，最优选小于约15％的硫 存在于硫化催化剂中的有机液体中加入。 本发明的方法使得可以在不能实现气相启动或需要进行压力试验的单位中使用不含活性的添加剂的催化剂。 有机液体可以是沸点为约150-500℃的烃，优选汽油，白酒，柴油，瓦斯油，矿物润滑油或白油。 使催化剂与氢气和含硫化合物接触的步骤可以在约150-450℃的温度下在一个步骤中进行。它也可以在两个步骤中进行，第一步是在 低于第二步骤，第一步骤在约100-250℃的温度下进行，第二步在约150-450℃的温度下进行。

    Process for sulfiding catalyst in a column
    2.
    发明授权
    Process for sulfiding catalyst in a column 失效

    公开(公告)号：US06503864B2

    公开(公告)日：2003-01-07

    申请号：US09779759

    申请日：2001-02-08

    申请人： Mitchell E. Loescher ,  Gary G. Podrebarac ,  Purvis K. Ho

    发明人： Mitchell E. Loescher ,  Gary G. Podrebarac ,  Purvis K. Ho

    IPC分类号： B01J2702

    CPC分类号： C10G45/04 ,  B01J37/20

    摘要： A process for the sulfiding of a hydrodesulfurization catalyst for example in a distillation column reactor. The catalyst in the distillation column reactor is first dried using nitrogen and the reactor is filled with a sulfiding solvent and circulation begun. The reactor is heated to a temperature above the decomposition temperature of the sulfiding agent to be used and the sulfiding agent charged to the reactor. When sulfiding agent breakthrough is noted in the overheads the temperature is raised and held until sulfiding is complete.

    Process for sulfiding a catalyst containing an S-containing additive
    3.
    发明授权
    Process for sulfiding a catalyst containing an S-containing additive 有权

    公开(公告)号：US06509291B2

    公开(公告)日：2003-01-21

    申请号：US09829624

    申请日：2001-04-10

    申请人： Sonja Eijsbouts

    发明人： Sonja Eijsbouts

    IPC分类号： B01J2702

    CPC分类号： B01J31/04 ,  B01J23/85 ,  B01J31/0217 ,  B01J31/28 ,  B01J37/20 ,  C10G45/08

    摘要： The present invention pertains to a process for sulfiding a catalyst composition comprising at least one hydrogenation metal component of Group VI and/or Group VIII of the Periodic Table, and an S-containing organic additive wherein the catalyst composition is first contacted with an organic liquid, followed by the catalyst being contacted with hydrogen and a sulfur-containing compound in the gaseous phase. The invention also pertains to the sulfided catalyst composition and its use in hydrotreating. Catalysts sulfided by the process according to the invention show a higher activity than the same catalysts which have not been sulfided. It is preferred to carry out the process according to the invention ex situ, where it solves the problem of difficult start-up and the formation of undesirable side products in the hydrotreating unit. The organic liquid may be a hydrocarbon with a boiling range of about 150-500° C., preferably white oil, gasoline, diesel, gas oil, or mineral lube oil. The S-containing organic additive preferably is a mercapto-compound, more preferably a mercaptocarboxylic acid represented by the general formula HS—R1—COOR, wherein R1 stands for a divalent hydrocarbon group with 1- about 10 carbon atoms and R stands for a hydrogen atom, an alkali metal, an alkaline earth metal, ammonium, or a linear or branched alkyl group having 1 to about 10 carbon atoms.

    Method for pre-sulphurization of catalysts
    5.
    发明授权
    Method for pre-sulphurization of catalysts 失效
    催化剂预硫化方法

    公开(公告)号：US06288006B1

    公开(公告)日：2001-09-11

    申请号：US09341652

    申请日：1999-09-22

    申请人： Emmanuel Arretz

    发明人： Emmanuel Arretz

    IPC分类号： B01J2702

    CPC分类号： B01J37/20 ,  B01J23/882

    摘要： For the presulphurization of catalysts based on metal oxides, intended especially for the hydrotreating of hydrocarbon feedstocks, at least one tertiary mercaptan (for example tert-dodecyl mercaptan) is employed as sulphurizing agent. This tertiary mercaptan can be employed alone or combined with another sulphur-donor compound. The presulphurization according to the invention may be carried out in situ or ex situ.

