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    Process for producing ether
    1.
    发明申请
    Process for producing ether 审中-公开
    生产乙醚的方法

    公开(公告)号：US20030139632A1

    公开(公告)日：2003-07-24

    申请号：US10257272

    申请日：2002-12-16

    发明人： Outi Krause ,  Reetta Karinen ,  Juhani Aittamaa

    IPC分类号： C07C041/06

    CPC分类号： C07C41/42 ,  C07C41/06 ,  C07C43/046

    摘要： This invention concerns a process and an apparatus for producing ether and the use of a dimerised reaction product as the olefinic feedstock in etherification. According to the present process alcohol and C8-C12 olefin(s) are fed to a first reaction zone (21-25) comprising at least one reactor, the olefin(s) and alcohol are subjected to an etherification reaction in the presence of an acidic catalyst. The effluent from the first reaction zone (21-25) is fed to a fractionation zone (26). From the fractionation zone (26) is withdrawn a side-flow which is conducted either back to the first reaction zone (21-25) or to a second reaction zone. The effluent of the first reaction zone (21-25) or the second reaction zone is circulated back to the fractionation zone (26), and the ether is recovered from the fractionation zone (26).

    摘要翻译： 本发明涉及一种用于生产醚的方法和设备，以及二聚反应产物在醚化中作为烯烃原料的用途。 根据本发明方法，将醇和C 8 -C 12烯烃进料到包含至少一个反应器的第一反应区（21-25）中，使烯烃和醇在存在下进行醚化反应 酸性催化剂。 将来自第一反应区（21-25）的流出物进料至分馏区（26）。 从分馏区（26）中取出侧流，其返回到第一反应区（21-25）或第二反应区。 第一反应区（21-25）或第二反应区的流出物循环回至分馏区（26），从分馏区（26）回收乙醚。

    Process for making butyl ethers of glycols
    2.
    发明申请
    Process for making butyl ethers of glycols 失效
    制备二醇的丁基醚的方法

    公开(公告)号：US20020065438A1

    公开(公告)日：2002-05-30

    申请号：US09844442

    申请日：2001-04-30

    发明人： Benjamin Patrick Gracey

    IPC分类号： C07C041/06

    CPC分类号： C07C41/06 ,  C07C41/42 ,  Y02P20/582 ,  C07C43/178

    摘要： Processes are described for the preparation of glycol butyl ethers involving reaction of butadiene with saturated aliphatic glycols, separating the thus formed n- and sec-butenyl glycol ethers and hydrogenating the n-butenyl glycol ethers. Additional features are the use in the first step of heterogeneous catalyst modified by alkylpyridinium quaternary ammonium, quaternary arsonium quaternary phosphonium counterions and/or the conversion of sec-butenyl glycol ethers to butadiene and saturated aliphatic glycols.

    摘要翻译： 描述了制备包含丁二烯与饱和脂族二醇反应的二醇丁基醚的方法，分离由此形成的正丁烯基和仲丁二醇醚，并氢化正丁烯基二醇醚。 另外的特征是在烷基吡啶鎓季铵，季铵季铵抗衡离子改性的非均相催化剂和/或将仲丁二醇醚转化成丁二烯和饱和脂肪族二醇的第一步中的用途。

    Ice nucleating non-stick coating
    3.
    发明申请
    Ice nucleating non-stick coating 有权
    冰晶不粘涂层

    公开(公告)号：US20040249222A1

    公开(公告)日：2004-12-09

    申请号：US10477183

    申请日：2004-07-19

    发明人： Thomas Zwieg

    IPC分类号： C07C041/06 ,  B01J031/00

    CPC分类号： C09D183/06 ,  C09D183/08 ,  C09K3/18

    摘要： Heterogeneous surface with polar functional groups as nucleation points. These nucleation points cause precipitation of a substance, for example ice or salt, in a fluid at these nucleation points under suitable physical conditions because the Gibbs free energy of the system is lower at the nucleation points than between the nucleation points, where said system comprises said surface and said fluid with said substance near said surface.

