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    FLAME-RETARDANT POLYMERS DERIVED FROM POLYOLS AND POLYACIDS
    1.
    发明申请
    FLAME-RETARDANT POLYMERS DERIVED FROM POLYOLS AND POLYACIDS 有权
    从聚合物和聚合物衍生的阻燃聚合物

    公开(公告)号：US20160251485A1

    公开(公告)日：2016-09-01

    申请号：US14632392

    申请日：2015-02-26

    申请人： International Business Machines Corporation

    发明人： Dylan J. Boday ,  Joseph Kuczynski ,  Timothy C. Mauldin

    IPC分类号： C08J3/24 ,  C08G63/12

    CPC分类号： C08G63/12 ,  C08G63/6924 ,  C08G63/78 ,  C09D5/18

    摘要： In an example, a process for the production of a flame-retardant polymer is disclosed. The process includes reacting a polyol with a phosphorus-containing material to produce a phosphorus-functionalized polyol derivative. The process further includes reacting the phosphorus-functionalized polyol derivative with a polyacid to form the flame-retardant polymer. Phosphorus is chemically bound to a polymer chain of the flame-retardant polymer.

    摘要翻译： 在一个实例中，公开了制备阻燃聚合物的方法。 该方法包括使多元醇与含磷材料反应以产生磷官能化多元醇衍生物。 该方法还包括使磷官能化多元醇衍生物与多元酸反应形成阻燃聚合物。 磷与阻燃聚合物的聚合物链化学键合。

    Copolyester fibers
    3.
    发明授权
    Copolyester fibers 失效
    共聚酯纤维

    公开(公告)号：US06383433B1

    公开(公告)日：2002-05-07

    申请号：US09906577

    申请日：2001-07-13

    申请人： Heinz-Dieter Schumann

    发明人： Heinz-Dieter Schumann

    IPC分类号： B29C4788

    CPC分类号： C08G63/6924 ,  C08G63/668 ,  D01F6/86 ,  Y10T428/2913

    摘要： The present invention provides a copolyester fiber consisting of a copolyester with primarily C2-4 alkylene terephthalate units and a process for producing these copolyester fibers. The copolyester contains more than 4 wt % up to 12 wt % poly(C2-4 alkylene glycol) units and 60 to 260 ppm pentaerythritol units and/or a total of 150 to less than 2500 ppm carboxy methylene phosphonic acid units and/or carboxy ethylene phosphonic acid units polymerized into it.

    摘要翻译： 本发明提供了由主要具有C2-4亚烷基对苯二甲酸酯单元的共聚酯和这种共聚酯纤维的生产方法组成的共聚酯纤维。共聚酯含有多于4重量％的至多12重量％的聚（C 2-4亚烷基二醇）单元 和60至260ppm的季戊四醇单元和/或总共150至小于2500ppm的羧基亚甲基膦酸单元和/或其中聚合的羧基乙烯膦酸单元。

    Copolyester fiber
    4.
    发明授权
    Copolyester fiber 失效
    共聚纤维

    公开(公告)号：US06261686B1

    公开(公告)日：2001-07-17

    申请号：US09353165

    申请日：1999-07-14

    申请人： Heinz-Dieter Schumann

    发明人： Heinz-Dieter Schumann

    IPC分类号： D02G300

    CPC分类号： C08G63/6924 ,  C08G63/668 ,  D01F6/86 ,  Y10T428/2913

    摘要： The present invention provides a copolyester fiber consisting of a copolyester with primarily C2-4 alkylene terephthalate units and a process for producing these copolyester fibers. The copolyester contains more than 4 wt % up to 12 wt % poly(C2-4 alkylene glycol) units and 60 to 260 ppm pentaerythritol units and/or a total of 150 to less than 2500 ppm carboxy methylene phosphonic acid units and/or carboxy ethylene phosphonic acid units polymerized into it.