    摘要翻译： 对于基于金属氧化物的催化剂的预硫化，特别用于烃原料的加氢处理，至少使用一种叔硫醇（例如叔十二烷基硫醇）作为硫化剂。该叔硫醇可单独使用或与另一种硫 - 给体化合物。根据本发明的预硫化可以在原位或非原位进行。

    Process for sulphurizing catalysts in the presence of carbon and elemental sulphur
    7.
    发明授权
    Process for sulphurizing catalysts in the presence of carbon and elemental sulphur 有权
    在碳和元素硫存在下硫化催化剂的方法

    公开(公告)号：US06242378B1

    公开(公告)日：2001-06-05

    申请号：US09344349

    申请日：1999-06-25

    申请人： Slavik Kasztelan

    发明人： Slavik Kasztelan

    IPC分类号： B01J2702

    CPC分类号： B01J37/20 ,  C10G45/04 ,  C10G47/06

    摘要： The invention concerns a process for sulphurising supported catalysts containing at least one element selected from group IIIB, including the lanthanides and actinides, group IVB and group VB, said process being characterized in that said catalyst is sulphurised using a mixture containing at least one source of elemental sulphur and at least one source of carbon in an autogenous or inert atmosphere. Also disclosed are sulphurised catalysts obtained by the process of the invention, the use of the catalysts in processes for hydrocracking and hydrotreatment of hydrocarbon-containing feeds.

    摘要翻译： 本发明涉及一种用于硫化载体催化剂的方法，所述催化剂含有至少一种选自IIIB族的元素，包括镧系元素和锕系元素，IVB族和VB族，所述方法的特征在于所述催化剂使用含至少一种 元素硫和自发或惰性气氛中的至少一种碳源。 还公开了通过本发明的方法获得的硫化催化剂，在含烃进料的加氢裂化和加氢处理方法中使用催化剂。

    Method of preserving sulfonic acid-type cation-exchange resin modified with thiol-containing amine compound
    8.
    发明授权
    Method of preserving sulfonic acid-type cation-exchange resin modified with thiol-containing amine compound 有权
    用含硫醇的胺化合物改性的磺酸型阳离子交换树脂的保存方法

    公开(公告)号：US06696385B2

    公开(公告)日：2004-02-24

    申请号：US10436282

    申请日：2003-05-13

    申请人： Koichi Hayashi ,  Hideto Hayashi

    发明人： Koichi Hayashi ,  Hideto Hayashi

    IPC分类号： B01J2702

    CPC分类号： B01J47/14 ,  B01J39/18 ,  B01J47/016 ,  Y10S502/514

    摘要： The present invention aims at inhibiting a lowering in the modification ratio of a modified cation-exchange resin, in which part of the sulfonic acid groups have been modified with a thiol-containing amine compound and which is employed as a catalyst for producing bisphenol, during preservation. In the present invention, a modified cation-exchange resin is packed together with water into a container while regulating the surface area of the container to 0.5 m2 or less per liter of the resin and then the container is sealed up so that the resin is preserved in a state of being soaked in water.

    摘要翻译： 本发明的目的在于抑制改性阳离子交换树脂的改性率的降低，其中部分磺酸基已被含硫醇的胺化合物改性，并且用作生产双酚的催化剂 保存。 在本发明中，将改性阳离子交换树脂与水一起包装在容器中，同时将容器的表面积调节为每升树脂0.5m 2以下，然后将容器密封， 树脂被保存在浸泡在水中的状态。

    Process for sulfurizing catalysts in a reducing medium
    9.
    发明授权
    Process for sulfurizing catalysts in a reducing medium 有权
    在还原介质中使催化剂硫化的方法

    公开(公告)号：US06432867B1

    公开(公告)日：2002-08-13

    申请号：US09344351

    申请日：1999-06-25

    申请人： Slavik Kasztelan

    发明人： Slavik Kasztelan

    IPC分类号： B01J2702

    CPC分类号： C10G49/02 ,  B01J23/10 ,  B01J23/20 ,  B01J23/83 ,  B01J23/8474 ,  B01J37/20

    摘要： Sulfided catalysts produced by sulfurizing supported catalysts containing at least one element selected from group IIIB, including the lanthanides and actinides, group IVB and group VB, wherein the catalyst is brought into contact with at least one source of elemental sulfur e.g. flowers of sulfur in an atmosphere of at least one reducing gas other than hydrogen e.g. carbon monoxide. The catalyst is suitable for converting hydrocarbon-containing feeds, such as hydrocracking and hydrotreatment.

    摘要翻译： 通过使含有至少一种选自IIIB族的元素，包括镧系元素和锕系元素，IVB族和VB族的硫化负载催化剂生产的硫化催化剂，其中催化剂与至少一种元素硫源接触。 在除氢之外的至少一种还原气体的气氛中的硫的花例如 一氧化碳。 该催化剂适用于转化含烃进料，如加氢裂化和加氢处理。