公开(公告)号：US3812095A

公开(公告)日：1974-05-21

申请号：US3731070

申请日：1970-05-14

申请人： PENNWALT CORP

发明人： SHEPPARD C ,  MACLEAY R ,  BAFFORD R

IPC分类号： C07C245/04 ,  C07C247/04 ,  C07C409/40 ,  C07C409/42 ,  C08F293/00 ,  C07C107/02

CPC分类号： C07C247/04 ,  C07C245/04 ,  C07C409/40 ,  C07C409/42 ,  C07C2601/02 ,  C07C2601/08 ,  C07C2603/74 ,  C07D209/48 ,  C07D271/10 ,  C08F293/00

摘要： (I) COMPOUNDS HAVINGINDEPENDENT PEROXIDIC (X) AND ALIPHATIC AZO GROUPS OF THE FORMULA

((R-N=N-R'')M-X)N

EXAMPLE: DI-T-BYTYLPEROXY ESTER OF CIS-4,4''-AZOBIS-(4CYANOVALERIC ACID). (II) A METHOD OF MAKING A BLOCK POLYMER WHERE VINYL MONOMER IS INITIATED SEQUENTIALLY TO PRODUCE IN ONE INSTANCE: A POLYMER HAVING AZO-CARBON LINKAGES PRESENT, WHICH IS THEN REACTED WITH VINYL MONOMER UNDER CONDITIONS TO RUPTURE THE AZO-CARBON LINKAGES, AND IN ANOTHER INSTANCE: A POLYMER HAVING PEROXY-CARBON LINKAGES PRESENT, WHICH IS THEN REACTED WITH VINYL MONOMER UNDER CONDITIONS TO RUPTURE THE PEROXY CARBON LINKAGES.

公开(公告)号：US3800007A

公开(公告)日：1974-03-26

申请号：US19037671

申请日：1971-10-18

申请人： PENNWALT CORP

发明人： BAFFORD R

IPC分类号： C07C409/16 ,  C07C409/18 ,  C08F293/00 ,  C08F1/60

CPC分类号： C08F293/00 ,  Y10S260/28

摘要： Block copolymers are prepared by polymerizing an unsaturated monomer in the presence of a polymerization catalyst and a chain transfer agent which is a cumyl peroxide containing one or more alkyl or cycloalkyl substituents, which substituents have at least one benzylic hydrogen atom, at a temperature below that which the peroxide decomposes, and subsequently polymerizing the peroxy containing polymer so formed in the presence of additional monomer at a temperature above the decomposition point of the peroxide.

摘要翻译： 嵌段共聚物通过在聚合催化剂和链转移剂的存在下聚合不饱和单体来制备，所述链转移剂是含有一个或多个烷基或环烷基取代基的异丙苯过氧化物，该取代基具有至少一个苄基氢原子，该取代基具有至少一个苄基氢原子， 过氧化物分解，然后在高于过氧化物分解点的温度下，在另外的单体存在下聚合如此形成的过氧化物的聚合物。

公开(公告)号：US3763112A

公开(公告)日：1973-10-02

申请号：US3763112D

申请日：1971-04-02

申请人： PENNWALT CORP

发明人： BAFFORD R ,  KAMENS E ,  MAGELI O

IPC分类号： C07C51/38 ,  C07C59/185 ,  C07C59/347 ,  C07C409/38 ,  C07C409/40 ,  C07C409/42 ,  C07D307/24 ,  C08F4/32 ,  C08F8/06 ,  C08G65/332 ,  C07C69/00 ,  C08F1/60 ,  C08F27/00

CPC分类号： C08G65/332 ,  C07C51/38 ,  C07C59/185 ,  C07C59/347 ,  C07C407/00 ,  C07C409/38 ,  C07C409/42 ,  C07D307/24 ,  C08F4/32 ,  C08F283/06 ,  Y10S260/28 ,  C07C59/305 ,  C08F212/08

摘要： A DIESTER OF DIPEROXYFUMARIC ACID IS REACTED AT ITS DOUBLE BOND WITH AN ORGANIC COMPOUND R-(X)S WHERE "X" IS A MONOVALENT ATOM READILY ABSTRATABLE BY A FREE RADICAL, E.G., HYDROGEN, CHLORINE OR BROMINE, AND R IS INERT TO THE PEROXYCARBONYL GROUPS OF THE DIPEROXYFUNARATE TO FORM AN ADDITION PRODUCT INCLUDING AT LEAST ONE DIESTER OF A SUBSTITUTED DIPEROXYSUCCINIC ACID. FOR EXAMPLE: TETRAHYDROFURAN AND DI-T-BUTYL DIPEROXYFUMARATE REACT AT ABOUT 0*C. TO FROM DI-T-BUTYL ALPHA-(2-TETRAHYDROFURYL)DIPEROXYSUCCINATE. POLYGLOCOLS AND POLYVINYL ETHERS, ALCOHOLS, HALIDES, ETC. REACT TO GIVE POLYMERS HAVING PENDANT PAIRS OF PEROXYCARBONYL ESTES GROUPS IN GAMMA RELATIONSHIP TO EACH OTHER. THESE COMPOUNDS ARE OF ESPECIAL INTEREST IN THE PREPARATION OF BLOCK AND GRAFT COPOLYMERS.

公开(公告)号：US3755464A

公开(公告)日：1973-08-28

申请号：US3755464D

申请日：1970-02-25

申请人： PENNWALT CORP

发明人： BAFFORD R

IPC分类号： C07C409/14 ,  C07C409/16 ,  C08F4/34 ,  C08F283/01 ,  C08K5/14 ,  C07C73/08

CPC分类号： C08K5/14 ,  C07C409/16 ,  C08F283/01 ,  C08F4/00

摘要： TERTIARY-ALKYL HALOCUMYL PEROXIDES OF THE FORMULA

((X)N,R(5-N)-PHENYL)-C(-CH3)2-O-O-R1

WHEREIN X IS F, CL, OR BR; N=1-5; R IS H, ALKYL, CYCLOALKYL, OR ARYL; AND R1 IS TERTIARY-ALKYL OF 4-8 CARBON ATOMS. THESE PEROXIDES ARE USEFUL FOR CROSSLINKING POLYMERIC MATERIALS WITHOUT PRODUCING AN OBJECTIONABLE ODOR.