    摘要翻译： 本发明提供了由主要具有C2-4亚烷基对苯二酸酯单元的共聚酯和这些共聚酯纤维的制备方法组成的共聚酯纤维。 共聚多酯包含多于4重量％的至多12重量％的聚（C 2-4亚烷基二醇）单元和60至260ppm的季戊四醇单元和/或总共150至小于2500ppm的羧基亚甲基膦酸单元和/或羧基 乙烯膦酸单元聚合成它。

    Polymer compositions
    5.
    发明授权
    Polymer compositions 失效
    聚合物组合物

    公开(公告)号：US6111061A

    公开(公告)日：2000-08-29

    申请号：US853166

    申请日：1997-05-08

    申请人： Mohsen Zakikhani ,  Karen Sarah Mitchie

    发明人： Mohsen Zakikhani ,  Karen Sarah Mitchie

    IPC分类号： C08G18/38 ,  C08G59/14 ,  C08G59/40 ,  C08G63/692 ,  C08G79/04 ,  C08G79/02

    CPC分类号： C08G59/1488 ,  C08G18/3878 ,  C08G59/4071 ,  C08G63/6924

    摘要： A polymer composition including phosphorus substituents which comprises:(a) a phosphono-substituted carboxylic acid or an ester of such acid; and(b) a mono- or polyfunctional entity polymerizable with (a).Substances suitable for use as (a) are aliphatic or aromatic phosphono substituted dicarboxylic acids or esters thereof.Substances suitable for use as (b) are polyhydric alcohols, aliphatic mononuclear or polynuclear aromatic polycarboxylic acids or esters or anhydrides thereof. Also suitable for use as (b) are aliphatic or aromatic polyamines and aliphatic or aromatic polyisocyanates or polyepoxides.

    摘要翻译： 包含磷取代基的聚合物组合物包括：（a）膦酰取代的羧酸或这种酸的酯; 和（b）可与（a）可聚合的单官能或多官能的实体。 适合用作（a）的物质是脂族或芳族膦酰取代的二羧酸或其酯。 适合用作（b）的物质是多元醇，脂族单核或多环芳族多羧酸或其酯或酸酐。 也适合用作（b）脂族或芳族多胺和脂族或芳族多异氰酸酯或聚环氧化物。

    Aqueous filler composition
    6.
    发明授权
    Aqueous filler composition 失效
    水性填料组合物

    公开(公告)号：US5436312A

    公开(公告)日：1995-07-25

    申请号：US306813

    申请日：1994-09-15

    申请人： Reiner Exner ,  Michael Schwab ,  Ute Kuhn ,  Joachim Zoeller

    发明人： Reiner Exner ,  Michael Schwab ,  Ute Kuhn ,  Joachim Zoeller

    IPC分类号： C08L67/00 ,  C08G63/68 ,  C08G63/688 ,  C08G63/692 ,  C09D167/00 ,  C08G63/00 ,  C08G63/02

    CPC分类号： C08G63/6884 ,  C08G63/6924 ,  C09D167/00

    摘要： Aqueous filler composition comprising a polyester resin, which is built up of the educts (a), (b), (c), (d) and (e) or their ester-forming derivatives, the sum of the reactants corresponding to 100 mol-% and the ratio of the sum of the hydroxyl equivalents (eg OH) to the sum of the carboxyl equivalents in the reactants being between 0.5 and 2.0, where(a) is at least one dicarboxylic acid which is not a sulfo or phosphorus monomer,(b) is 0 to 15 mol-% of at least one difunctional sulfo or phosphono monomer, the functional groups of which are carboxyl and/or hydroxyl groups, having at least one sulfonate or phosphonate group,(c) is at least one difunctional compound which is derived from a glycol containing two --C(R).sub.2 --OH groups,(d) is up to 40 mol-% of a higher functional compound (functionality >2), the functional groups of which comprise hydroxyl and/or carboxyl groups, and(e) is 0 to 20 mol-% of a monofunctional carboxylic acid,it being possible for the radicals R in (c) independently of one another to be hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.6 -C.sub.10 -aryl, the amounts of free hydroxyl groups being between 30 and 350 milliequivalents OH/100 g, preferably between 100 and 250 meq (OH)/100 g, and the content of free neutralized and/or neutralizable acid groups, in particular sulfonic acid groups, phosphonic acid groups and carboxylic acid groups, being between 5 and 350 meq acid groups/100 g, preferably between 9 and 120 meq acid groups/100 g.

