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    Catalyst activator
    1.
    发明授权
    Catalyst activator 失效
    催化剂活化剂

    公开(公告)号：US06794329B2

    公开(公告)日：2004-09-21

    申请号：US10301377

    申请日：2002-11-21

    Applicant: Wei Xu

    Inventor： Wei Xu

    IPC: B01J3114

    CPC classification number: C08F10/02 ,  C08F4/65908 ,  C08F4/65916 ,  C08F4/6592 ,  C08F110/02 ,  C08F210/16 ,  C08F4/65912

    Abstract: A two component catalyst activator comprises: 1) a Lewis acidic organoboron (or an orgonoaluminum) component; and 2) a component defined by the formula AOSO2R wherein A is a pseudo cationic group and R is a hydrocarbyl or substituted hydrocarbyl. The catalyst activator is used in combination with a transition metal catalyst for the polymerization of olefins. The catalyst activator provides improved catalyst activities. It is especially useful in solution polymerizations because of desirable solubility characteristics in comparison to the borate salts used in prior activators.

    Abstract translation: 双组分催化剂活化剂包括：1）路易斯酸性有机硼（或羟基铝）组分; 和2）由式AOSO2R定义的组分，其中A是假阳离子基团，R是烃基或取代的烃基。 催化剂活化剂与用于烯烃聚合的过渡金属催化剂组合使用。 催化剂活化剂提供改进的催化剂活性。 与在现有的活化剂中使用的硼酸盐相比，由于具有理想的溶解度特性，因此在溶液聚合中特别有用。

    Metallocene catalyst systems
    2.
    发明授权
    Metallocene catalyst systems 失效
    茂金属催化剂体系

    公开(公告)号：US06184170B2

    公开(公告)日：2001-02-06

    申请号：US09565854

    申请日：2000-05-05

    Applicant: Main Chang

    Inventor： Main Chang

    IPC: B01J3114

    CPC classification number: C08F10/00 ,  C08F4/65916 ,  C08F4/65927 ,  Y10S526/943 ,  C08F4/65912

    Abstract: This invention relates generally to metallocene catalyst systems and to methods for their production and use. Specifically, this invention relates to a method for preparing metallocene catalyst systems using olefin additives which promote catalyst activity.

    Abstract translation: 本发明一般涉及茂金属催化剂体系及其生产和使用方法。 具体地说，本发明涉及使用促进催化剂活性的烯烃添加剂制备茂金属催化剂体系的方法。

    High activity carbenium-activated polymerization catalysts
    3.
    发明授权
    High activity carbenium-activated polymerization catalysts 有权
    高活性碳腈活化聚合催化剂

    公开(公告)号：US06486088B1

    公开(公告)日：2002-11-26

    申请号：US09694142

    申请日：2000-10-23

    Applicant: Donna Jean Crowther ,  Bernard Jean Folie

    Inventor： Donna Jean Crowther ,  Bernard Jean Folie

    IPC: B01J3114

    CPC classification number: C08F10/00 ,  C07F17/00 ,  C08F4/65908 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2/06 ,  C08F2500/03 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/04

    Abstract: This application discloses triphenyl carbenium NCA's as catalyst activators for a class of asymmetrically bridged hafnocene catalyst precursors. These catalsyst precursors are activated into olefin polymerization catalysts and are suitable for gas, solution, and slurry-phase polymerization reactions. The disclosed bridge is methylenyl- or silanylenyl-based and is optionally, alkyl or aryl substituted. The catalytic activity of the disclosed hafnocene catalyt precursors is substantially enhanced over identical catalysts that are activated with other activators.

