Activator composition comprising aluminum compound mixture
    1.
    发明授权
    Activator composition comprising aluminum compound mixture 有权
    包含铝化合物混合物的活化剂组合物

    公开(公告)号:US06211111B1

    公开(公告)日:2001-04-03

    申请号:US09330675

    申请日:1999-06-11

    IPC分类号: B01J3100

    摘要: Compositions comprising: A) an aluminum compound corresponding to the formula AlArf3, where Arf is a fluorinated aromatic hydrocarbyl moiety of from 6 to 30 carbon atoms; B) an aluminum compound corresponding to the formula: AlArfQ1Q2, or a dimer, adduct, or mixture thereof; where: Arf is as previously defined; Q1 is Arf or a C1-20 hydrocarbyl group, optionally substituted with one or more cyclohydrocarbyl, hydrocarbyloxy, hydrocarbylsiloxy, hydrocarbylsilylamino, hydrocarbylsilyl, silylhydrocarbyl, di(hydrocarbylsilyl)amino, hydrocarbylamino, di(hydrocarbyl)amino, di(hydrocarbyl)phosphino, or hydrocarbylsulfido groups having from 1 to 20 atoms other than hydrogen, or, further optionally, such substituents may be covalently linked with each other to form one or more fused rings or ring systems; and Q2is an aryloxy, arylsulfide or di(hydrocarbyl)amido group, optionally substituted with one or more hydrocarbyl, cyclohydrocarbyl, hydrocarbyloxy, hydrocarbylsiloxy, hydrocarbylsilylamino, hydrocarbylsilyl, silyhydrocarbyl, di(hydrocarbylsilyl)amino, hydrocarbylamino, di(hydrocarbyl)amino, di(hydrocarbyl)phosphino, or hydrocarbylsulfido groups having from 1 to 20 atoms other than hydrogen, or, further optionally such substituents may be covalently linked with each other to form one or more fused rings or ring systems, said Q2 having from 3 to 20 atoms other than hydrogen; and the molar ratio of A):B) in the composition being from 0.1:1 to 10:1 are useful as activators for olefin polymerizations.

    摘要翻译: 组合物,其包含:A)对应于式AlArf 3的铝化合物,其中Arf为6至30个碳原子的氟化芳族烃基部分; B)对应于式AlArfQ1Q2的铝化合物或其二聚物,加合物或其混合物 ; 其中:Arf如前所定义; Q 1是Arf或C 1-20烃基,任选被一个或多个环烃基,烃氧基,烃基甲硅烷氧基,烃基甲硅烷基氨基,烃基甲硅烷基,甲硅烷基烃基,二(烃基甲硅烷基)氨基,烃基氨基,二(烃基)氨基 ,二(烃基)膦基或具有除氢以外的1至20个原子的烃基硫基,或者进一步任选地,这些取代基可彼此共价连接以形成一个或多个稠环或环系; 任选被一个或多个烃基,环烃基,烃氧基,烃基甲硅烷氧基,烃基甲硅烷基氨基,烃基甲硅烷基,巯基烃基,二(烃基甲硅烷基)氨基,烃基氨基,二(烃基)氨基,二(烃基) )膦基或具有除氢以外的1至20个原子的烃基硫基,或者进一步任选地,这些取代基可以彼此共价连接以形成一个或多个稠环或环系,所述Q2具有3至20个以外的原子,除了 氢; 并且组分中A):B)的摩尔比为0.1:1至10:1可用作烯烃聚合的活化剂。

    Three coordinate aluminum catalyst activator composition
    2.
    发明授权
    Three coordinate aluminum catalyst activator composition 有权
    三配位铝催化剂活化剂组成

    公开(公告)号:US06528449B1

    公开(公告)日:2003-03-04

    申请号:US09702442

    申请日:2000-10-31

    IPC分类号: B01J3114

    摘要: Catalyst compositions useful for olefin polymerizations comprising a Group 3-10 metal complex and a compound corresponding to the formula: AlArfQ1Q2, or a dimer, adduct, or mixture thereof and further mixtures with aluminum compounds of the formula AlArf3, where: Arf is a fluorinated aromatic hydrocarbyl moiety of from 6 to 30 carbon atoms; Q1 is Arf or a C1-20 hydrocarbyl group, optionally substituted with one or more cyclohydrocarbyl, hydrocarbyloxy, hydrocarbylsiloxy, hydrocarbylsilylamino, hydrocarbylsilyl, silylhydrocarbyl, di(hydrocarbylsilyl)amino, hydrocarbylamino, di(hydrocarbyl)amino, di(hydrocarbyl)phosphino, or hydrocarbylsulfido groups having from 1 to 20 atoms other than hydrogen, or, further optionally, such substituents may be covalently linked with each other to form one or more fused rings or ring systems; and Q2 is an aryloxy, arylsulfide or di(hydrocarbyl)amido group, optionally substituted with one or more hydrocarbyl, cyclohydrocarbyl, hydrocarbyloxy, hydrocarbylsiloxy, hydrocarbylsilylamino, hydrocarbylsilyl, silylhydrocarbyl, di(hydrocarbylsilyl)amino, hydrocarbylamino, di(hydrocarbyl)amino, di(hydrocarbyl)phosphino, or hydrocarbylsulfido groups having from 1 to 20 atoms other than hydrogen, or, further optionally such substituents may be covalently linked with each other to form one or more fused rings or ring systems, said Q2 having from 3 to 20 atoms other than hydrogen are useful as activators for olefin polymerizations.

