公开(公告)号：US3523976A

公开(公告)日：1970-08-11

申请号：US67530467

申请日：1967-10-16

申请人： SIR SOC ITALIANA RESINE SPA

发明人： RENI CESARE ,  LUGO LUIGI

IPC分类号： C07C409/10 ,  C07C73/08

CPC分类号： C07C409/10 ,  C07C407/00

公开(公告)号：US3519690A

公开(公告)日：1970-07-07

申请号：US3519690D

申请日：1967-01-30

申请人： ALLIED CHEM

发明人： JORIS GEORGE G ,  FUHRMANN ROBERT ,  JEROLAMON DAVID

IPC分类号： C07C407/00 ,  C07C73/06 ,  C07C73/08

CPC分类号： C07C407/003 ,  C07C409/08 ,  C07C409/12 ,  C07C409/04

公开(公告)号：US3845140A

公开(公告)日：1974-10-29

申请号：US1704870

申请日：1970-03-10

申请人： SUN RESEARCH DEVELOPMENT

发明人： BROWNSTEIN A ,  KERR D

IPC分类号： C07C409/08 ,  C07C409/10 ,  C07C409/14 ,  C07C73/08

CPC分类号： C07C409/10 ,  C07C407/00 ,  C07C409/08 ,  C07C409/14 ,  C07C2601/14

摘要： 1. IN A PROCESS FOR THE OXIDATION OF SECONDARY AND TERTIARY ALKYL AROMATIC HYDROCARBONS WITH OXYGEN OR AN OXYGEN-CONTAINING GAS AT TEMPERATURES OF FROM 80* TO 130* C. IN THE PRESENCE OF A CATALYST TO PRODUCE THE CORRESPONDING HYDROPEROXIDE COMPOUNDS, THE IMPROVEMENT WHICH COMPRISES OXIDIZING SAID ALKYL AROMATIC HYDROCAR: BONS HAVING THE FORMULA

R1-CH(-R)-AR

IN WHICH R IS A LOWER ALKYL GROUP HAVING FROM ONE TO SEVEN CARBON ATOMS; R1 IS HYDROGEN OR A LOWER ALKYL GROUP HAVING FROM ONE TO SIX CARBON ATOMS; R AND R1, TAKEN TOGETHER, FORM A CYCLOALKYL RING HAVING FROM FOUR TO SEVEN CARBON ATOMS; AND AR IS PHENYL OR NAPHTHYL, IN THE PRESENCE OF A CATALYST COMPRISING A CUPROUS HALIDE SELECTED FROM THE GROUP CONSISTING OF CUPROUS CHLORIDE, CUPROUS BROMIDE, AND CUPROUS IODIDE, AND AN AROMATIC HETEROCYCLIC AMINE SELECTED FROM THE GROUP CONSISTING OF PYRIDINE, QUINOLINE, ISOQUINOLINE, TRIAZINE AND PYRAZINE, WHEREIN THE RATIO OF CUPROUS HALIDE TO AMINE IS IN TTHE RANGE OF ABOUT 1 TO 100 PARTS BY WEIGHT OF SAID HALIDE FOR EACH 100 PARTS OF AMINE.

公开(公告)号：US3634328A

公开(公告)日：1972-01-11

申请号：US3634328D

申请日：1970-04-21

申请人： SUN OIL CO

发明人： BROWNSTEIN ARTHUR M ,  KERR DAVID L

IPC分类号： C07C409/08 ,  C07C409/10 ,  C07C409/12 ,  C07C409/14 ,  C07C73/08

CPC分类号： C07C409/10 ,  C07C407/00 ,  C07C409/08 ,  C07C409/12 ,  C07C409/14 ,  C07C2601/14

摘要： COPPER POLYPHTHALOCYANINE WHICH HAS BEEN ACTIVATED BY CONTACT WITH AN AROMATIC HETEROCYCLIC AMINE TO FORM A NOVEL COMPLEX IS FOUND TO BE AN EFFECTIVE CATALYST FOR THE OXIDATION OF SECONDARY AND TERTIARY ALKYL AROMATICS SUCH AS ETHYLBENZENE OR CUMENE TO FORM THE CORRESPONDING HYDROPEROXIDE. THE RATE OF CONVERSION AND THE PERCENTAGE YIELD IS GREATER THAN THAT WITH COPPER PHTHALOCYANINE OR COPPER POLYPHTHALOCYANINE PER SE.