    Abstract translation: 该申请公开了三苯基碳鎓NCA作为一类不对称桥联的茂金属催化剂前体的催化剂活化剂。 这些催化剂前体被活化成烯烃聚合催化剂，适用于气体，溶液和淤浆相聚合反应。 所公开的桥是亚甲基或甲硅烷基基，并且任选地被烷基或芳基取代。 所公开的下氢催化剂前体的催化活性通过用其它活化剂活化的相同催化剂显着增强。

    Catalyst activators
    4.
    发明授权
    Catalyst activators 失效
    催化剂活化剂

    公开(公告)号：US06232261B1

    公开(公告)日：2001-05-15

    申请号：US09354270

    申请日：1999-07-15

    Applicant: Ian Raymond Little

    Inventor： Ian Raymond Little

    IPC: B01J3114

    CPC classification number: C08F10/02 ,  C08F4/65904 ,  C08F4/65916 ,  C08F4/6592 ,  C08F210/16 ,  C08F4/65912 ,  C08F4/6465 ,  C08F210/14

    Abstract: A catalyst system suitable for the polymerization of olefins comprising an olefin polymerization catalyst and an activator comprising the reaction product of (i) an aluminoxane or (ii) the reaction product of an alkylaluminum and water with a silicon-containing compound, for example diphenylsilane diol. Preferred catalysts are metallocene complexes. The activators provide an alternative to the traditional use of aluminoxanes alone.

    Abstract translation: 一种适用于烯烃聚合的催化剂体系，包括烯烃聚合催化剂和活化剂，其包含（i）铝氧烷或（ii）烷基铝和水与含硅化合物的反应产物如二苯基硅烷二醇 。 优选的催化剂是茂金属络合物。 活化剂为传统使用铝氧烷单独提供了替代方案。

    High activity ziegler-natta catalyst for high molecular weight polyolefins
    5.
    发明授权
    High activity ziegler-natta catalyst for high molecular weight polyolefins 失效
    用于高分子量聚烯烃的高活性齐格勒 - 纳塔催化剂

    公开(公告)号：US06723677B1

    公开(公告)日：2004-04-20

    申请号：US09891632

    申请日：2001-06-25

    Applicant: Jesus Vela Estrada ,  Vaclav George Zboril

    Inventor： Jesus Vela Estrada ,  Vaclav George Zboril

    IPC: B01J3114

    CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F4/6555 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/03 ,  C08F210/08 ,  C08F210/14

    Abstract: By controlling the hold up times, concentrations and temperatures for mixing the components of aluminum, titanium and magnesium based catalyst for solution polymerization it is possible to prepare a catalyst having a high activity, which prepares high molecular weight polyolefins. Generally, a catalyst loses activity and produces lower molecular weight polymer at higher temperatures. The catalyst of the present invention permits comparable polymers to be produced with higher catalyst activity and at higher reaction temperatures by increasing the concentration of the components used during the preparation of the catalyst.

    Abstract translation: 通过控制用于混合铝，钛和镁基催化剂组分的保持时间，浓度和温度用于溶液聚合，可以制备具有高活性的催化剂，其制备高分子量聚烯烃。 通常，催化剂在较高温度下失去活性并产生较低分子量的聚合物。 本发明的催化剂允许以更高的催化剂活性和在较高的反应温度下生产可比较的聚合物，通过增加在制备催化剂期间使用的组分的浓度。

    Aluminoxane modification
    6.
    发明授权
    Aluminoxane modification 有权
    氧化铝修饰

    公开(公告)号：US06710005B1

    公开(公告)日：2004-03-23

    申请号：US10410850

    申请日：2003-04-10

    Applicant: Shao-Hua Guo ,  Shaotian Wang

    Inventor： Shao-Hua Guo ,  Shaotian Wang

    IPC: B01J3114

    CPC classification number: B01J31/2295 ,  B01J31/143 ,  B01J31/1616 ,  B01J2531/48 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/02 ,  Y10S526/943 ,  C08F4/65912 ,  C08F2500/12

    Abstract: A modified aluminoxane is disclosed. Aluminoxane compounds are modified with glycol ethers or polyethers. The modified aluminoxanes are effective activators for single-site catalysts. Catalyst activated with the modified aluminoxane produces polyolefin with increased melt flow index, broadened molecular weight distribution, and improved thermal processability.

