Cladding resin composition
    1.
    发明授权
    Cladding resin composition 失效
    包覆树脂组合物

    公开(公告)号:US06552159B1

    公开(公告)日:2003-04-22

    申请号:US08811068

    申请日:1997-03-03

    IPC分类号: C08G63692

    摘要: The invention relates to a cladding resin composition curable by heat, ultraviolet radiation, an electron beam or the like. The composition comprises a polyoxyalkylene polyol phosphate ester (hydroxyl value: 10-2,000 mg KOH/g) and a polymerizable or reactive functional group-containing compound. This composition is highly conductive as it is and, without incorporation of the conventional conductive additives, can be used successfully in the field of coatings and protective films where electric conductivity is a requisite.

    摘要翻译: 本发明涉及通过热,紫外线,电子束等可固化的包层树脂组合物。 组合物包含聚氧化烯多元醇磷酸酯(羟基值:10-2,000mg KOH / g)和可聚合或反应性官能团的化合物。 该组合物是高导电性的,并且不含常规导电添加剂可以成功地用于需要导电性的涂料和保护膜领域。

    Polymeric phosphite composition and hydrocyanation of unsaturated organic compounds and the isomerization of unsaturated nitriles
    2.
    发明授权
    Polymeric phosphite composition and hydrocyanation of unsaturated organic compounds and the isomerization of unsaturated nitriles 失效
    聚合亚磷酸酯组合物和不饱和有机化合物的氢氰化和不饱和腈的异构化

    公开(公告)号:US06284865B1

    公开(公告)日:2001-09-04

    申请号:US09399261

    申请日:1999-09-20

    IPC分类号: C08G63692

    摘要: A polymeric composition, a process for producing the composition, and a process for using the composition in, for example, hydrocyanation or isomerization are disclosed. The composition comprises repeat units derived from (1) a carbonyl compound, a monomer, and phosphorochloridite; (2) phosphorus trichloride, a polyhydric alcohol, and an aromatic diol; or (3) combinations of (1) and (2) in which the monomer can be a polyhydric alcohol, an amine, combinations thereof. The composition can further comprise a Group VIII metal and optionally a Lewis acid. The composition can be produced by (1) contacting a carbonyl compound with the monomer to produce an intermediate and contacting the intermediate with phosphorochloridite; (2) contacting phosphorus trichloride with a second polyhydric alcohol under a condition sufficient to produce a phosphorus-containing polymer and contacting the phosphorus-containing polymer with an aromatic diol; or (3) contacting an N,N-dialkyl dichlorophosphoramidite with a second polyhydric alcohol to produce a polymer phosphoramidite, contacting the polymer phosphoramidite with an acid such as HCl to produce the phosphorus-containing polymer, which is then contacted with an aromatic diol. The composition can be used as catalyst, for example, for converting an unsaturated organic compound to a nitrile and isomerizing a nitrile.

    摘要翻译: 公开了一种聚合物组合物,用于生产该组合物的方法以及该组合物在例如氢氰化或异构化中的使用方法。 该组合物包含衍生自(1)羰基化合物,单体和磷酰氯的重复单元; (2)三氯化磷,多元醇和芳族二醇; 或(3)(1)和(2)的组合,其中所述单体可以是多元醇,胺及其组合。 组合物还可以包含VIII族金属和任选的路易斯酸。 组合物可以通过(1)使羰基化合物与单体接触以制备中间体并使中间体与磷酰氯接触而制备; (2)在足以产生含磷聚合物并使含磷聚合物与芳族二醇接触的条件下,使三氯化磷与第二多元醇接触; 或(3)使N,N-二烷基二氯亚磷酰胺与第二多元醇接触以产生聚合亚磷酰胺,使聚亚磷酰胺与酸如HCl接触以制备含磷聚合物,然后与芳族二醇接触。 该组合物可用作催化剂,例如用于将不饱和有机化合物转化为腈并使腈异构化。