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    Polymer containing substituted triphenylamine units
    1.
    发明申请
    Polymer containing substituted triphenylamine units 有权
    含有取代的三苯胺单元的聚合物

    公开(公告)号：US20040254324A1

    公开(公告)日：2004-12-16

    申请号：US10481439

    申请日：2004-05-17

    发明人： Richard O'Dell ,  Carl Towns

    IPC分类号： C08G061/00

    CPC分类号： H01L51/0043 ,  C08G61/12 ,  C08G73/02 ,  C08G73/026 ,  C09K11/06 ,  C09K2211/1425 ,  C09K2211/1433 ,  H01L51/0035 ,  H01L51/0059 ,  H01L51/5012 ,  H05B33/14

    摘要： A method for making a polymer containing a first repeat unit having formula: nullArnullN(R)nullArnull(N(Rnull)nullAr)xnull which may be substituted or unsubstituted where x is 0 or 1; each Ar is the same or different and independently is a substituted or unsubstituted aryl or heteroaryl group and R and Rnull each is hydrogen or a substituent group and a second repeat unit that is the same or different from the first repeat unit and comprises a substituted or unsubstituted, aryl or heteroaryl group. The polymer is made by Suzuki polymerisation wherein the monomer from which repeat unit (1) is derived comprises one or two reactive boron groups.

    摘要翻译： 制备含有具有式-Ar-N（R）-Ar-（N（R'）-Ar）x-的第一重复单元的聚合物的方法，其可以是取代或未取代的，其中x是0或1; 每个Ar相同或不同，独立地为取代或未取代的芳基或杂芳基，R和R'各自为氢或取代基，第二重复单元与第一重复单元相同或不同，并且包含取代的 或未取代的芳基或杂芳基。 聚合物通过Suzuki聚合制备，其中衍生重复单元（1）的单体包含一个或两个反应性硼基团。

    Electroluminescent copolymers with multi-functional monomers and methods for use thereof
    2.
    发明申请
    Electroluminescent copolymers with multi-functional monomers and methods for use thereof 有权
    具有多官能单体的电致发光共聚物及其使用方法

    公开(公告)号：US20040204557A1

    公开(公告)日：2004-10-14

    申请号：US10771045

    申请日：2004-02-03

    发明人： Frank P. Uckert ,  Howard E. Simmons III

    IPC分类号： C08G061/00

    CPC分类号： H01L51/0043 ,  C08G61/02 ,  C08G73/02 ,  C09K11/06 ,  C09K2211/1416 ,  C09K2211/1433 ,  H01L51/0037 ,  H01L51/0039 ,  H01L51/0059 ,  H01L51/5012 ,  H01L2251/308 ,  H05B33/14 ,  Y10S428/917

    摘要： Polymeric compositions are provided comprising a first plurality of first monomeric units comprising an aromatic group with at least one substituent selected from alkyl, heteroalkyl, alkenyl, heteroalkenyl, alkynyl, heteroalkynyl, aryl, arylalkyl, heteroaryl, heteroarylalkyl, and amino, and a second plurality of second multi-functional monomeric units, wherein each multi-functional monomeric unit is capable of forming a branching point in the polymeric composition, thereby resulting in a branched material. Invention compositions therefore have an altered morphology relative to similar non-branched materials. When used to form an EL layer within an EL device, this altered morphology results in EL layers with improved efficiency, which in turn results in more efficient EL devices.

    摘要翻译： 提供聚合物组合物，其包含第一多个第一单体单元，其包含芳族基团和至少一个选自烷基，杂烷基，烯基，杂烯基，炔基，杂炔基，芳基，芳基烷基，杂芳基，杂芳基烷基和氨基的取代基，第二多个 的第二多官能单体单元，其中每个多官能单体单元能够在聚合物组合物中形成支化点，从而得到支链材料。 因此，本发明组合物相对于相似的非支化材料具有改变的形态。 当用于在EL器件中形成EL层时，这种改变的形态导致EL层具有改进的效率，这又导致更有效的EL器件。

    Surface-active photoinitiators
    4.
    发明申请
    Surface-active photoinitiators 有权
    表面活性光引发剂

    公开(公告)号：US20040034115A1

    公开(公告)日：2004-02-19

    申请号：US10450228

    申请日：2003-06-11

    发明人： Gisele Baudin ,  Tunja Jung

    IPC分类号： C08G061/00

    CPC分类号： G03F7/031 ,  B33Y70/00 ,  C07C45/54 ,  C07C45/64 ,  C07C45/71 ,  C07C49/825 ,  C07C49/84 ,  C08F2/50 ,  Y10T428/12097 ,  Y10T428/12104