    摘要翻译: 用于烯烃聚合的催化剂组合物,其包含3-10金属络合物和对应于式AlArfQ1Q2的化合物或其二聚体,加合物或其混合物,以及与式AlArf 3的铝化合物的其它混合物,其中:Arf是氟化 6至30个碳原子的芳族烃基部分; Q 1是Arf或C 1-20烃基,任选地被一个或多个环烃基,烃氧基,烃基甲硅烷氧基,烃基甲硅烷基氨基,烃基甲硅烷基,甲硅烷基烃基,二(烃基甲硅烷基)氨基,烃基氨基,二 烃基)氨基,二(烃基)膦基或具有除氢以外的1至20个原子的烃基硫基,或者进一步任选地,这些取代基可以彼此共价连接以形成一个或多个稠环或环系; 环烷氧基,烃基甲硅烷氧基,烃基甲硅烷基氨基,烃基甲硅烷氧基,烃基甲硅烷基氨基,烃基甲硅烷基,甲硅烷基烃基,二(烃基甲硅烷基)氨基,烃基氨基,二(烃基)氨基,二(烃基)氨基, 烃基)膦基或具有除氢之外的1至20个原子的烃基硫基,或者进一步任选地,这些取代基可以彼此共价连接以形成一个或多个稠环或环系,所述Q2具有3至20个原子的其它 氢可用作烯烃聚合的活化剂。

    HARDENER COMPOSITION FOR EPOXY RESINS
    3.
    发明申请
    HARDENER COMPOSITION FOR EPOXY RESINS 审中-公开
    环氧树脂硬化剂组合物

    公开(公告)号:US20120083564A1

    公开(公告)日:2012-04-05

    申请号:US13263766

    申请日:2010-06-14

    摘要: A composition comprising: a) an epoxy resin; and b) a hardener comprising a copolymer of: i) an ethylenically unsaturated anhydride, and ii) a vinyl compound, wherein the vinyl compound is styrene or a styrene derivative and wherein the copolymer has an anhydride content of less than 15 weight percent, based on the total weight of the copolymer, wherein said composition is prepared from a halogen-containing compound, and uses thereof, are disclosed.

    摘要翻译: 一种组合物,其包含:a)环氧树脂; 和b)包含以下共聚物的固化剂:i)烯属不饱和酸酐和ii)乙烯基化合物,其中所述乙烯基化合物是苯乙烯或苯乙烯衍生物,并且其中所述共聚物的酸酐含量小于15重量% 关于共聚物的总重量,其中所述组合物由含卤素化合物制备及其用途。

    Transparent polyurethane-hydrogel composition, method of making transparent polyurethane-hydrogel composition, and air-freshener application
    7.
    发明授权
    Transparent polyurethane-hydrogel composition, method of making transparent polyurethane-hydrogel composition, and air-freshener application 有权
    透明聚氨酯 - 水凝胶组合物,透明聚氨酯 - 水凝胶组合物的制备方法和空气清新剂的应用

    公开(公告)号:US06960625B2

    公开(公告)日:2005-11-01

    申请号:US10152888

    申请日:2002-05-21

    摘要: A transparent polyurethane-hydrogel composition includes a reaction product in aqueous solvent of a prepolymer and a water-soluble crosslinker in the substantial absence of organic solvent, and such a composition can be prepared by admixing a prepolymer and a water-soluble crosslinker in aqueous solvent and in the substantial absence of organic solvent. A prepolymer is present in an amount of no greater than about 5 weight percent based on total weight of all hydrogel components. The prepolymer is generally prepared from at least one water-soluble polyol and an isocyanate. A water-soluble crosslinker generally has a crosslinker functionality of at least 2 and is selected to provide a site ratio of initial isocyanate to crosslinker (i.e., moles NCO×functionality/moles crosslinker×functionality) of at least about 1.5 and no greater than about 2.6. In one embodiment, a crosslinker is effective to react with and solubilize residual isocyanate concurrently with the reaction between prepolymer and crosslinker. A transparent polyurethane-hydrogel composition has desirable gel physical properties and is useful for an air-freshener application.

    摘要翻译: 透明的聚氨酯 - 水凝胶组合物包括基本上不存在有机溶剂的预聚物的水性溶剂中的反应产物和水溶性交联剂,并且这种组合物可以通过将预聚物和水溶性交联剂混合在水性溶剂中来制备 并且基本上不存在有机溶剂。 基于所有水凝胶组分的总重量,预聚物的存在量不大于约5重量%。 预聚物通常由至少一种水溶性多元醇和异氰酸酯制备。 水溶性交联剂通常具有至少为2的交联剂官能度,并且被选择为提供至少约1.5且不大于约2.6的起始异氰酸酯与交联剂的位点比率(即摩尔NCO x官能度/摩尔交联剂官能度)。 在一个实施方案中,交联剂与预聚物和交联剂之间的反应同时有效地与残余异氰酸酯反应并溶解。 透明的聚氨酯 - 水凝胶组合物具有所需的凝胶物理性质,并且可用于空气清新剂的应用。