    摘要翻译： 具有极性官能团的非均相表面为成核点。 这些成核点在合适的物理条件下在这些成核点处的液体中导致物质（例如冰或盐）的沉淀，因为系统的吉布斯自由能在成核点比在成核点之间低，其中所述体系包含 所述表面和所述物质在所述表面附近。

    Ferrocenyl diphosphines and their use
    4.
    发明申请
    Ferrocenyl diphosphines and their use 有权
    二茂铁二膦及其用途

    公开(公告)号：US20030212284A1

    公开(公告)日：2003-11-13

    申请号：US10312816

    申请日：2002-12-31

    发明人： Walter Weissensteiner ,  Thomas Sturm ,  Felix Spindler

    IPC分类号： C07F015/02 ,  C07C29/60 ,  C07C029/04 ,  C07C041/06

    CPC分类号： B01J31/2409 ,  B01J31/2295 ,  B01J31/24 ,  B01J2231/643 ,  B01J2231/645 ,  B01J2531/16 ,  B01J2531/17 ,  B01J2531/18 ,  B01J2531/31 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  B01J2531/84 ,  C07B53/00 ,  C07C67/31 ,  C07C231/18 ,  C07F17/02 ,  C07C69/68

    摘要： Compounds of the formula (I) and (Ia) in the form of racemates, mixtures of diastereomers or in essentially enantiomerically pure form, (I), (Ia), where R is hydrogen, C1-C8alkyl, C5-C12cycloakyl, phenyl or phenyl substituted by from 1 to 3 C1-C4alky or C1-C4alkoxy groups; n is 0 or an integer from 1 to 4 and R1 are identical or different subtitutuents selected from the group consisting of C1-C4alkyl, C1-C4fluoroalkyl and C1-C4alkoxy; X1 and X2 are each, indenpendently of one another, secondary phosphino; T is C6-C20arylene or C3-C16heteroarylene; and X2 is bound in the ortho position relative to the T-cyclopenitadienyl bond. The compounds are ligands for complexes of metal selected from transition groups (I) and (VIII) of the Periodic Table of the Elements, and these metal complexes are valuable catalysts for the asymmetric addition of hydrogen, boron hydrides or silanes onto carbon-carbon or carbon-heteroatom multiple bonds in prochiral organic compounds or the asymmetric addition of carbon nucleophiles or amines onto allyl compounds. 1

    摘要翻译： 式（I）和（Ia）化合物为外消旋体形式，非对映异构体混合物或基本上为对映体纯形式的（I），（Ia），其中R为氢，C 1 -C 8烷基，C 5 -C 12环烷基，苯基或 被1至3个C 1 -C 4烷基或C 1 -C 4烷氧基取代的苯基; n为0或1至4的整数，R 1为选自C 1 -C 4烷基，C 1 -C 4氟烷基和C 1 -C 4烷氧基的相同或不同的选择基团; X1和X2各自独立地为二次膦基; T是C 6 -C 20亚芳基或C 3 -C 16亚芳基; 并且X2相对于T-环戊二烯基键在邻位上结合。 这些化合物是选自元素周期表的转变基团（I）和（VIII）的金属络合物的配体，这些金属络合物是用于将氢，硼氢化物或硅烷不对称加成到碳 - 碳上的有价值的催化剂 前手性有机化合物中的碳 - 杂原子多重键或碳亲核试剂或胺不对称加成到烯丙基化合物上。

    Process and apparatus for catalytic distillations
    6.
    发明申请
    Process and apparatus for catalytic distillations 有权

    公开(公告)号：US20040204614A1

    公开(公告)日：2004-10-14

    申请号：US10839405

    申请日：2004-05-05

    申请人： CATALYTIC DISTILLATION TECHNOLOGIES

    发明人： Willibrord A. Groten ,  Mario J. Maraschino

    IPC分类号： C07C319/04 ,  C07C319/02 ,  C07C041/06

    CPC分类号： B01D3/141 ,  B01D3/009 ,  C07C2/06 ,  C07C2/66 ,  C07C5/03 ,  C07C5/10 ,  C07C5/23 ,  C07C5/2506 ,  C07C5/27 ,  C07C41/06 ,  C07C41/42 ,  C07C319/18 ,  Y02P20/127 ,  C07C43/046