    摘要： A process for the production of coatings with scratch-resistant durable surfaces that comprise as photoinitiator (B) in a photocurable formulation at least one surface-active photoinitiator, concentrated at the surface of the formulation, of formula (Ia) or (Ib), wherein Ra is a radical of formula (IIa), Rb is a radical of formula (IIb)), or Ra and Rb are naphthyl, anthracyl, phenanthryl or a heterocyclic radical each of which is unsubstituted or substituted; R1, R2, R3, R4, R5, R6, R7, R8, R9 and R10 are, for example, each independently of the others hydrogen; AnullY; C1-C12alkyl, halogen or phenyl; R11 and R12 are, for example, C1 -C12 alkyl; X is nullOR20 or nullN(R21)(R22); R20 is, for example, hydrogen or C1-C4alkyl; R21 and R22 are, for example, hydrogen or C1-C12 alkyl; X1 is, for example, nullOnull; Y is, for example, a single bond or nullOnull; Y1 is, for example, a single bond; and A is, for example, C6-C30alkyl.

    摘要翻译： 一种用于生产具有抗划伤耐久表面的涂层的方法，其在光固化制剂中包含作为光引发剂（B）的至少一种表面活性光引发剂，其在制剂的表面浓缩，式（Ia）或（Ib）， 其中Ra是式（IIa）的基团，Rb是式（IIb）的基团），或Ra和Rb是萘基，蒽基，菲基或杂环基，其各自是未取代或取代的; R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9和R 10各自独立地为氢; A-Y; C 1 -C 12烷基，卤素或苯基; R 11和R 12是例如C 1 -C 12烷基; X是-OR 20或-N（R 21）（R 22）; R 20为例如氢或C 1 -C 4烷基; R 21和R 22是例如氢或C 1 -C 12烷基; X1是例如-O-; Y是例如单键或-O-; Y1例如为单键; A是例如C 6 -C 30烷基。

    Hot-melt adhesives based on polyamide-block graft copolymers
    5.
    发明申请
    Hot-melt adhesives based on polyamide-block graft copolymers 失效
    基于聚酰胺嵌段共聚物的热熔胶

    公开(公告)号：US20040024127A1

    公开(公告)日：2004-02-05

    申请号：US10373201

    申请日：2003-02-26

    申请人： ATOFINA

    发明人： Martin Baumert ,  Francois Court ,  Christian Laurichesse

    IPC分类号： C08G061/00

    CPC分类号： C09J151/06 ,  C08G81/028 ,  C08L51/00 ,  C08L51/06 ,  C08L77/00 ,  C08L93/00 ,  C08L2205/08 ,  C08L2666/02 ,  C08L2666/04 ,  C08L2666/14 ,  C09J123/02 ,  C09J193/00

    摘要： The present invention relates to a hot-melt adhesive composition comprising: 20 to 80% of a blend comprising: 50 to 100% of (A), which denotes a polyamide-block graft copolymer consisting of a polyolefin backbone and at least one polyamide graft, 0 to 50% of at least one polymer (B) chosen from polyolefins and polyamides; 80 to 20% of a blend comprising at least one tackifying resin and optionally at least one product chosen from waxes, plasticizers and mineral fillers; in which: the said graft is attached to the backbone via the residues of an unsaturated monomer (X) chosen from unsaturated carboxylic acids, anhydrides of unsaturated carboxylic acids and unsaturated epoxides; the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from its double bond; the molar mass {overscore (M)}n of the grafts is between 1000 and 5000; the melting point of the grafts is between 100 and 190null C.; and the MFI of (A) is between 1 and 500 (g/10 min at 190null C. under a load of 2.16 kg). This composition has many advantages: it is processed at the usual temperatures for hot-melt adhesives, that is to say around 180null C.; it is not necessary, after application, to wait for crosslinking; it is simpler to use than two-component adhesives such as epoxy adhesives in which a hardener is necessary; and it has a markedly improved shear adhesive failure temperature (SAFT) compared with crosslinkable hot-melt adhesives.

    摘要翻译： 本发明涉及一种热熔粘合剂组合物，其包含：20至80％的共混物，其包含：50至100％的（A），其表示由聚烯烃主链和至少一个聚酰胺接枝物组成的聚酰胺嵌段接枝共聚物 ，0至50％的至少一种选自聚烯烃和聚酰胺的聚合物（B）; 80至20％的包含至少一种增粘树脂和任选的至少一种选自蜡，增塑剂和矿物填料的产品的共混物; 其中：所述接枝通过选自不饱和羧酸，不饱和羧酸的酸酐和不饱和环氧化物的不饱和单体（X）的残基连接到主链上; 不饱和单体（X）的残基通过其双键的接枝或共聚连接到主链上; 摩擦质量（超芯（移植物的Mn在1000和5000之间;移植物的熔点在100和190℃之间）;（A）的MFI在1和500之间（190 / g / 10分钟 该组合物具有许多优点：在通常的温度下对热熔胶进行加工，也就是说在180℃附近;施用后不需要等待 用于交联;其比使用需要硬化剂的环氧粘合剂的双组分粘合剂更简单;与可交联热熔粘合剂相比，其具有显着改善的剪切粘合破坏温度（SAFT）。