公开(公告)号：US3428689A

公开(公告)日：1969-02-18

申请号：US3428689D

申请日：1964-09-20

申请人： LAPORTE CHEMICAL

发明人： MANLY THOMAS D

IPC分类号： C07C409/00 ,  C07C73/00 ,  C07C73/08

CPC分类号： C07C407/006 ,  C07C2601/14 ,  C07C409/22 ,  C07C409/16 ,  C07C409/10 ,  C07C409/04

公开(公告)号：US3833663A

公开(公告)日：1974-09-03

申请号：US78419868

申请日：1968-12-16

申请人： ICI LTD

发明人： MC AVOY J

IPC分类号： C07C409/04 ,  C07C409/08 ,  C07C409/10 ,  C07C409/12 ,  C07C409/14 ,  C07C73/08

CPC分类号： C07C407/00 ,  C07C409/10

摘要： HYDROCARBON HYDROPEROXIDES ARE PRODUCED BY OXIDISING A HYDROCARBON HAVING AT LEAST ONE SECONDARY OR TERTIARY CARBON ATOM, FOR EXAMPLE CUMENE, IN THE LIQUID PHASE WITH A GAS CONTAINING FREE OXYGEN IN THE PRESENCE OF A FLUORIDE OF AN ALKALI OR ALKALINE EARTH METAL, PARTICULARLY SODIUM FLUORIDE.

公开(公告)号：US3725484A

公开(公告)日：1973-04-03

申请号：US3725484D

申请日：1968-02-21

申请人： SUMITOMO CHEMICAL CO

发明人： KOTERA N ,  YAMAMOTO S ,  ITO K ,  KAMINAKA H ,  HASEGAWA S ,  KOBAYASHI N ,  YOSHITAKE H ,  TANIMOTO K ,  KURUMA H ,  CHINUKI T ,  DOGANE I ,  SHIGEHIRO K

IPC分类号： C07C409/08 ,  C07C409/10 ,  C07C409/40 ,  C07C73/08

CPC分类号： C07C409/08 ,  C07C407/00 ,  C07C409/10 ,  C07C409/40

摘要： Hydroperoxides of alkylaromatic compounds are prepared by contacting the alkylaromatic compounds having at least one alkyl or cycloalkyl substituent group having a tertiary carbon atom in the Alpha -position with respect to the aromatic nucleus, with oxygen or a molecular oxygen-containing gas in the presence of 0.001 to 10 percent by weight of molybdenum disulfide at room temperature to 200*C. for 1 to 100 hours.

摘要翻译： 烷基芳族化合物的氢过氧化物是通过使具有至少一个在α-位上具有叔碳原子的烷基或环烷基取代基相对于芳族核的烷基芳族化合物与氧或含分子氧的气体在存在 0.001至10重量％的二硫化钼在室温至200℃下反应1至100小时。

公开(公告)号：US3639486A

公开(公告)日：1972-02-01

申请号：US3639486D

申请日：1967-12-15

申请人： ATLANTIC RICHFIELD CO

发明人： ROSENTHAL RUDOLPH ,  SHENG MING NAN ,  ZAJACEK JOHN G

IPC分类号： C07C407/00 ,  C07C73/08

CPC分类号： C07C407/003 ,  C07C409/10

摘要： METHOD FOR THE TREATMENT OF CUMENE HYDROPEROXIDE FOR USE IN EPOXIDATION REACTIONS BY DILUTING THE CUMENE HYDROEROXIDE WITH A HYDROCARBON WITH FORMS AN AZEOTROPE WITH WATER, WASHING THE DILUTED CUMENE HYDROPEROXIDE AND REMOVING THE HYDROCARBON-WATER-AZEOTROPE.

公开(公告)号：US3755464A

公开(公告)日：1973-08-28

申请号：US3755464D

申请日：1970-02-25

申请人： PENNWALT CORP

发明人： BAFFORD R

IPC分类号： C07C409/14 ,  C07C409/16 ,  C08F4/34 ,  C08F283/01 ,  C08K5/14 ,  C07C73/08

CPC分类号： C08K5/14 ,  C07C409/16 ,  C08F283/01 ,  C08F4/00

摘要： TERTIARY-ALKYL HALOCUMYL PEROXIDES OF THE FORMULA

((X)N,R(5-N)-PHENYL)-C(-CH3)2-O-O-R1

WHEREIN X IS F, CL, OR BR; N=1-5; R IS H, ALKYL, CYCLOALKYL, OR ARYL; AND R1 IS TERTIARY-ALKYL OF 4-8 CARBON ATOMS. THESE PEROXIDES ARE USEFUL FOR CROSSLINKING POLYMERIC MATERIALS WITHOUT PRODUCING AN OBJECTIONABLE ODOR.

公开(公告)号：US3666815A

公开(公告)日：1972-05-30

申请号：US3666815D

申请日：1970-05-18

申请人： TNO

发明人： SCHELTUS PAULUS I T

IPC分类号： C07C29/50 ,  C07C45/36 ,  C07C409/08 ,  C07C409/10 ,  C07C409/12 ,  C07C409/16 ,  C07C49/78 ,  C07C31/14 ,  C07C73/08

CPC分类号： C07C409/16 ,  C07C29/50 ,  C07C45/36 ,  C07C407/00 ,  C07C409/08 ,  C07C409/10 ,  C07C409/12 ,  C07C49/76 ,  C07C33/20

摘要： This invention relates to the oxidation of alkyl aromatic compounds with an alkyl-substituted phthalocyanine as a catalyst and with methods for the preparation of this catalyst.

摘要翻译： 本发明涉及烷基芳族化合物与烷基取代酞菁作为催化剂的氧化及其制备方法。