    摘要翻译： 包含由（a），（b），（c），（d）和（e）衍生物或其酯形成衍生物构成的聚酯树脂的水性填料组合物，相当于100mol - ％，羟基当量（例如OH）之和与反应物中的羧基当量之和的比例在0.5和2.0之间，其中（a）是至少一种不是磺基或磷单体的二羧酸 ，（b）为0至15摩尔％的至少一种二官能磺基或膦酰基单体，其官能团为羧基和/或羟基，具有至少一个磺酸酯或膦酸酯基团，（c）为至少一种 衍生自含有两个-C（R）2 -OH基团的二元醇的二官能化合物，（d）为高达40mol％的高官能化合物（官能度> 2），其官能团包含羟基和/ 或羧基，（e）为0〜20摩尔％的单官能羧酸，（c）中的基团R 彼此之间是氢，C 1 -C 4 - 烷基或C 6 -C 10 - 芳基，游离羟基的量为30-350毫当量OH / 100g，优选为100-250meq（OH）/ 100g， 和游离中和和/或可中和的酸基团，特别是磺酸基团，膦酸基团和羧酸基团的含量为5- 350meq酸基团/ 100g，优选9至120meq酸基团/ 100g 。

    Phosphorus-containing flame retardant compositions
    7.
    发明授权
    Phosphorus-containing flame retardant compositions 失效
    含磷阻燃剂组合物

    公开(公告)号：US4181646A

    公开(公告)日：1980-01-01

    申请号：US925020

    申请日：1978-07-17

    申请人： Kurt Moedritzer

    发明人： Kurt Moedritzer

    IPC分类号： C08G63/692 ,  C08G79/04 ,  C08L85/02 ,  C08K5/52 ,  C07F9/09

    CPC分类号： C08L85/02 ,  C08G63/6924 ,  C08G79/04

    摘要： The present invention relates to phosphorus-containing compositions which are polymeric esters having flame retardant properties and also a process for the production thereof, as well as the combinations of such phosphorus compositions with otherwise combustible base materials exemplified by various organic polymers, for example polyamides or polyesters.The phosphorus compositions of the present invention are polymeric esters having as moieties thereof, (A) an aliphatic alcoholic moiety of an alcoholic reactant of 5 to 20 carbon atoms, and from 2 to 10 or preferably 2 to 6 hydroxyl functional groups, with the proviso that there is no hydrogen atom on the carbon atoms which are beta to the hydroxyl oxygen, (B) a moiety of a phosphorus-containing acid halide reactant of 0 to 20 carbon atoms, and having from 1 to 4 halogen functional groups, and (C) a different alcoholic moiety as defined in (A) or a different phosphorus-containing moiety as defined in (B), the said ester having a degree of molecular aggregation of 2 to 100, and with each of (A), (B) and (C) being present at from 1 mole to 99 mole %, with the proviso that the number of alcoholic functional groups on the alcoholic reactants is equal to the number of the said functional groups on the phosphorus-containing reactants.

    摘要翻译： 本发明涉及含磷组合物，它们是具有阻燃性能的聚合酯，也涉及其制备方法，以及这些磷组合物与其它可燃基材的组合，例如聚酰胺或各种有机聚合物， 聚酯。 本发明的磷组合物是具有其部分的聚合酯，（A）5至20个碳原子的醇反应物的脂族醇部分和2至10个或优选2至6个羟基官能团，条件是 碳原子上没有羟基氧原子上没有氢原子，（B）含有0至20个碳原子的含磷酰卤反应物的部分，具有1至4个卤素官能团，和（ C）如（A）所定义的不同的醇部分或如（B）中所定义的不同的含磷部分，所述酯的分子聚集度为2〜100，并且与（A），（B ）和（C）以1摩尔至99摩尔％存在，条件是醇反应物上的醇官能团的数目等于含磷反应物上所述官能团的数目。