    Production of polytrimethylene ether glycol and copolymers thereof
    7.
    发明申请
    Production of polytrimethylene ether glycol and copolymers thereof 有权
    聚三亚甲基醚二醇的制备及其共聚物

    公开(公告)号：US20020007043A1

    公开(公告)日：2002-01-17

    申请号：US09738688

    申请日：2000-12-15

    发明人： Hari B. Sunkara ,  Leo E. Manzer

    IPC分类号： C08G061/00

    CPC分类号： C07C41/09 ,  C08G65/34 ,  C07C43/135

    摘要： A process for the manufacture of polytrimethylene ether glycol comprising the steps of: (a) providing (1) 1,3-propanediol reactant selected from the group consisting of 1,3-propanediol and/or oligomers or prepolymers of 1,3-propanediol having a degree of polymerization of 2-9 and mixtures thereof, and (2) a polycondensation catalyst; and (b) polycondensing the 1,3-propanediol reactant to form a polytrimethylene ether glycol at less than one atmosphere pressure, and the product of the process. In addition, polytrimethylene ether glycol has a number average molecular weight greater than 1,500, an APHA color of less than 120, an unsaturation of less than 20 meq/kg, and a content of cyclic ether oligomers of less than 2%.

    摘要翻译： 一种制备聚三亚甲基醚二醇的方法，包括以下步骤：（a）提供（1）选自1,3-丙二醇和/或低聚物的1,3-丙二醇反应物或1,3-丙二醇的预聚物 具有2-9的聚合度及其混合物，和（2）缩聚催化剂; 和（b）缩聚1,3-丙二醇反应物以在小于一个大气压下形成聚三亚甲基醚二醇，以及该方法的产物。 此外，聚三亚甲基醚二醇的数均分子量大于1500，APHA颜色小于120，不饱和度小于20meq / kg，环醚低聚物的含量小于2％。

    Electroluminescent conjugated polymers containing phosphorescent moieties and the application thereof in LED
    8.
    发明申请
    Electroluminescent conjugated polymers containing phosphorescent moieties and the application thereof in LED 有权
    含有磷光部分的电致发光共轭聚合物及其在LED中的应用

    公开(公告)号：US20040260047A1

    公开(公告)日：2004-12-23

    申请号：US10735693

    申请日：2003-12-16

    申请人： National Tsing Hua University

    发明人： Show-An Chen ,  Xiwen Chen ,  Jin-long Liao ,  Yongmin Liang ,  Yen-Chun Chen

    IPC分类号： C08G061/00

    CPC分类号： H05B33/14 ,  C09K11/06 ,  C09K2211/1029 ,  C09K2211/1037 ,  C09K2211/1088 ,  C09K2211/1092 ,  C09K2211/1416 ,  C09K2211/1458 ,  C09K2211/1466 ,  C09K2211/1475 ,  C09K2211/1483 ,  C09K2211/185 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/0085 ,  H01L51/0087 ,  H01L51/5016 ,  H01L51/5036 ,  Y10S428/917

    摘要： This invention provides a new electroluminescent conjugated polymers grafted with highly efficient phosphorescent organometallic complexes (such as iridium, platinum, osmium, rubidium, etc.) and charge transport moieties (such as oxadiazole, thiadiazole, triazole, pyridine, pyrimidine, substituted or non-substituted tertiary arylamines, substituted or non-substituted quarternary arylammonium salts, substituted or non-substituted tertiary heterocyclic aromatic amines, substituted or non-substituted quarternary heterocyclic aromatic ammonium, etc.). The emissive polymers (fully conjugated or limited conjugating length) covering the full visible range can be prepared. The polymeric light emitting diodes with these materials can be used as indicators, light source and display for cellular phones, digital camera, pager, portable computer, personal data acquisition (PDA), watch, hand-held videogame, billboard, etc.

    摘要翻译： 本发明提供一种新的电致发光共轭聚合物，其接枝有高效磷光有机金属配合物（如铱，铂，锇，铷等）和电荷输送部分（如恶二唑，噻二唑，三唑，吡啶，嘧啶， 取代或未取代的季铵芳基铵盐，取代或未取代的叔杂环芳族胺，取代或未取代的季铵杂环芳族铵等）。 可以制备覆盖整个可见光范围的发射聚合物（完全共轭或有限共轭长度）。 具有这些材料的聚合物发光二极管可用作蜂窝电话，数码相机，寻呼机，便携式计算机，个人数据采集（PDA），手表，手持式视频游戏，广告牌等的指示器，光源和显示器。