Radical cascade-enabled synthesis of precision polymers with complex main-chain structures

    公开(公告)号:US11186678B2

    公开(公告)日:2021-11-30

    申请号:US16701031

    申请日:2019-12-02

    摘要: Radical cascade reactions enabling sequence-controlled ring-closing polymerization and ring-opening polymerization for the controlled synthesis of polymers with complex main-chain structures are provided. Facile syntheses leading to low-strain macrocyclic monomers consisting of the ring-opening triggers and extended main-chain structures are also provided. The present disclosure further provides methods for excellent control over polymer molecular weights and molecular weight distributions and high chain-end fidelity allows for the preparation of polymeric systems with well-defined architectures. Further provided are the general nature of the radical cascade-triggered transformations in polymer chemistry, and its application to the synthesis of polymers with diverse main-chain structural motifs with tailored functions. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

    PRODUCTION METHOD FOR MEDICAL BALLOON

    公开(公告)号:US20210339434A1

    公开(公告)日:2021-11-04

    申请号:US17271784

    申请日:2019-08-19

    申请人: ZEON CORPORATION

    摘要: This application relates to a production method for a medical balloon that can suppress the occurrence of the symptom of delayed-type allergy (Type IV) in addition to immediate-type allergy (Type I). The production method includes molding a composition containing a carboxy-modified conjugated diene polymer, a vulcanizing agent, and a xanthogen compound into the shape of a balloon. The molding of the composition into the shape of a balloon includes dipping a balloon-shaped mold in the composition in the form of latex.

    FILM FOR MEDICINE PACKAGING AND METHOD OF PREPARING THE SAME

    公开(公告)号:US20200282714A1

    公开(公告)日:2020-09-10

    申请号:US16880142

    申请日:2020-05-21

    摘要: The present invention discloses a film for a medicine packaging and a method of preparing the same. The film for the medicine packaging includes a polymer film layer, a graphene composite layer and a light-curable adhesive, wherein the polymer film layer is bonded with a graphene composite layer by a light-curable adhesive, the graphene composite layer includes multiple graphene layers bonded by the light-curable adhesive; and the light-curable adhesive includes a hyperbranched cationic mussel-imitated polymer including a multi-hydroxylbenzoylbenzamide ene amide monomer, a cationic monomer and a photo-responsive monomer. The present invention provides strong adhesion with reduced adhesive layer, allowing greatly increasing the number of the graphene layers in the graphene composite layer without obvious increase in the total thickness and mass. This can meet the requirements of the medicine packaging material, as it obviously lowers the film's permeation to water vapor and oxygen and significantly enhances the tensile strength.

    Curable Polymer Latex Compositions for the Manufacture of Rubber Articles

    公开(公告)号:US20200062879A1

    公开(公告)日:2020-02-27

    申请号:US16469547

    申请日:2016-12-15

    摘要: A curable polymer latex composition obtainable by: (a) subjecting a monomer mixture comprising i. at least one conjugated diene; ii. at least one ethylenically unsaturated nitrile; iii. optionally at least one ethylenically unsaturated acid; iv. optionally at least one further ethylenically unsaturated compound different from any of the compounds (i)-(iii); to free-radical emulsion polymerization in an aqueous reaction medium to form a raw polymer latex; and (b) allowing the obtained raw latex to mature in the presence of at least one thiocarbonyl-functional compound, wherein the at least one thiocarbonyl-functional compound is present in an amount of at least 0.05 wt.-%, based on the total amount of monomers subjected to free-radical emulsion polymerization in step (a), and (c) optionally compounding the matured polymer latex with one or more cross-linking agent. Methods for making such curable polymer latex composition or rubber articles made therefrom, respectively.