    Abstract translation: 公开了一种改性的铝氧烷。 氧化铝化合物用二醇醚或聚醚改性。 改性铝氧烷是单中心催化剂的有效活化剂。 用改性铝氧烷活化的催化剂产生具有增加的熔体流动指数，扩大的分子量分布和改进的热加工性的聚烯烃。

    Three coordinate aluminum catalyst activator composition
    9.
    发明授权
    Three coordinate aluminum catalyst activator composition 有权
    三配位铝催化剂活化剂组成

    公开(公告)号：US06528449B1

    公开(公告)日：2003-03-04

    申请号：US09702442

    申请日：2000-10-31

    Applicant: Eugene Y. Chen ,  William J. Kruper, Jr. ,  Gordon R. Roof ,  David J. Schwartz ,  Joey W. Storer

    Inventor： Eugene Y. Chen ,  William J. Kruper, Jr. ,  Gordon R. Roof ,  David J. Schwartz ,  Joey W. Storer

    IPC: B01J3114

    CPC classification number: C08F10/00 ,  C07F5/062 ,  C07F5/066 ,  C08F4/6592 ,  C08F4/65927 ,  C08F110/06 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/642 ,  C08F4/65912 ,  C08F210/14 ,  C08F2500/12

    Abstract: Catalyst compositions useful for olefin polymerizations comprising a Group 3-10 metal complex and a compound corresponding to the formula: AlArfQ1Q2, or a dimer, adduct, or mixture thereof and further mixtures with aluminum compounds of the formula AlArf3, where: Arf is a fluorinated aromatic hydrocarbyl moiety of from 6 to 30 carbon atoms; Q1 is Arf or a C1-20 hydrocarbyl group, optionally substituted with one or more cyclohydrocarbyl, hydrocarbyloxy, hydrocarbylsiloxy, hydrocarbylsilylamino, hydrocarbylsilyl, silylhydrocarbyl, di(hydrocarbylsilyl)amino, hydrocarbylamino, di(hydrocarbyl)amino, di(hydrocarbyl)phosphino, or hydrocarbylsulfido groups having from 1 to 20 atoms other than hydrogen, or, further optionally, such substituents may be covalently linked with each other to form one or more fused rings or ring systems; and Q2 is an aryloxy, arylsulfide or di(hydrocarbyl)amido group, optionally substituted with one or more hydrocarbyl, cyclohydrocarbyl, hydrocarbyloxy, hydrocarbylsiloxy, hydrocarbylsilylamino, hydrocarbylsilyl, silylhydrocarbyl, di(hydrocarbylsilyl)amino, hydrocarbylamino, di(hydrocarbyl)amino, di(hydrocarbyl)phosphino, or hydrocarbylsulfido groups having from 1 to 20 atoms other than hydrogen, or, further optionally such substituents may be covalently linked with each other to form one or more fused rings or ring systems, said Q2 having from 3 to 20 atoms other than hydrogen are useful as activators for olefin polymerizations.

    Abstract translation: 用于烯烃聚合的催化剂组合物，其包含3-10金属络合物和对应于式AlArfQ1Q2的化合物或其二聚体，加合物或其混合物，以及与式AlArf 3的铝化合物的其它混合物，其中：Arf是氟化 6至30个碳原子的芳族烃基部分; Q 1是Arf或C 1-20烃基，任选地被一个或多个环烃基，烃氧基，烃基甲硅烷氧基，烃基甲硅烷基氨基，烃基甲硅烷基，甲硅烷基烃基，二（烃基甲硅烷基）氨基，烃基氨基，二 烃基）氨基，二（烃基）膦基或具有除氢以外的1至20个原子的烃基硫基，或者进一步任选地，这些取代基可以彼此共价连接以形成一个或多个稠环或环系; 环烷氧基，烃基甲硅烷氧基，烃基甲硅烷基氨基，烃基甲硅烷氧基，烃基甲硅烷基氨基，烃基甲硅烷基，甲硅烷基烃基，二（烃基甲硅烷基）氨基，烃基氨基，二（烃基）氨基，二（烃基）氨基， 烃基）膦基或具有除氢之外的1至20个原子的烃基硫基，或者进一步任选地，这些取代基可以彼此共价连接以形成一个或多个稠环或环系，所述Q2具有3至20个原子的其它 氢可用作烯烃聚合的活化剂。

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