    摘要： A process for reacting a first component with itself or a second component to produce a third component in which a first material comprising a first component or said first component and a second component is fed to divided wall column having a catalytic distillation structure in at least one of the separate vertical sections of the divided wall column where concurrently: (1) a first component alone or with a second component is contacted with a catalytic distillation structure in a distillation reaction zone thereby catalytically reacting at least a portion of the first component with itself or with the second component to form a product and (2) a first mixture comprising the first component and the product or the first component, the second component and the product; and withdrawing the product from the distillation column reactor; while within the column concurrently with the catalytic reaction and fractionation a second mixture is fractionated, which contains the first component and the product or first and second components (if a second component is present) and the product in a parallel and separate distillation non reaction zone to fractionate the product and withdrawing the product from said distillation non reaction zone. For example, tertiary amyl methyl ether may be prepared by reacting methanol with isoamylene in a C5 stream utilizing a distillation column reactor wherein the distillation column reactor comprises one side of a divided wall column. On one side the product, tertiary amyl methyl ether, is separated from the unreacted methanol and C5's and on the other side the remaining isoamylenes are reacted with methanol and a separation of the tertiary amyl methyl ether and C5's from the methanol/C5 azeotrope is effected.

    Process for production of monoalkyl ethers
    8.
    发明申请
    Process for production of monoalkyl ethers 有权
    单烷基醚的制备方法

    公开(公告)号：US20010056212A1

    公开(公告)日：2001-12-27

    申请号：US09867460

    申请日：2001-05-31

    申请人： KAO CORPORATION

    发明人： Munehisa Okutsu ,  Tomohito Kitsuki ,  Atsushi Nagasawa

    IPC分类号： C07C041/06

    CPC分类号： C07C41/06 ,  C07C41/20 ,  Y02P20/584 ,  C07C43/13 ,  C07C43/135 ,  C07C43/178

    摘要： A process for producing a monoalkyl ether which comprises a first step of contacting the following components (A) and (B):(A): an aqueous liquid phase containing: (a1) a C3-6 polyol having 3 or 4 hydroxyl groups, a palladium compound, a water-soluble tertiary phosphine or phosphite, and water; or (a2) a C3-6 polyol having 3 to 4 hydroxyl groups, a complex of palladium and a water-soluble tertiary phosphine or phosphite, and water, and (B): an oily liquid phase containing a conjugated diene, to give an alkadienyl ether containing an alkadienyl group resulting from dimerization of conjugated dienes; and a second step of hydrogenating the alkadienyl group in the alkadienyl ether in a hydrogen atmosphere in the presence of a catalyst containing an element selected from the Groups 8 to 10 elements of the periodic table. According to the process of the invention, monoalkyl ethers of polyols are produced selectively in a simple manner and advantageously from the economical viewpoint. The present process enables recovery and recycling of the catalyst.

    摘要翻译： 一种制备单烷基醚的方法，其包括使以下组分（A）和（B）：A）接触的第一步：含有（a1）具有3或4个羟基的C 3-6多元醇的水性液相， 钯化合物，水溶性叔膦或亚磷酸酯和水; 或（a2）具有3〜4个羟基的C3-6多元醇，钯和水溶性叔膦或亚磷酸酯的配合物和水，和（B）：含有共轭二烯的油性液相，得到 含有由共轭二烯的二聚产生的链二烯基的链二烯基醚; 以及在含有选自元素周期表第8〜10族的元素的催化剂存在下，在氢气气氛中，在链二烯基醚中氢化链二烯基的第二工序。 根据本发明的方法，多元醇的单烷基醚以简单的方式选择性地产生，并且从经济的观点来看是有利的。 本方法能够回收和再循环催化剂。