摘要:
Compositions comprising: A) an aluminum compound corresponding to the formula AlArf3, where Arf is a fluorinated aromatic hydrocarbyl moiety of from 6 to 30 carbon atoms; B) an aluminum compound corresponding to the formula: AlArfQ1Q2, or a dimer, adduct, or mixture thereof; where: Arf is as previously defined; Q1 is Arf or a C1-20 hydrocarbyl group, optionally substituted with one or more cyclohydrocarbyl, hydrocarbyloxy, hydrocarbylsiloxy, hydrocarbylsilylamino, hydrocarbylsilyl, silylhydrocarbyl, di(hydrocarbylsilyl)amino, hydrocarbylamino, di(hydrocarbyl)amino, di(hydrocarbyl)phosphino, or hydrocarbylsulfido groups having from 1 to 20 atoms other than hydrogen, or, further optionally, such substituents may be covalently linked with each other to form one or more fused rings or ring systems; and Q2is an aryloxy, arylsulfide or di(hydrocarbyl)amido group, optionally substituted with one or more hydrocarbyl, cyclohydrocarbyl, hydrocarbyloxy, hydrocarbylsiloxy, hydrocarbylsilylamino, hydrocarbylsilyl, silyhydrocarbyl, di(hydrocarbylsilyl)amino, hydrocarbylamino, di(hydrocarbyl)amino, di(hydrocarbyl)phosphino, or hydrocarbylsulfido groups having from 1 to 20 atoms other than hydrogen, or, further optionally such substituents may be covalently linked with each other to form one or more fused rings or ring systems, said Q2 having from 3 to 20 atoms other than hydrogen; and the molar ratio of A):B) in the composition being from 0.1:1 to 10:1 are useful as activators for olefin polymerizations.
摘要:
Catalyst compositions useful for olefin polymerizations comprising a Group 3-10 metal complex and a compound corresponding to the formula: AlArfQ1Q2, or a dimer, adduct, or mixture thereof and further mixtures with aluminum compounds of the formula AlArf3, where: Arf is a fluorinated aromatic hydrocarbyl moiety of from 6 to 30 carbon atoms; Q1 is Arf or a C1-20 hydrocarbyl group, optionally substituted with one or more cyclohydrocarbyl, hydrocarbyloxy, hydrocarbylsiloxy, hydrocarbylsilylamino, hydrocarbylsilyl, silylhydrocarbyl, di(hydrocarbylsilyl)amino, hydrocarbylamino, di(hydrocarbyl)amino, di(hydrocarbyl)phosphino, or hydrocarbylsulfido groups having from 1 to 20 atoms other than hydrogen, or, further optionally, such substituents may be covalently linked with each other to form one or more fused rings or ring systems; and Q2 is an aryloxy, arylsulfide or di(hydrocarbyl)amido group, optionally substituted with one or more hydrocarbyl, cyclohydrocarbyl, hydrocarbyloxy, hydrocarbylsiloxy, hydrocarbylsilylamino, hydrocarbylsilyl, silylhydrocarbyl, di(hydrocarbylsilyl)amino, hydrocarbylamino, di(hydrocarbyl)amino, di(hydrocarbyl)phosphino, or hydrocarbylsulfido groups having from 1 to 20 atoms other than hydrogen, or, further optionally such substituents may be covalently linked with each other to form one or more fused rings or ring systems, said Q2 having from 3 to 20 atoms other than hydrogen are useful as activators for olefin polymerizations.
摘要:
A composition comprising: a) an epoxy resin; and b) a hardener comprising a copolymer of: i) an ethylenically unsaturated anhydride, and ii) a vinyl compound, wherein the vinyl compound is styrene or a styrene derivative and wherein the copolymer has an anhydride content of less than 15 weight percent, based on the total weight of the copolymer, wherein said composition is prepared from a halogen-containing compound, and uses thereof, are disclosed.
摘要:
The disclosure provides for a phase compensation film that includes nano-particles of a cross-linked polymer with a largest dimension of a quarter of a wavelength of visible light or less, and a liquid crystal substance imbibed substantially throughout the cross-linked polymer of the nano-particles to provide a phase compensation value for a pixel of a liquid crystal display.
摘要:
The disclosure provides for a small scale functional material, where the small scale functional material is imbibed with a material having a functionality response to an externally applied field.
摘要:
The present invention generally relates to solution electrospinning processes for fabricating fibers, to the fibers prepared thereby, and to non-woven webs, fabrics, porous composite filter media, and articles comprising the fibers.
摘要:
A transparent polyurethane-hydrogel composition includes a reaction product in aqueous solvent of a prepolymer and a water-soluble crosslinker in the substantial absence of organic solvent, and such a composition can be prepared by admixing a prepolymer and a water-soluble crosslinker in aqueous solvent and in the substantial absence of organic solvent. A prepolymer is present in an amount of no greater than about 5 weight percent based on total weight of all hydrogel components. The prepolymer is generally prepared from at least one water-soluble polyol and an isocyanate. A water-soluble crosslinker generally has a crosslinker functionality of at least 2 and is selected to provide a site ratio of initial isocyanate to crosslinker (i.e., moles NCO×functionality/moles crosslinker×functionality) of at least about 1.5 and no greater than about 2.6. In one embodiment, a crosslinker is effective to react with and solubilize residual isocyanate concurrently with the reaction between prepolymer and crosslinker. A transparent polyurethane-hydrogel composition has desirable gel physical properties and is useful for an air-freshener application.
摘要:
The present invention generally relates to solution electrospinning processes for fabricating fibers, to the fibers prepared thereby, and to non-woven webs, fabrics, porous composite filter media, and articles comprising the fibers.
摘要:
A process for fabricating fibers, including nano-scale fibers, comprising electrospinning a melt of a self assembling material and fibers fabricated by the process are disclosed.
摘要:
A composition comprising: a) an epoxy resin; b) a hardener; and c) a stabilizer comprising a metal-containing compound, the metal-containing compound comprising a metal selected from the group consisting of Group 11-13 metals and combinations thereof, wherein the composition is prepared from a halogen-containing compound is disclosed.